Cited by 4Geological and Geochemical AnalysisHigh-pressure geophysics and materialsAstro and Planetary Science

The role of excess oxygen for modeling high-Mn, low-Ca garnets in metapelites from the northern Central Metasedimentary Belt of the Grenville Province, Ontario, Canada

Open access
Duesterhoeft, Erik, Raase, Peter, Duguet, Manuel, Easton, Robert Michael·2021·Canadian Journal of Earth Sciences

Abstract

The Bancroft terrane and the associated Central Metasedimentary Belt boundary thrust zone represent the northern part of the Central Metasedimentary Belt (CMB) of the Canadian Grenville Province. Only a few direct pressure and temperature calculations based on phase equilibrium petrology methods exist in the central Bancroft terrane, and this study applies thermodynamic approaches such as garnet isopleth geothermobarometry to fill this gap and investigate the metamorphic history of the northern CMB. Four metapelitic rock samples were collected in the vicinity of the enigmatic Bancroft shear zone, which approximates the border between the Bancroft terrane and the Elzevir terrane to the south. Garnet isopleths for these samples only intersect if a certain amount of excess oxygen is added to the bulk rock composition corresponding to a Fe 3+/Fe tot ratio of 0.33–0.38. The northernmost sample records metamorphic peak conditions of approximately 1 GPa and 780 °C, whereas the southernmost sample, which is located in the Elzevir terrane, records a peak metamorphic pressure of approximately 0.9 GPa at a temperature of 520 °C. The latter result contradicts previous pressure estimates of the region and the proposed metamorphic field gradient but is based on a poorly constrained sample in terms of thermodynamic modeling. Hence, we conclude that the metamorphic field gradient in the northern CMB conceals two different P–T trajectories. Such a scenario is commonly observed in crustal thickening models and suggests that the cold upper plate (Elzevir terrane) was thrust over the warm lower plate (Bancroft terrane) in a northwesterly direction.

AI snapshot

Written from the paper’s full text.

TL;DR

Garnet isopleth thermobarometry in four metapelites from the northern Central Metasedimentary Belt only yields intersections when excess oxygen is added to the bulk composition, corresponding to Fe³⁺/Feₜₒₜ ratios of 30–38%. The results support two different P-T trajectories, interpreted as cold upper Elzevir terrane thrust over warm lower Bancroft terrane.

Key findings

  • Garnet isopleths for samples BC04, BC12, and BAN015 do not intersect under standard modeling with all Fe as ferrous; adding excess oxygen produces intersections at Fe³⁺/Feₜₒₜ ratios of 30%, 38%, and 35%, respectively.
  • For BC04, excess oxygen gives a garnet-core intersection at 785 °C and 0.99 GPa, with a garnet-mantle intersection at 742 °C and 0.94 GPa. For BC12, two solutions are found at 730 °C/0.58 GPa and 630 °C/0.56 GPa; the second fits observed cordierite mode (2 vol% modeled vs 28 vol% for solution 1) and sillimanite (11.5 vol%). For BAN015, garnet core intersects at 635 °C/0.45 GPa and rim at ca. 550 °C/0.36 GPa.
  • Sample BAN030b records garnet core conditions of ca. 520 °C and 0.87 GPa, with garnet mantle at ca. 610 °C and 0.7 GPa; the gedrite–anthophyllite solvus limits maximum temperature to 600 ± 25 °C.
  • Iterative thermodynamic modeling of BC12a with BINGO-ANTIDOTE gives 636 °C and 0.54 GPa, with Qₜₒₜ = 91.5% and Q_cmp = 82%, consistent with conventional and garnet-isopleth results. The paper concludes the metamorphic field gradient conceals two P-T loops, consistent with overthrusting of the Elzevir terrane over the Bancroft terrane.

Methods

  • Four metapelitic samples were collected along an east–west traverse near the Bancroft shear zone in the northern Central Metasedimentary Belt, Ontario.
  • Whole-rock major and trace elements were measured by XRF; mineral compositions and X-ray maps were obtained by EPMA, with XMAPTOOLS used to determine microdomain bulk compositions.
  • Conventional geothermobarometry used TWQ with GASP and garnet–biotite thermometry; phase equilibria were modeled with THERIAK-DOMINO using JUN92 and BED92 databases; garnet isopleth thermobarometry used GRTMOD; iterative thermodynamic modeling used BINGO-ANTIDOTE.

Limitations

  • The paper states that forward phase-equilibrium modeling is affected by kinetic factors, uncertainty in the reactive bulk composition, compositional variations due to partial melting, and database/software limitations.
  • The paper states that sample BAN030b is challenging because suitable solid-solution models for clino- and orthoamphibole are lacking; JUN92 produces artificial clinopyroxene/olivine stability, and BED92 predicts orthopyroxene where orthoamphibole should be stable.
  • The paper states that the southernmost sample’s pressure estimate contradicts previous regional estimates and is based on a poorly constrained sample in thermodynamic modeling; conventional geothermometry results are also described as minimum metamorphic temperatures because rim compositions were used.

Model-written summary. Check it against the paper before relying on it.

Integrity signals

Registry

Crossref · 10.1139/cjes-2019-0238

Cites

86 of 86 references verified0 citation errors · 0 not checkable

Statistics

Nothing to recompute.

Claims the paper makes

21 of 97 cited sources checked · 8 supported · 0 flagged · accuracy not yet measured

  • Interpretationcitation

    The growth zoning of garnet in sample BAN030b provides confirmation of a temperature increase for the samples.

    “The growth zoning of garnet in sample BAN030b provides confirmation of a temperature increase for samples of the Thompson 1984, Thompson andEngland 1984), where the high temperature path represents the lower plate (Bancroft terrane + CMBbtz) and the medium temperature path the upper plate (Elzevir terrane).”
    Quote in the paperNot a substantial claim2 of 2 sources checked
    • cites Thompson 1984 source

      Section 2.4 states that chemical zoning can indicate the direction of temperature change during mineral growth and gives an example of garnet growth zoning associated with increasing temperature. It does not discuss sample BAN030b or establish that its zoning confirms a temperature increase; that sample-specific conclusion is not supported by this source. (LLM, conf=0.85)

      Experimental — accuracy not yet measured
    • cites Thompson and England 1984 source

      Section 2.4 (page not provided) says mineral growth zoning can indicate the direction of temperature change and gives garnet zoning during a reaction driven by increasing temperature as an example. It does not discuss sample BAN030b or establish that its zoning confirms a temperature increase. (LLM, conf=0.86)

      Experimental — accuracy not yet measured
  • Premisecitation

    The sample HAL104 of the West Guilford area followed a clockwise P-T trajectory from approximately 780°C and 0.95 GPa to 650°C and 0.6 GPa.

    “The sample HAL104 of the West Guilford area followed a clockwise P-T trajectory starting from approximately 780°C and 0.95 GPa to 650°C and 0.6 GPa (see white stars in Fig. 9A) as recently shown by Duesterhoeft and Lanari (2020).”
    Quote in the paperSubstantial claim1 of 1 sources checked
    • cites Duesterhoeft and Lanari (2020) source

      Section 4 identifies HAL104 as a West Guilford sample with distinct peak and retrograde assemblages. Sections 4.3 and 4.6 describe higher-temperature, higher-pressure conditions followed by lower-condition re-equilibration, including an estimate of 649°C and 0.59 GPa. But the paper does not establish the claimed 780°C, 0.95 GPa starting point or a clockwise trajectory; section 4.6 says a proposed P–T trend cannot be completely ruled out as the sample’s trajectory. (LLM, conf=0.84)

      Experimental — accuracy not yet measured
  • Premisecitation

    The Telemark sector of the Sveconorwegian Province in South Norway exhibits a similar metamorphic and magmatic history to the CMB between 1.35-1.10 Ga.

    “However, the Telemark sector of the Sveconorwegian Province in South Norway exhibits a similar metamorphic and magmatic history to the CMB between 1.35-1.10Ga (Bingen et al. 2008, Bingen andSolli 2009).”
    Quote in the paperNot a substantial claim1 of 2 sources checked
    • cites Bingen et al. 2008 source

      The “1.34–1.14 Ga Pre-Sveconorwegian interval” section describes magmatism in the Sveconorwegian terranes, which include Telemarkia. But the paper does not compare the Telemark sector’s metamorphic and magmatic history with the CMB over 1.35–1.10 Ga; its “1.14–0.90 Ga Sveconorwegian orogeny” section places the metamorphism it describes in Telemarkia chiefly after 1.10 Ga. (LLM, conf=0.82)

      Experimental — accuracy not yet measured
    • cites Bingen andSolli 2009

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Premisecitation

    Published monazite ages and zircon ages of the region indicate that the initial crustal stacking occurred before 1100 Ma.

    “Published monazite ages (Markley et al. 2018) and zircon ages (McEachern and van Breemen 1993) of the region indicate that the initial crustal stacking occurred before 1100 Ma.”
    Quote in the paperNot a substantial claim1 of 2 sources checked
    • cites Markley et al. 2018 source
    • cites McEachern and van Breemen 1993 source
  • Premiseown data

    Sample HAL104 may show a clockwise P-T trajectory starting from approximately 780°C and 0.95 GPa to 650°C and 0.6 GPa.

    “The sample may show a clockwise P-T trajectory starting from approximately 780°C and 0.95 GPa to 650°C and 0.6 GPa (see white stars in Fig.9A).”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Duesterhoeft and Lanari (2020) source

      Section 4.5 places HAL104’s inferred peak assemblage within a broad 670–800°C, 0.64–1.0 GPa field, which includes the proposed starting conditions. Section 4.6 reports later re-equilibration at about 660°C and 0.6–0.7 GPa. Our copy does not establish a clockwise trajectory between the stated endpoints, and its reported optimal peak conditions are 671°C and 0.64 GPa. (LLM, conf=0.84)

      Experimental — accuracy not yet measured
  • Classified as probably not a substantial claim. 77
  • May combine two claims. 76
  • The quote only partly states this claim. 2
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Markley et al. (2018) data provided evidence for a late Ottawan event at ca. 1045 Ma that they interpreted to be related to extensional tectonics.

    “Specifically their data provided evidence for: i) a well-defined prograde, pre-to late Shawinigan event (i.e., 1220-1160 Ma), ii ) a prograde early Ottawan event (1100-1075 Ma), and iii) a late Ottawan event at ca. 1045 Ma that they interpreted to be related to extensional tectonics.”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Markley et al. (2018) source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Three monazite ages of schists, one metamorphic zircon age of a quartzose gneiss in marble and one titanite age of a skarn of the supracrustal package yield metamorphic Ottawan ages of 1041-1092 Ma in the Bancroft terrane.

    “Three monazite ages of schists (Mezger et al. 1993, Burr andCarr 1994), one metamorphic zircon age of a quartzose gneiss in marble (Magnus 2013) and one titanite age of a skarn (Mezger et al. 1993) of the supracrustal package yield metamorphic Ottawan ages of 1041-1092 Ma in the Bancroft terrane.”
    Quote in the paperNot a substantial claim1 of 3 sources checked
    • cites Mezger et al. 1993 source

      In “Central Metasedimentary Belt Boundary Zone and Bancroft domain” (page unavailable), the paper reports sphene (titanite) ages from Bancroft-area skarns, but attributes their growth to igneous activity; it instead assigns regional metamorphism to sphene ages of 1045–1030 Ma from marbles and calc-silicate gneisses. Table 1 (page unavailable) lists a 1041 Ma monazite age, but the paper does not identify three Bancroft schist monazite ages or establish the stated 1041–1092 Ma metamorphic range. The zircon age is cited to Magnus, not Mezger, in the citing sentence. (LLM, conf=0.84)

      Experimental — accuracy not yet measured
    • cites Burr and Carr 1994

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Magnus 2013

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Markley et al. (2018) data provided evidence for a prograde early Ottawan event (1100-1075 Ma).

    “Specifically their data provided evidence for: i) a well-defined prograde, pre-to late Shawinigan event (i.e., 1220-1160 Ma), ii ) a prograde early Ottawan event (1100-1075 Ma), and iii) a late Ottawan event at ca. 1045 Ma that they interpreted to be related to extensional tectonics.”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Markley et al. (2018) source
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation

    Iterative thermodynamic models (ITM) are built on a forward simulation and coupled to an iterative optimization refining the causal factors.

    “Iterative thermodynamic models (ITM) are built on a forward simulation (i.e., equilibrium phase diagrams) and then coupled to an iterative optimization refining the causal factors (Lanari and Duesterhoeft 2019, Duesterhoeft and Lanari 2020).”
    Quote in the paperNot a substantial claim1 of 2 sources checked
    • cites Lanari and Duesterhoeft 2019

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Duesterhoeft and Lanari 2020 source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Markley et al. (2018) published monazite U-Th-Pb ages for the Bancroft terrane and the CMBbtz that support the previously interpreted polymetamorphic history.

    “Recently, Markley et al. (2018) published monazite U-Th-Pb ages for the Bancroft terrane and the CMBbtz that support the previously interpreted polymetamorphic history.”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Markley et al. (2018) source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Markley et al. (2018) data provided evidence for a well-defined prograde, pre-to late Shawinigan event (i.e., 1220-1160 Ma).

    “Specifically their data provided evidence for: i) a well-defined prograde, pre-to late Shawinigan event (i.e., 1220-1160 Ma), ii ) a prograde early Ottawan event (1100-1075 Ma), and iii) a late Ottawan event at ca. 1045 Ma that they interpreted to be related to extensional tectonics.”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Markley et al. (2018) source

      In the Discussion (manuscript p. 19), Markley et al. interpret Killaloe monazite dates of 1220–1160 Ma and decreasing yttrium as recording prograde metamorphism associated with the Shawinigan event. The interpretation is qualified elsewhere (manuscript p. 17) as tentative, and the older Shawinigan record is reported for the Killaloe samples rather than throughout the CMBbz. Calling the prograde event “well-defined” overstates that certainty. (LLM, conf=0.83)

      Experimental — accuracy not yet measured
  • May combine two claims.

    Interpretationcitation

    For the Bancroft terrane, the T max stage is represented by the early Ottawan phase before 1.08 Ga, supported by monazite ages of Markley et al. (2018) who observed prograde metamorphism from 1.095 to 1.08 Ga in the West Guilford area.

    “For the Bancroft terrane this T max stage is represented by the early Ottawan phase before 1.08 Ga, which is supported by the monazite ages of Markley et al. (2018) who observed prograde metamorphism from 1.095 to 1.08 Ga in the West Guilford area (Bancroft terrane).”
    Quote in the paperSubstantial claim1 of 1 sources checked
    • cites Markley et al. (2018) source

      The Discussion: Monazite Petrochronology (p. 15) reports West Guilford monazite core ages of approximately 1095 and 1080 Ma and says their progression may record prograde metamorphism. It associates peak Ottawan metamorphism with the approximately 1080 Ma domains, rather than establishing a temperature maximum strictly before 1.08 Ga. The claim also states as an observation what the paper presents as an interpretation. (LLM, conf=0.84)

      Experimental — accuracy not yet measured
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    The onset of erosion may correlate with the deposition of the Flinton Group metasediments in the southernmost part of the hanging wall, as proposed by Markley et al. (2018).

    “The onset of erosion may correlate with the deposition of the Flinton Group metasediments in the D r a f t 39 southernmost part of the hanging wall, as proposed by Markley et al. (2018).”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Markley et al. (2018) source

      The discussion passage (labelled “D r a f t”; page not supplied) places Flinton Group sediment deposition in the CMBbz hanging wall between the Shawinigan and Ottawan orogenies. It does not propose that the onset of erosion correlated with that deposition, so the central correlation attributed to Markley et al. is unsupported. (LLM, conf=0.85)

      Experimental — accuracy not yet measured
  • May combine two claims.

    Premisecitation

    The supracrustal Bandak Group was deposited at circa 1.15 Ga, an age that correlates well with the Flinton Group in the CMB that was deposited after 1.15 Ga.

    “In addition, the supracrustal Bandak Group was deposited at circa 1.15 Ga (Laajoki et al. 2002, Spencer et al. 2014), an age that correlates well with the Flinton Group in the CMB that was deposited after 1.15 Ga (Moore andThompson 1980, Sager-Kinsman andParrish 1993).”
    Quote in the paperNot a substantial claim1 of 3 sources checked
    • cites Laajoki et al. 2002
    • cites Spencer et al. 2014 source
    • cites Moore andThompson 1980

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Premisecitation

    Cl-rich brines would not change the grossular content and can lead to higher mobility of Fe(II) in fluids.

    “In contrast, Cl-rich brines wouldn't change the grossular content and can lead to higher mobility of Fe(II) in fluids (Debret and Sverjensky 2017).”
    Quote in the paperSubstantial claim1 of 1 sources checked
    • cites Debret and Sverjensky 2017 source

      In “Evolution of oxygen fugacity and implications for the nature of slab derived fluids” (page unavailable), the paper says that chlorine concentrations up to 2 wt% NaCl could potentially increase Fe(II) mobility in serpentinite-derived fluids. It does not address whether Cl-rich brines leave grossular content unchanged; a search for “grossular” found no relevant passage. (LLM, conf=0.88)

      Experimental — accuracy not yet measured
  • May combine two claims.

    Interpretationcitation

    Titanite U-Pb ages of 1.08-1.05 Ga in the Bancroft terrane show that the rocks were below 650°C at that time and thus define the time of the dominant metamorphic stage at 0.6 GPa and 650°C for the lower plate (Bancroft terrane).

    “Titanite U-Pb ages of 1.08-1.05Ga in the Bancroft terrane (Hanmer andMcEachern 1992, Mezger et al. 1993) show that the rocks have been below 650°C (max.closure temperature of titanite) at this point of time and thus define the time of the dominant metamorphic stage at 0.6 GPa and 650°C for the lower plate (i.e. the Bancroft terrane).”
    Quote in the paperSubstantial claim1 of 2 sources checked
    • cites Hanmer andMcEachern 1992

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Mezger et al. 1993 source

      The Central Metasedimentary Belt Boundary Zone and Bancroft domain section (page unavailable) reports sphene ages of 1074–1045 Ma, but identifies those grains as igneous; it dates regional metamorphism from metamorphic sphene ages of 1045–1030 Ma instead. The Closure temperatures section estimates about 650°C for most analyzed sphenes, not a universal maximum, while the Geological setting section reports about 6 kbar for Bancroft. Thus the paper supports the approximate temperature and pressure, but not the claim that 1.08–1.05 Ga titanite ages define the dominant Bancroft metamorphic stage. (LLM, conf=0.88)

      Experimental — accuracy not yet measured
  • May combine two claims.

    Interpretationcitation

    The high temperature path represents the lower plate (Bancroft terrane + CMBbtz) and the medium temperature path represents the upper plate (Elzevir terrane).

    “The growth zoning of garnet in sample BAN030b provides confirmation of a temperature increase for samples of the Thompson 1984, Thompson andEngland 1984), where the high temperature path represents the lower plate (Bancroft terrane + CMBbtz) and the medium temperature path the upper plate (Elzevir terrane).”
    Quote in the paperNot a substantial claim2 of 2 sources checked
    • cites Thompson 1984 source

      Section 3.1 distinguishes the thermal paths of rocks below thrust sheets from those within thrust sheets, and section 2.5 describes heating below a thrust surface and possible cooling above it. This supports a general lower-versus-upper-plate contrast, but the paper does not identify the Bancroft, CMBbtz, or Elzevir terranes with the claimed high- and medium-temperature paths. (LLM, conf=0.82)

      Experimental — accuracy not yet measured
    • cites Thompson and England 1984 source

      Section 3.1 discusses modeled pressure–temperature paths for rocks above and below thrust sheets, but does not assign high- and medium-temperature paths to the named plates or terranes. Searches for Bancroft, CMBbtz, Elzevir, and the proposed upper-/lower-plate assignment found no passage addressing that mapping. (LLM, conf=0.76)

      Experimental — accuracy not yet measured
  • May combine two claims.

    Premisecitation

    Forward phase equilibrium modeling has weaknesses, including geological uncertainties (kinetic factors, determination of the reactive bulk composition, compositional variations due to partial melting) and database/software limitations, which are difficult to quantify and may affect the outcome of every phase equilibrium model.

    “However, the forward phase equilibrium modeling approach also has its weaknesses, including both geological uncertainties such as kinetic factors (e.g.,Waters and Lovegrove 2002, Carlson et al. 2015, Pattison and Spear 2018), determination of the reactive bulk composition (e.g.,Palin et al. 2016), and compositional variations due to partial melting (e.g.,Guevara and Caddick 2016); and database-and”
    Quote in the paperNot a substantial claim1 of 3 sources checked
    • cites Waters and Lovegrove 2002 source
    • cites Palin et al. 2016 source
    • cites Forshaw et al. 2019

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Sample HAL104 of the West Guilford area is investigated with the ITM approach using the software BINGO-ANTIDOTE in an accompanying study by Duesterhoeft and Lanari (2020).

    “In an accompanying study byDuesterhoeft and Lanari (2020), sample HAL104 of the West Guilford area is investigated with the ITM approach using the software BINGO-ANTIDOTE.”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Duesterhoeft and Lanari (2020) source
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingown data

    A minor amount of gedrite (Na-Al bearing) is present in the matrix of sample BAN030b and is in equilibrium with anthophyllite.

    “A minor amount of gedrite (Na-Al bearing) is also present in the matrix and is in equilibrium with anthophyllite; both types of orthoamphibole are decomposing to chlorite.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingown data

    In sample BC04, sillimanite is abundant in the matrix and is aligned with the foliation of the light bands, but is also present as inclusion in the rim of garnet.

    “Sillimanite is abundant in the matrix and is aligned with the foliation of the light bands, but is also present as inclusion in the rim of garnet (Fig. 3D).”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    Anthophyllite is the dominant orthoamphibole in sample BAN030b and occurs as a reaction rim and in the matrix.

    “Anthophyllite is the dominant orthoamphibole and occurs as a reaction rim and in the matrix.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingnone given

    In sample BAN015, foliation is characterized by dark biotite bearing bands interlayered with light bands, the latter mainly composed of quartz and plagioclase.

    “Foliation is characterized by dark biotite bearing bands that are interlayered with light bands, the latter being mainly composed of quartz and plagioclase.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingnone given

    Garnet paragneiss sample BAN015 was collected along the old Hastings railway track, northeast of Bronson Lake.

    “Garnet paragneiss sample BAN015 was collected along the old Hastings railway track, northeast of Bronson Lake.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    Sample BC12 yielded a metamorphic temperature of 630 °C at 0.6 GPa, corresponding to the middle amphibolite facies.

    “The same approach was adopted for sample BC12 which yielded metamorphic temperature of 630 °C at 0.6 GPa that corresponds to the middle amphibolite facies.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    Minor biotite (1 vol%) occurs along garnet contacts and in the matrix of sample BAN030b.

    “Minor biotite (1 vol%) occurs along garnet contacts (Fig. S1A) and in the matrix.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    The kyanite-to-sillimanite reaction is only modeled at pressures above 0.8 GPa.

    “This reaction is only modeled at pressures above 0.8 GPa (Fig. 6C).”
    Quote in the paperNot a substantial claim
  • The quote only partly states this claim.

    Findingown data

    Grt-Bt reaction lines yield temperatures between 480 and 550 °C for two rim-rim measurements.

    “The Grt-Bt reaction lines yield temperatures between 480 and 550 °C.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    Reflected light microscopy of sample BAN015 shows small euhedral ilmenite blades grown after larger subhedral magnetite grains.

    “Reflected light microscopy shows small euhedral ilmenite blades obviously grown after larger subhedral magnetite grains (Fig. 3G).”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    In sample BC04, the almandine component of garnet is the highest (Xalm ~0.57), followed by the pyrope component (Xprp ~0.27).

    “The almandine component of this garnet is the highest (X alm ~0.57), followed by the pyrope component (X prp ~0.27).”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    Quartz in sample BAN030b occurs only as inclusions in garnet.

    “Quartz occurs only as inclusions in garnet.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingnone given

    Sample BC04 crops out in a small siliceous schistose metasedimentary layer surrounded by alkali granitic gneiss east of Clear Lake in the Sebastopol area.

    “It crops out in a small siliceous schistose metasedimentary layer surrounded by alkali granitic gneiss east of Clear Lake in the Sebastopol area”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    The resorbed feather amphiboles in sample BAN030b are rimmed by plagioclase and euhedral anthophyllite.

    “They are rimmed by plagioclase and euhedral anthophyllite (Fig. S1 A,C).”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingnone given

    In sample BAN015, cordierite, white mica and opaque phases are accessory.

    “Cordierite, white mica and opaque phases are accessory.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    In sample BAN015, tiny rutile lamellae or needles are observed inside the ilmenite grains.

    “Tiny rutile lamellae or needles can be observed inside the ilmenite grains (Fig. 3H).”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    Oxide phases in sample BAN030b are ilmenite and pyrite.

    “Oxide phases are ilmenite and pyrite.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based). May combine two claims.

    Findingnone given

    The spessartine component decreases from core to rim in sample BC12, a pattern referred to as a bell-shaped profile in the literature.

    “The spessartine component decreases from core to rim, describing what is referred to as a”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    In sample BC04, a kyanite-magnetite symplectite is observed.

    “Furthermore, we observed a kyanite-magnetite symplectite, which we interpret as a pseudomorph of staurolite.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    Plagioclase in sample BAN030b shows reverse zoning in the matrix with a more anorthite-rich rim.

    “Plagioclase shows reverse zoning in the matrix with a more anorthite-rich rim (Fig. S1 D).”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    The major element patterns of garnet in sample BC04 do not show chemical zoning, but a minor rimward decrease in Mg and minor rimward increase in Ca are observed.

    “The major element patterns of garnet do not show chemical zoning (Fig. 4A), but a minor rimward decrease in Mg and minor rimward increase in Ca are observed (Fig. 4A).”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingnone given

    In sample BAN015, biotite porphyroblasts are up to 3 mm in length, whereas the common grain-size of other crystals does not exceed 1 mm.

    “Biotite porphyroblasts are up to 3 mm in length, whereas the common grain-size of the other crystals does not exceed 1 mm.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingnone given

    Sample BAN030b crops out along Highway 62, south of L'Amable, and is part of the Elzevir terrane.

    “Sample BAN030b crops out along the Highway 62, south of L'Amable, and is part of the Elzevir terrane.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingnone given

    The outcrop of sample BAN015 is located within the Elzevir terrane slightly south of the inferred trace of the Bancroft shear zone.

    “The outcrop is located within the Elzevir terrane slightly south of the inferred trace of the Bancroft shear zone.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingnone given

    Sample BC04 is a dark, fine-grained, sillimanite-bearing garnet paragneiss composed mainly of biotite, quartz and plagioclase.

    “Sample BC04 is a dark, fine-grained, sillimanite-bearing garnet paragneiss that is composed mainly of biotite, quartz and plagioclase.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingown data

    Garnet in sample BAN015 exhibits resorbed grain boundaries and inclusions of quartz.

    “It exhibits resorbed grain boundaries and inclusions of quartz.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingnone given

    Most of the resorbed feather amphiboles in sample BAN030b are pargasitic in composition.

    “Most of the resorbed feather amphiboles are pargasitic in composition.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    No sillimanite was observed in sample BAN015, although it is reported from outcrops nearby.

    “no sillimanite was observed in the sample although it is reported from outcrops nearby.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingown data

    In sample BAN015, garnet is sparse and is not larger than 3 mm in diameter.

    “Garnet is sparse in the sample and is not larger than 3 mm in diameter.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingown data

    Both anthophyllite and gedrite in sample BAN030b are decomposing to chlorite.

    “A minor amount of gedrite (Na-Al bearing) is also present in the matrix and is in equilibrium with anthophyllite; both types of orthoamphibole are decomposing to chlorite.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingnone given

    Sample BAN030b is a feather amphibolite typically streaked with calcitic veins, although the matrix does not react with HCl and no carbonates were observed in thin section.

    “It is a feather amphibolite that is typically streaked with calcitic veins, although the matrix does not react with HCl and no carbonates were observed in thin section.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    No sillimanite was observed in sample BAN015.

    “No sillimanite was observed in this sample but has been reported from nearby outcrops (see map of Hewitt and James 1955).”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    Other inclusions in garnet in sample BAN030b are ilmenite, pyrite, plagioclase and chlorite.

    “Other inclusions in garnet are ilmenite, pyrite, plagioclase and chlorite.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingnone given

    Garnet porphyroblasts are up to 2 cm in diameter and display a flattened habit aligned with the foliation.

    “Garnet porphyroblasts are up to 2 cm in diameter and display a flattened habit aligned with the foliation.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    In sample BC04, sillimanite, magnetite and rutile grains are absent from the matrix but occur as inclusions in the garnet mantle and rim, not in the core.

    “Sillimanite as well as magnetite and rutile grains are absent from the matrix but can be observed as inclusions in the garnet mantle and rim (i.e.not in the core, see Fig.3A).”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    The sample BC12 modeled mineral modes at a temperature of 636°C and pressure of 0.54 GPa.

    “modeled mineral modes (Mod.) at a temperature of 636 °C and pressure of 0.54 GPa.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingnone given

    The grossular component is invariant throughout (X grs =0.05).

    “The grossular component is invariant throughout (X grs =0.05).”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    Sillimanite is not stable at these conditions; it is stable at pressures of less than 0.85 GPa down to 0.6 GPa.

    “However, sillimanite (only present in the garnet mantle) is not stable at these conditions.It is stable at pressures of less than 0.85 GPa down to 0.6 GPa”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    In BAN030b, the core is rich in manganese (X sps =0.05) in comparison to the rim.

    “The core is also rich in manganese (X sps =0.05) in comparison to the rim.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    In sample BC12, extensive alteration of cordierite leads to pinitized pseudomorphs, commonly in the form of pseudo-hexagonal prisms.

    “Extensive alteration of cordierite in both bands leads to pinitized pseudomorphs, commonly in the form of pseudo-hexagonal prisms (Fig.3B).”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    The GRTMOD software finds the best intersection of garnet core isopleths at 785 °C and 0.99 GPa using excess oxygen, which would correspond to Fe3+/Fe tot ratio of 30 %.

    “The GRTMOD software finds the best intersection of garnet core isopleths at 785 °C and 0.99 GPa (see green star) using excess oxygen which would correspond to Fe 3+ /Fe tot ratio of 30 %.”
    Quote in the paperSubstantial claim
  • May combine two claims.

    Findingown data

    In the zoned samples, garnet shows a high spessartine (X sps >=0.1) and a low grossular component (X grs <=0.1).

    “garnet shows a high spessartine (X sps >=0.1) and a low grossular component (X grs <=0.1)”
    Quote in the paperSubstantial claim
  • May combine two claims.

    Findingreasoning

    The stability of clinoamphibole increases and replaces clinopyroxene at temperatures below 550°C.

    “the stability of clinoamphibole increases and replaces clinopyroxene at temperatures below 550°C”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    The mole fraction of almandine increases from 0.58 in the core to 0.62 in the rim.

    “The mole fraction of almandine increases from 0.58 in the core to 0.62 in the rim.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingnone given

    Grains exhibit resorbed grain boundaries.

    “Grains exhibit resorbed grain boundaries.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    The amount of excess oxygen affects the incorporation of Mn into garnet, and addition of excess oxygen is the only way for the garnet isopleths of the samples to intersect.

    “As shown in Fig. 6, the amount of excess oxygen also affects the incorporation of Mn into garnet and addition of excess oxygen is the only way for the garnet isopleths of our samples to intersect.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data

    The garnet mantle has a higher X prp =0.24 compared to X prp =0.23 in the core and X prp =0.2 in the rim.

    “poorly shaped garnet mantle (slight shoulder) with a higher X prp =0.24 compared to X prp =0.23 in the core and X prp =0.2 in the rim”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    It was not possible to thermodynamically mimic the garnet core composition of sample BAN030b by adding various amounts of CO2 to the bulk rock composition, mainly because it results in an increase of the grossular component in garnet.

    “However, it was not possible to thermodynamically mimic the garnet core composition of the sample by adding various amounts of CO 2 to the bulk rock composition, mainly because it results in an increase of the grossular component in garnet.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingnone given

    Calcitic veinlets were observed in sample BAN030b.

    “Calcitic veinlets were observed in sample BAN030b.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data

    Two samples (BC12, BAN030b) from the transition zone of the Bancroft terrane with the Elzevir terrane reveal a second event, of which the most southerly sample (BAN030b), with a pressure of 0.87 GPa at medium temperatures, is not compatible with the regional metamorphic field gradient defined by Rivers (2012).

    “However, two samples (BC12, BAN030b) from the transition zone of the Bancroft terrane with the Elzevir terrane reveal a second event, of which the most southerly sample (BAN030b), with a pressure of 0.87 GPa at medium temperatures (Fig. 9), is not compatible with the regional metamorphic field gradient defined by Rivers (2012).”
    Quote in the paperSubstantial claim0 of 1 sources checked
    • cites Rivers (2012) source
  • May combine two claims.

    Findingcitation

    Applying the database, the garnet core composition yielded P-T conditions of 560 °C and 0.79 GPa, similar to the results above.

    “Applying this database, the garnet core composition yielded P-T conditions of 560 °C and 0.79 GPa, which is similar to the results above (see Fig. 7B).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Diener and Powell (2012) source
    • cites Holland and Powell (1998) source
  • May combine two claims.

    Findingcitation

    The three samples BC04, BC12 and BAN015 are oxidized, showing a high Fe3+/Fe tot ratio of 0.33-0.38 that corresponds to a relative oxygen fugacity between the fayalite-magnetite-quartz (FMQ) and magnetite-hematite buffers.

    “The three samples BC04, BC12 and BAN015 are oxidized, showing a high Fe 3+ /Fe tot ratio of 0.33-0.38 that corresponds to a relative oxygen fugacity between the fayalite-magnetite-quartz (= FMQ) and magnetite-hematite buffers”
    Quote in the paperSubstantial claim0 of 1 sources checked
    • cites Iacovino et al. 2020 source
  • May combine two claims.

    Findingnone given

    In the garnet cores, magnetite and rutile are the dominant oxide phases, whereas ilmenite-hematite grains can be observed in and at the garnet rims.

    “In the garnet cores, magnetite and rutile are the dominant oxide phases, whereas ilmenite-hematite grains can be observed in and at the garnet rims”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingnone given

    The addition of even very small amounts of CO2 increases the pressure estimates, whereas temperature is unaffected.

    “The addition of even very small amounts of CO 2 increases the pressure estimates, whereas temperature is unaffected.”
    Quote in the paperSubstantial claim
  • May combine two claims.

    Findingown data

    In BAN030b, pyrope content in the core is low (X prp =0.05) and continuously increases to 0.18 in the rim.

    “Pyrope content in the core is low (X prp =0.05) and continuously increases to 0.18 in the rim.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingnone given

    The GASP reaction line intersects the Grt-Bt geothermometer at 0.925 GPa and thus plots in the upper amphibolite facies.

    “The GASP reaction line intersects the Grt-Bt geothermometer at 0.925 GPa and thus plotting in the upper amphibolite facies.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).

    Findingnone given

    Chlorite and white mica are secondary mineral phases resulting from pinitization of cordierite.

    “Chlorite and white mica are secondary mineral phases resulting from pinitization of cordierite”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingreasoning

    Regarding sample BC04, the GASP barometer is in line with our garnet isopleth thermobarometry, whereas the Grt-Bt thermometer applied to the garnet rim is 100 °C lower than the temperatures derived by garnet core isopleths geothermobarometry.

    “Regarding sample BC04, the GASP barometer is in line with our garnet isopleth thermobarometry, whereas the Grt-Bt thermometer applied to the garnet rim is 100 °C lower than the temperatures derived by garnet core isopleths geothermobarometry.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Former geothermobarometric investigations of the CMB were compiled by Streepey et al. (1997).

    “Former geothermobarometric investigations of the CMB were compiled by Streepey et al. (1997).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Streepey et al. (1997)

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Premisecitation

    The compilation by Streepey et al. (1997) reveals an abundance of temperature data in the Elzevir terrane, but few P or T estimates for the Bancroft terrane.

    “This compilation reveals an abundance of temperature data in the Elzevir terrane (see also Rathmell et al. 1999, Dunn 2005, Dunn et al. 2019 for more temperature data and Fig. 2), but few P or T estimates for the Bancroft terrane.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Streepey et al. (1997)

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    During the Shawinigan orogenic pulse, some CMB terranes and domains were imbricated under mid-crustal thrusting and high-grade metamorphism.

    “During the Shawinigan orogenic pulse, some CMB terranes and domains were imbricated under mid-crustal thrusting and high-grade metamorphism.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Interpretationreasoning

    The maximum temperature for sample BAN030b is 600±25 °C, which marks the crest of the solvus studied by Spear (1980).

    “Since gedrite and anthophyllite (which is the dominant phase) exist in equilibrium, the maximum temperature is 600±25 °C, which marks the crest of the solvus studied by Spear (1980).”
    Quote in the paperSubstantial claim0 of 1 sources checked
    • cites Spear (1980)
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    During the Ottawan orogenic pulse (circa 1080-1020 Ma) renewed thrusting occurred throughout the CMB, including in the Bancroft terrane.

    “Simultaneously, a structural boundary developed between the Bancroft and the Elzevir terranes during the Shawinigan orogenic pulse, and during the Ottawan orogenic pulse (circa 1080-1020 Ma) renewed thrusting occurred throughout the CMB, including in the Bancroft terrane (McEachern andvan Breemen 1993, Timmerman et al. 1997).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites McEachern and van Breemen 1993 source
    • cites Timmerman et al. 1997

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation

    High-grade fabrics record the Shawinigan event in the Bancroft terrane and in some parts of the northern Elzevir terrane, but they are not present throughout the southern Elzevir terrane.

    “High-grade fabrics record this event in the Bancroft terrane and in some parts of the northern Elzevir terrane (Duguet and Easton 2017), but they are not present throughout the southern Elzevir terrane, perhaps because the latter was situated in the upper crust at that time (Rivers andCorrigan 2000, Rivers 2008).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Duguet and Easton 2017

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Premisecitation

    The Grt-Bt temperature of 670°C and GASP pressure of 0.6 GPa for sample BAN015 is identical with temperatures of 650 °C and 670 °C (and GASP pressure of 0.53 GPa) found in the same area by Rathmell et al. (1999) and Dunn (2005), respectively.

    “This temperature is identical with the Grt-Bt geothermometer temperature of 650 °C and 670 °C (and GASP pressure of 0.53 GPa) found in the same area by Rathmell et al. (1999) and Dunn (2005), respectively.”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Rathmell et al. (1999) source
    • cites Dunn (2005) source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Anovitz and Essene (1990) estimated temperature of approximately 750°C and 0.9 GPa for the CMBbtz.

    “However, Anovitz and Essene (1990) estimated temperature of approximately 600 °C and pressure of approximately 0.6 GPa in the Bancroft terrane and a temperature of approximately 750°C and 0.9 GPa for the CMBbtz based on a combination of geothermoand geobarometers.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Anovitz and Essene (1990) source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Field studies point to an earlier amphibolite to granulite facies event in the CMB at >1100 Ma affecting the supracrustal rocks.

    “The published metamorphic grade for the Bancroft terrane is amphibolite facies at 1080-1060 Ma (McEachern and van Breemen 1993, Timmerman et al. 1997)), but field studies point to an earlier amphibolite to granulite facies event in the CMB at >1100 Ma affecting the supracrustal rocks (Easton 1992(Easton , 2000)).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Easton 1992

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Easton 2000 source
  • May combine two claims.

    Interpretationown data

    The weak character of the bell-shape profile of BC12 and the close position of the core and rim isopleths intersections indicate diffusional relaxation.

    “The weak character of the bell-shape profile of BC12 (Fig. 4B)”
    • Also stated in: § Geothermobarometry · plain
      “and the close position of the core and rim isopleths (Fig. 6D)”
    • Also stated in: § Geothermobarometry · hedged
      “intersections indicate diffusional relaxation.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation

    At ca. 1020 Ma (not precisely dated), localized extension and accompanying lower amphibolite-facies metamorphism occurred along the Bancroft shear zone.

    “At ca. 1020 Ma (not precisely dated), localized extension and accompanying lower amphibolite-facies metamorphism occurred along the Bancroft shear zone (van der Pluijm and Carlson 1989).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites van der Pluijm and Carlson 1989

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Premisecitation

    Anovitz and Essene (1990) estimated temperature of approximately 600 °C and pressure of approximately 0.6 GPa in the Bancroft terrane.

    “However, Anovitz and Essene (1990) estimated temperature of approximately 600 °C and pressure of approximately 0.6 GPa in the Bancroft terrane and a temperature of approximately 750°C and 0.9 GPa for the CMBbtz based on a combination of geothermoand geobarometers.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Anovitz and Essene (1990) source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Study design and conductcitation

    GRTMOD used with unweighted isopleths provides statistical uncertainty and accuracy of each solution.

    “GRTMOD was used with unweighted isopleths (see Lanari et al. 2017), meaning that the program automates the manual search of the point of intersection of all garnet isopleths, but gives the additional information of statistical uncertainty and accuracy of each solution.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Lanari et al. 2017

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    In the Fishtail Lake area at the border between Bancroft terrane and the CMBbtz, prograde sillimanite with retrograde kyanite and andalusite was observed by Lal and Moorhouse (1969).

    “In the Fishtail Lake area at the border between Bancroft terrane and the CMBbtz, Lal and Moorhouse (1969) observed prograde sillimanite with retrograde kyanite and andalusite.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Lal and Moorhouse (1969) source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Sillimanite has been reported from nearby outcrops to sample BAN015.

    “No sillimanite was observed in this sample but has been reported from nearby outcrops (see map of Hewitt and James 1955).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Hewitt and James 1955

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation

    The CMB in Ontario is subdivided into two parts: the Composite Arc Belt (CAB) in the north and the northern Frontenac Adirondack Belt in the south, which includes the Frontenac terrane.

    “The CMB in Ontario is subdivided in two parts: the Composite Arc Belt (CAB = the Bancroft terrane, Elzevir terrane (sensu lato) and its various subdomains) in the north and the northern Frontenac Adirondack Belt in the south, which includes the Frontenac terrane (Easton 1992, Carr et al. 2000).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Easton 1992

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Carr et al. 2000

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Interpretationown data

    The mode of cordierite observed in thin section matches solution 2, with computed mode of cordierite 2 vol% for solution 2 versus 28 vol% for solution 1.

    “First, the mode of cordierite observed in thin section matches the one for solution 2 (the computed mode of cordierite is 2 vol% for solution 2 versus 28 vol% of solution 1).”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation

    The CMBbtz consists of ductile tectonites, whereas the Bancroft terrane is composed of platformal marine metasedimentary rocks (e.g. dolomitic and calcitic marbles and quartzites), tectonic breccias and mostly metamorphosed intrusive rocks.

    “The CMBbtz consists of ductile tectonites, whereas the Bancroft terrane is composed of platformal marine metasedimentary rocks (e.g.dolomitic and calcitic marbles and quartzites), tectonic breccias and mostly metamorphosed intrusive rocks (Lumbers et al. 1990, Easton 1992).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Lumbers et al. 1990

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Easton 1992

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Interpretationown data

    At lower pressure (0.5-0.8 GPa), the kyanite-to-sillimanite reaction is hindered by the stability of staurolite, which is not observed in the sample.

    “At lower pressure (0.5-0.8 GPa), this reaction is hindered by the stability of staurolite, which is not observed in the sample.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Interpretationown data

    The kyanite-magnetite symplectite in sample BC04 is a pseudomorph of staurolite.

    “Furthermore, we observed a kyanite-magnetite symplectite, which we interpret as a pseudomorph of staurolite.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    The published metamorphic grade for the Bancroft terrane is amphibolite facies at 1080-1060 Ma.

    “The published metamorphic grade for the Bancroft terrane is amphibolite facies at 1080-1060 Ma (McEachern and van Breemen 1993, Timmerman et al. 1997)), but field studies point to an earlier amphibolite to granulite facies event in the CMB at >1100 Ma affecting the supracrustal rocks (Easton 1992(Easton , 2000)).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites McEachern and van Breemen 1993 source
    • cites Timmerman et al. 1997

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Premisecitation

    The kyanite-sillimanite isograd is identified in the southwestern Elzevir terrane (Belmont domain) and could be extrapolated close to the town of Bancroft.

    “The kyanite-sillimanite isograd is identified in the southwestern Elzevir terrane (Belmont domain) and could be extrapolated close to the town of Bancroft (Carmichael et al. 1978, Anovitz andEssene 1990).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Carmichael et al. 1978

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Anovitz and Essene 1990 source
  • May combine two claims.

    Interpretationnone given

    The garnet in sample BC12a shows a resorbed margin and slight compositional zoning, indicative of a prograde history and subsequent re-equilibration at peak conditions.

    “The garnet shows a resorbed margin and slight compositional zoning, indicative of a prograde history and subsequent re-equilibration at peak conditions.”
    Quote in the paperNot a substantial claim
    • The authors state this as an assumption: All minerals coexisted in equilibrium at peak conditions.
  • Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).

    Premisenone given

    The Bancroft terrane (and the adjacent Central Metasedimentary Belt boundary thrust zone (CMBbtz) to the north) is the structurally lowest unit of the CMB structural stack.

    “The Bancroft terrane (and the adjacent Central Metasedimentary Belt boundary thrust zone (CMBbtz) to the north) is the structurally lowest unit of the CMB structural stack.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).

    Premisenone given

    After a period of time (typically ~60 Ma), the lower plate reaches its thermal maximum, which is represented by metamorphic ages of minerals with high closure temperatures such as monazite or zircon.

    “After a period of time (typically ~60 Ma), the lower plate reaches its thermal maximum, which is represented by metamorphic ages of minerals with high closure temperatures such as monazite or zircon.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation

    The CMBbtz was involved in ductile thrusting at ca. 1.18 Ga that was a result of the emplacement of the Elzevir terrane onto the Proterozoic Laurentia margin.

    “They infer that the CMBbtz was involved in ductile thrusting at ca. 1.18 Ga that was a result of the emplacement of the Elzevir terrane onto the Proterozoic Laurentia margin.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites McEachern and van Breemen (1993) source
  • May combine two claims.

    Premisecitation

    In crustal thickening models, the cold P-T loop is representative for the metamorphic history of the upper plate (Elzevir terrane) and the warmer loop correlates with the lower plate (Bancroft terrane + CMBbtz).

    “Such a scenario is commonly observed in crustal thickening models (England andThompson 1984, Thompson andEngland 1984), where the cold P-T loop is representative for the metamorphic history of the upper plate (here Elzevir terrane) and the warmer loop correlates with the lower plate (here Bancroft terrane + CMBbtz, see Fig. 9B).”
    Quote in the paperSubstantial claim0 of 2 sources checked
    • cites England andThompson 1984

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Thompson andEngland 1984

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Interpretationown data

    The southernmost sample's result contradicts previous pressure estimates of the region and the proposed metamorphic field gradient.

    “The later result contradicts previous pressure estimates of the region and the proposed metamorphic field gradient”
    Quote in the paperSubstantial claim
  • May combine two claims.

    Interpretationreasoning

    The BED92 database has no effect on the outcome of garnet isopleth geothermobarometry, since the GRTMOD solutions for intersection of garnet isopleths are the same within their uncertainties.

    “database has no effect on the outcome of garnet isopleth geothermobarometry, since the GRTMOD solutions for intersection of garnet isopleths are the same within their uncertainties.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation

    The proposed OOL is less extensive than suggested by Rivers (2008) and mainly comprises the area around the Tudor gabbro pluton in the southern Elzevir terrane.

    “Recently, Dunn et al. (2019) also inferred that the proposed OOL is less extensive than suggested by Rivers (2008) and only comprises mainly the area around the Tudor gabbro pluton in the southern Elzevir terrane”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Dunn et al. (2019) source
    • cites Rivers (2008) source
  • May combine two claims.

    Interpretationreasoning

    The Ottawan Orogenic Lid (OOL) in the western CMB is less extensive and represents the upper (unaffected by metamorphism) parts of the hanging wall.

    “by indicating that the OOL in the western CMB is less extensive and represents the upper (unaffected by metamorphism) parts of the hanging wall.”
    Quote in the paperNot a substantial claim
  • The quote only partly states this claim.

    Study design and conductnone given

    The southernmost sample's result is based on a poorly constrained sample in terms of thermodynamic modeling.

    “but is based on a poorly constrained sample in terms of thermodynamic modeling.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Interpretationnone given

    In sample BC12, chlorite and white mica are secondary mineral phases resulting from pinitization of cordierite.

    “Chlorite and white mica are secondary mineral phases resulting from pinitization of cordierite”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Interpretationown data

    The occurrence of sillimanite in the garnet mantle of sample BC04, and minor alkali feldspar in the matrix, indicates metamorphic conditions at 700°C and 0.6 GPa, defined by the small stability field of the equilibrium assemblage grt-bt-pl-qz-sil-kfs-ilm-H2O.

    “The occurrence of sillimanite in the garnet mantle of sample BC04, and minor alkali feldspar in the matrix, indicates metamorphic conditions at 700°C and 0.6 GPa, which is defined by the small stability field of the equilibrium assemblage grtbt-pl-qz-sil-kfs-ilm-H 2 O”
    Quote in the paperSubstantial claim
    • Rests on an assumption: The bulk-rock chemistry represents the initial garnet growth conditions.
  • Probably not a substantial claim: may not pass S4 (based).

    Interpretationnone given

    Fluids may affect the oxygen fugacity regime and thus the position of garnet isopleths of the samples from the northern CMB.

    “fluids may affect the oxygen fugacity regime and thus the position of garnet isopleths of the samples from the northern CMB.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Interpretationnone given

    In sample BC04, chlorite is mostly associated with biotite and is interpreted as a retrograde phase.

    “Chlorite is mostly associated with biotite and is interpreted as a retrograde phase.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Interpretationcitation

    The first growing garnet core takes in most Mn from the rock and is richer in Mn than the later formed, prograde garnet mantle.

    “Therefore, the first growing garnet core takes in most Mn from the rock and is richer in Mn than the later formed, prograde garnet mantle.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based). May combine two claims.

    Premisenone given

    Pressure decreases due to isostatic uplift (because of crustal thickening) and accompanying erosion, while temperature is increasing because of the continuing thermal relaxation of the perturbed geotherm.

    “Then pressure decreases due to isostatic uplift (because of crustal thickening) and accompanying erosion, while temperature is increasing because of the continuing thermal relaxation of the perturbed geotherm.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Premisecitation

    The Huntsville region experienced peak metamorphism of ca. 730°C at 1.0 GPa before 1.1 Ga that is associated with crustal thickening caused by significant northwest-directed overthrusting by the CMBbtz.

    “The Huntsville region experienced peak metamorphism of ca.730°C at 1.0 GPa before 1.1 Ga that is associated with crustal thickening caused by D r a f t 37 significant northwest-directed overthrusting by the CMBbtz.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Nadeau 1990

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Harlov (2000) identified CO2-rich fluids as the principal driver for oxidation of granulites from the Sveconorwegian Bamble terrane, which were metamorphosed during the Arendal phase around 1.14-1.08 GPa.

    “For instance, Harlov (2000) identified CO 2rich fluids as the principal driver for oxidation of granulites from the Sveconorwegian Bamble terrane, which were metamorphosed during the Arendal phase around 1.14-1.08GPa (e.g., Bingen 2008).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Harlov (2000) source
    • cites Bingen 2008

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    McEachern and van Breemen (1993) proposed that northwest-directed thrusting occurred in two pulses at initially 1.19-1.18 Ga and again at 1.08-1.05 Ga.

    “They proposed that northwest-directed thrusting occurred in two pulses at initially 1.19-1.18Ga and again at 1.08-1.05Ga.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites McEachern and van Breemen (1993) source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Hanmer and McEachern (1992) inferred that the metagabbros may have acted as a physical barrier to the upward migration of metasomatic fluids in the Elzevir terrane.

    “Hanmer and McEachern (1992) inferred that the metagabbros may have acted as physical barrier to the upward migration of metasomatic fluids in the Elzevir terrane (see Fig. 2).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Hanmer and McEachern (1992) source
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation

    The Tudor gabbro pluton is a 1.24 Ga old intrusion that experienced metasomatism between 1.24 and 1.08 Ga.

    “a 1.24 Ga old intrusion that experienced metasomatism between 1.24 and 1.08 Ga (Dunn andValley 1996, Duesterhoeft et al. 2017).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Dunn andValley 1996

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Duesterhoeft et al. 2017 source
  • May combine two claims.

    Interpretationreasoning

    The spessartine component of garnet is very closely correlated with the amount of garnet, because the Mn content in garnet should be higher the less garnet there is in the rock.

    “As a consequence, spessartine component of garnet is very closely correlated with the amount of garnet, since the Mn content in garnet should be higher the less garnet there is in the rock.”
    Quote in the paperSubstantial claim
  • May combine two claims.

    Interpretationreasoning

    The calculated temperature shows the minimum metamorphic temperature of the rock, because garnet rim compositions were used for the geothermometry.

    “The calculated temperature shows the minimum metamorphic temperature of the rock, because we used garnet rim compositions for the geothermometry.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).

    Interpretationnone given

    The high variety of older metagabbros and metasedimentary rocks in the Elzevir terrane are most likely remnants of the lower parts of the Elzevir terrane that were probably tectonically intercalated with the upper parts during the contractional crustal thickening phase of the Ottawan event.

    “The high variety of older metagabbros, but also metasedimentary rocks in the Elzevir terrane are most likely remnants of the lower parts (crust?) of the Elzevir terrane that were probably tectonically intercalated with the upper parts during the contractional crustal thickening phase of the Ottawan event.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).

    Interpretationnone given

    The oxidation potential of seawater in the Mesoproterozoic is uncertain.

    “However, the oxidation potential of seawater in the Mesoproterozoic is uncertain.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Premisecitation

    Cooling after the metamorphic peak is documented for samples south of Barry's Bay and for rocks in the northeastern CMB.

    “This cooling is also documented by Anovitz and Essene (1990) for the samples south of Barry's Bay (see Fig. 2) and by Duguet and Easton (2017) for rocks in the northeastern CMB (just east of our study area).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Anovitz and Essene (1990) source
    • cites Duguet and Easton (2017)

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Study design and conductown data

    Garnets of samples BC04, BC12 and BAN015 are only slightly zoned, which rules out the possibility of a bulk compositional bias based on garnet fractionation on the retrograde path.

    “Moreover, garnets of sample BC04, BC12 and BAN015 are only slightly zoned, which rules out the possibility of a bulk compositional bias based on garnet fractionation on the retrograde path.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based). May combine two claims.

    Premisenone given

    Sample HAL104 comes from a well-known outcrop near the village of West Guilford and is located between the Redstone and Dysart thrust sheets and thus at the top of CMBbtz.

    “This sample comes from a well-known outcrop near the village of West Guilford and is located between the Redstone and Dysart thrust sheets and thus at the top of CMBbtz.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Interpretationreasoning

    Garnet rim and adjacent biotite record retrograde Fe-Mg exchange and equilibrates later than the plagioclase corona around garnet.

    “This means that garnet rim and adjacent biotite record retrograde Fe-Mg exchange and equilibrates later than the plagioclase corona around garnet (see also Fig.3A).”
    Quote in the paperSubstantial claim
  • May combine two claims.

    Interpretationown data

    There are two different P-T paths in the region: (1) a retrograde P-T trajectory similar to the proposed one for the CMB by Anovitz and Essene (1990) and (2) a cryptic medium temperature P-T path for the northern Elzevir terrane (Belmont domain).

    “we have two different P-T paths in the region: (1) a retrograde P-T trajectory similar to the proposed one for the CMB byAnovitz and Essene (1990) and (2) a cryptic medium temperature P-T path for the northern Elzevir terrane (Belmont domain).”
    Quote in the paperSubstantial claim0 of 1 sources checked
    • cites Anovitz and Essene (1990) source
  • May combine two claims.

    Interpretationnone given

    Pargasite decomposed to orthoamphibole during pressure decrease and temperature increase, and orthoamphibole subsequently altered to chlorite during the ensuing retrograde event.

    “Pargasite decomposed to orthoamphibole during pressure decrease and temperature increase, and orthoamphibole subsequently altered to chlorite during the ensuing retrograde event.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Interpretationcitation

    Sample BC04 shows microstructures that reflect decompression at higher temperature, as the GASP reaction or resorbed garnet with corona of biotite and plagioclase.

    “The sample also shows microstructures that reflect decompression at higher temperature, as the GASP reaction or resorbed garnet with corona of biotite and plagioclase (e.g., Waters 2019).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Waters 2019 source
  • Probably not a substantial claim: may not pass S4 (based). May combine two claims.

    Interpretationnone given

    The latter compositions could be affected by different degree of oxidation and thus bias chemical equilibrium.

    “The latter compositions could be affected by different degree of oxidation and thus bias chemical equilibrium.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Interpretationreasoning

    Sillimanite, garnet rim and adjacent biotite and plagioclase are in equilibrium and record peak metamorphism.

    “Consequently, sillimanite, garnet rim and adjacent biotite and plagioclase are in equilibrium and record peak metamorphism.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation

    Such P-T paths are classically associated with an overthrust model.

    “Such P-T paths are classically associated with an overthrust model (seeEngland and”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites England and

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).

    Interpretationnone given

    The proposed P-T-trajectory for the three samples is typical for regions that have experienced crustal thickening.

    “The proposed P-T-trajectory (Fig.9A) for the three samples is typical for regions that have experienced crustal thickening.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Interpretationreasoning

    Our results from geothermometry should be considered as minimum metamorphic temperature and might represent the blocking temperatures for Fe-Mg diffusion.

    “Hence, our results from geothermometry should be considered as minimum metamorphic temperature and might represent the blocking temperatures for Fe-Mg diffusion.”
    Quote in the paperSubstantial claim
131 of 131
  • The paper relies on this without support.

    Most exposed rocks in the northern CMB are characterized by relatively non-diagnostic bulk rock compositions (e.g., marbles, metagranitoids).

    “However, a lack of combined pressure-temperature (P-T) data exists for the northern part of the CMB, namely the Bancroft terrane and Central Metasedimentary Belt boundary thrust zone (CMBbtz), because most exposed rocks are characterized by relatively non-diagnostic bulk rock compositions (e.g., marbles, metagranitoids; see Fig. 2).”
  • The paper relies on this without support.

    The ages of magmatism and metamorphism in the CMB are restricted to the period of ~1.3-1.0 Ga.

    “Because ages of magmatism and metamorphism in the CMB are restricted to the period of ~1.3-1.0Ga, it is an ideal natural laboratory to study the late Mesoproterozoic metamorphic history of the Grenville Province and its supracrustal rocks.”
  • The paper relies on this without support.

    Much of the detailed metamorphic history of the northern CMB remains unknown due to sparse P-T-t data.

    “Due to sparse P-T-t data in the northern CMB much of its detailed metamorphic history remains unknown.”
  • The authors state this as an assumption.

    All samples were saturated in H2O.

    “All samples were assumed to be saturated in H 2 O, which is the standard approximation in thermodynamic modeling for rocks that did not experience partial melting.”
  • The authors state this as an assumption.

    All iron in the samples is ferrous.

    “The second standard assumption in thermodynamic modeling is that all iron is ferrous (i.e. for each Fe one O is added to the bulk rock composition).”
  • The paper relies on this without support.

    The addition of excess oxygen enhances the stability of ferric iron bearing minerals (hematite, magnetite, epidote) in the JUN92 database.

    “The addition of”
  • The paper relies on this without support.

    GASP geobarometry results represent the maximum achieved pressure.

    “the results for GASP geobarometry, representing the maximum achieved pressure, should be considered with caution (Fig. 5B).”
  • The paper relies on this without support.

    Suitable solid solution models for clino- and orthoamphibole are lacking, making modeling of sample BAN030b challenging.

    “Modeling of sample BAN030b is challenging due to the lack of suitable solid solution models for clino-and D r a f t 25 orthoamphibole.”
  • The paper relies on this without support.

    The incorporation of excess oxygen to garnet isopleth thermobarometry is novel.

    “Since the incorporation of excess oxygen to garnet isopleth thermobarometry is novel, we use BINGO-ANTIDOTE that is D r a f t 27 independent of the excess oxygen assumption, if all opaque phases are ignored.”
  • The authors state this as an assumption.

    All minerals coexisted in equilibrium at peak conditions.

    “Here, we assume that all the minerals coexisted in equilibrium at peak conditions.”
  • The paper relies on this without support.

    The database can calculate assemblages with up to three clinoamphiboles at temperatures below 600 °C.

    “In addition, the database can calculate assemblages with up to three clinoamphiboles at temperatures below 600 °C.”
  • The paper relies on this without support.

    Kyanite reacts to sillimanite subsequently.

    “Subsequently, kyanite reacts to sillimanite.”
  • The paper relies on this without support.

    The oxidation potential of present-day seawater is high enough to convert ferrous to ferric iron.

    “The oxidation potential of present-day seawater is high enough to convert ferrous to ferric iron.”
  • The paper relies on this without support.

    No thermodynamic model describes the effect of incorporation of chlorine into amphibole on its stability.

    “since no thermodynamic model describes the effect of incorporation of chlorine into amphibole on its stability.”
  • The paper relies on this without support.

    Only a few direct pressure and temperature calculations based on phase equilibrium petrology methods exist in the central Bancroft terrane.

    “Only a few direct pressure and temperature calculations based on phase equilibrium petrology methods exist in the central Bancroft terrane”
  • The paper relies on this without support.

    Orthopyroxene and orthoamphibole are chemically similar in the water-saturated system.

    “Since orthopyroxene and orthoamphibole are chemically similar in our water-saturated system”
  • The paper relies on this without support.

    The observed orthoamphibole should be stable between 550 and 650°C.

    “where the observed orthoamphibole should be stable”
  • The paper relies on this without support.

    The bulk-rock chemistry represents the initial garnet growth conditions.

    “initial garnet growth conditions that should have crystallized from the bulk-rock chemistry”
18 of 18

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

Each contradiction between two passages listed here was confirmed by an independent check.

  • Reported oxidation range excludes BC04

    Minor

    The modeled Fe3+/Fetot ratio for BC04 is 30%, but the later stated range for BC04, BC12, and BAN015 is 0.33-0.38 (33-38%).

1 of 1

Cites

Flagged first, then by citations

Research works printed but not linked: 8

  1. Armstrong J.T., 1995, Microbeam Analysis, 4, 177
  2. Burr J.L., 1994, Lithoprobe Abitibi- Grenville Project Report, 41, 59
  3. Carmichael, D.M., Moore, J.M., and Skippen, G.B. 1978. Isograds around the Hastings metamorphic “low.” In Toronto ’78 field trips guidebook. Edited by A.L. Currie and W.O. Mackasey. Geological Association of Canada, St. John’s, Newfoundland. pp. 325–346.
  4. Duguet M., 2017, Ontario Geological Survey, Open File Report, 6331, 115
  5. Easton R.M., 2006, Ontario Geological Survey, Open File Report, 5454, 165
  6. Laajoki K., 2002, Norwegian Journal of Geology, 82, 119
  7. Lumbers, S.B., Heaman, L.M., Vertolli, V.M., and Wu, T.W. 1990. Nature and timing of Middle Proterozoic magmatism in the Central Metasedimentary Belt, Grenville Province, Ontario. In Mid-Proterozoic Laurentia-Baltica. Edited by C.F. Gower, T. Rivers, and A.B. Ryan. Geological Association of Canada, Special Paper 38, pp. 243–276.
  8. Turner, A. 1999. Laser 40Ar/39Ar study to assess magnitude of displacement on the Bancroft shear zone, Grenville Province, Gooderham, Ontario. B.Sc. thesis, Carleton University, Ottawa, Ontario.

Cited by

Sorted by citations

Authors
Duesterhoeft, E., Raase, P., Duguet, M., & Easton, R. M.
Affiliations
  • Christian-Albrechts-Universität zu Kiel (DE)
  • Ontario Geological Survey, 933 Ramsey Lake Road, Sudbury, Ontario, Canada.
Venue
Canadian Journal of Earth Sciences
Published
2021-01
Volume
58
Issue
1
Pages
21-37
ISSN
  • 0008-4077 (ISSN-L)
  • 1480-3313
OpenAlex
W3045893813
Cited by
4
References
79
Citations by year
2025: 1 · 2023: 1 · 2022: 2
FWCI
0.46
Type
journal article
Language
en
Open access
Locations
  • Canadian Journal of Earth Sciences (publishedVersion)
  • TSpace (University of Toronto) (acceptedVersion)
Funders
Deutsche Forschungsgemeinschaft
Topics
  • Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
  • Physical Sciences › Earth and Planetary Sciences › Geophysics › High-pressure geophysics and materials
  • Physical Sciences › Physics and Astronomy › Astronomy and Astrophysics › Astro and Planetary Science
Keywords
oxygen excess, metapelites, Central Metasedimentary Belt, Grenville Province, crustal thickening, pressure-temperature conditions

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Claims read by deepseek-v4.1-flash under definition version 3 (extract-v3) on 2026-10-26.

Classified by jev-1.13-20260917 (gold-guideline-v0.2) on 2026-10-26.

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Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

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