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Cu2O Nanoparticles with Both {100} and {111} Facets for Enhancing the Selectivity and Activity of CO2 Electroreduction to Ethylene

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Gao, Yugang, Wu, Qian, Liang, Xizhuang, Wang, Zeyan, Zheng, Zhaoke, Wang, Peng, Liu, Yuanyuan, Dai, Ying, Whangbo, Myung‐Hwan, Huang, Baibiao·2020·Advanced Science

DOI 10.1002/advs.201902820

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Abstract

Cu 2 O nanoparticles (NPs) enclosed with different crystal facets, namely, c‐Cu 2 O NPs with {100} facets, o‐Cu 2 O NPs with {111} facets, and t‐Cu 2 O NPs with both {111} and {100} facets, are prepared and their electrocatalytic properties for the reduction of CO 2 to C 2 H 4 are evaluated. It is shown that the selectivity and activity of the C 2 H 4 production depend strongly on the crystal facets exposed in Cu 2 O NPs. The selectivities for the C 2 H 4 production increases in the order, c‐Cu 2 O < o‐Cu 2 O < t‐Cu 2 O, (with FE C2H4 = 38%, 45%, and 59%, respectively). This study suggests that Cu 2 O NPs are more likely responsible for the selectivity and activity for the C 2 H 4 production than the metallic Cu NPs produced on the surface of Cu 2 O NPs. This work provides a new route for enhancing the selectivity of the electrocatalytic CO 2 reduction by crystal facet engineering.

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Authors: Gao, Y., Wu, Q., Liang, X., Wang, Z., Zheng, Z., Wang, P., Liu, Y., Dai, Y., Whangbo, M., & Huang, B.
Venue: Advanced Science
Publisher: Wiley
Published: 2020-01-30
Volume: 7
Issue: 6
Pages: 1902820-1902820
ISSN: 2198-3844 (ISSN-L)
DOI: 10.1002/advs.201902820
OpenAlex: W3003894457
Cited by: 331
References: 54
FWCI: 8.82
Type: journal article
Language: en
Open access: gold

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Cu2O Nanoparticles with Both {100} and {111} Facets for Enhancing the Selectivity and Activity of CO2 Electroreduction to Ethylene

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