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Cited by 509

The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.

Unveiling the Promotion of Surface‐Adsorbed Chalcogenate on the Electrocatalytic Oxygen Evolution Reaction

Shi, Yanmei, Du, Wei, Zhou, Wei, Wang, Changhong, Lu, Shanshan, Lu, Siyu, Zhang, Bin·2020·Angewandte Chemie International Edition

Abstract

Transition metal chalcogenides (TMCs) are efficient oxygen evolution reaction (OER) pre‐electrocatalysts, and will in situ transform into metal (oxy)hydroxides under OER condition. However, the role of chalcogen is not fully elucidated after oxidation and severe leaching. Here we present the vital promotion of surface‐adsorbed chalcogenates on the OER activity. Taking NiSe 2 as an example, in situ Raman spectroscopy revealed the oxidation of Se‐Se to selenites (SeO 32−) then to selenates (SeO 42−). Combining the severe Se leaching and the strong signal of selenates, it is assumed that the selenates are rich on the surface and play significant roles. As expected, adding selenites to the electrolyte of Ni(OH)2 dramatically enhance its OER activity. And sulfates also exhibit the similar effect, suggesting the promotion of surface‐adsorbed chalcogenates on OER is universal. Our findings offer unique insight into the transformation mechanism of materials during electrolysis.

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Metadata

Authors
Shi, Y., Du, W., Zhou, W., Wang, C., Lu, S., Lu, S., & Zhang, B.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2020-10-04
Volume
59
Issue
50
Pages
22470-22474
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W3083836886
Cited by
509
References
7
FWCI
11.61
Type
journal article
Language
en
Open access
closed
Funders
  • National Natural Science Foundation of China (21871206, 21901180)
  • Natural Science Foundation of Tianjin City (17JCJQJC44700)
  • Postdoctoral Research Foundation of China (2019TQ0226)

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Shi, Y., Du, W., Zhou, W., Wang, C., Lu, S., Lu, S., & Zhang, B. (2020). Unveiling the Promotion of Surface‐Adsorbed Chalcogenate on the Electrocatalytic Oxygen Evolution Reaction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202011097

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