The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Unveiling the Promotion of Surface‐Adsorbed Chalcogenate on the Electrocatalytic Oxygen Evolution Reaction
Abstract
Transition metal chalcogenides (TMCs) are efficient oxygen evolution reaction (OER) pre‐electrocatalysts, and will in situ transform into metal (oxy)hydroxides under OER condition. However, the role of chalcogen is not fully elucidated after oxidation and severe leaching. Here we present the vital promotion of surface‐adsorbed chalcogenates on the OER activity. Taking NiSe 2 as an example, in situ Raman spectroscopy revealed the oxidation of Se‐Se to selenites (SeO 32−) then to selenates (SeO 42−). Combining the severe Se leaching and the strong signal of selenates, it is assumed that the selenates are rich on the surface and play significant roles. As expected, adding selenites to the electrolyte of Ni(OH)2 dramatically enhance its OER activity. And sulfates also exhibit the similar effect, suggesting the promotion of surface‐adsorbed chalcogenates on OER is universal. Our findings offer unique insight into the transformation mechanism of materials during electrolysis.
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Cited by
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Trimetallic Spinel NiCo2−xFexO4 Nanoboxes for Highly Efficient Electrocatalytic Oxygen Evolution
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Metadata
- Authors
- Shi, Y., Du, W., Zhou, W., Wang, C., Lu, S., Lu, S., & Zhang, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-10-04
- Volume
- 59
- Issue
- 50
- Pages
- 22470-22474
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3083836886
- Cited by
- 509
- References
- 7
- FWCI
- 11.61
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- National Natural Science Foundation of China (21871206, 21901180)
- Natural Science Foundation of Tianjin City (17JCJQJC44700)
- Postdoctoral Research Foundation of China (2019TQ0226)
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- Shi, Y., Du, W., Zhou, W., Wang, C., Lu, S., Lu, S., & Zhang, B. (2020). Unveiling the Promotion of Surface‐Adsorbed Chalcogenate on the Electrocatalytic Oxygen Evolution Reaction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202011097
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