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Room temperature ionic liquids as emerging solvents for the pretreatment of lignocellulosic biomass
Abstract
Room temperature ionic liquids (RTILs) are emerging as attractive and green solvents for lignocellulosic biomass pretreatment. The unique solvating properties of RTILs foster the disruption of the 3D network structure of lignin, cellulose, and hemicellulose, which allows high yields of fermentable sugars to be produced in subsequent enzymatic hydrolysis. In the current review, we summarize the physicochemical properties of RTILs that make them effective solvents for lignocellulose pretreatment including mechanisms of interaction between lignocellulosic biomass subcomponents and RTILs. We also highlight several recent strategies that exploit RTILs and generate high yields of fermentable sugars suitable for downstream biofuel production, and address new opportunities for use of lignocellulosic components, including lignin. Finally, we address some of the challenges that remain before large‐scale use of RTILs may be achieved. Biotechnol. Bioeng. 2011;108:1229–1245. © 2011 Wiley Periodicals, Inc.
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Bui, M., Adjiman, C. S., Bardow, A., Anthony, E. J., Boston, A., Brown, S., Fennell, P. S., Fuss, S., Galindo, A., Hackett, L. A., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02342a · Cited by 4,374
Deconstruction of lignocellulosic biomass with ionic liquids
Brandt, A., Gräsvik, J., Hallett, J. P., & Welton, T. (2013) · Green Chemistry · doi:10.1039/c2gc36364j · Cited by 1,557
Conversion of Lignocellulosic Biomass to Nanocellulose: Structure and Chemical Process
Lee, H. V., Hamid, S. B. A., & Zain, S. K. (2014) · The Scientific World Journal · doi:10.1155/2014/631013 · Cited by 700
Liu, Q.-P., Hou, X.-D., Li, N., & Zong, M.-H. (2012) · Green Chem. · doi:10.1039/c2gc16128a · Cited by 441
Egorova, K. S., & Ananikov, V. P. (2014) · ChemSusChem · doi:10.1002/cssc.201300459 · Cited by 441
Metadata
- Authors
- Mora‐Pale, M., Meli, L., Doherty, T. V., Linhardt, R. J., & Dordick, J. S.
- Venue
- Biotechnology and Bioengineering
- Publisher
- Wiley
- Published
- 2011-04-12
- Volume
- 108
- Issue
- 6
- Pages
- 1229-1245
- ISSN
- 0006-3592 (ISSN-L)
- 1097-0290
- OpenAlex
- W2142729066
- Cited by
- 384
- References
- 106
- FWCI
- 24.80
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.