Lizardite serpentine dissolution kinetics as a function of pH and temperature, including effects of elevated pCO2
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The tailings also benefited from brucite content, which is far more reactive than serpentine.
“However, the tailings also benefited from brucite content, which is far more reactive than serpentine [31].”
From Carbon Mineralization with North American PGM Mine Tailings—Characterization and Reactivity Analysis (2021) · cites this paper as [31]
Phyllosilicates like lizardite are reported to react more slowly compared to anhydrous silicates such as olivine due to the abundance of tetrahedra containing Si-O bonds, which are stronger than Mg-O bonds.
“Phyllosilicates like lizardite are reported to react more slowly compared to anhydrous silicates such as olivine due to the abundance of tetrahedra containing Si-O bonds, which are stronger than Mg-O bonds [31,46].”
From Carbon Mineralization with North American PGM Mine Tailings—Characterization and Reactivity Analysis (2021) · cites this paper as [31]
The reactivity of ultramafic mine waste is enhanced by increased surface area due to mineral processing, yet dissolution rates remain sluggish at the alkaline pH of process waters.
“The reactivity of ultramafic mine waste is enhanced by increased surface area due to mineral processing, yet dissolution rates remain sluggish at the alkaline pH of process waters [11,38,[52][53][54][55].”
From Strategizing carbon-neutral mines: A case for pilot projects (2014) · cites this paper as [55]
pH-dependent dissolution rates for lizardite, chrysotile, forsterite, and brucite have been experimentally determined and generally increase with increasing acidity.
“The pH-dependent dissolution rates for some common ultramafic tailings minerals such lizardite [55], chrysotile [38], forsterite [53] and brucite [54] have been experimentally determined and generally increase with increasing acidity.”
From Strategizing carbon-neutral mines: A case for pilot projects (2014) · cites this paper as [55]
Daval et al. demonstrated that the dissolution rate of lizardite is increased by 5 times at pH 5 in solutions equilibrated with CO2 as compared to CO2-free solutions at the same pH.
“However, Daval et al. demonstrated that the dissolution rate of lizardite is increased by 5 times at pH 5 in solutions equilibrated with CO 2 as compared to CO 2 -free solutions at the same pH [55]”
From Strategizing carbon-neutral mines: A case for pilot projects (2014) · cites this paper as [55]
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Self-citation
- Authors
- Daval, D., Hellmann, R., Martinez, I., Gangloff, S., & Guyot, F.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Institut de physique du globe de Paris (FR)
- Corresponding author
- Daval, Damien
- Venue
- Chemical Geology
- Publisher
- Elsevier BV
- Published
- 2013-08
- Volume
- 351
- Pages
- 245-256
- ISSN
- 0009-2541 (ISSN-L)
- OpenAlex
- W2102403376
- Cited by
- 115
- References
- 97
- Citations by year
- 2026: 7 · 2025: 18 · 2024: 20 · 2023: 3 · 2022: 7 · 2021: 9 · 2020: 7 · 2019: 11 · 2018: 2 · 2017: 7 · 2016: 7 · 2015: 7 · 2014: 9 · 2013: 1
- FWCI
- 6.65
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Geology (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
- Keywords
- lizardite, dissolution kinetics, pH dependence, temperature dependence, elevated pCO2, carbonation, magnesium ion release, silicon release, activation energy, olivine, pyroxene
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