Sorption of naphthalene and 1-naphthol by biochars of orange peels with different pyrolytic temperatures
Abstract
Biochars, derived from biomass, are increasingly recognized as an environmental-friendly sorbent to abate organic pollutants. Sorption variations of biochars with their pyrolytic temperatures are evaluated. Nine biochars of orange peels with different pyrolytic temperatures (150-700 degrees C, referred as OP150-OP700) were characterized via elemental analysis, BET-N(2) surface area, and Fourier transform infrared spectroscopy. Sorption of naphthalene and 1-naphthol by the biochars in water are compared. Sorption isotherms varied from linear to Freundlich with increasing pyrolytic temperature. The respective contributions of adsorption and partition to total sorption were correlated with biochars' structural parameters. For OP150-OP600, sorption of 1-naphthol was significantly larger than naphthalene due to the former owning additional specific interactions. For 1-naphthol with high concentrations, the OP200 exhibited the maximal sorption capacity due to its largest partition and high adsorption among nine biochars. For 1-naphthol with low concentrations and naphthalene, the OP700 displayed the maximal sorption capacity. These observations provide a reference to the use of biochars as engineered sorbents for environmental applications.
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The pore size and specific surface areas of biochar increase proportionally with pyrolysis temperature.
“They showed that the pore size and the specific surface areas of biochar increase proportionally with the pyrolysis temperature.”
From Mechanisms and adsorption capacities of biochar for the removal of organic and inorganic pollutants from industrial wastewater (2021) · cites this paper as Chen and Chen (2009)
Destruction of aliphatic alkyls and ester groups and exposure of the aromatic lignin core under higher pyrolysis temperatures may result in increased surface area.
“the destruction of aliphatic alkyls and ester groups as well as the exposure of the aromatic lignin core under higher pyrolysis temperatures may result in increased surface area”
From Biochar physicochemical properties: pyrolysis temperature and feedstock kind effects (2020) · cites this paper as Chen and Chen 2009
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- Authors
- Chen, B., & Chen, Z.
- Affiliations
- Zhejiang University (CN)
- Corresponding author
- Chen, Baoliang
- Venue
- Chemosphere
- Publisher
- Elsevier BV
- Published
- 2009-06
- Volume
- 76
- Issue
- 1
- Pages
- 127-133
- ISSN
- 0045-6535 (ISSN-L)
- OpenAlex
- W2083918445
- Cited by
- 654
- References
- 25
- Citations by year
- 2026: 19 · 2025: 33 · 2024: 45 · 2023: 36 · 2022: 55 · 2021: 57 · 2020: 62 · 2019: 45 · 2018: 53 · 2017: 56 · 2016: 35 · 2015: 50 · 2014: 40 · 2013: 27 · 2012: 17
- FWCI
- 13.74
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemosphere (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China
- Program for New Century Excellent Talents in University
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Keywords
- biochar, orange peel, pyrolysis temperature, naphthalene, 1-naphthol, organic pollutant sorption, Freundlich isotherm, adsorption, partitioning, biomass-derived adsorbents
- MeSH terms
- Adsorption, Charcoal, Naphthalenes, Naphthols, Temperature, Water Pollutants, Chemical, Spectroscopy, Fourier Transform Infrared, Citrus sinensis
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