Synthesis of natural deep eutectic solvents using a mixture design for extraction of animal and plant samples prior to ICP-MS analysis
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Solvents with both low density and viscosity have the advantage of higher extraction efficiency due to lower diffusivity and consequently higher mass transfer. In this study, a mixture design was performed for the synthesis of three different natural deep eutectic solvents (NADES) using citric acid, malic acid, and xylitol. The optimized proportion for each of the three solvents synthesized was selected based on density and viscosity values. The NADES were characterized by infrared spectroscopy analysis, that showed characteristic bands of the initial reagents and the presence of hydrogen bonds confirming the formation of each deep eutectic solvent. Then, the NADES were used as solvents in ultrasound-assisted extraction (UAE) and microwave-assisted extraction (MAE) of biological tissue and plant material samples for the determination of As, Cd, Hg, Pb, Se, and V by inductively coupled plasma mass spectrometry (ICP-MS). The results for the proposed methods were compared to microwave-assisted acid digestion (MW-AD). The extraction recoveries ranged from 80 to 120% for most of the elements determined. The use of NADES as carbon sources improved the sensitivity of the As and Cd analyses, due to charge transfer reactions between the analyte and C+ and/or other carbon species. In addition, the Analytical Eco-Scale was used to assess the greenness of the proposed analytical procedures (UAE and MAE). It showed that the UAE and MAE methods provided excellent green analyses, while the MW-AD method was rated as an acceptable green procedure.
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MAE and UAE have shown promise for the determination of inorganic analytes in plant and biological tissue samples.
“These methodologies have been used for the determination of organic analytes [18] and have shown promise for the determination of inorganic analytes in plant and biological tissue samples [19,20].”
From Greenness of procedures using NADES in the preparation of vegetal samples: Comparison of five green metrics (2022) · cites this paper as [20]
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- Authors
- Santana, A. P. R., Andrade, D. F., Guimarães, T. G. S., Amaral, C. D. B., Oliveira, A., & Gonzalez, M. H.
- Affiliations
- Universidade Estadual Paulista (Unesp) (BR)
- Universidade Federal de São Carlos (BR)
- Universidade Federal do Paraná (BR)
- Corresponding author
- Gonzalez, Mario H.
- ORCID
- Venue
- Talanta
- Publisher
- Elsevier BV
- Published
- 2020-08
- Volume
- 216
- Pages
- 120956
- ISSN
- 0039-9140 (ISSN-L)
- OpenAlex
- W3014291230
- Cited by
- 69
- References
- 59
- Citations by year
- 2026: 13 · 2025: 16 · 2024: 12 · 2023: 11 · 2022: 8 · 2021: 7 · 2020: 2
- FWCI
- 3.63
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- Locations
- Talanta (publishedVersion)
- PubMed (publishedVersion)
- LA Referencia (Red Federada de Repositorios Institucionales de Publicaciones Científicas) (submittedVersion, other-oa)
- Funders
- Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
- Fundação de Amparo à Pesquisa do Estado de São Paulo (2017/18531\u20133, 2015/08873\u20139, 2016/17304\u20130)
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Chemistry › Inorganic Chemistry › Radioactive element chemistry and processing
- Keywords
- natural deep eutectic solvents, citric acid, malic acid, xylitol, ultrasound-assisted extraction, microwave-assisted extraction, acid digestion, trace element analysis, arsenic, cadmium, mercury, lead, selenium, vanadium, green analytical chemistry, Analytical Eco-Scale, plant material, hydrogen bonding
- MeSH terms
- Ultrasonic Waves, Animals, Hydrogen-Ion Concentration, Malates, Microwaves, Plants, Solvents, Mass Spectrometry, Viscosity, Xylitol, Metals, Heavy, Citric Acid
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