Monolayer-Protected Cluster Molecules

Templeton, Allen C., Wuelfing, W. Peter, Murray, Royce W.·2000·Accounts of Chemical Research

Open this paper in CoChat — free account

Abstract

In this report, we evaluate the present state of the rapidly emerging field of monolayer-protected cluster (MPC) molecules with regard to their synthesis and monolayer functionalization, their core and monolayer structure, their composition, and their properties. Finally, we canvass some of the important remaining research opportunities involving MPCs.

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Integrity signals

Registry

Crossref · 10.1021/ar9602664

Cites

Statistics

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications toward Biology, Catalysis, and Nanotechnology
Daniel, M.-C., & Astruc, D. (2004) · Chemical Reviews · doi:10.1021/cr030698+ · Cited by 12,446
Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200802248 · Cited by 5,702
Gold Nanoparticles in Chemical and Biological Sensing
Saha, K., Agasti, S. S., Kim, C., Li, X., & Rotello, V. M. (2012) · Chemical Reviews · doi:10.1021/cr2001178 · Cited by 4,620
Interparticle Coupling Effect on the Surface Plasmon Resonance of Gold Nanoparticles: From Theory to Applications
Ghosh, S. K., & Pal, T. (2007) · Chemical Reviews · doi:10.1021/cr0680282 · Cited by 2,782
Exploitation of Localized Surface Plasmon Resonance
Hutter, E., & Fendler, J. H. (2004) · Advanced Materials · doi:10.1002/adma.200400271 · Cited by 2,726
Gold nanoparticles in delivery applications☆
GHOSH, P., HAN, G., DE, M., KIM, C., & ROTELLO, V (2008) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2008.03.016 · Cited by 2,694
Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å Resolution
Jadzinsky, P. D., Calero, G., Ackerson, C. J., Bushnell, D. A., & Kornberg, R. D. (2007) · Science · doi:10.1126/science.1148624 · Cited by 2,654
Self-Assembly of Colloidal Nanocrystals: From Intricate Structures to Functional Materials
Boles, M. A., Engel, M., & Talapin, D. V. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00196 · Cited by 2,051
Photophysical, Photochemical and Photocatalytic Aspects of Metal Nanoparticles
Kamat, P. V. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0209289 · Cited by 1,924
A unified view of ligand-protected gold clusters as superatom complexes
Walter, M., Akola, J., Lopez-Acevedo, O., Jadzinsky, P. D., Calero, G., Ackerson, C. J., Whetten, R. L., Grönbeck, H., & Häkkinen, H. (2008) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0801001105 · Cited by 1,742
Glutathione-Protected Gold Clusters Revisited: Bridging the Gap between Gold(I)−Thiolate Complexes and Thiolate-Protected Gold Nanocrystals
Negishi, Y., Nobusada, K., & Tsukuda, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja042218h · Cited by 1,646
Seeding Growth for Size Control of 5−40 nm Diameter Gold Nanoparticles
Jana, N. R., Gearheart, L., & Murphy, C. J. (2001) · Langmuir · doi:10.1021/la0104323 · Cited by 1,359
Catalytic nanoarchitectures—The importance of nothing and the unimportance of periodicity
Rolison, D. R. (2003) · Science · doi:10.1126/science.1082332 · Cited by 1,037
Laser ablation synthesis in solution and size manipulation of noble metal nanoparticles
Amendola, V., & Meneghetti, M. (2009) · Physical Chemistry Chemical Physics · doi:10.1039/b900654k · Cited by 1,020
Charge Transfer on the Nanoscale: Current Status
Adams, D. M., Brus, L., Chidsey, C. E. D., Creager, S., Creutz, C., Kagan, C. R., Kamat, P. V., Lieberman, M., Lindsay, S., Marcus, R. A., et al. (2003) · The Journal of Physical Chemistry B · doi:10.1021/jp0268462 · Cited by 1,013
State of the art in gold nanoparticle synthesis
Zhao, P., Li, N., & Astruc, D. (2013) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2012.09.002 · Cited by 964
Self-Assembled Nanoparticle Probes for Recognition and Detection of Biomolecules
Maxwell, D. J., Taylor, J. R., & Nie, S. (2002) · Journal of the American Chemical Society · doi:10.1021/ja025814p · Cited by 890
Synthesis, Characterization, and Applications of Dendrimer-Encapsulated Nanoparticles
Scott, R. W. J., Wilson, O. M., & Crooks, R. M. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp0469665 · Cited by 866
Fluorescent Gold Nanoclusters: Recent Advances in Sensing and Imaging
Chen, L.-Y., Wang, C.-W., Yuan, Z., & Chang, H.-T. (2015) · Analytical Chemistry · doi:10.1021/ac503636j · Cited by 848
Metal–Organic Framework Nanoparticles
Wang, S., McGuirk, C. M., d'Aquino, A., Mason, J. A., & Mirkin, C. A. (2018) · Advanced Materials · doi:10.1002/adma.201800202 · Cited by 833
Glutathione-Mediated Delivery and Release Using Monolayer Protected Nanoparticle Carriers
Hong, R., Han, G., Fernández, J. M., Kim, B.-J., Forbes, N. S., & Rotello, V. M. (2006) · Journal of the American Chemical Society · doi:10.1021/ja056726i · Cited by 817
Building plasmonic nanostructures with DNA
Tan, S. J., Campolongo, M. J., Luo, D., & Cheng, W. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2011.49 · Cited by 802
All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures
Yang, H., Wang, Y., Huang, H., Gell, L., Lehtovaara, L., Malola, S., Häkkinen, H., & Zheng, N. (2013) · Nature Communications · doi:10.1038/ncomms3422 · Cited by 786
A nanometre-scale electronic switch consisting of a metal cluster and redox-addressable groups
Gittins, D. I., Bethell, D., Schiffrin, D. J., & Nichols, R. J. (2000) · Nature · doi:10.1038/35040518 · Cited by 744
Evidence for Seed-Mediated Nucleation in the Chemical Reduction of Gold Salts to Gold Nanoparticles
Jana, N. R., Gearheart, L., & Murphy, C. J. (2001) · Chemistry of Materials · doi:10.1021/cm000662n · Cited by 718
A Study of the Surface Plasmon Resonance of Silver Nanoparticles by the Discrete Dipole Approximation Method: Effect of Shape, Size, Structure, and Assembly
Amendola, V., Bakr, O. M., & Stellacci, F. (2010) · Plasmonics · doi:10.1007/s11468-009-9120-4 · Cited by 695
Chromophore-Functionalized Gold Nanoparticles
Thomas, K. G., & Kamat, P. V. (2003) · Accounts of Chemical Research · doi:10.1021/ar030030h · Cited by 686
Effect of Nanoparticle Surface Charge at the Plasma Membrane and Beyond
Arvizo, R. R., Miranda, O. R., Thompson, M. A., Pabelick, C. M., Bhattacharya, R., Robertson, J. D., Rotello, V. M., Prakash, Y. S., & Mukherjee, P. (2010) · Nano Letters · doi:10.1021/nl101140t · Cited by 621
Synthesis of Gold Nanoparticles Modified with Ionic Liquid Based on the Imidazolium Cation
Itoh, H., Naka, K., & Chujo, Y. (2004) · Journal of the American Chemical Society · doi:10.1021/ja039895g · Cited by 559
Luminescent metal complexes of d6, d8 and d10 transition metal centres
Yam, V. W.-W., & Wong, K. M.-C. (2011) · Chemical Communications · doi:10.1039/c1cc13767k · Cited by 553
Nanoparticles: Emerging carriers for drug delivery
Mudshinge, S. R., Deore, A. B., Patil, S., & Bhalgat, C. M. (2011) · Saudi Pharmaceutical Journal · doi:10.1016/j.jsps.2011.04.001 · Cited by 543
Manipulation of Charge Transfer Across Semiconductor Interface. A Criterion That Cannot Be Ignored in Photocatalyst Design
Kamat, P. V. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201629p · Cited by 543
Surface Modification and Functionalization of Metal and Metal Oxide Nanoparticles by Organic Ligands
Neouze, M.-A., & Schubert, U. (2008) · Monatshefte für Chemie - Chemical Monthly · doi:10.1007/s00706-007-0775-2 · Cited by 538
Ultrasensitive Immunosensor for Cancer Biomarker Proteins Using Gold Nanoparticle Film Electrodes and Multienzyme-Particle Amplification
Mani, V., Chikkaveeraiah, B. V., Patel, V., Gutkind, J. S., & Rusling, J. F. (2009) · ACS Nano · doi:10.1021/nn800863w · Cited by 532
Nanoparticles: Scaffolds and Building Blocks
Shenhar, R., & Rotello, V. M. (2003) · Accounts of Chemical Research · doi:10.1021/ar020083j · Cited by 521
Nanoparticles functionalised with reversible molecular and supramolecular switches
Klajn, R., Stoddart, J. F., & Grzybowski, B. A. (2010) · Chemical Society Reviews · doi:10.1039/b920377j · Cited by 517
The Story of a Monodisperse Gold Nanoparticle: Au25L18
Parker, J. F., Fields-Zinna, C. A., & Murray, R. W. (2010) · Accounts of Chemical Research · doi:10.1021/ar100048c · Cited by 503
Self-citation
Charge Transport in Nanoparticle Assemblies
Zabet-Khosousi, A., & Dhirani, A.-A. (2008) · Chemical Reviews · doi:10.1021/cr0680134 · Cited by 503
Green Emission to Probe Photoinduced Charging Events in ZnO−Au Nanoparticles. Charge Distribution and Fermi-Level Equilibration
Subramanian, V., Wolf, E. E., & Kamat, P. V. (2003) · The Journal of Physical Chemistry B · doi:10.1021/jp0275037 · Cited by 503
Beyond superquenching: Hyper-efficient energy transfer from conjugated polymers to gold nanoparticles
Fan, C., Wang, S., Hong, J. W., Bazan, G. C., Plaxco, K. W., & Heeger, A. J. (2003) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1132025100 · Cited by 502
A General Synthetic Strategy for Oxide-Supported Metal Nanoparticle Catalysts
Zheng, N., & Stucky, G. D. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0659929 · Cited by 502
Photochemistry on Metal Nanoparticles
Watanabe, K., Menzel, D., Nilius, N., & Freund, H.-J. (2006) · Chemical Reviews · doi:10.1021/cr050167g · Cited by 486
Paclitaxel-Functionalized Gold Nanoparticles
Gibson, J. D., Khanal, B. P., & Zubarev, E. R. (2007) · Journal of the American Chemical Society · doi:10.1021/ja075181k · Cited by 484
Gold nanoparticle platforms as drug and biomacromolecule delivery systems
Duncan, B., Kim, C., & Rotello, V. M. (2010) · Journal of Controlled Release · doi:10.1016/j.jconrel.2010.06.004 · Cited by 469
Selective Gold-Nanoparticle-Based “Turn-On” Fluorescent Sensors for Detection of Mercury(II) in Aqueous Solution
Huang, C.-C., & Chang, H.-T. (2006) · Analytical Chemistry · doi:10.1021/ac061487i · Cited by 462
Transition-metal nanocluster stabilization for catalysis: A critical review of ranking methods and putative stabilizers
Ott, L. S., & Finke, R. G. (2007) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2006.08.016 · Cited by 454
Transition‐metal nanoparticles: synthesis, stability and the leaching issue
Pachón, L. D., & Rothenberg, G. (2008) · Applied Organometallic Chemistry · doi:10.1002/aoc.1382 · Cited by 443
Thermosensitive Gold Nanoparticles
Zhu, M.-Q., Wang, L.-Q., Exarhos, G. J., & Li, A. D. Q. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038544z · Cited by 437
Fluorescent Ag Clusters via a Protein-Directed Approach as a Hg(II) Ion Sensor
Guo, C., & Irudayaraj, J. (2011) · Analytical Chemistry · doi:10.1021/ac1032403 · Cited by 422
Quantum-dot nanocrystals for ultrasensitive biological labeling and multicolor optical encoding
Gao, X., Chan, W. C. W., & Nie, S. (2002) · Journal of Biomedical Optics · doi:10.1117/1.1506706 · Cited by 422
Functionalized gold nanoparticles: Synthesis, structure and colloid stability
Zhou, J., Ralston, J., Sedev, R., & Beattie, D. A. (2009) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2008.12.002 · Cited by 417
Linkers for anchoring sensitizers to semiconductor nanoparticles
Galoppini, E. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.03.016 · Cited by 417
Recent advances in polymer protected gold nanoparticles: synthesis, properties and applications
Shan, J., & Tenhu, H. (2007) · Chemical Communications · doi:10.1039/b707740h · Cited by 411
Modulating Pharmacokinetics, Tumor Uptake and Biodistribution by Engineered Nanoparticles
Arvizo, R. R., Miranda, O. R., Moyano, D. F., Walden, C. A., Giri, K., Bhattacharya, R., Robertson, J. D., Rotello, V. M., Reid, J. M., & Mukherjee, P. (2011) · PLoS ONE · doi:10.1371/journal.pone.0024374 · Cited by 403
Nanoparticles in Liquid Crystals: Synthesis, Self-Assembly, Defect Formation and Potential Applications
Hegmann, T., Qi, H., & Marx, V. M. (2007) · Journal of Inorganic and Organometallic Polymers and Materials · doi:10.1007/s10904-007-9140-5 · Cited by 396
Electrochemistry and Electrogenerated Chemiluminescence of CdTe Nanoparticles
Bae, Y., Myung, N., & Bard, A. J. (2004) · Nano Letters · doi:10.1021/nl049516x · Cited by 386
Gold nanoparticle probes
Wang, Z., & Ma, L. (2009) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2009.01.005 · Cited by 383
Know Thy Nano Neighbor. Plasmonic versus Electron Charging Effects of Metal Nanoparticles in Dye-Sensitized Solar Cells
Choi, H., Chen, W. T., & Kamat, P. V. (2012) · ACS Nano · doi:10.1021/nn301137r · Cited by 381
Capture, Store, and Discharge. Shuttling Photogenerated Electrons across TiO2–Silver Interface
Takai, A., & Kamat, P. V. (2011) · ACS Nano · doi:10.1021/nn202294b · Cited by 371
Inhibition of Herpes Simplex Virus Type 1 Infection by Silver Nanoparticles Capped with Mercaptoethane Sulfonate
Baram-Pinto, D., Shukla, S., Perkas, N., Gedanken, A., & Sarid, R. (2009) · Bioconjugate Chemistry · doi:10.1021/bc900215b · Cited by 368
Sputter deposition onto ionic liquids: Simple and clean synthesis of highly dispersed ultrafine metal nanoparticles
Torimoto, T., Okazaki, K.-I., Kiyama, T., Hirahara, K., Tanaka, N., & Kuwabata, S. (2006) · Applied Physics Letters · doi:10.1063/1.2404975 · Cited by 368
Giant Multiporphyrin Arrays as Artificial Light-Harvesting Antennas
Imahori, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp038036b · Cited by 353
Entrapment of Hydrophobic Drugs in Nanoparticle Monolayers with Efficient Release into Cancer Cells
Kim, C. K., Ghosh, P., Pagliuca, C., Zhu, Z.-J., Menichetti, S., & Rotello, V. M. (2009) · Journal of the American Chemical Society · doi:10.1021/ja808137c · Cited by 340
Novel one-step synthesis of amine-stabilized aqueous colloidal gold nanoparticlesElectronic supplementary information (ESI) available: FTIR, TEM, UV-vis and XRD results. See http://www.rsc.org/suppdata/jm/b4/b402823f/
Aslam, M., Fu, L., Su, M., Vijayamohanan, K., & Dravid, V. P. (2004) · Journal of Materials Chemistry · doi:10.1039/b402823f · Cited by 324
Synthesis and Optical Properties of Anisotropic Metal Nanoparticles
Hao, E., Schatz, G. C., & Hupp, J. T. (2004) · Journal of Fluorescence · doi:10.1023/b:jofl.0000031815.71450.74 · Cited by 312
Generation of Cytotoxic Singlet Oxygen via Phthalocyanine-Stabilized Gold Nanoparticles: A Potential Delivery Vehicle for Photodynamic Therapy
Hone, D. C., Walker, P. I., Evans-Gowing, R., FitzGerald, S., Beeby, A., Chambrier, I., Cook, M. J., & Russell, D. A. (2002) · Langmuir · doi:10.1021/la0256230 · Cited by 306
Chiral Bisphosphine BINAP-Stabilized Gold and Palladium Nanoparticles with Small Size and Their Palladium Nanoparticle-Catalyzed Asymmetric Reaction
Tamura, M., & Fujihara, H. (2003) · Journal of the American Chemical Society · doi:10.1021/ja0369055 · Cited by 302
Small is different: energetic, structural, thermal, and mechanical properties of passivated nanocluster assemblies
Landman, U., & Luedtke, W. D. (2004) · Faraday Discussions · doi:10.1039/b312640b · Cited by 278
Light-controlled nitric oxide delivering molecular assemblies
Sortino, S. (2010) · Chemical Society Reviews · doi:10.1039/b908663n · Cited by 277
Silver-Enhanced Colloidal Gold Electrochemical Stripping Detection of DNA Hybridization
Wang, J., Polsky, R., & Xu, D. (2001) · Langmuir · doi:10.1021/la011002f · Cited by 273
Control of Protein Structure and Function through Surface Recognition by Tailored Nanoparticle Scaffolds
Hong, R., Fischer, N. O., Verma, A., Goodman, C. M., Emrick, T., & Rotello, V. M. (2004) · Journal of the American Chemical Society · doi:10.1021/ja037470o · Cited by 273
Multimodal drug delivery using gold nanoparticles
Kim, C.-K., Ghosh, P., & Rotello, V. M. (2009) · Nanoscale · doi:10.1039/b9nr00112c · Cited by 267
Transformation Chemistry of Gold Nanoclusters: From One Stable Size to Another
Zeng, C., Chen, Y., Das, A., & Jin, R. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01150 · Cited by 258
Tunable Inhibition and Denaturation of α-Chymotrypsin with Amino Acid-Functionalized Gold Nanoparticles
You, C.-C., De, M., Han, G., & Rotello, V. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0512881 · Cited by 255
Nanostructured catalysts in fuel cells
Zhong, C.-J., Luo, J., Fang, B., Wanjala, B. N., Njoki, P. N., Loukrakpam, R., & Yin, J. (2010) · Nanotechnology · doi:10.1088/0957-4484/21/6/062001 · Cited by 198
Nitric Oxide Donors for Cardiovascular Implant Applications
Naghavi, N., de Mel, A., Alavijeh, O. S., Cousins, B. G., & Seifalian, A. M. (2013) · Small · doi:10.1002/smll.201200458 · Cited by 188
Stability Studies on Nanomaterials Used in Drugs
Selvamani, V. (2019) · Characterization and Biology of Nanomaterials for Drug Delivery · doi:10.1016/b978-0-12-814031-4.00015-5 · Cited by 151
Water-Soluble Nitric Oxide-Releasing Gold Nanoparticles
Polizzi, M. A., Stasko, N. A., & Schoenfisch, M. H. (2007) · Langmuir · doi:10.1021/la0633841 · Cited by 133
Gold nanoparticles: an era in bionanotechnology
Kumar, D., Saini, N., Jain, N., Sareen, R., & Pandit, V. (2013) · Expert Opinion on Drug Delivery · doi:10.1517/17425247.2013.749854 · Cited by 96

Authors: Templeton, A. C., Wuelfing, W. P., & Murray, R. W.
Venue: Accounts of Chemical Research
Publisher: American Chemical Society (ACS)
Published: 1999-11-18
Volume: 33
Issue: 1
Pages: 27-36
ISSN: 0001-4842 (ISSN-L)
1520-4898
DOI: 10.1021/ar9602664
OpenAlex: W2033096857
Cited by: 2,392
References: 0
FWCI: 52.32
Type: journal article
Language: en
Open access: closed

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.

Monolayer-Protected Cluster Molecules

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Self-check

Citations

Cited by

Metadata

Record

About these checks

Data sources