The DOI matches its Crossref record; 64 of the 64 references it cites were found in a registry or an index.
Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways
Abstract
The utilization of solar energy for the conversion of CO 2 into valuable organic products is one of the best solutions to solve the problems of global warming and energy shortage. The development of photocatalysts capable of reducing CO 2 under visible light, especially those containing earth-abundant metals, is significant. Herein we report that a series of earth-abundant Fe-containing MOFs (MIL-101(Fe), MIL-53(Fe), MIL-88B(Fe)) show photocatalytic activity for CO 2 reduction to give formate under visible light irradiation. The direct excitation of the Fe–O clusters in these MOFs induces the electron transfer from O 2– to Fe 3+ to form Fe 2+, which is responsible for the photocatalytic CO 2 reduction. Among the three investigated Fe-based MOFs, MIL-101(Fe) showed the best activity due to the existence of the coordination unsaturated Fe sites in its structure. All three amine-functionalized Fe-containing MOFs (NH 2 -MIL-101(Fe), NH 2 -MIL-53(Fe) and NH 2 -MIL-88B(Fe)) showed enhanced photocatalytic activity in comparison to the unfunctionalized MOF, due to the existence of dual excitation pathways: i.e., excitation of an NH 2 functionality followed by an electron transfer to the Fe center in addition to the direct excitation of Fe–O clusters.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Selective gas adsorption and separation in metal–organic frameworks
Li, J.-R., Kuppler, R. J., & Zhou, H.-C. (2009) · Chemical Society Reviews · doi:10.1039/b802426j · Cited by 8,932
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Carbon Dioxide Capture: Prospects for New Materials
D'Alessandro, D. M., Smit, B., & Long, J. R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000431 · Cited by 4,046
Nano‐photocatalytic Materials: Possibilities and Challenges
Tong, H., Ouyang, S., Bi, Y., Umezawa, N., Oshikiri, M., & Ye, J. (2012) · Advanced Materials · doi:10.1002/adma.201102752 · Cited by 3,827
Engineering Metal Organic Frameworks for Heterogeneous Catalysis
Corma, A., García, H., & Llabrés i Xamena, F. X. (2010) · Chemical Reviews · doi:10.1021/cr9003924 · Cited by 3,478
Enantioselective catalysis with homochiral metal–organic frameworks
Ma, L., Abney, C., & Lin, W. (2009) · Chemical Society Reviews · doi:10.1039/b807083k · Cited by 3,109
Photocatalytic Reduction of CO2 on TiO2 and Other Semiconductors
Habisreutinger, S. N., Schmidt‐Mende, L., & Stolarczyk, J. K. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201207199 · Cited by 2,989
Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders
INOUE, T., FUJISHIMA, A., KONISHI, S., & HONDA, K. (1979) · Nature · doi:10.1038/277637a0 · Cited by 2,919
Industrial applications of metal–organic frameworks
Czaja, A. U., Trukhan, N., & Müller, U. (2009) · Chemical Society Reviews · doi:10.1039/b804680h · Cited by 2,341
Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules
Chen, B., Xiang, S., & Qian, G. (2010) · Accounts of Chemical Research · doi:10.1021/ar100023y · Cited by 2,033
Cited by
Carbon capture and conversion using metal–organic frameworks and MOF-based materials
Ding, M., Flaig, R. W., Jiang, H.-L., & Yaghi, O. M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00829a · Cited by 2,616
Cocatalysts for Selective Photoreduction of CO2into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,304
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
Huang, Y.-B., Liang, J., Wang, X.-S., & Cao, R. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00250a · Cited by 1,908
The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
Trickett, C. A., Helal, A., Al-Maythalony, B. A., Yamani, Z. H., Cordova, K. E., & Yaghi, O. M. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2017.45 · Cited by 1,524
Recent Advances in Heterogeneous Photocatalytic CO 2 Conversion to Solar Fuels
Li, K., Peng, B., & Peng, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02089 · Cited by 1,355
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
Kornienko, N., Zhao, Y., Kley, C. S., Zhu, C., Kim, D., Lin, S., Chang, C. J., Yaghi, O. M., & Yang, P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08212 · Cited by 1,158
Kökçam-Demir, Ü., Goldman, A., Esrafili, L., Gharib, M., Morsali, A., Weingart, O., & Janiak, C. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00609e · Cited by 895
Simultaneously efficient adsorption and photocatalytic degradation of tetracycline by Fe-based MOFs
Wang, D., Jia, F., Wang, H., Chen, F., Fang, Y., Dong, W., Zeng, G., Li, X., Yang, Q., & Yuan, X. (2018) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2018.02.067 · Cited by 802
Self-citationPristine Metal–Organic Frameworks and their Composites for Energy Storage and Conversion
Liang, Z., Qu, C., Guo, W., Zou, R., & Xu, Q. (2018) · Advanced Materials · doi:10.1002/adma.201702891 · Cited by 787
The role of reticular chemistry in the design of CO2 reduction catalysts
Diercks, C. S., Liu, Y., Cordova, K. E., & Yaghi, O. M. (2018) · Nature Materials · doi:10.1038/s41563-018-0033-5 · Cited by 721
Plasmon-Enhanced Photocatalytic CO2 Conversion within Metal–Organic Frameworks under Visible Light
Choi, K. M., Kim, D., Rungtaweevoranit, B., Trickett, C. A., Barmanbek, J. T. D., Alshammari, A. S., Yang, P., & Yaghi, O. M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11027 · Cited by 632
Gao, Y., Li, S., Li, Y., Yao, L., & Zhang, H. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.09.005 · Cited by 622
Multifunctional Metal–Organic Frameworks for Photocatalysis
Wang, S., & Wang, X. (2015) · Small · doi:10.1002/smll.201500084 · Cited by 615
Metal–Organic-Framework-Based Materials for Antimicrobial Applications
Li, R., Chen, T., & Pan, X. (2021) · ACS Nano · doi:10.1021/acsnano.0c09617 · Cited by 555
Li, X., Wen, J., Low, J., Fang, Y., & Yu, J. (2014) · Science China Materials · doi:10.1007/s40843-014-0003-1 · Cited by 517
CuInS2 sensitized TiO2 hybrid nanofibers for improved photocatalytic CO2 reduction
Xu, F., Zhang, J., Zhu, B., Yu, J., & Xu, J. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.02.042 · Cited by 490
Metal organic framework based catalysts for CO2 conversion
Maina, J. W., Pozo-Gonzalo, C., Kong, L., Schütz, J., Hill, M., & Dumée, L. F. (2017) · Materials Horizons · doi:10.1039/c6mh00484a · Cited by 423
Boutin, E., Merakeb, L., Ma, B., Boudy, B., Wang, M., Bonin, J., Anxolabéhère-Mallart, E., & Robert, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00218f · Cited by 423
Wang, X.-K., Liu, J., Zhang, L., Dong, L.-Z., Li, S.-L., Kan, Y.-H., Li, D.-S., & Lan, Y.-Q. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04887 · Cited by 384
Metal–organic frameworks for photocatalysis
Li, Y., Xu, H., Ouyang, S., & Ye, J. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp05885f · Cited by 362
Conferring Ti‐Based MOFs with Defects for Enhanced Sonodynamic Cancer Therapy
Liang, S., Xiao, X., Bai, L., Liu, B., Yuan, M., Ma, P., Pang, M., Cheng, Z., & Lin, J. (2021) · Advanced Materials · doi:10.1002/adma.202100333 · Cited by 359
Lu, M., Li, Q., Liu, J., Zhang, F.-M., Zhang, L., Wang, J.-L., Kang, Z.-H., & Lan, Y.-Q. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.05.033 · Cited by 334
Programmable Logic in Metal–Organic Frameworks for Catalysis
Shen, Y., Pan, T., Wang, L., Ren, Z., Zhang, W., & Huo, F. (2021) · Advanced Materials · doi:10.1002/adma.202007442 · Cited by 316
Chen, D., Xing, H., Wang, C., & Su, Z. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta00429f · Cited by 286
Alkhatib, I. I., Garlisi, C., Pagliaro, M., Al-Ali, K., & Palmisano, G. (2020) · Catalysis Today · doi:10.1016/j.cattod.2018.09.032 · Cited by 284
Liao, X., Wang, F., Wang, F., Cai, Y., Yao, Y., Teng, B.-T., Hao, Q., & Shuxiang, L. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118064 · Cited by 283
Wang, C.-C., Wang, X., & Liu, W. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.123601 · Cited by 258
Self-citationPolyoxometalate@Metal–Organic Framework Composites as Effective Photocatalysts
Liu, Y., Tang, C., Cheng, M., Chen, M., Chen, S., Lei, L., Chen, Y., Yi, H., Fu, Y., & Li, L. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c03866 · Cited by 253
Wang, J., Cherevan, A. S., Hannecart, C., Naghdi, S., Nandan, S. P., Gupta, T., & Eder, D. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119626 · Cited by 217
Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Hou, S., Dong, J., & Zhao, B. (2020) · Advanced Materials · doi:10.1002/adma.201806163 · Cited by 142
Metadata
- Authors
- Wang, D., Huang, R., Liu, W., Sun, D., & Li, Z.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-31
- Volume
- 4
- Issue
- 12
- Pages
- 4254-4260
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2322118693
- Cited by
- 869
- References
- 64
- FWCI
- 13.86
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
