Cited by 423

The DOI matches its Crossref record; 61 of the 61 references it cites were found in a registry or an index.

Multifunctional PdAg@MIL-101 for One-Pot Cascade Reactions: Combination of Host–Guest Cooperation and Bimetallic Synergy in Catalysis

Chen, Yu-Zhen, Zhou, Yu-Xiao, Wang, Hengwei, Lu, Junling, Uchida, Takeyuki, Xu, Qiang, Yu, Shu-Hong, Jiang, Hai-Long·2015·ACS Catalysis

DOI 10.1021/cs501953d

Open this paper in CoChat — free account

Abstract

Metal nanoparticles (NPs) stabilized by metal–organic frameworks (MOFs) are very promising for catalysis, while reports on their cooperative catalysis for a cascade reaction have been very rare. In this work, Pd NPs incorporated into a MOF, MIL-101, have jointly completed a tandem reaction on the basis of MOF Lewis acidity and Pd NPs. Subsequently, ultrafine PdAg alloy NPs (∼1.5 nm) have been encapsulated into MIL-101. The obtained multifunctional PdAg@MIL-101 exhibits good catalytic activity and selectivity in cascade reactions under mild conditions, on the basis of the combination of host–guest cooperation and bimetallic synergy, where MIL-101 affords Lewis acidity and Pd offers hydrogenation activity while Ag greatly improves selectivity to the target product. As far as we know, this is the first work on bimetallic NP@MOFs as multifunctional catalysts with multiple active sites (MOF acidity and bimetallic species) that exert respective functions and cooperatively catalyze a one-pot cascade reaction.

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Integrity signals

Registry

Crossref · 10.1021/cs501953d

Cites

61 of 61 references verified0 citation errors · 0 not checkable

Statistics

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Introduction to Metal–Organic Frameworks
Zhou, H.-C., Long, J. R., & Yaghi, O. M. (2012) · Chemical Reviews · doi:10.1021/cr300014x · Cited by 7,720
Metal–Organic Framework Materials as Chemical Sensors
Kreno, L. E., Leong, K., Farha, O. K., Allendorf, M., Van Duyne, R. P., & Hupp, J. T. (2012) · Chemical Reviews · doi:10.1021/cr200324t · Cited by 7,136
Carbon Dioxide Capture in Metal–Organic Frameworks
Sumida, K., Rogow, D. L., Mason, J. A., McDonald, T. M., Bloch, E. D., Herm, Z. R., Bae, T.-H., & Long, J. R. (2012) · Chemical Reviews · doi:10.1021/cr2003272 · Cited by 6,408
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
Férey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., Surblé, S., & Margiolaki, I. (2005) · Science · doi:10.1126/science.1116275 · Cited by 5,430
Luminescent metal–organic frameworks for chemical sensing and explosive detection
Hu, Z., Deibert, B. J., & Li, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00010b · Cited by 4,169
Metal–Organic Frameworks in Biomedicine
Horcajada, P., Gref, R., Baati, T., Allan, P. K., Maurin, G., Couvreur, P., Férey, G., Morris, R. E., & Serre, C. (2012) · Chemical Reviews · doi:10.1021/cr200256v · Cited by 4,168
Metal–Organic Frameworks (MOFs)
Zhou, H.-C. “., & Kitagawa, S. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs90059f · Cited by 4,125
A homochiral metal–organic porous material for enantioselective separation and catalysis
Seo, J. S., Whang, D., Lee, H., Jun, S. I., Oh, J., Jeon, Y. J., & Kim, K. (2000) · Nature · doi:10.1038/35010088 · Cited by 3,924
Hydrogen Storage in Metal–Organic Frameworks
Suh, M. P., Park, H. J., Prasad, T. K., & Lim, D.-W. (2012) · Chemical Reviews · doi:10.1021/cr200274s · Cited by 3,689
Engineering Metal Organic Frameworks for Heterogeneous Catalysis
Corma, A., García, H., & Llabrés i Xamena, F. X. (2010) · Chemical Reviews · doi:10.1021/cr9003924 · Cited by 3,478
Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials
Cook, T. R., Zheng, Y.-R., & Stang, P. J. (2013) · Chemical Reviews · doi:10.1021/cr3002824 · Cited by 2,950
Applications of metal–organic frameworks in heterogeneous supramolecular catalysis
Liu, J., Chen, L., Cui, H., Zhang, J., Zhang, L., & Su, C.-Y. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00094c · Cited by 2,894
The pervasive chemistry of metal–organic frameworks
Long, J. R., & Yaghi, O. M. (2009) · Chemical Society Reviews · doi:10.1039/b903811f · Cited by 2,394
Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
Nugent, P., Belmabkhout, Y., Burd, S. D., Cairns, A. J., Luebke, R., Forrest, K., Pham, T., Ma, S., Space, B., Wojtas, L., et al. (2013) · Nature · doi:10.1038/nature11893 · Cited by 2,387
Metal–organic frameworks for artificial photosynthesis and photocatalysis
Zhang, T., & Lin, W. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00103f · Cited by 2,163
Imparting functionality to a metal–organic framework material by controlled nanoparticle encapsulation
Lu, G., Li, S., Guo, Z., Farha, O. K., Hauser, B. G., Qi, X., Wang, Y., Wang, X., Han, S., Liu, X., et al. (2012) · Nature Chemistry · doi:10.1038/nchem.1272 · Cited by 2,148
Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules
Chen, B., Xiang, S., & Qian, G. (2010) · Accounts of Chemical Research · doi:10.1021/ar100023y · Cited by 2,033
Postsynthetic modification of metal–organic frameworks
Wang, Z., & Cohen, S. M. (2009) · Chemical Society Reviews · doi:10.1039/b802258p · Cited by 1,973
Metal–Organic Frameworks: Opportunities for Catalysis
Farrusseng, D., Aguado, S., & Pinel, C. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200806063 · Cited by 1,888
An Amine‐Functionalized Titanium Metal–Organic Framework Photocatalyst with Visible‐Light‐Induced Activity for CO2 Reduction
Fu, Y., Sun, D., Chen, Y., Huang, R., Ding, Z., Fu, X., & Li, Z. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201108357 · Cited by 1,741
Self-citation
Methane storage in metal–organic frameworks
He, Y., Zhou, W., Qian, G., & Chen, B. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00032c · Cited by 1,674
Gas storage in porous metal–organic frameworks for clean energy applications
Ma, S., & Zhou, H.-C. (2010) · Chem. Commun. · doi:10.1039/b916295j · Cited by 1,349
Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation
Hwang, Y. K., Hong, D., Chang, J., Jhung, S. H., Seo, Y., Kim, J., Vimont, A., Daturi, M., Serre, C., & Férey, G. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200705998 · Cited by 1,243
Improved synthesis, thermal stability and catalytic properties of the metal-organic framework compound Cu3(BTC)2
Schlichte, K., Kratzke, T., & Kaskel, S. (2004) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2003.12.027 · Cited by 1,112
Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr)
Vermoortele, F., Bueken, B., Le Bars, G., Van de Voorde, B., Vandichel, M., Houthoofd, K., Vimont, A., Daturi, M., Waroquier, M., Van Speybroeck, V., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405078u · Cited by 1,110
Cation-Triggered Drug Release from a Porous Zinc−Adeninate Metal−Organic Framework
An, J., Geib, S. J., & Rosi, N. L. (2009) · Journal of the American Chemical Society · doi:10.1021/ja902972w · Cited by 1,076
Metal Organic Framework Catalysis: Quo vadis?
Gascon, J., Corma, A., Kapteijn, F., & Llabrés i Xamena, F. X. (2014) · ACS Catalysis · doi:10.1021/cs400959k · Cited by 960
Synergistic Catalysis of Au@Ag Core−Shell Nanoparticles Stabilized on Metal−Organic Framework
Jiang, H.-L., Akita, T., Ishida, T., Haruta, M., & Xu, Q. (2011) · Journal of the American Chemical Society · doi:10.1021/ja1099006 · Cited by 931
Self-citation
Porous metal–organic frameworks as platforms for functional applications
Jiang, H.-L., & Xu, Q. (2011) · Chemical Communications · doi:10.1039/c0cc05419d · Cited by 859
Self-citation
Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal−Organic Framework
Jiang, H.-L., Liu, B., Akita, T., Haruta, M., Sakurai, H., & Xu, Q. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9047653 · Cited by 850
Self-citation
Size-Selective Lewis Acid Catalysis in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites
Horike, S., Dincǎ, M., Tamaki, K., & Long, J. R. (2008) · Journal of the American Chemical Society · doi:10.1021/ja800669j · Cited by 834
Molecular decoding using luminescence from an entangled porous framework
Takashima, Y., Martínez, V. M., Furukawa, S., Kondo, M., Shimomura, S., Uehara, H., Nakahama, M., Sugimoto, K., & Kitagawa, S. (2011) · Nature Communications · doi:10.1038/ncomms1170 · Cited by 773
Immobilizing Metal Nanoparticles to Metal–Organic Frameworks with Size and Location Control for Optimizing Catalytic Performance
Zhu, Q.-L., Li, J., & Xu, Q. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403330m · Cited by 729
Self-citation
Metal@MOF: Loading of Highly Porous Coordination Polymers Host Lattices by Metal Organic Chemical Vapor Deposition
Hermes, S., Schröter, M., Schmid, R., Khodeir, L., Muhler, M., Tissler, A., Fischer, R. W., & Fischer, R. A. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462515 · Cited by 712
Core–Shell Palladium Nanoparticle@Metal–Organic Frameworks as Multifunctional Catalysts for Cascade Reactions
Zhao, M., Deng, K., He, L., Liu, Y., Li, G., Zhao, H., & Tang, Z. (2014) · Journal of the American Chemical Society · doi:10.1021/ja411468e · Cited by 685
Yolk–Shell Nanocrystal@ZIF-8 Nanostructures for Gas-Phase Heterogeneous Catalysis with Selectivity Control
Kuo, C.-H., Tang, Y., Chou, L.-Y., Sneed, B. T., Brodsky, C. N., Zhao, Z., & Tsung, C.-K. (2012) · Journal of the American Chemical Society · doi:10.1021/ja306869j · Cited by 660
Two-Dimensional Metal–Organic Framework with Wide Channels and Responsive Turn-On Fluorescence for the Chemical Sensing of Volatile Organic Compounds
Zhang, M., Feng, G., Song, Z., Zhou, Y.-P., Chao, H.-Y., Yuan, D., Tan, T. T. Y., Guo, Z., Hu, Z., Tang, B. Z., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502643p · Cited by 657
Self-citation
Core–Shell Noble‐Metal@Metal‐Organic‐Framework Nanoparticles with Highly Selective Sensing Property
He, L., Liu, Y., Liu, J., Xiong, Y., Zheng, J., Liu, Y., & Tang, Z. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209903 · Cited by 641
Heterogeneous Catalysis for Tandem Reactions
Climent, M. J., Corma, A., Iborra, S., & Sabater, M. J. (2014) · ACS Catalysis · doi:10.1021/cs401052k · Cited by 361
Well‐Defined Metal–Organic Framework Hollow Nanocages
Zhang, Z., Chen, Y., Xu, X., Zhang, J., Xiang, G., He, W., & Wang, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201308589 · Cited by 350
Self-citation
Multifunctional Nanoparticle@MOF Core–Shell Nanostructures
Liu, Y., & Tang, Z. (2013) · Advanced Materials · doi:10.1002/adma.201302781 · Cited by 323
Redox‐Active Porous Metal–Organic Framework Producing Silver Nanoparticles from AgI Ions at Room Temperature
Moon, H. R., Kim, J. H., & Suh, M. P. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200461408 · Cited by 292
Hollow Mesoporous Aluminosilica Spheres with Perpendicular Pore Channels as Catalytic Nanoreactors
Fang, X., Liu, Z., Hsieh, M.-F., Chen, M., Liu, P., Chen, C., & Zheng, N. (2012) · ACS Nano · doi:10.1021/nn3011703 · Cited by 284
Metal Nanocrystals Embedded in Single Nanocrystals of MOFs Give Unusual Selectivity as Heterogeneous Catalysts
Na, K., Choi, K. M., Yaghi, O. M., & Somorjai, G. A. (2014) · Nano Letters · doi:10.1021/nl503007h · Cited by 251
Silver Cluster Formation, Dynamics, and Chemistry in Metal−Organic Frameworks
Houk, R. J. T., Jacobs, B. W., Gabaly, F. E., Chang, N. N., Talin, A. A., Graham, D. D., House, S. D., Robertson, I. M., & Allendorf, M. D. (2009) · Nano Letters · doi:10.1021/nl901397k · Cited by 249
Tiny Pd@Co Core–Shell Nanoparticles Confined inside a Metal–Organic Framework for Highly Efficient Catalysis
Chen, Y., Xu, Q., Yu, S., & Jiang, H. (2015) · Small · doi:10.1002/smll.201401875 · Cited by 236
Self-citation
Metal–Organic Frameworks as Efficient Heterogeneous Catalysts for the Regioselective Ring Opening of Epoxides
Dhakshinamoorthy, A., Alvaro, M., & Garcia, H. (2010) · Chemistry – A European Journal · doi:10.1002/chem.201000588 · Cited by 217
Tandem Catalysis by Palladium Nanoclusters Encapsulated in Metal–Organic Frameworks
Li, X., Guo, Z., Xiao, C., Goh, T. W., Tesfagaber, D., & Huang, W. (2014) · ACS Catalysis · doi:10.1021/cs5006635 · Cited by 209
Ni/Pd@MIL‐101: Synergistic Catalysis with Cavity‐Conform Ni/Pd Nanoparticles
Hermannsdörfer, J., Friedrich, M., Miyajima, N., Albuquerque, R. Q., Kümmel, S., & Kempe, R. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201205078 · Cited by 192
Palladium Nanoparticles Encapsulated in a Metal–Organic Framework as Efficient Heterogeneous Catalysts for Direct C2 Arylation of Indoles
Huang, Y., Lin, Z., & Cao, R. (2011) · Chemistry – A European Journal · doi:10.1002/chem.201101705 · Cited by 191
A Noble‐Metal‐Free Porous Coordination Framework with Exceptional Sensing Efficiency for Oxygen
Lin, R., Li, F., Liu, S., Qi, X., Zhang, J., & Chen, X. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201307217 · Cited by 181
Formation of monometallic Au and Pd and bimetallic Au–Pd nanoparticles confined in mesopores via Ar glow-discharge plasma reduction and their catalytic applications in aerobic oxidation of benzyl alcohol
Chen, Y., Wang, H., Liu, C.-J., Zeng, Z., Zhang, H., Zhou, C., Jia, X., & Yang, Y. (2012) · Journal of Catalysis · doi:10.1016/j.jcat.2012.01.020 · Cited by 171
Self-citation
Structure and Mobility of Metal Clusters in MOFs: Au, Pd, and AuPd Clusters in MOF-74
Vilhelmsen, L. B., Walton, K. S., & Sholl, D. S. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305004a · Cited by 159
Alkylamine‐Tethered Stable Metal–Organic Framework for CO2 Capture from Flue Gas
Hu, Y., Verdegaal, W. M., Yu, S., & Jiang, H. (2014) · ChemSusChem · doi:10.1002/cssc.201301163 · Cited by 152
Self-citation
Bifunctional Metal Organic Framework Catalysts for Multistep Reactions: MOF‐Cu(BTC)‐[Pd] Catalyst for One‐Pot Heteroannulation of Acetylenic Compounds
Arnanz, A., Pintado‐Sierra, M., Corma, A., Iglesias, M., & Sánchez, F. (2012) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.201100503 · Cited by 113
Transported into fuel cells
Kitagawa, H. (2009) · Nature Chemistry · doi:10.1038/nchem.454 · Cited by 90
P123-stabilized Au–Ag alloy nanoparticles for kinetics of aerobic oxidation of benzyl alcohol in aqueous solution
Huang, X., Wang, X., Wang, X., Wang, X., Tan, M., Ding, W., & Lu, X. (2013) · Journal of Catalysis · doi:10.1016/j.jcat.2013.02.011 · Cited by 88
1-[4-(1H-Benzoimidazol-2-yl)-phenyl]-3-[4-(1H-benzoimidazol-2-yl)-phenyl]-urea derivatives as small molecule heparanase inhibitors
Pan, W., Miao, H., Xu, Y.-J., et al. (2005) · Bioorganic & Medicinal Chemistry Letters · doi:10.1016/j.bmcl.2005.09.069 · Cited by 63
Size and alloying induced shift in core and valence bands of Pd-Ag and Pd-Cu nanoparticles
Sengar, S. K., Mehta, B. R., & Govind, G. (2014) · Journal of Applied Physics · doi:10.1063/1.4869437 · Cited by 61

Encapsulated Metal Nanoparticles for Catalysis
Gao, C., Lyu, F., & Yin, Y. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00237 · Cited by 855
MOF Thin Film‐Coated Metal Oxide Nanowire Array: Significantly Improved Chemiresistor Sensor Performance
Yao, M., Tang, W., Wang, G., Nath, B., & Xu, G. (2016) · Advanced Materials · doi:10.1002/adma.201506457 · Cited by 641
Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CO2 and epoxides
Deacy, A. C., Kilpatrick, A. F. R., Regoutz, A., & Williams, C. K. (2020) · Nature Chemistry · doi:10.1038/s41557-020-0450-3 · Cited by 325
Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Hou, S., Dong, J., & Zhao, B. (2020) · Advanced Materials · doi:10.1002/adma.201806163 · Cited by 142
Self-hydrogen transfer hydrogenolysis of β-O-4 linkages in lignin catalyzed by MIL-100(Fe) supported Pd-Ni BMNPs
Zhang, J.-W., Lu, G.-P., & Cai, C. (2017) · Green Chemistry · doi:10.1039/c7gc02087b · Cited by 101

See all 423

Authors: Chen, Y.-Z., Zhou, Y.-X., Wang, H., Lu, J., Uchida, T., Xu, Q., Yu, S.-H., & Jiang, H.-L.
Venue: ACS Catalysis
Publisher: American Chemical Society (ACS)
Published: 2015-02-27
Volume: 5
Issue: 4
Pages: 2062-2069
ISSN: 2155-5435 (ISSN-L)
DOI: 10.1021/cs501953d
OpenAlex: W2327433125
Cited by: 423
References: 61
FWCI: 19.76
Type: journal article
Language: en
Open access: closed

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.

Multifunctional PdAg@MIL-101 for One-Pot Cascade Reactions: Combination of Host–Guest Cooperation and Bimetallic Synergy in Catalysis

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Self-check

Citations

Cites

Cited by

Metadata

Record

About these checks

Data sources