Cited by 394Soil Carbon and Nitrogen DynamicsPhosphorus and nutrient managementThermochemical Biomass Conversion Processes

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pH-Dependent Mineral Release and Surface Properties of Cornstraw Biochar: Agronomic Implications

Silber, A., Levkovitch, I., Graber, E. R.·2010·Environmental Science & Technology

DOI 10.1021/es101283d

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Abstract

Surface charge and pH-dependent nutrient release properties of cornstraw biochar were examined to elucidate its potential agronomic benefits. Kinetics of element release was characterized by rapid H(+) consumption and rapid, pH-dependent P, Ca, and Mg release, followed by zero-order H(+) consumption and mineral dissolution reactions. Initial K release was not pH-dependent, nor was it followed by a zero-order reaction at any pH. Rapid and constant rate P releases were significant, having the potential to substitute substantial proportions of P fertilizer. K releases were also significant and may replace conventional K fertilizers, however, not long-term plant demand. The cation exchange capacity (CEC) of the biochar leached with a mild acidic solution increased linearly from 179 to 888 mmol(c) (kg C)(-1) over a pH range of 4-8, while the anion exchange capacity of 154 mmol(c) (kg C)(-1) was constant over the same pH range. Since native soil organic constituents have much higher CEC values (average 2800 mmol(c) (kg C)(-1) at pH 7), improved soil fertility as a result of enhanced cation retention by the biochar probably will be favorable only in sandy and low organic matter soils, unless surface oxidation during aging significantly increases its CEC.

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Authors: Silber, A., Levkovitch, I., & Graber, E. R.
Affiliations: Agricultural Research Organization (IL)
Institute of Soils, Water and Environmental Sciences, Agricultural Research Organization, The Volcani Center, Bet Dagan, 50250, Israel
Corresponding author: Silber, A.
ORCID: Silber, A.
Venue: Environmental Science & Technology
Publisher: American Chemical Society (ACS)
Published: 2010-11-23
Volume: 44
Issue: 24
Pages: 9318-9323
ISSN: 0013-936X (ISSN-L)
1520-5851
DOI: 10.1021/es101283d
OpenAlex: W2328874691
Cited by: 394
References: 26
Citations by year: 2026: 13 · 2025: 15 · 2024: 24 · 2023: 33 · 2022: 34 · 2021: 28 · 2020: 35 · 2019: 35 · 2018: 40 · 2017: 29 · 2016: 24 · 2015: 14 · 2014: 27 · 2013: 18 · 2012: 18
FWCI: 22.61
Type: journal article
Language: en
Open access: closed
Locations: Environmental Science & Technology (publishedVersion)
PubMed (publishedVersion)
Topics: Life Sciences › Agricultural and Biological Sciences › Soil Science › Soil Carbon and Nitrogen Dynamics
Physical Sciences › Environmental Science › Waste Management and Disposal › Phosphorus and nutrient management
Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
Keywords: surface charge, nutrient release kinetics, phosphorus release, potassium release, calcium and magnesium release, cation exchange capacity, anion exchange capacity, soil fertility, biochar aging
MeSH terms: Agriculture, Charcoal, Zea mays, Fertilizers, Hydrogen-Ion Concentration, Kinetics, Magnesium, Minerals, Phosphorus, Potassium, Soil, Surface Properties

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pH-Dependent Mineral Release and Surface Properties of Cornstraw Biochar: Agronomic Implications

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