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Pore Space Partition by Symmetry-Matching Regulated Ligand Insertion and Dramatic Tuning on Carbon Dioxide Uptake
Abstract
Metal-organic frameworks (MOFs) with the highest CO(2) uptake capacity are usually those equipped with open metal sites. Here we seek alternative strategies and mechanisms for developing high-performance CO(2) adsorbents. We demonstrate that through a ligand insertion pore space partition strategy, we can create crystalline porous materials (CPMs) with superior CO(2) uptake capacity. Specifically, a new material, CPM-33b-Ni without any open metal sites, exhibits the CO(2) uptake capacity comparable to MOF-74 with the same metal (Ni) at 298 K and 1 bar.
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Metadata
- Authors
- Zhao, X., Bu, X., Zhai, Q.-G., Tran, H., & Feng, P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-01-26
- Volume
- 137
- Issue
- 4
- Pages
- 1396-1399
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2325300464
- Cited by
- 355
- References
- 53
- FWCI
- 16.49
- Type
- journal article
- Language
- en
- Open access
- closed
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