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Novel Route to Size-Controlled Fe–MIL-88B–NH2 Metal–Organic Framework Nanocrystals
Abstract
A new approach for the synthesis of uniform metal-organic framework (MOF) nanocrystals with controlled sizes and aspect ratios has been developed using simultaneously the non-ionic triblock co-polymer F127 and acetic acid as stabilizing and deprotonating agents, respectively. The alkylene oxide segments of the triblock co-polymer can coordinate with metal ions and stabilize MOF nuclei in the early stage of the formation of MOF nanocrystals. Acetic acid can control the deprotonation of carboxylic linkers during the synthesis and, thus, enables the control of the rate of nucleation, leading to the tailoring of the size and aspect ratio (length/width) of nanocrystals. Fe-MIL-88B-NH(2), as an iron-based MOF crystal, was selected as a typical example to illustrate our approach. The results reveal that this approach is used for not only the synthesis of uniform nanocrystals but also the control of the size and aspect ratio of the materials. The size and aspect ratio of nanocrystals increase with an increase in the concentration of acetic acid in the synthetic mixture. The non-ionic triblock co-polymer F127 and acetic acid can be easily removed from the Fe-MIL-88B-NH(2) nanocrystal products by washing with ethanol, and thus, their amine groups are available for practical applications. The approach is expected to synthesize various nanosized carboxylate-based MOF members, such as MIL-53, MIL-89, MIL-100, and MIL-101.
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Citations
Cites
Selective gas adsorption and separation in metal–organic frameworks
Li, J.-R., Kuppler, R. J., & Zhou, H.-C. (2009) · Chemical Society Reviews · doi:10.1039/b802426j · Cited by 8,932
Eddaoudi, M., Kim, J., Rosi, N., Vodak, D., Wachter, J., O'Keeffe, M., & Yaghi, O. M. (2002) · Science · doi:10.1126/science.1067208 · Cited by 8,132
Hybrid porous solids: past, present, future
Férey, G. (2008) · Chem. Soc. Rev. · doi:10.1039/b618320b · Cited by 5,822
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
Férey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., Surblé, S., & Margiolaki, I. (2005) · Science · doi:10.1126/science.1116275 · Cited by 5,430
Horcajada, P., Chalati, T., Serre, C., Gillet, B., Sebrie, C., Baati, T., Eubank, J. F., Heurtaux, D., Clayette, P., Kreuz, C., et al. (2010) · Nature Materials · doi:10.1038/nmat2608 · Cited by 4,260
Ultrahigh Porosity in Metal-Organic Frameworks
Furukawa, H., Ko, N., Go, Y. B., Aratani, N., Choi, S. B., Choi, E., Yazaydin, A. Ö., Snurr, R. Q., O’Keeffe, M., Kim, J., et al. (2010) · Science · doi:10.1126/science.1192160 · Cited by 3,904
Engineering Metal Organic Frameworks for Heterogeneous Catalysis
Corma, A., García, H., & Llabrés i Xamena, F. X. (2010) · Chemical Reviews · doi:10.1021/cr9003924 · Cited by 3,478
BioMOFs: Metal–Organic Frameworks for Biological and Medical Applications
McKinlay, A. C., Morris, R. E., Horcajada, P., Férey, G., Gref, R., Couvreur, P., & Serre, C. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000048 · Cited by 1,256
Postsynthetic modification of metal–organic frameworks—a progress report
Tanabe, K. K., & Cohen, S. M. (2011) · Chem. Soc. Rev. · doi:10.1039/c0cs00031k · Cited by 1,173
Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks
Serre, C., Mellot-Draznieks, C., Surblé, S., Audebrand, N., Filinchuk, Y., & Férey, G. (2007) · Science · doi:10.1126/science.1137975 · Cited by 1,095
Hasegawa, S., Horike, S., Matsuda, R., Furukawa, S., Mochizuki, K., Kinoshita, Y., & Kitagawa, S. (2007) · Journal of the American Chemical Society · doi:10.1021/ja067374y · Cited by 954
Nanoscale Metal−Organic Frameworks as Potential Multimodal Contrast Enhancing Agents
Rieter, W. J., Taylor, K. M. L., An, H., Lin, W., & Lin, W. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0627444 · Cited by 891
Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth
Tsuruoka, T., Furukawa, S., Takashima, Y., Yoshida, K., Isoda, S., & Kitagawa, S. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200901177 · Cited by 708
Hafizovic, J., Bjørgen, M., Olsbye, U., Dietzel, P. D. C., Bordiga, S., Prestipino, C., Lamberti, C., & Lillerud, K. P. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0675447 · Cited by 683
Amino-based metal-organic frameworks as stable, highly active basic catalysts
GASCON, J., AKTAY, U., HERNANDEZALONSO, M., VANKLINK, G., & KAPTEIJN, F. (2009) · Journal of Catalysis · doi:10.1016/j.jcat.2008.11.010 · Cited by 667
Why hybrid porous solids capture greenhouse gases?
Férey, G., Serre, C., Devic, T., Maurin, G., Jobic, H., Llewellyn, P. L., De Weireld, G., Vimont, A., Daturi, M., & Chang, J.-S. (2011) · Chem. Soc. Rev. · doi:10.1039/c0cs00040j · Cited by 652
Bauer, S., Serre, C., Devic, T., Horcajada, P., Marrot, J., Férey, G., & Stock, N. (2008) · Inorganic Chemistry · doi:10.1021/ic800538r · Cited by 620
Jiang, H.-L., Tatsu, Y., Lu, Z.-H., & Xu, Q. (2010) · Journal of the American Chemical Society · doi:10.1021/ja101541s · Cited by 614
Serre, C., Millange, F., Surblé, S., & Férey, G. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200454250 · Cited by 592
Rieter, W. J., Taylor, K. M. L., & Lin, W. (2007) · Journal of the American Chemical Society · doi:10.1021/ja073506r · Cited by 588
Controlled Multiscale Synthesis of Porous Coordination Polymer in Nano/Micro Regimes
Diring, S., Furukawa, S., Takashima, Y., Tsuruoka, T., & Kitagawa, S. (2010) · Chemistry of Materials · doi:10.1021/cm101778g · Cited by 527
A Crystalline Mesoporous Coordination Copolymer with High Microporosity
Koh, K., Wong‐Foy, A. G., & Matzger, A. J. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200705020 · Cited by 526
Semiconducting superlattices templated by molecular assemblies
Braun, P. V., Osenar, P., & Stupp, S. I. (1996) · Nature · doi:10.1038/380325a0 · Cited by 518
Qiu, L.-G., Li, Z.-Q., Wu, Y., Wang, W., Xu, T., & Jiang, X. (2008) · Chemical Communications · doi:10.1039/b804126a · Cited by 516
Stress-Induced Chemical Detection Using Flexible Metal−Organic Frameworks
Allendorf, M. D., Houk, R. J. T., Andruszkiewicz, L., Talin, A. A., Pikarsky, J., Choudhury, A., Gall, K. A., & Hesketh, P. J. (2008) · Journal of the American Chemical Society · doi:10.1021/ja805235k · Cited by 488
A Porous Coordination Copolymer with over 5000 m2/g BET Surface Area
Koh, K., Wong-Foy, A. G., & Matzger, A. J. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809985t · Cited by 487
Structure-Directing Role of Graphene in the Synthesis of Metal−Organic Framework Nanowire
Jahan, M., Bao, Q., Yang, J.-X., & Loh, K. P. (2010) · Journal of the American Chemical Society · doi:10.1021/ja105089w · Cited by 466
Prussian Blue Nanoparticles Protected by Poly(vinylpyrrolidone)
Uemura, T., & Kitagawa, S. (2003) · Journal of the American Chemical Society · doi:10.1021/ja0356582 · Cited by 456
Docking in Metal-Organic Frameworks
Li, Q., Zhang, W., Miljanić, O. Š., Sue, C.-H., Zhao, Y.-L., Liu, L., Knobler, C. B., Stoddart, J. F., & Yaghi, O. M. (2009) · Science · doi:10.1126/science.1175441 · Cited by 393
Farha, O. K., Malliakas, C. D., Kanatzidis, M. G., & Hupp, J. T. (2010) · Journal of the American Chemical Society · doi:10.1021/ja909519e · Cited by 363
A Mesoporous Metal–Organic Framework
Klein, N., Senkovska, I., Gedrich, K., Stoeck, U., Henschel, A., Mueller, U., & Kaskel, S. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200904599 · Cited by 346
Tanaka, D., Henke, A., Albrecht, K., Moeller, M., Nakagawa, K., Kitagawa, S., & Groll, J. (2010) · Nature Chemistry · doi:10.1038/nchem.627 · Cited by 342
Crystal Splitting in the Growth of Bi2S3
Tang, J., & Alivisatos, A. P. (2006) · Nano Letters · doi:10.1021/nl0615930 · Cited by 326
Hermes, S., Witte, T., Hikov, T., Zacher, D., Bahnmüller, S., Langstein, G., Huber, K., & Fischer, R. A. (2007) · Journal of the American Chemical Society · doi:10.1021/ja068835i · Cited by 303
Zhao, Y., Zhang, J., Han, B., Song, J., Li, J., & Wang, Q. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201005314 · Cited by 302
Colloidal Route for Preparing Optical Thin Films of Nanoporous Metal–Organic Frameworks
Horcajada, P., Serre, C., Grosso, D., Boissière, C., Perruchas, S., Sanchez, C., & Férey, G. (2009) · Advanced Materials · doi:10.1002/adma.200801851 · Cited by 289
Synthesis and properties of nano zeolitic imidazolate frameworks
Nune, S. K., Thallapally, P. K., Dohnalkova, A., Wang, C., Liu, J., & Exarhos, G. J. (2010) · Chemical Communications · doi:10.1039/c002088e · Cited by 255
Size and Surface Effects of Prussian Blue Nanoparticles Protected by Organic Polymers
Uemura, T., Ohba, M., & Kitagawa, S. (2004) · Inorganic Chemistry · doi:10.1021/ic0488435 · Cited by 210
Scherb, C., Schödel, A., & Bein, T. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200704034 · Cited by 208
Seo, J., Bonneau, C., Matsuda, R., Takata, M., & Kitagawa, S. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201484s · Cited by 207
Alkylene oxides and their polymers
Doelker, É. (1993) · Journal of Controlled Release · doi:10.1016/0168-3659(93)90196-c · Cited by 138
Vuong, G., & Do, T. (2007) · Journal of the American Chemical Society · doi:10.1021/ja069058p · Cited by 104
Self-citationGaudin, C., da Cunha, D. P., Ivanoff, E., Horcajada, P., Chevé, G., Yasri, A., Loget, O., Serre, C., & Maurin, G. (2011) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2011.06.011 · Cited by 92
Taylor-Pashow, K. M. L., Jin, A., & Lin, W. (2008) · Angewandte Chemie · doi:10.1002/ange.200802911 · Cited by 89
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Xu, X., Cao, R., Jeong, S., & Cho, J. (2012) · Nano Letters · doi:10.1021/nl302618s · Cited by 914
Zhao, S., Yin, H., Du, L., He, L., Zhao, K., Chang, L., Yin, G., Zhao, H., Liu, S., & Tang, Z. (2014) · ACS Nano · doi:10.1021/nn505582e · Cited by 532
Liu, Y. L., Zhao, X. J., Yang, X. X., & Li, Y. F. (2013) · The Analyst · doi:10.1039/c3an00560g · Cited by 320
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Metadata
- Authors
- Pham, M.-H., Vuong, G.-T., Vu, A.-T., & Do, T.-O.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-11-18
- Volume
- 27
- Issue
- 24
- Pages
- 15261-15267
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2076756203
- Cited by
- 273
- References
- 44
- FWCI
- 5.40
- Type
- journal article
- Language
- en
- Open access
- closed
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