The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.
Functionalization of Transition Metal Dichalcogenides with Metallic Nanoparticles: Implications for Doping and Gas-Sensing
Abstract
Transition metal dichalcogenides (TMDs), belonging to the class of two-dimensional (2D) layered materials, have instigated a lot of interest in diverse application fields due to their unique electrical, mechanical, magnetic, and optical properties. Tuning the electrical properties of TMDs through charge transfer or doping is necessary for various optoelectronic applications. This paper presents the experimental investigation of the doping effect on TMDs, mainly focusing on molybdenum disulfide (MoS2), by metallic nanoparticles (NPs), exploring noble metals such as silver (Ag), palladium (Pd), and platinum (Pt) as well as the low workfunction metals such as scandium (Sc) and yttrium (Y) for the first time. The dependence of the doping behavior of MoS2 on the metal workfunction is demonstrated and it is shown that Pt nanoparticles can lead to as large as 137 V shift in threshold voltage of a back-gated monolayered MoS2 FET. Variation of the MoS2 FET transfer curves with the increase in the dose of NPs as well as the effect of the number of MoS2 layers on the doping characteristics are also discussed for the first time. Moreover, the doping effect on WSe2 is studied with the first demonstration of p-type doping using Pt NPs. Apart from doping, the use of metallic NP functionalized TMDs for gas sensing application is also demonstrated.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Grimme, S., Antony, J., Ehrlich, S., & Krieg, H. (2010) · The Journal of Chemical Physics · doi:10.1063/1.3382344 · Cited by 59,686
Geim, A. K., & Novoselov, K. S. (2007) · Nature Materials · doi:10.1038/nmat1849 · Cited by 39,979
Self-interaction correction to density-functional approximations for many-electron systems
Perdew, J. P., & Zunger, A. (1981) · Physical Review B · doi:10.1103/physrevb.23.5048 · Cited by 20,887
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
Wang, Q. H., Kalantar-Zadeh, K., Kis, A., Coleman, J. N., & Strano, M. S. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.193 · Cited by 16,374
Atomically Thin MoS 2 : A New Direct-Gap Semiconductor
Mak, K. F., Lee, C., Hone, J., Shan, J., & Heinz, T. F. (2010) · Physical Review Letters · doi:10.1103/physrevlett.105.136805 · Cited by 15,586
Radisavljevic, B., Radenovic, A., Brivio, J., Giacometti, V., & Kis, A. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2010.279 · Cited by 14,939
Two-dimensional atomic crystals
Novoselov, K. S., Jiang, D., Schedin, F., Booth, T. J., Khotkevich, V. V., Morozov, S. V., & Geim, A. K. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0502848102 · Cited by 11,788
Electronic Population Analysis on LCAO–MO Molecular Wave Functions. I
Mulliken, R. S. (1955) · The Journal of Chemical Physics · doi:10.1063/1.1740588 · Cited by 11,049
Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials
Coleman, J. N., Lotya, M., O’Neill, A., Bergin, S. D., King, P. J., Khan, U., Young, K., Gaucher, A., De, S., Smith, R. J., et al. (2011) · Science · doi:10.1126/science.1194975 · Cited by 7,242
From Bulk to Monolayer MoS2: Evolution of Raman Scattering
Li, H., Zhang, Q., Yap, C. C. R., Tay, B. K., Edwin, T. H. T., Olivier, A., & Baillargeat, D. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201102111 · Cited by 4,249
Valley polarization in MoS2 monolayers by optical pumping
Zeng, H., Dai, J., Yao, W., Xiao, D., & Cui, X. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.95 · Cited by 3,693
Growth of Large-Area and Highly Crystalline MoS2 Thin Layers on Insulating Substrates
Liu, K.-K., Zhang, W., Lee, Y.-H., Lin, Y.-C., Chang, M.-T., Su, C.-Y., Chang, C.-S., Li, H., Shi, Y., Zhang, H., et al. (2012) · Nano Letters · doi:10.1021/nl2043612 · Cited by 1,958
Self-citationHigh-Performance Single Layered WSe2 p-FETs with Chemically Doped Contacts
Fang, H., Chuang, S., Chang, T. C., Takei, K., Takahashi, T., & Javey, A. (2012) · Nano Letters · doi:10.1021/nl301702r · Cited by 1,862
Large‐Area Vapor‐Phase Growth and Characterization of MoS2 Atomic Layers on a SiO2 Substrate
Zhan, Y., Liu, Z., Najmaei, S., Ajayan, P. M., & Lou, J. (2012) · Small · doi:10.1002/smll.201102654 · Cited by 1,741
High-mobility and low-power thin-film transistors based on multilayer MoS2 crystals
Kim, S., Konar, A., Hwang, W.-S., Lee, J. H., Lee, J., Yang, J., Jung, C., Kim, H., Yoo, J.-B., Choi, J.-Y., et al. (2012) · Nature Communications · doi:10.1038/ncomms2018 · Cited by 1,636
Li, H., Yin, Z., He, Q., Li, H., Huang, X., Lu, G., Fam, D. W. H., Tok, A. I. Y., Zhang, Q., & Zhang, H. (2012) · Small · doi:10.1002/smll.201101016 · Cited by 1,536
Self-citationTunable Photoluminescence of Monolayer MoS2 via Chemical Doping
Mouri, S., Miyauchi, Y., & Matsuda, K. (2013) · Nano Letters · doi:10.1021/nl403036h · Cited by 1,517
Large‐Scale Exfoliation of Inorganic Layered Compounds in Aqueous Surfactant Solutions
Smith, R. J., King, P. J., Lotya, M., Wirtz, C., Khan, U., De, S., O'Neill, A., Duesberg, G. S., Grunlan, J. C., Moriarty, G., et al. (2011) · Advanced Materials · doi:10.1002/adma.201102584 · Cited by 1,161
Symmetry-dependent phonon renormalization in monolayer MoS2transistor
Chakraborty, B., Bera, A., Muthu, D. V. S., Bhowmick, S., Waghmare, U. V., & Sood, A. K. (2012) · Physical Review B · doi:10.1103/physrevb.85.161403 · Cited by 1,140
Chemical Vapor Sensing with Monolayer MoS2
Perkins, F. K., Friedman, A. L., Cobas, E., Campbell, P. M., Jernigan, G. G., & Jonker, B. T. (2013) · Nano Letters · doi:10.1021/nl3043079 · Cited by 1,138
Hysteresis in Single-Layer MoS2 Field Effect Transistors
Late, D. J., Liu, B., Matte, H. S. S. R., Dravid, V. P., & Rao, C. N. R. (2012) · ACS Nano · doi:10.1021/nn301572c · Cited by 1,123
MoS2 Field-Effect Transistor for Next-Generation Label-Free Biosensors
Sarkar, D., Liu, W., Xie, X., Anselmo, A. C., Mitragotri, S., & Banerjee, K. (2014) · ACS Nano · doi:10.1021/nn5009148 · Cited by 1,047
Self-citationRole of Metal Contacts in Designing High-Performance Monolayer n-Type WSe2 Field Effect Transistors
Liu, W., Kang, J., Sarkar, D., Khatami, Y., Jena, D., & Banerjee, K. (2013) · Nano Letters · doi:10.1021/nl304777e · Cited by 985
Self-citationHighly Flexible MoS2 Thin-Film Transistors with Ion Gel Dielectrics
Pu, J., Yomogida, Y., Liu, K.-K., Li, L.-J., Iwasa, Y., & Takenobu, T. (2012) · Nano Letters · doi:10.1021/nl301335q · Cited by 823
Tongay, S., Zhou, J., Ataca, C., Liu, J., Kang, J. S., Matthews, T. S., You, L., Li, J., Grossman, J. C., & Wu, J. (2013) · Nano Letters · doi:10.1021/nl4011172 · Cited by 788
Self-citationDegenerate n-Doping of Few-Layer Transition Metal Dichalcogenides by Potassium
Fang, H., Tosun, M., Seol, G., Chang, T. C., Takei, K., Guo, J., & Javey, A. (2013) · Nano Letters · doi:10.1021/nl400044m · Cited by 760
Mao, S., Lu, G., Yu, K., Bo, Z., & Chen, J. (2010) · Advanced Materials · doi:10.1002/adma.201000520 · Cited by 471
Selective Decoration of Au Nanoparticles on Monolayer MoS2 Single Crystals
Shi, Y., Huang, J.-K., Jin, L., Hsu, Y.-T., Yu, S. F., Li, L.-J., & Yang, H. Y. (2013) · Scientific Reports · doi:10.1038/srep01839 · Cited by 433
Selective Gas Sensing with a Single Pristine Graphene Transistor
Rumyantsev, S., Liu, G., Shur, M. S., Potyrailo, R. A., & Balandin, A. A. (2012) · Nano Letters · doi:10.1021/nl3001293 · Cited by 408
Palladium Nanoparticles Decorated Single-Walled Carbon Nanotube Hydrogen Sensor
Mubeen, S., Zhang, T., Yoo, B., Deshusses, M. A., & Myung, N. V. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp067716m · Cited by 407
Enhancement of Photovoltaic Response in Multilayer MoS2 Induced by Plasma Doping
Wi, S., Kim, H., Chen, M., Nam, H., Guo, L. J., Meyhofer, E., & Liang, X. (2014) · ACS Nano · doi:10.1021/nn5013429 · Cited by 402
Hydrogen Sensing Using Pd‐Functionalized Multi‐Layer Graphene Nanoribbon Networks
Johnson, J. L., Behnam, A., Pearton, S. J., & Ural, A. (2010) · Advanced Materials · doi:10.1002/adma.201001798 · Cited by 347
p-type doping of MoS2 thin films using Nb
Laskar, M. R., Nath, D. N., Ma, L., Lee, E. W., Lee, C. H., Kent, T., Yang, Z., Mishra, R., Roldan, M. A., Idrobo, J.-C., et al. (2014) · Applied Physics Letters · doi:10.1063/1.4867197 · Cited by 319
Sreeprasad, T. S., Nguyen, P., Kim, N., & Berry, V. (2013) · Nano Letters · doi:10.1021/nl402278y · Cited by 304
Proposal for tunnel-field-effect-transistor as ultra-sensitive and label-free biosensors
Sarkar, D., & Banerjee, K. (2012) · Applied Physics Letters · doi:10.1063/1.3698093 · Cited by 295
Self-citationEdge-dependent structural, electronic and magnetic properties of MoS2 nanoribbons
Pan, H., & Zhang, Y.-W. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm15906f · Cited by 276
Air Stable p-Doping of WSe2 by Covalent Functionalization
Zhao, P., Kiriya, D., Azcatl, A., Zhang, C., Tosun, M., Liu, Y.-S., Hettick, M., Kang, J. S., McDonnell, S., KC, S., et al. (2014) · ACS Nano · doi:10.1021/nn5047844 · Cited by 260
Self-citationDu, Y., Liu, H., Neal, A. T., Si, M., & Ye, P. D. (2013) · IEEE Electron Device Letters · doi:10.1109/led.2013.2277311 · Cited by 253
Lin, J. D., Han, C., Wang, F., Wang, R., Xiang, D., Qin, S., Zhang, X.-A., Wang, L., Zhang, H., Wee, A. T. S., et al. (2014) · ACS Nano · doi:10.1021/nn501580c · Cited by 249
Self-citationCarrier Control of MoS2 Nanoflakes by Functional Self-Assembled Monolayers
Li, Y., Xu, C.-Y., Hu, P., & Zhen, L. (2013) · ACS Nano · doi:10.1021/nn402682j · Cited by 235
Stable few-layer MoS2 rectifying diodes formed by plasma-assisted doping
Chen, M., Nam, H., Wi, S., Ji, L., Ren, X., Bian, L., Lu, S., & Liang, X. (2013) · Applied Physics Letters · doi:10.1063/1.4824205 · Cited by 223
Liu, W., Kräemer, S., Sarkar, D., Li, H., Ajayan, P. M., & Banerjee, K. (2013) · Chemistry of Materials · doi:10.1021/cm4021854 · Cited by 149
Self-citationZhang, Y., Xu, J., Xu, P., Zhu, Y., Chen, X., & Yu, W. (2010) · Nanotechnology · doi:10.1088/0957-4484/21/28/285501 · Cited by 146
Fundamental limitations of conventional-FET biosensors: Quantum-mechanical-tunneling to the rescue
Sarkar, D., & Banerjee, K. (2012) · Conference digest · doi:10.1109/drc.2012.6256950 · Cited by 117
Self-citationSarkar, D., Goßner, H., Hänsch, W., & Banerjee, K. (2013) · Applied Physics Letters · doi:10.1063/1.4775358 · Cited by 109
Self-citationModulating electronic transport properties of MoS2 field effect transistor by surface overlayers
Lin, J., Zhong, J., Zhong, S., Li, H., Zhang, H., & Chen, W. (2013) · Applied Physics Letters · doi:10.1063/1.4818463 · Cited by 103
Self-citationProposal for all-graphene monolithic logic circuits
Kang, J., Sarkar, D., Khatami, Y., & Banerjee, K. (2013) · Applied Physics Letters · doi:10.1063/1.4818462 · Cited by 64
Self-citationLiquid-gated electric-double-layer transistor on layered metal dichalcogenide, SnS2
Yuan, H., Toh, M., Morimoto, K., Tan, W., Wei, F., Shimotani, H., Kloc, C., & Iwasa, Y. (2011) · Applied Physics Letters · doi:10.1063/1.3535613 · Cited by 61
A highly sensitive and selective hydrogen gas sensor from thick oriented films of MoS 2
Miremadi, B. K., Singh, R. C., Morrison, S. R., & Colbow, K. (1996) · Applied Physics A · doi:10.1007/bf01567880 · Cited by 43
Sarkar, D., Krall, M., & Banerjee, K. (2010) · Applied Physics Letters · doi:10.1063/1.3528338 · Cited by 41
Self-citationThe physics and backward diode behavior of heavily doped single layer MoS2 based p-n junctions
Sun, Q., Li, Y., He, J., et al. (2013) · Applied Physics Letters · doi:10.1063/1.4794802 · Cited by 39
Sarkar, D., Goßner, H., Hänsch, W., & Banerjee, K. (2013) · Applied Physics Letters · doi:10.1063/1.4804577 · Cited by 28
Self-citation
Cited by
Environmental Applications of 2D Molybdenum Disulfide (MoS2) Nanosheets
Wang, Z., & Mi, B. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.7b01466 · Cited by 914
Two‐Dimensional Nanostructured Materials for Gas Sensing
Liu, X., Ma, T., Pinna, N., & Zhang, J. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201702168 · Cited by 851
Electrically-Transduced Chemical Sensors Based on Two-Dimensional Nanomaterials
Meng, Z., Stolz, R. M., Mendecki, L., & Mirica, K. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00311 · Cited by 773
Chemical sensing with 2D materials
Anichini, C., Czepa, W., Pakulski, D., Aliprandi, A., Ciesielski, A., & Samorì, P. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00417j · Cited by 756
Superior Chemical Sensing Performance of Black Phosphorus: Comparison with MoS2 and Graphene
Cho, S., Lee, Y., Koh, H., Jung, H., Kim, J., Yoo, H., Kim, J., & Jung, H. (2016) · Advanced Materials · doi:10.1002/adma.201601167 · Cited by 431
Metadata
- Authors
- Sarkar, D., Xie, X., Kang, J., Zhang, H., Liu, W., Navarrete, J., Moskovits, M., & Banerjee, K.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-04-17
- Volume
- 15
- Issue
- 5
- Pages
- 2852-2862
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2037658908
- Cited by
- 395
- References
- 52
- FWCI
- 16.79
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
