Activation of metal–organic framework materials

Reticular synthesis and the design of new materials

Yaghi, O. M., O'Keeffe, M., Ockwig, N. W., Chae, H. K., Eddaoudi, M., & Kim, J. (2003) · Nature · doi:10.1038/nature01650 · Cited by 9,101

Design and synthesis of an exceptionally stable and highly porous metal-organic framework

Li, H., Eddaoudi, M., O'Keeffe, M., & Yaghi, O. M. (1999) · Nature · doi:10.1038/46248 · Cited by 8,554

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage

Eddaoudi, M., Kim, J., Rosi, N., Vodak, D., Wachter, J., O'Keeffe, M., & Yaghi, O. M. (2002) · Science · doi:10.1126/science.1067208 · Cited by 8,132

Metal-organic framework materials as catalysts

Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability

Cavka, J. H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., & Lillerud, K. P. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8057953 · Cited by 7,336

Metal–Organic Framework Materials as Chemical Sensors

Kreno, L. E., Leong, K., Farha, O. K., Allendorf, M., Van Duyne, R. P., & Hupp, J. T. (2012) · Chemical Reviews · doi:10.1021/cr200324t · Cited by 7,136

Metal–Organic Frameworks for Separations

Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323

Hybrid porous solids: past, present, future

Férey, G. (2008) · Chem. Soc. Rev. · doi:10.1039/b618320b · Cited by 5,822

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area

Férey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., Surblé, S., & Margiolaki, I. (2005) · Science · doi:10.1126/science.1116275 · Cited by 5,430

Hydrogen storage in metal–organic frameworks

Murray, L. J., Dincă, M., & Long, J. R. (2009) · Chemical Society Reviews · doi:10.1039/b802256a · Cited by 4,532

High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO 2 Capture

Banerjee, R., Phan, A., Wang, B., Knobler, C., Furukawa, H., O'Keeffe, M., & Yaghi, O. M. (2008) · Science · doi:10.1126/science.1152516 · Cited by 4,205

Metal–Organic Frameworks in Biomedicine

Horcajada, P., Gref, R., Baati, T., Allan, P. K., Maurin, G., Couvreur, P., Férey, G., Morris, R. E., & Serre, C. (2012) · Chemical Reviews · doi:10.1021/cr200256v · Cited by 4,168

Ultrahigh Porosity in Metal-Organic Frameworks

Furukawa, H., Ko, N., Go, Y. B., Aratani, N., Choi, S. B., Choi, E., Yazaydin, A. Ö., Snurr, R. Q., O’Keeffe, M., Kim, J., et al. (2010) · Science · doi:10.1126/science.1192160 · Cited by 3,904

Enantioselective catalysis with homochiral metal–organic frameworks

Ma, L., Abney, C., & Lin, W. (2009) · Chemical Society Reviews · doi:10.1039/b807083k · Cited by 3,109

Soft porous crystals

Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486

Large-Pore Apertures in a Series of Metal-Organic Frameworks

Deng, H., Grunder, S., Cordova, K. E., Valente, C., Furukawa, H., Hmadeh, M., Gándara, F., Whalley, A. C., Liu, Z., Asahina, S., et al. (2012) · Science · doi:10.1126/science.1220131 · Cited by 2,126

Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery

Della Rocca, J., Liu, D., & Lin, W. (2011) · Accounts of Chemical Research · doi:10.1021/ar200028a · Cited by 2,087

Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts

Feng, D., Gu, Z., Li, J., Jiang, H., Wei, Z., & Zhou, H. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201204475 · Cited by 1,978

Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?

Farha, O. K., Eryazici, I., Jeong, N. C., Hauser, B. G., Wilmer, C. E., Sarjeant, A. A., Snurr, R. Q., Nguyen, S. T., Yazaydın, A. Ö., & Hupp, J. T. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3055639 · Cited by 1,958

Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4.xC6H5NO2

Hoskins, B. F., & Robson, R. (1990) · Journal of the American Chemical Society · doi:10.1021/ja00160a038 · Cited by 1,933

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities

Farha, O. K., Özgür Yazaydın, A., Eryazici, I., Malliakas, C. D., Hauser, B. G., Kanatzidis, M. G., Nguyen, S. T., Snurr, R. Q., & Hupp, J. T. (2010) · Nature Chemistry · doi:10.1038/nchem.834 · Cited by 1,741

Large-scale screening of hypothetical metal–organic frameworks

Wilmer, C. E., Leaf, M., Lee, C. Y., Farha, O. K., Hauser, B. G., Hupp, J. T., & Snurr, R. Q. (2012) · Nature Chemistry · doi:10.1038/nchem.1192 · Cited by 1,439

Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials

Farha, O. K., & Hupp, J. T. (2010) · Accounts of Chemical Research · doi:10.1021/ar1000617 · Cited by 1,426

Establishing Microporosity in Open Metal−Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)

Li, H., Eddaoudi, M., Groy, T. L., & Yaghi, O. M. (1998) · Journal of the American Chemical Society · doi:10.1021/ja981669x · Cited by 1,220

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework

Mondloch, J. E., Bury, W., Fairen-Jimenez, D., Kwon, S., DeMarco, E. J., Weston, M. H., Sarjeant, A. A., Nguyen, S. T., Stair, P. C., Snurr, R. Q., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4050828 · Cited by 1,008

Supercritical fluids as solvents for chemical and materials processing

Eckert, C. A., Knutson, B. L., & Debenedetti, P. G. (1996) · Nature · doi:10.1038/383313a0 · Cited by 923

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks

Morris, W., Volosskiy, B., Demir, S., Gándara, F., McGrier, P. L., Furukawa, H., Cascio, D., Stoddart, J. F., & Yaghi, O. M. (2012) · Inorganic Chemistry · doi:10.1021/ic300825s · Cited by 906

Ion Conductivity and Transport by Porous Coordination Polymers and Metal–Organic Frameworks

Horike, S., Umeyama, D., & Kitagawa, S. (2013) · Accounts of Chemical Research · doi:10.1021/ar300291s · Cited by 839

Methane storage in advanced porous materials

Makal, T. A., Li, J.-R., Lu, W., & Zhou, H.-C. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35251f · Cited by 812

Light-Harvesting Metal–Organic Frameworks (MOFs): Efficient Strut-to-Strut Energy Transfer in Bodipy and Porphyrin-Based MOFs

Lee, C. Y., Farha, O. K., Hong, B. J., Sarjeant, A. A., Nguyen, S. T., & Hupp, J. T. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206029a · Cited by 795

Assembly of porphyrin building blocks into network structures with large channels

Abrahams, B. F., Hoskins, B. F., Michail, D. M., & Robson, R. (1994) · Nature · doi:10.1038/369727a0 · Cited by 786

Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks

Nouar, F., Eubank, J. F., Bousquet, T., Wojtas, L., Zaworotko, M. J., & Eddaoudi, M. (2008) · Journal of the American Chemical Society · doi:10.1021/ja710123s · Cited by 668

Framework-Catenation Isomerism in Metal−Organic Frameworks and Its Impact on Hydrogen Uptake

Ma, S., Sun, D., Ambrogio, M., Fillinger, J. A., Parkin, S., & Zhou, H.-C. (2007) · Journal of the American Chemical Society · doi:10.1021/ja067435s · Cited by 636

Light-Harvesting and Ultrafast Energy Migration in Porphyrin-Based Metal–Organic Frameworks

Son, H.-J., Jin, S., Patwardhan, S., Wezenberg, S. J., Jeong, N. C., So, M., Wilmer, C. E., Sarjeant, A. A., Schatz, G. C., Snurr, R. Q., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja310596a · Cited by 592

Interpenetration control in metal–organic frameworks for functional applications

Jiang, H.-L., Makal, T. A., & Zhou, H.-C. (2013) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2013.03.017 · Cited by 563

Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials

Nelson, A. P., Farha, O. K., Mulfort, K. L., & Hupp, J. T. (2009) · Journal of the American Chemical Society · doi:10.1021/ja808853q · Cited by 539

Controlling interpenetration in metal–organic frameworks by liquid-phase epitaxy

Shekhah, O., Wang, H., Paradinas, M., Ocal, C., Schüpbach, B., Terfort, A., Zacher, D., Fischer, R. A., & Wöll, C. (2009) · Nature Materials · doi:10.1038/nmat2445 · Cited by 529

Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework

An, J., Farha, O. K., Hupp, J. T., Pohl, E., Yeh, J. I., & Rosi, N. L. (2012) · Nature Communications · doi:10.1038/ncomms1618 · Cited by 426

Porous Materials and Supercritical Fluids

Cooper, A. I. (2003) · Advanced Materials · doi:10.1002/adma.200300380 · Cited by 389

Temperature and Concentration Control over Interpenetration in a Metal−Organic Material

Zhang, J., Wojtas, L., Larsen, R. W., Eddaoudi, M., & Zaworotko, M. J. (2009) · Journal of the American Chemical Society · doi:10.1021/ja906911q · Cited by 388

Control over Catenation in Metal−Organic Frameworks via Rational Design of the Organic Building Block

Farha, O. K., Malliakas, C. D., Kanatzidis, M. G., & Hupp, J. T. (2010) · Journal of the American Chemical Society · doi:10.1021/ja909519e · Cited by 363

Energy Transfer Dynamics in Metal−Organic Frameworks

Kent, C. A., Mehl, B. P., Ma, L., Papanikolas, J. M., Meyer, T. J., & Lin, W. (2010) · Journal of the American Chemical Society · doi:10.1021/ja102804s · Cited by 355

Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows

Zhao, D., Yuan, D., Sun, D., & Zhou, H.-C. (2009) · Journal of the American Chemical Society · doi:10.1021/ja901109t · Cited by 339

A General Thermolabile Protecting Group Strategy for Organocatalytic Metal−Organic Frameworks

Lun, D. J., Waterhouse, G. I. N., & Telfer, S. G. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202223d · Cited by 330

Metal–Organic Framework Nanospheres with Well‐Ordered Mesopores Synthesized in an Ionic Liquid/CO2/Surfactant System

Zhao, Y., Zhang, J., Han, B., Song, J., Li, J., & Wang, Q. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201005314 · Cited by 302

Metal–organic framework (MOF) aerogels with high micro- and macroporosity

Lohe, M. R., Rose, M., & Kaskel, S. (2009) · Chemical Communications · doi:10.1039/b910175f · Cited by 286

Post-Synthesis Modification of a Metal–Organic Framework To Form Metallosalen-Containing MOF Materials

Shultz, A. M., Sarjeant, A. A., Farha, O. K., Hupp, J. T., & Nguyen, S. T. (2011) · Journal of the American Chemical Society · doi:10.1021/ja204820d · Cited by 268

Ternary Systems of Liquid Carbon Dioxide

Francis, A. W. (1954) · The Journal of Physical Chemistry · doi:10.1021/j150522a014 · Cited by 265

Chirality-Controlled and Solvent-Templated Catenation Isomerism in Metal−Organic Frameworks

Ma, L., & Lin, W. (2008) · Journal of the American Chemical Society · doi:10.1021/ja804944r · Cited by 257

Gram-scale, high-yield synthesis of a robust metal–organic framework for storing methane and other gases

Wilmer, C. E., Farha, O. K., Yildirim, T., Eryazici, I., Krungleviciute, V., Sarjeant, A. A., Snurr, R. Q., & Hupp, J. T. (2013) · Energy & Environmental Science · doi:10.1039/c3ee24506c · Cited by 237

Designing Higher Surface Area Metal–Organic Frameworks: Are Triple Bonds Better Than Phenyls?

Farha, O. K., Wilmer, C. E., Eryazici, I., Hauser, B. G., Parilla, P. A., O’Neill, K., Sarjeant, A. A., Nguyen, S. T., Snurr, R. Q., & Hupp, J. T. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302623w · Cited by 222

A Metal−Organic Framework with Covalently Bound Organometallic Complexes

Oisaki, K., Li, Q., Furukawa, H., Czaja, A. U., & Yaghi, O. M. (2010) · Journal of the American Chemical Society · doi:10.1021/ja103016y · Cited by 222

Reconciling the Discrepancies between Crystallographic Porosity and Guest Access As Exemplified by Zn-HKUST-1

Feldblyum, J. I., Liu, M., Gidley, D. W., & Matzger, A. J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2055935 · Cited by 221

Magnesium Nanocrystals Embedded in a Metal–Organic Framework: Hybrid Hydrogen Storage with Synergistic Effect on Physi‐ and Chemisorption

Lim, D., Yoon, J. W., Ryu, K. Y., & Suh, M. P. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201206055 · Cited by 171

A Highly Porous Metal–Organic Framework with Open Nickel Sites

Gedrich, K., Senkovska, I., Klein, N., Stoeck, U., Henschel, A., Lohe, M. R., Baburin, I. A., Mueller, U., & Kaskel, S. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201001735 · Cited by 167

Control of Interpenetration and Gas‐Sorption Properties of Metal–Organic Frameworks by a Simple Change in Ligand Design

Prasad, T. K., & Suh, M. P. (2012) · Chemistry – A European Journal · doi:10.1002/chem.201200456 · Cited by 166

Adsorptive capturing and storing greenhouse gases such as sulfur hexafluoride and carbon tetrafluoride using metal–organic frameworks

Senkovska, I., Barea, E., Navarro, J. A. R., & Kaskel, S. (2012) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2012.02.021 · Cited by 146

Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal–organic framework NU-111

Peng, Y., Gadipelli, S., Wilmer, C. E., Eryazici, I., Snurr, R. Q., Hupp, J. T., Yildirim, T., & Farha, O. K. (2013) · Chemical Communications · doi:10.1039/c3cc40819a · Cited by 146

Control over Catenation in Pillared Paddlewheel Metal–Organic Framework Materials via Solvent-Assisted Linker Exchange

Bury, W., Fairen‐Jiménez, D., Lalonde, M. B., Snurr, R. Q., Farha, O. K., & Hupp, J. T. (2013) · Chemistry of Materials · doi:10.1021/cm303749m · Cited by 141

Selective CO 2 adsorption in a flexible non-interpenetrated metal–organic framework

Kim, T. K., & Suh, M. P. (2011) · Chemical Communications · doi:10.1039/c0cc05199c · Cited by 129

A Straight Forward Route for the Development of Metal–Organic Frameworks Functionalized with Aromatic −OH Groups: Synthesis, Characterization, and Gas (N 2 , Ar, H 2 , CO 2 , CH 4 , NH 3 ) Sorption Properties

Spanopoulos, I., Xydias, P., Malliakas, C. D., & Trikalitis, P. N. (2013) · Inorganic Chemistry · doi:10.1021/ic302010e · Cited by 128

A non-interpenetrated porous metal–organic framework with high gas-uptake capacity

Han, D., Jiang, F., Wu, M., Chen, L., Chen, Q., & Hong, M. (2011) · Chemical Communications · doi:10.1039/c1cc12858b · Cited by 118

Dye Encapsulation Inside a New Mesoporous Metal–Organic Framework for Multifunctional Solvatochromic‐Response Function

Grünker, R., Bon, V., Heerwig, A., Klein, N., Müller, P., Stoeck, U., Baburin, I. A., Müeller, U., Senkovska, I., & Kaskel, S. (2012) · Chemistry - A European Journal · doi:10.1002/chem.201202352 · Cited by 91

High-throughput screening: speeding up porous materials discovery

Wollmann, P., Leistner, M., Stoeck, U., Grünker, R., Gedrich, K., Klein, N., Throl, O., Grählert, W., Senkovska, I., Dreisbach, F., et al. (2011) · Chemical Communications · doi:10.1039/c1cc10674k · Cited by 79

Comparative Study of Activation Methods on Tuning Gas Sorption Properties of a Metal–Organic Framework with Nanosized Ligands

He, Y., Tan, Y., & Zhang, J. (2012) · Inorganic Chemistry · doi:10.1021/ic3017529 · Cited by 60

New synthetic routes towards MOF production at scale

Rubio-Martinez, M., Avci-Camur, C., Thornton, A. W., Imaz, I., Maspoch, D., & Hill, M. R. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00109f · Cited by 990

Metal–Organic Frameworks for Drug Delivery: A Design Perspective

Lawson, H. D., Walton, S. P., & Chan, C. (2021) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.1c01089 · Cited by 916

Advances, Updates, and Analytics for the Computation-Ready, Experimental Metal–Organic Framework Database: CoRE MOF 2019

Chung, Y. G., Haldoupis, E., Bucior, B. J., Haranczyk, M., Lee, S., Zhang, H., Vogiatzis, K. D., Milisavljevic, M., Ling, S., Camp, J. S., et al. (2019) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.9b00835 · Cited by 863

Best Practices for the Synthesis, Activation, and Characterization of Metal–Organic Frameworks

Howarth, A. J., Peters, A. W., Vermeulen, N. A., Wang, T. C., Hupp, J. T., & Farha, O. K. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02626 · Cited by 746

A dual Ni/Co-MOF-reduced graphene oxide nanocomposite as a high performance supercapacitor electrode material

Rahmanifar, M. S., Hesari, H., Noori, A., Masoomi, M. Y., Morsali, A., & Mousavi, M. F. (2018) · Electrochimica Acta · doi:10.1016/j.electacta.2018.04.130 · Cited by 389