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A rechargeable zinc-air battery based on zinc peroxide chemistry
Abstract
When two is better than four: Batteries based on the reaction of zinc and oxygen have been used for more than a century, but these have been primary (that is, nonrechargeable) cells. These batteries use an alkaline electrolyte and require a four-electron reduction of oxygen to water, which is a slow process. Sun et al. show that with the right choice of nonalkaline electrolyte, the battery can operate using a two-electron zinc-oxygen/zinc peroxide chemistry that is far more reversible. By making the electrolyte hydrophobic, water is excluded from the near surface of the cathode, thus preventing the four-electron reduction. These batteries also show higher energy density and better cycling stability. Science , this issue p. 46
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Metadata
- Authors
- Sun, W., Wang, F., Zhang, B., Zhang, M., Küpers, V., Ji, X., Theile, C., Bieker, P., Xu, K., Wang, C., & Winter, M.
- Venue
- Science
- Published
- 2021-01
- Volume
- 371
- Issue
- 6524
- Pages
- 46-51
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W3114432452
- Cited by
- 1,082
- References
- 63
- FWCI
- 42.20
- Type
- journal article
- Language
- en
- Open access
- closed
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