Metal‐Organic Frameworks Derived Nanotube of Nickel–Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water Splitting

Yan, Liting; Cao, Lei; Dai, Pengcheng; Gu, Xin; Liu, Dandan; Li, Liangjun; Wang, Ying; Zhao, Xuebo

doi:10.1002/adfm.201703455

Cited by 738

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Metal‐Organic Frameworks Derived Nanotube of Nickel–Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water Splitting

Yan, Liting, Cao, Lei, Dai, Pengcheng, Gu, Xin, Liu, Dandan, Li, Liangjun, Wang, Ying, Zhao, Xuebo·2017·Advanced Functional Materials

DOI 10.1002/adfm.201703455

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Abstract

The design of highly efficient, stable, and noble‐metal‐free bifunctional electrocatalysts for overall water splitting is critical but challenging. Herein, a facile and controllable synthesis strategy for nickel–cobalt bimetal phosphide nanotubes as highly efficient electrocatalysts for overall water splitting via low‐temperature phosphorization from a bimetallic metal‐organic framework (MOF‐74) precursor is reported. By optimizing the molar ratio of Co/Ni atoms in MOF‐74, a series of Co x Ni y P catalysts are synthesized, and the obtained Co4Ni1P has a rare form of nanotubes that possess similar morphology to the MOF precursor and exhibit perfect dispersal of the active sites. The nanotubes show remarkable hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) catalytic performance in an alkaline electrolyte, affording a current density of 10 mA cm−2 at overpotentials of 129 mV for HER and 245 mV for OER, respectively. An electrolyzer with Co4Ni1P nanotubes as both the cathode and anode catalyst in alkaline solutions achieves a current density of 10 mA cm−2 at a voltage of 1.59 V, which is comparable to the integrated Pt/C and RuO 2 counterparts and ranks among the best of the metal‐phosphide electrocatalysts reported to date.

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Authors: Yan, L., Cao, L., Dai, P., Gu, X., Liu, D., Li, L., Wang, Y., & Zhao, X.
Venue: Advanced Functional Materials
Publisher: Wiley
Published: 2017-08-25
Volume: 27
Issue: 40
ISSN: 1616-301X (ISSN-L)
1616-3028
DOI: 10.1002/adfm.201703455
OpenAlex: W2749119548
Cited by: 738
References: 16
FWCI: 23.70
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Funders: National Natural Science Foundation of China (21473254)

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This page: CoChat. (2026). Citation check: Metal‐Organic Frameworks Derived Nanotube of Nickel–Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water Splitting. https://app.cochat.ai/papers/10.1002/adfm.201703455
The paper: Yan, L., Cao, L., Dai, P., Gu, X., Liu, D., Li, L., Wang, Y., & Zhao, X. (2017). Metal‐Organic Frameworks Derived Nanotube of Nickel–Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water Splitting. Advanced Functional Materials. https://doi.org/10.1002/adfm.201703455

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Metal‐Organic Frameworks Derived Nanotube of Nickel–Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water Splitting

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