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Mechanochemistry: New Tools to Navigate the Uncharted Territory of “Impossible” Reactions
Open accessAbstract
Mechanochemical transformations have made chemists enter unknown territories, forcing a different chemistry perspective. While questioning or revisiting familiar concepts belonging to solution chemistry, mechanochemistry has broken new ground, especially in the panorama of organic synthesis. Not only does it foster new “thinking outside the box”, but it also has opened new reaction paths, allowing to overcome the weaknesses of traditional chemistry exactly where the use of well‐established solution‐based methodologies rules out progress. In this Review, the reader is introduced to an intriguing research subject not yet fully explored and waiting for improved understanding. Indeed, the study is mainly focused on organic transformations that, although impossible in solution, become possible under mechanochemical processing conditions, simultaneously entailing innovation and expanding the chemical space.
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Self-citationA Comparison of Environmental Impact of Various Silicas Using a Green Chemistry Evaluator
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Epimerization-Free C-Term Activation of Peptide Fragments by Ball Milling
Yeboue, Y., Jean, M., Subra, G., Martínez, J., Lamaty, F., & Métro, T. (2021) · Organic Letters · doi:10.1021/acs.orglett.0c03209 · Cited by 42
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Cheruku, S., Sajith, A. M., Narayana, Y., Shetty, P., Sandhya, N. C., Sagar, K. S., Manikyanally, K. N., Rangappa, K. S., & Mantelingu, K. (2021) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.0c02999 · Cited by 36
Grindstone chemistry: A “green” approach for the synthesis and derivatization of heterocycles
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Advanced Mechanochemistry Device for Sustainable Synthetic Processes
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Kabachnik–Fields Reaction by Mechanochemistry: New Horizons from Old Methods
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Self-citationMei, K., Guo, Y., Bai, J., Costa, P. M., Kafa, H., Protti, A., Hider, R. C., & Al‐Jamal, K. T. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b03577 · Cited by 34
Mechanochemical Fischer indolisation: an eco-friendly design for a timeless reaction
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Catalytic Room‐Temperature C−N Coupling of Amides and Isocyanates by Using Mechanochemistry
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Competition between Hydrogen and Halogen Bonds: The Effect of Solvent Volume
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Epimerization‐Free C‐Terminal Peptide Activation
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Synthesis of acylglycerol derivatives by mechanochemistry
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Stainless Steel Ball Milling for Hydrogen Generation and its Application for Reduction
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Developing benign syntheses using ion pairs via solvent-free mechanochemistry
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Air–Water Interface Assembly of Protein Nanofibrils Promoted by Hydrophobic Additives
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Mechanochemical Preparation and Self-Assembly of Protein:Dye Hybrids for White Luminescence
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Mechanochemistry for sustainable and efficient dehydrogenation/hydrogenation
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Protein-assisted scalable mechanochemical exfoliation of few-layer biocompatible graphene nanosheets
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Cited by
Green metrics in mechanochemistry
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Self-citation
Metadata
- Authors
- Cuccu, F., De Luca, L., Delogu, F., Colacino, E., Solin, N., Mocci, R., & Porcheddu, A.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2022-07-21
- Volume
- 15
- Issue
- 17
- Pages
- e202200362-e202200362
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W4286494080
- Cited by
- 339
- References
- 136
- FWCI
- 19.27
- Type
- journal article
- Language
- en
- Open access
- hybrid
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
