A Versatile Polymer Co-Network with Broadened Glass Transition Showing Adjustable Multiple Shape Memory Effect
Abstract
Abstract In this study, a versatile poly(methyl methacrylate)–poly(ϵ‐caprolactone) covalently crosslinked polymer co‐network (PMMA–PCL CPN) tethering all polymeric chains between netpoints is designed and prepared to develop a novel type of adjustable multiple‐shape memory polymers. The CPN is demonstrated to produce a broadening of glass transition and memorize up to four different shapes based on a single thermal transition for the first time, as the whole energy stored in the broad transition can be distributed into several parts for multi‐step shape fixation and recovery in one‐shape memory cycle. Furthermore, the versatile multiple‐shape memory effects from dual to quadruple can be adjusted simply by shifting the corresponding deformation temperatures on demands, without variation of material chemistry.
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The temperature-memory effect approach has been largely employed to achieve multiple-way SMPs with a broad glass transition or a broad melting transition as the switching transition.
“Such an approach has been largely employed to achieve multiple-way SMPs with a broad glass transition [82-92] and a broad melting transition [93-95] as the switching transition.”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [85]
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- Authors
- Li, J., Liu, T., Pan, Y., Xia, S., Zheng, Z., Ding, X., & Peng, Y.
- Affiliations
- Chinese Academy of Sciences (CN)
- Corresponding author
- Ding, Xiaobin
- Peng, Yuxing
- Venue
- Macromolecular Chemistry and Physics
- Publisher
- Wiley
- Published
- 2012-09-27
- Volume
- 213
- Issue
- 21
- Pages
- 2246-2252
- ISSN
- 1022-1352 (ISSN-L)
- 1521-3935
- OpenAlex
- W2027110710
- Cited by
- 32
- References
- 27
- Citations by year
- 2025: 1 · 2024: 1 · 2023: 5 · 2022: 1 · 2021: 3 · 2020: 3 · 2019: 4 · 2018: 4 · 2016: 1 · 2015: 2 · 2014: 6 · 2013: 1
- FWCI
- 2.26
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecular Chemistry and Physics (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Materials Chemistry › Material Dynamics and Properties
- Keywords
- shape memory polymers, poly(methyl methacrylate), polycaprolactone, shape recovery
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