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New insights into Archean sulfur cycle from mass-independent sulfur isotope records from the Hamersley Basin, Australia
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“The pyrite in the S-MIF interval (below the pink band in Fig. 2) carries distinct S-MIF signals, with Δ33S reaching as high as +8‰ and the Δ36S/Δ33S ratios centering around −0.98, which is characteristic of the Neoarchean array (Fig. 3) (30, 43).”
From Rapid oxygenation of Earth’s atmosphere 2.33 billion years ago (2016) · cites this paper as [30]
In the citing paper
“This is also supported by the Δ36S/Δ33S slope of −0.9, which is widespread in Neoarchean sedimentary rocks and interpreted to be of atmospheric origin (9, 25, 30, 43).”
From Rapid oxygenation of Earth’s atmosphere 2.33 billion years ago (2016) · cites this paper as [30]
In the citing paper
“For simplicity, we did not explicitly model different kinetics for different forms of sulfur (for example, thiosulfate, S8, or sulfate) that are likely present in the Archean oceans (1, 30).”
From Rapid oxygenation of Earth’s atmosphere 2.33 billion years ago (2016) · cites this paper as [30]
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Cited by
Sorted by citations
The oxygenation of the atmosphere and oceans
Holland, H. D. (2006) · Philosophical Transactions of the Royal Society B: Biological Sciences · doi:10.1098/rstb.2006.1838 · Cited by 1,535
“2000, 2002; Ono et al .”
Dating the rise of atmospheric oxygen
Bekker, A., Holland, H. D., Wang, P.-L., Rumble, D., Stein, H. J., Hannah, J. L., Coetzee, L. L., & Beukes, N. J. (2004) · Nature · doi:10.1038/nature02260 · Cited by 1,435
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“…ultraviolet radiation-induced photochemical processes, have been identifi ed in pyrite, pyrrhotite, chalcopyrite, and galena, in addition to sulfate minerals, in the Archean geologic record (Farquhar et al. 2000a; Hu et al. 2003; Mojzsis et al. 2003; Ono et al. 2003; Bekker et al. 2004).”
BackgroundInfluentialPavlov, A. A., & Kasting, J. F. (2002) · Astrobiology · doi:10.1089/153110702753621321 · Cited by 912
Self-citationHazen, R. M., Papineau, D., Bleeker, W., Downs, R. T., Ferry, J. M., McCoy, T. J., Sverjensky, D. A., & Yang, H. (2008) · American Mineralogist · doi:10.2138/am.2008.2955 · Cited by 701
“…that the atmosphere was mostly anoxic from the beginning of the sedimentary rock record at about 3.85 Ga until the Paleoproterozoic glaciations (Farquhar et al. 2000, 2001, 2007; Mojzsis et al. 2003; Ono et al. 2003; Bekker et al. 2004; Papineau et al. 2005, 2007; Papineau and Mojzsis 2006).”
BackgroundInfluentialMultiple sulfur isotopes and the evolution of the atmosphere
Farquhar, J., & Wing, B. A. (2003) · Earth and Planetary Science Letters · doi:10.1016/s0012-821x(03)00296-6 · Cited by 638
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“However, it can form through the photolysis of volcanic SO2 gas (Farquhar et al. 2001; Pavlov & Kasting 2002; Ono et al. 2003) or from the SO2 released in hydrothermal settings (Canfield & Raiswell 1999).”
BackgroundHISTORY AND APPLICATIONS OF MASS-INDEPENDENT ISOTOPE EFFECTS
Thiemens, M. H. (2006) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev.earth.34.031405.125026 · Cited by 412
“Recent work by Ono et al. (2003) has simultaneously extended the measurement base and developed a sulfur photochemical model for the Archean atmosphere.”
BackgroundRapid oxygenation of Earth’s atmosphere 2.33 billion years ago
Luo, G., Ono, S., Beukes, N. J., Wang, D. T., Xie, S., & Summons, R. E. (2016) · Science Advances · doi:10.1126/sciadv.1600134 · Cited by 371
“For simplicity, we did not explicitly model different kinetics for different forms of sulfur (for example, thiosulfate, S8, or sulfate) that are likely present in the Archean oceans (1, 30).”
BackgroundSelf-citationMultiple sulfur isotopes and the evolution of Earth's surface sulfur cycle
Johnston, D. T. (2011) · Earth-Science Reviews · doi:10.1016/j.earscirev.2011.02.003 · Cited by 383
“First noted in (Ono et al., 2003), this array – where 1.”
BackgroundHow Earth's atmosphere evolved to an oxic state: A status report
Catling, D. C., & Claire, M. W. (2005) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2005.06.013 · Cited by 376
Late Archean Biospheric Oxygenation and Atmospheric Evolution
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Early Archaean Microorganisms Preferred Elemental Sulfur, Not Sulfate
Philippot, P., Van Zuilen, M., Lepot, K., Thomazo, C., Farquhar, J., & Van Kranendonk, M. J. (2007) · Science · doi:10.1126/science.1145861 · Cited by 365
Ono, S., Wing, B., Johnston, D., Farquhar, J., & Rumble, D. (2006) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2006.01.022 · Cited by 347
“Recent multiple-sulfur isotope studies have been fueled by a discovery of anomalous S and S abundances in Archean sulfate and sulfide minerals that reflect unique atmospheric sulfur chemistry in an early anoxic atmosphere (Farquhar et al., 2000a; Ono et al., 2003; Mojzsis et al., 2003).”
BackgroundInfluentialSelf-citationDauphas, N., John, S. G., & Rouxel, O. J. (2017) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2017.82.11 · Cited by 339
“Past studies of non-mass dependent and mass dependent sulfur isotope records of sedimentary pyrite have placed important constraints on the biogeochemical cycle of sulfur and the evolution of ocean chemistry during the rise in atmospheric oxygen (Cameron 1982; Farquhar et al. 2000, 2007; Mojzsis et al. 2003; Ono et al…”
BackgroundA coupled atmosphere–ecosystem model of the early Archean Earth
KHARECHA, P., KASTING, J., & SIEFERT, J. (2005) · Geobiology · doi:10.1111/j.1472-4669.2005.00049.x · Cited by 321
“Because the SO2 outgassing rate was likely approximately 1011 mol year−1 (Ono et al., 2003), and the H2 outgassing rate was set at approximately 5 × 1012 mol year−1, we expected that this ecosystem would show lower NPP values than our H2-based ones.”
ResultSelf-citationThe Pale Orange Dot: The Spectrum and Habitability of Hazy Archean Earth
Arney, G., Domagal-Goldman, S. D., Meadows, V. S., Wolf, E. T., Schwieterman, E., Charnay, B., Claire, M., Hébrard, E., & Trainer, M. G. (2016) · Astrobiology · doi:10.1089/ast.2015.1422 · Cited by 327
“…also has a long heritage of being used to study photochemistry in nonhazy atmospheres ( e.g. , Kasting and Donahue, 1980; Pavlov and Kasting, 2002; Ono et al. , 2003; Segura et al. , 2003, 2005, 2007, 2010; Zahnle et al. , 2006; Grenfell et al. , 2007; Catling et al. , 2010; Domagal-Goldman et…”
Sulfate was a trace constituent of Archean seawater
Crowe, S. A., Paris, G., Katsev, S., Jones, C., Kim, S.-T., Zerkle, A. L., Nomosatryo, S., Fowle, D. A., Adkins, J. F., Sessions, A. L., et al. (2014) · Science · doi:10.1126/science.1258966 · Cited by 328
Isotopic evidence for Mesoarchaean anoxia and changing atmospheric sulphur chemistry
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“Ono et al. (2003) consider 3.5 × 108, 1 × 109, and 3.5 × 109 cm−2 s−1 for their low, medium and high volcanic fluxes, respectively.”
BackgroundResultInfluentialA Late Archean Sulfidic Sea Stimulated by Early Oxidative Weathering of the Continents
Reinhard, C. T., Raiswell, R., Scott, C., Anbar, A. D., & Lyons, T. W. (2009) · Science · doi:10.1126/science.1176711 · Cited by 287
Pervasive oxygenation along late Archaean ocean margins
Kendall, B., Reinhard, C. T., Lyons, T. W., Kaufman, A. J., Poulton, S. W., & Anbar, A. D. (2010) · Nature Geoscience · doi:10.1038/ngeo942 · Cited by 286
Reconstructing Earth's surface oxidation across the Archean-Proterozoic transition
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“3A), which is in agreement with previous multiple sulfur isotope studies of Neoarchean successions (Kaufman et al., 2007; Ono et al., 2003), as well as the products of ultraviolet (UV) photolysis experiments with SO 2 in the absence of oxygen (Farquhar and Wing, 2003).”
Spectral Evolution of an Earth‐like Planet
Kaltenegger, L., Traub, W. A., & Jucks, K. W. (2007) · The Astrophysical Journal · doi:10.1086/510996 · Cited by 274
“From a variety of geological evidence, we know that significant concentrations of free O2 began to appear in the atmosphere (see e.g Cloud 1972; Farquhar et al. 2000, 2001; Kasting 2002; Pavlov et al. 2001; Ono et al. 2003).”
BackgroundBeukes, N. J., & Gutzmer, J. (2008) · doi:10.5382/rev.15.01 · Cited by 275
Late Archean rise of aerobic microbial ecosystems
Eigenbrode, J. L., & Freeman, K. H. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0607540103 · Cited by 251
Self-citationSulphur isotope evidence for an oxic Archaean atmosphere
Ohmoto, H., Watanabe, Y., Ikemi, H., Poulson, S. R., & Taylor, B. E. (2006) · Nature · doi:10.1038/nature05044 · Cited by 261
Ueno, Y., Ono, S., Rumble, D., III, & Maruyama, S. (2008) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2008.08.026 · Cited by 254
Self-citationA 200-million-year delay in permanent atmospheric oxygenation
Poulton, S. W., Bekker, A., Cumming, V. M., Zerkle, A. L., Canfield, D. E., & Johnston, D. T. (2021) · Nature · doi:10.1038/s41586-021-03393-7 · Cited by 243
A bistable organic-rich atmosphere on the Neoarchaean Earth
Zerkle, A. L., Claire, M. W., Domagal-Goldman, S. D., Farquhar, J., & Poulton, S. W. (2012) · Nature Geoscience · doi:10.1038/ngeo1425 · Cited by 239
““Ono et al., 2003”, (in blue) refers to the proposed explanation for the Archean reference line 14 .”
Geological constraints on the origin of oxygenic photosynthesis
Farquhar, J., Zerkle, A. L., & Bekker, A. (2011) · Photosynthesis Research · doi:10.1007/s11120-010-9594-0 · Cited by 223
“The threshold for the opening of this pathway was constrained to be approximately 10 PAL (10 bar) (Pavlov and Kasting 2002), but is sensitive to the concentration of atmospheric sulfur (Ono et al. 2003) 24 Photosynth Res (2011) 107:11–36”
BackgroundInfluentialS-33 constraints on the seawater sulfate contribution in modern seafloor hydrothermal vent sulfides
Ono, S., Shanks, W. C., Rouxel, O. J., & Rumble, D., III (2006) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2006.11.017 · Cited by 226
“Ono et al.(2007) GCA 71, 1170-1182 S-33 constraints on the hydrothermal vent sulfides”
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Organic haze, glaciations and multiple sulfur isotopes in the Mid-Archean Era
Domagal-Goldman, S. D., Kasting, J. F., Johnston, D. T., & Farquhar, J. (2008) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2008.01.040 · Cited by 204
Self-citationShen, Y., Farquhar, J. D., Masterson, A. L., Kaufman, A. J., & Buick, R. (2009) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2009.01.018 · Cited by 205
“…and rd. Plotted here are data for North Pole sulfate analyzed here (black filled circular symbols), s (black unfilled symbols), Mesoarchean samples (grey unfilled squares), Neoarchean (grey et al. (2006), Ono et al. (2003), Mojzsis et al. (2003), Papineau et al. (2007), Kamber and al.”
BackgroundBiogeochemical modelling of the rise in atmospheric oxygen
CLAIRE, M. W., CATLING, D. C., & ZAHNLE, K. J. (2006) · Geobiology · doi:10.1111/j.1472-4669.2006.00084.x · Cited by 200
“Analyses that show the presence of massindependent fractionation (MIF) of sulfur isotopes in Archean rocks (Farquhar et al., 2000; Farquhar & Wing, 2003; Ono et al., 2003; Zahnle et al., 2006) provide to many observers convincing evidence that the Archean atmosphere was globally weakly reducing.”
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Craddock, P. R., & Dauphas, N. (2011) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2010.12.045 · Cited by 202
“The primarymechanism for oxidation of Fe(II)aq in an Archean ocean that was purportedly anoxic (Canfield et al., 2000; Farquhar et al., 2000; Kasting, 1987; Ono et al., 2003; Pavlov and Kasting, 2002), is uncertain.”
BackgroundAn iron shuttle for deepwater silica in Late Archean and early Paleoproterozoic iron formation
Fischer, W. W., & Knoll, A. H. (2006) · Geological Society of America Bulletin · doi:10.1130/b26328.1 · Cited by 196
“…rock-based proxies suggest that very little if any O 2 was present in the atmosphere or oceans (atmospheric O 2 mixing ratio << 10 −5 ) (Rye and Holland, 1998; Rasmussen and Buick, 1999; Farquhar et al., 2000; Pavlov and Kasting, 2002; Ono et al., 2003; Bekker et al., 2004; Frimmel, 2005).”
BackgroundMethane and climate during the Precambrian era
KASTING, J. (2005) · Precambrian Research · doi:10.1016/j.precamres.2005.03.002 · Cited by 190
Self-citationSulfur isotope measurement of sulfate and sulfide by high-resolution MC-ICP-MS
Craddock, P. R., Rouxel, O. J., Ball, L. A., & Bach, W. (2008) · Chemical Geology · doi:10.1016/j.chemgeo.2008.04.017 · Cited by 191
“…fractionation of S isotopes in late Archean sedimentary sulfides (Jeerinah Formation; Table 4) is consistent with previous studies suggesting sulfate reduction at low sulfate concentrations (Canfield et al., 2000) due to low levels of atmospheric oxygen (Farquhar et al., 2000; Ono et al., 2003).”
BackgroundPalaeoproterozoic Supercontinents and Global Evolution
Reddy, S. M., Mazumder, R., Evans, D. A. D., & Collins, A. S. (2009) · Cited by 181
Mass-Independent Sulfur Isotopic Compositions in Stratospheric Volcanic Eruptions
Baroni, M., Thiemens, M. H., Delmas, R. J., & Savarino, J. (2007) · Science · doi:10.1126/science.1131754 · Cited by 178
Bontognali, T. R. R., Sessions, A. L., Allwood, A. C., Fischer, W. W., Grotzinger, J. P., Summons, R. E., & Eiler, J. M. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1207491109 · Cited by 169
“Positive correlations between Δ(33)S anomalies and δ(34)S values recorded in pyrites have been interpreted to represent a photolytic signal, without further modification by other fractionation processes (45).”
Palaeoproterozoic supercontinents and global evolution: correlations from core to atmosphere
Reddy, S. M., & Evans, D. A. D. (2009) · Geological Society London Special Publications · doi:10.1144/sp323.1 · Cited by 172
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“…that substantial Mass Independent Fractionation (MIF) of sulfur isotopes is restricted to the time interval before ~2.3 Ga argues for an anoxic atmosphere at that time (Farquhar, 2000; Pavlov and Kasting, 2002; Mojzsis et al., 2003; Ono et al., 2003; Bekker et al., 2004; Farquhar et al., 2007).”
BackgroundInfluentialThe Great Oxidation Event preceded a Paleoproterozoic “snowball Earth”
Warke, M. R., Rocco, T. D., Zerkle, A. L., Lepland, A., Prave, A. R., Martin, A. P., Ueno, Y., Condon, D. J., & Claire, M. W. (2020) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.2003090117 · Cited by 165
Anomalous Fractionations of Sulfur Isotopes During Thermochemical Sulfate Reduction
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Self-citationPathways for Neoarchean pyrite formation constrained by mass-independent sulfur isotopes
Farquhar, J. D., Cliff, J., Zerkle, A. L., Kamyshny, A., Poulton, S. W., Claire, M. W., Adams, D. T., & Harms, B. (2013) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1218851110 · Cited by 153
Evidence for Paleoproterozoic cap carbonates in North America
BEKKER, A., KAUFMAN, A., KARHU, J., & ERIKSSON, K. (2005) · Precambrian Research · doi:10.1016/j.precamres.2005.03.009 · Cited by 147
“, 2002, 2004), suggesting that immediately before the oldest Paleoproterozoic glaciation the atmosphere became more oxidizing than in the latest Neoarchean (Farquhar et al., 2000; Ono et al., 2003).”
Electrons, life and the evolution of Earth's oxygen cycle
Falkowski, P. G., & Godfrey, L. V. (2008) · Philosophical Transactions of the Royal Society B: Biological Sciences · doi:10.1098/rstb.2008.0054 · Cited by 144
“Data from Hayes et al. (1983), Sano & Pillinger (1990), Pinti & Hashizume (2001), Hu et al. (2003), Mosjzsis et al. (2003), Ono et al. (2003, 2006), Jia & Kerrich (2004), Bekker et al. (2004), Johnston et al. (2005), Papineau et al. (2005), Ohmoto et al. (2006) and Kaufman et al. (2007). passive…”
Palaeoclimates: The first two billion years
Kasting, J. F., & Ono, S. (2006) · Philosophical Transactions of the Royal Society B Biological Sciences · doi:10.1098/rstb.2006.1839 · Cited by 144
“5 to 8.2‰) for older rock formations (figure 6; Farquhar et al. 2000; Mojzsis et al. 2003; Ono et al. 2003).”
BackgroundInfluentialSelf-citationWhat caused the rise of atmospheric O2?
Kasting, J. F. (2013) · Chemical Geology · doi:10.1016/j.chemgeo.2013.05.039 · Cited by 144
“In particular, the idea that sulfur was less mobile, and therefore less available, in the Archean has been emphasized by many different authors (e.g., Walker and Brimblecombe, 1985; Ono et al., 2003; Canfield et al., 2006).”
BackgroundUeno, Y., Johnson, M. S., Danielache, S. O., Eskebjerg, C., Pandey, A., & Yoshida, N. (2009) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0903518106 · Cited by 144
“The predicted positive 33S of the sulfate is incompatible with the geological record suggesting Archean seawater sulfate would have had negative 33S values (1, 3, 7, 10).”
BackgroundInfluentialExplaining the Structure of the Archean Mass-Independent Sulfur Isotope Record
Halevy, I., Johnston, D. T., & Schrag, D. P. (2010) · Science · doi:10.1126/science.1190298 · Cited by 141
Contributions to late Archaean sulphur cycling by life on land
Stüeken, E. E., Catling, D. C., & Buick, R. (2012) · Nature Geoscience · doi:10.1038/ngeo1585 · Cited by 137
Did life originate from a global chemical reactor?
Stüeken, E. E., Anderson, R. E., Bowman, J. S., Brazelton, W. J., Colangelo-Lillis, J. R., Goldman, A. D., Som, S. M., & Baross, J. A. (2013) · Geobiology · doi:10.1111/gbi.12025 · Cited by 139
“For example, UV photolysis of volcanogenic SO2 and H2S is thought to have produced a mixture of SO2, H2S, S 0 and H2SO4 (Farquhar et al., 2001; Ono et al., 2003), which could have acted as important oxidation or reduction species for protometabolisms.”
BackgroundThe age of Rubisco: the evolution of oxygenic photosynthesis
Nisbet, E. G., Grassineau, N. V., Howe, C. J., Abell, P. I., Regelous, M., & Nisbet, R. E. R. (2007) · Geobiology · doi:10.1111/j.1472-4669.2007.00127.x · Cited by 132
“The bulk of the δ34S signal is likely to be from microbial processes (Ono et al., 2003; for discussion of older sulphur record see Ohmoto et al., 1993, 2001).”
BackgroundInfluentialHofmann, A., Bekker, A., Rouxel, O. J., Rumble, D., III, & Master, S. (2009) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2009.07.008 · Cited by 127
“Alternatively, the covariation in δ34S and Δ33S values could reflect a combination of mass-dependent and nonmass dependent isotope effects, as suggested by Ono et al. (2003), Ueno et al. (2008), and Shen et al. (2009).”
BackgroundMultiple sulfur isotopes monitor fluid evolution of an Archean orogenic gold deposit
LaFlamme, C. K., Sugiono, D., Thébaud, N., Caruso, S., Fiorentini, M. L., Selvaraja, V., Jeon, H., Voute, F., & Martin, L. A. J. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.11.003 · Cited by 127
Globally asynchronous sulphur isotope signals require re-definition of the Great Oxidation Event
Philippot, P., Ávila, J. N., Killingsworth, B. A., Tessalina, S. G., Baton, F., Caquineau, T., Muller, É., Ernesto Pecoits, A., Cartigny, P., Lalonde, S. V., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-04621-x · Cited by 127
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Frontiers of stable isotope geoscience
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“Earth's surface in H2SO4 and S8 aerosols as well as in the residual SO2 (e.g., Farquhar et al., 2000a, 2001; Pavlov and Kasting, 2002; Ono et al., 2003; Zahnle et al., 2006).”
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Self-citationMicro‐scale sulphur isotope evidence for sulphur cycling in the late Archean shallow ocean
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“The most negative ∆33S of −2.5‰ reported to date is from c. 2.6 Gyr Carrawine Dolomite sulphides (Ono et al., 2003), implied to have formed from H2SO4-derived sulphate.”
BackgroundInfluentialTrace Element Content of Pyrite from the Kapai Slate, St. Ives Gold District, Western Australia
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A Chronostratigraphic Division of the Precambrian
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The Pale Orange Dot: The Spectrum and Habitability of Hazy Archean Earth
Arney, G., Domagal-Goldman, S. D., Meadows, V., Wolf, E. T., Schwieterman, E. W., Charnay, B., Claire, M. W., Hébrard, É., & Trainer, M. G. (2025) · Figshare · Cited by 117
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“Parameter values for the reference case were chosen to approximately satisfy known constraints on: (1) the overall size of the crustal sulphur reservoir(53,81,99,100); (2) the residence time of sulphur as it cycles through the exogenic system(87,101); (3) the fraction of overall sulphur input derived from the rapidly…”
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“Elemental sulfur is highly insoluble and less amenable to biological processes; as a result, most of it is transferred to sediments as solid S (Ono et al., 2003).”
BackgroundModeling the signature of sulfur mass-independent fractionation produced in the Archean atmosphere
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“Compared to models without a photosynthetic O2 source (Pavlov and Kasting, 2002; Ono et al., 2003), SO2 is also a quantitatively significant exit channel, with positive D33S in SO2 delivered to the surface by a combination of wet and dry deposition.”
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“The development of an oxygenated atmosphere in the Palaeoproterozoic at ca. 2.3 Ga effectively shut down the mass-independent fractionation process (Farquhar and Wing 2003), but the signature provides an important tracer of the evolution and distribution of early sulfur reservoirs (Ono et al. 2003).”
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“…older than 2.4 Giga years ago (Ga) commonly show signatures of sulfur isotope mass-independent fractionation (S-MIF), anomalous isotope compositions that deviate from the mass-dependent scaling law of isotope fractionation [e.g., Farquhar et al., 2000a; Pavlov and Kasting, 2002; Ono et al., 2003].”
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Self-citationEarth's First Redox Revolution
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“3A), closely approximating both the general Neoarchaean reference array (−0.90; Ono et al., 2003) and those reported from GKF01 (−0.96; Zerkle et al., 2012).”
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Self-citationTurnstiles and bifurcators: The disequilibrium converting engines that put metabolism on the road
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Self-citationMass‐independent fractionation of sulfur isotopes by isotope‐selective photodissociation of SO2
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“Comparing these values to the maximum D33S measured in pyrites, which are 8–10% [Ono et al., 2003; Kamber and Whitehouse, 2007], and neglecting dilution by non-MIF sulfate, suggests pSO2 10 ppb during generation of the largest S-MIF signatures, or about 100 times the present-day global SO2…”
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False Negatives for Remote Life Detection on Ocean-Bearing Planets: Lessons from the Early Earth
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“When interpreted in the context of photochemical models (Pavlov and Kasting, 2002; Ono et al., 2003; Zahnle et al., 2006; Ueno et al., 2009), the presence of these isotopic anomalies implies a ground-level atmospheric pO2 value that was below 10 -5 times the present atmospheric level (PAL) and more likely below *10 PA…”
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“Kaufman et al. (2007) used a framework presented in Ono et al. (2003) suggesting that the sulphur reaching sedimentary environments carried an atmospheric isotope signature of 33λMt.”
Method
Metadata
- Authors
- Ono, S., Eigenbrode, J. L., Pavlov, A. A., Kharecha, P., Rumble, D., Kasting, J. F., & Freeman, K. H.
- Affiliations
- Carnegie Institution for Science (US)
- Pennsylvania State University (US)
- University of Colorado Boulder (US)
- Corresponding author
- Ono, Shuhei
- Venue
- Earth and Planetary Science Letters
- Publisher
- Elsevier BV
- Published
- 2003-08
- Volume
- 213
- Issue
- 1-2
- Pages
- 15-30
- ISSN
- 0012-821X (ISSN-L)
- OpenAlex
- W1988435801
- Cited by
- 363
- References
- 65
- Citations by year
- 2026: 13 · 2025: 7 · 2024: 12 · 2023: 8 · 2022: 18 · 2021: 17 · 2020: 15 · 2019: 19 · 2018: 22 · 2017: 18 · 2016: 13 · 2015: 10 · 2014: 14 · 2013: 24 · 2012: 22
- FWCI
- 14.66
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Earth and Planetary Science Letters (publishedVersion)
- Funders
- Pennsylvania State University
- University of Colorado
- National Science Foundation (EAR-0125096, EAR-0073831)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geological and Geochemical Analysis
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- Hamersley Basin, pyrite sulfur, sulfide sulfur, UV photolysis, early atmosphere, microbial sulfur metabolism, mass-dependent fractionation
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