50th Anniversary Perspective: Polymers and Mixed Matrix Membranes for Gas and Vapor Separation: A Review and Prospective Opportunities

The rise of graphene

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The Chemistry and Applications of Metal-Organic Frameworks

Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945

Improved Synthesis of Graphene Oxide

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Exceptional chemical and thermal stability of zeolitic imidazolate frameworks

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A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability

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Carbon Dioxide Capture in Metal–Organic Frameworks

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A Chemically Functionalizable Nanoporous Material [Cu 3 (TMA) 2 (H 2 O) 3 ] n

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The upper bound revisited

Robeson, L. M. (2008) · Journal of Membrane Science · doi:10.1016/j.memsci.2008.04.030 · Cited by 5,917

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area

Férey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., Surblé, S., & Margiolaki, I. (2005) · Science · doi:10.1126/science.1116275 · Cited by 5,430

Membrane Technology and Applications

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The solution-diffusion model: a review

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Correlation of separation factor versus permeability for polymeric membranes

Robeson, L. M. (1991) · Journal of Membrane Science · doi:10.1016/0376-7388(91)80060-j · Cited by 3,465

Metal− organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature

Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876

Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units

Rosi, N. L., Kim, J., Eddaoudi, M., Chen, B., O'Keeffe, M., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja045123o · Cited by 2,496

A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL‐53) Upon Hydration

Loiseau, T., Serre, C., Huguenard, C., Fink, G., Taulelle, F., Henry, M., Bataille, T., & Férey, G. (2004) · Chemistry – A European Journal · doi:10.1002/chem.200305413 · Cited by 2,166

Metal–organic framework nanosheets in polymer composite materials for gas separation

Rodenas, T., Luz, I., Prieto, G., Seoane, B., Miro, H., Corma, A., Kapteijn, F., Llabrés i Xamena, F. X., & Gascon, J. (2015) · Nature Materials · doi:10.1038/nmat4113 · Cited by 2,136

Synthesis and Stability of Tagged UiO-66 Zr-MOFs

Kandiah, M., Nilsen, M. H., Usseglio, S., Jakobsen, S., Olsbye, U., Tilset, M., Larabi, C., Quadrelli, E. A., Bonino, F., & Lillerud, K. P. (2010) · Chemistry of Materials · doi:10.1021/cm102601v · Cited by 2,031

Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2Oy

Serre, C., Millange, F., Thouvenot, C., Noguès, M., Marsolier, G., Louër, D., & Férey, G. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0276974 · Cited by 1,980

A facile synthesis of UiO-66, UiO-67 and their derivatives

Katz, M. J., Brown, Z. J., Colón, Y. J., Siu, P. W., Scheidt, K. A., Snurr, R. Q., Hupp, J. T., & Farha, O. K. (2013) · Chemical Communications · doi:10.1039/c3cc46105j · Cited by 1,756

Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes

Freeman, B. D. (1999) · Macromolecules · doi:10.1021/ma9814548 · Cited by 1,662

Selective Gas Transport Through Few-Layered Graphene and Graphene Oxide Membranes

Kim, H. W., Yoon, H. W., Yoon, S.-M., Yoo, B. M., Ahn, B. K., Cho, Y. H., Shin, H. J., Yang, H., Paik, U., Kwon, S., et al. (2013) · Science · doi:10.1126/science.1236098 · Cited by 1,481

Natural Gas Processing with Membranes: An Overview

Baker, R. W., & Lokhandwala, K. (2008) · Industrial & Engineering Chemistry Research · doi:10.1021/ie071083w · Cited by 1,381

Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials

Budd, P. M., Ghanem, B. S., Makhseed, S., McKeown, N. B., Msayib, K. J., & Tattershall, C. E. (2004) · Chemical Communications · doi:10.1039/b311764b · Cited by 1,366

Ultrathin, Molecular-Sieving Graphene Oxide Membranes for Selective Hydrogen Separation

Li, H., Song, Z., Zhang, X., Huang, Y., Li, S., Mao, Y., Ploehn, H. J., Bao, Y., & Yu, M. (2013) · Science · doi:10.1126/science.1236686 · Cited by 1,360

Cooperative insertion of CO2 in diamine-appended metal-organic frameworks

McDonald, T. M., Mason, J. A., Kong, X., Bloch, E. D., Gygi, D., Dani, A., Crocellà, V., Giordanino, F., Odoh, S. O., Drisdell, W. S., et al. (2015) · Nature · doi:10.1038/nature14327 · Cited by 1,342

Crystallized Frameworks with Giant Pores: Are There Limits to the Possible?

Férey, G., Mellot-Draznieks, C., Serre, C., & Millange, F. (2005) · Accounts of Chemical Research · doi:10.1021/ar040163i · Cited by 1,327

Interfacial polymerization of thin film nanocomposites: A new concept for reverse osmosis membranes

Jeong, B.-H., Hoek, E. M. V., Yan, Y., Subramani, A., Huang, X., Hurwitz, G., Ghosh, A. K., & Jawor, A. (2007) · Journal of Membrane Science · doi:10.1016/j.memsci.2007.02.025 · Cited by 1,307

Exceptional H2 Saturation Uptake in Microporous Metal−Organic Frameworks

Wong-Foy, A. G., Matzger, A. J., & Yaghi, O. M. (2006) · Journal of the American Chemical Society · doi:10.1021/ja058213h · Cited by 1,281

Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites

Britt, D., Furukawa, H., Wang, B., Glover, T. G., & Yaghi, O. M. (2009) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0909718106 · Cited by 1,211

Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations

Fairen-Jimenez, D., Moggach, S. A., Wharmby, M. T., Wright, P. A., Parsons, S., & Düren, T. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202154j · Cited by 1,211

Gas Separation Membrane Materials: A Perspective

Baker, R. W., & Low, B. T. (2014) · Macromolecules · doi:10.1021/ma501488s · Cited by 1,203

High Uptakes of CO2 and CH4 in Mesoporous Metal—Organic Frameworks MIL-100 and MIL-101

Llewellyn, P. L., Bourrelly, S., Serre, C., Vimont, A., Daturi, M., Hamon, L., De Weireld, G., Chang, J.-S., Hong, D.-Y., Kyu Hwang, Y., et al. (2008) · Langmuir · doi:10.1021/la800227x · Cited by 1,156

Membranes for Hydrogen Separation

Ockwig, N. W., & Nenoff, T. M. (2007) · Chemical Reviews · doi:10.1021/cr0501792 · Cited by 1,138

Polymers with Cavities Tuned for Fast Selective Transport of Small Molecules and Ions

Park, H. B., Jung, C. H., Lee, Y. M., Hill, A. J., Pas, S. J., Mudie, S. T., Van Wagner, E., Freeman, B. D., & Cookson, D. J. (2007) · Science · doi:10.1126/science.1146744 · Cited by 1,071

On the origin of the stability of graphene oxide membranes in water

Yeh, C.-N., Raidongia, K., Shao, J., Yang, Q.-H., & Huang, J. (2015) · Nature Chemistry · doi:10.1038/nchem.2145 · Cited by 961

Polymers for gas separations: the next decade

Alexander Stern, S. (1994) · Journal of Membrane Science · doi:10.1016/0376-7388(94)00141-3 · Cited by 954

Ultimate Permeation Across Atomically Thin Porous Graphene

Celebi, K., Buchheim, J., Wyss, R. M., Droudian, A., Gasser, P., Shorubalko, I., Kye, J.-I., Lee, C., & Park, H. G. (2014) · Science · doi:10.1126/science.1249097 · Cited by 910

Gas separation membranes from polymers of intrinsic microporosity

BUDD, P., MSAYIB, K., TATTERSHALL, C., GHANEM, B., REYNOLDS, K., MCKEOWN, N., & FRITSCH, D. (2005) · Journal of Membrane Science · doi:10.1016/j.memsci.2005.01.009 · Cited by 893

Two‐Dimensional‐Material Membranes: A New Family of High‐Performance Separation Membranes

Liu, G., Jin, W., & Xu, N. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201600438 · Cited by 841

Polymer nanosieve membranes for CO2-capture applications

Du, N., Park, H. B., Robertson, G. P., Dal-Cin, M. M., Visser, T., Scoles, L., & Guiver, M. D. (2011) · Nature Materials · doi:10.1038/nmat2989 · Cited by 805

Highly Water-Stable Zirconium Metal–Organic Framework UiO-66 Membranes Supported on Alumina Hollow Fibers for Desalination

Liu, X., Demir, N. K., Wu, Z., & Li, K. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b02276 · Cited by 802

Olefin/paraffin separation technology: a review

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Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation

Song, Q., Nataraj, S. K., Roussenova, M. V., Tan, J. C., Hughes, D. J., Li, W., Bourgoin, P., Alam, M. A., Cheetham, A. K., Al-Muhtaseb, S. A., et al. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21996d · Cited by 744

Mixed matrix membranes using carbon molecular sieves

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Interfacial microfluidic processing of metal-organic framework hollow fiber membranes

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Hydrogen Membrane Separation Techniques

Adhikari, S., & Fernando, S. (2006) · Industrial & Engineering Chemistry Research · doi:10.1021/ie050644l · Cited by 705

Challenges and opportunities for mixed-matrix membranes for gas separation

Dong, G., Li, H., & Chen, V. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta00927k · Cited by 691

Plasticization-Enhanced Hydrogen Purification Using Polymeric Membranes

Lin, H., Van Wagner, E., Freeman, B. D., Toy, L. G., & Gupta, R. P. (2006) · Science · doi:10.1126/science.1118079 · Cited by 679

Application of membrane separation processes in petrochemical industry: a review

Ravanchi, M. T., Kaghazchi, T., & Kargari, A. (2008) · Desalination · doi:10.1016/j.desal.2007.10.042 · Cited by 654

Polybenzimidazoles, new thermally stable polymers

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High-Capacity Methane Storage in Metal−Organic Frameworks M2(dhtp): The Important Role of Open Metal Sites

Wu, H., Zhou, W., & Yildirim, T. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900258t · Cited by 587

In Situ Synthesis of Thin Zeolitic–Imidazolate Framework ZIF-8 Membranes Exhibiting Exceptionally High Propylene/Propane Separation

Kwon, H. T., & Jeong, H.-K. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403849c · Cited by 581

Effect of partially immobilizing sorption on permeability and the diffusion time lag

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An Explanation for the Very Large Breathing Effect of a Metal–Organic Framework during CO2 Adsorption

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Predictive Models for Mixed-Matrix Membrane Performance: A Review

Vinh-Thang, H., & Kaliaguine, S. (2013) · Chemical Reviews · doi:10.1021/cr3003888 · Cited by 554

Catalytic properties of MIL-101

Henschel, A., Gedrich, K., Kraehnert, R., & Kaskel, S. (2008) · Chemical Communications · doi:10.1039/b718371b · Cited by 528

Reversed thermo-switchable molecular sieving membranes composed of two-dimensional metal-organic nanosheets for gas separation

Wang, X., Chi, C., Zhang, K., Qian, Y., Gupta, K. M., Kang, Z., Jiang, J., & Zhao, D. (2017) · Nature Communications · doi:10.1038/ncomms14460 · Cited by 519

Heteroepitaxially Grown Zeolitic Imidazolate Framework Membranes with Unprecedented Propylene/Propane Separation Performances

Kwon, H. T., Jeong, H.-K., Lee, A. S., An, H. S., & Lee, J. S. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06730 · Cited by 510

Enhanced ethylene separation and plasticization resistance in polymer membranes incorporating metal–organic framework nanocrystals

Bachman, J. E., Smith, Z. P., Li, T., Xu, T., & Long, J. R. (2016) · Nature Materials · doi:10.1038/nmat4621 · Cited by 504

Metal organic framework based mixed matrix membranes: An increasingly important field of research with a large application potential

Zornoza, B., Tellez, C., Coronas, J., Gascon, J., & Kapteijn, F. (2013) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2012.03.012 · Cited by 495

High performance ZIF-8/6FDA-DAM mixed matrix membrane for propylene/propane separations

Zhang, C., Dai, Y., Johnson, J. R., Karvan, O., & Koros, W. J. (2012) · Journal of Membrane Science · doi:10.1016/j.memsci.2011.10.003 · Cited by 488

Reformulation of the solution-diffusion theory of reverse osmosis

Paul, D. R. (2004) · Journal of Membrane Science · doi:10.1016/j.memsci.2004.05.026 · Cited by 485

High Propene/Propane Selectivity in Isostructural Metal–Organic Frameworks with High Densities of Open Metal Sites

Bae, Y., Lee, C. Y., Kim, K. C., Farha, O. K., Nickias, P., Hupp, J. T., Nguyen, S. T., & Snurr, R. Q. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201107534 · Cited by 461

Structure‐permeability relationships in silicone polymers

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Interfacial Design of Mixed Matrix Membranes for Improved Gas Separation Performance

Wang, Z., Wang, D., Zhang, S., Hu, L., & Jin, J. (2016) · Advanced Materials · doi:10.1002/adma.201504982 · Cited by 452

Reversible Structural Transition in MIL-53 with Large Temperature Hysteresis

Liu, Y., Her, J.-H., Dailly, A., Ramirez-Cuesta, A. J., Neumann, D. A., & Brown, C. M. (2008) · Journal of the American Chemical Society · doi:10.1021/ja803669w · Cited by 450

Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)

Queen, W. L., Hudson, M. R., Bloch, E. D., Mason, J. A., Gonzalez, M. I., Lee, J. S., Gygi, D., Howe, J. D., Lee, K., Darwish, T. A., et al. (2014) · Chem. Sci. · doi:10.1039/c4sc02064b · Cited by 446

Selective adsorption of ethylene over ethane and propylene over propane in the metal–organic frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn)

Geier, S. J., Mason, J. A., Bloch, E. D., Queen, W. L., Hudson, M. R., Brown, C. M., & Long, J. R. (2013) · Chemical Science · doi:10.1039/c3sc00032j · Cited by 443

Plasticization of glassy polymers by CO2

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Oxygen Transport through Hemoglobin Solutions

Scholander, P. F. (1960) · Science · doi:10.1126/science.131.3400.585 · Cited by 410

Subnanometer Two-Dimensional Graphene Oxide Channels for Ultrafast Gas Sieving

Shen, J., Liu, G., Huang, K., Chu, Z., Jin, W., & Xu, N. (2016) · ACS Nano · doi:10.1021/acsnano.5b07304 · Cited by 404

Mapping the Cu-BTC metal–organic framework (HKUST-1) stability envelope in the presence of water vapour for CO2 adsorption from flue gases

Al-Janabi, N., Hill, P., Torrente-Murciano, L., Garforth, A., Gorgojo, P., Siperstein, F., & Fan, X. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2015.07.020 · Cited by 386

Gas permeability properties of Matrimid® membranes containing the metal-organic framework Cu–BPY–HFS

Zhang, Y., Musselman, I. H., Ferraris, J. P., & Balkus, K. J. (2008) · Journal of Membrane Science · doi:10.1016/j.memsci.2008.01.005 · Cited by 378

Efficient CO2 Capture by Functionalized Graphene Oxide Nanosheets as Fillers To Fabricate Multi-Permselective Mixed Matrix Membranes

Li, X., Cheng, Y., Zhang, H., Wang, S., Jiang, Z., Guo, R., & Wu, H. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b00106 · Cited by 364

Facilitated transport of CO2 in novel PVAm/PVA blend membrane

Deng, L., Kim, T.-J., & Hägg, M.-B. (2009) · Journal of Membrane Science · doi:10.1016/j.memsci.2009.05.019 · Cited by 349

Membranes with Fast and Selective Gas‐Transport Channels of Laminar Graphene Oxide for Efficient CO2 Capture

Shen, J., Liu, G., Huang, K., Jin, W., Lee, K., & Xu, N. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201409563 · Cited by 347

Ending Aging in Super Glassy Polymer Membranes

Lau, C. H., Nguyen, P. T., Hill, M. R., Thornton, A. W., Konstas, K., Doherty, C. M., Mulder, R. J., Bourgeois, L., Liu, A. C. Y., Sprouster, D. J., et al. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402234 · Cited by 338

The effect of degree of acetylation on gas sorption and transport behavior in cellulose acetate

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Complex Adsorption of Short Linear Alkanes in the Flexible Metal-Organic-Framework MIL-53(Fe)

Llewellyn, P. L., Horcajada, P., Maurin, G., Devic, T., Rosenbach, N., Bourrelly, S., Serre, C., Vincent, D., Loera-Serna, S., Filinchuk, Y., et al. (2009) · Journal of the American Chemical Society · doi:10.1021/ja902740r · Cited by 317

Visualizing MOF Mixed Matrix Membranes at the Nanoscale: Towards Structure‐Performance Relationships in CO2/CH4 Separation Over NH2‐MIL‐53(Al)@PI

Rodenas, T., van Dalen, M., García‐Pérez, E., Serra‐Crespo, P., Zornoza, B., Kapteijn, F., & Gascon, J. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201203462 · Cited by 305

Chromium terephthalate metal–organic framework MIL-101: synthesis, functionalization, and applications for adsorption and catalysis

Bhattacharjee, S., Chen, C., & Ahn, W.-S. (2014) · RSC Adv. · doi:10.1039/c4ra11259h · Cited by 301

Carbon dioxide capture with membranes at an IGCC power plant

Merkel, T. C., Zhou, M., & Baker, R. W. (2011) · Journal of Membrane Science · doi:10.1016/j.memsci.2011.11.012 · Cited by 298

XRD and IR structural investigations of a particular breathing effect in the MOF-type gallium terephthalate MIL-53(Ga)

Volkringer, C., Loiseau, T., Guillou, N., Férey, G., Elkaïm, E., & Vimont, A. (2009) · Dalton Transactions · doi:10.1039/b817563b · Cited by 293

Asymmetric Matrimid®/[Cu3(BTC)2] mixed-matrix membranes for gas separations

Basu, S., Cano-Odena, A., & Vankelecom, I. F. J. (2010) · Journal of Membrane Science · doi:10.1016/j.memsci.2010.07.005 · Cited by 292

Highly permeable zeolitic imidazolate framework (ZIF)-71 nano-particles enhanced polyimide membranes for gas separation

Japip, S., Wang, H., Xiao, Y., & Shung Chung, T. (2014) · Journal of Membrane Science · doi:10.1016/j.memsci.2014.05.025 · Cited by 289

Metal Organic Framework Crystals in Mixed‐Matrix Membranes: Impact of the Filler Morphology on the Gas Separation Performance

Sabetghadam, A., Seoane, B., Keskin, D., Duim, N., Rodenas, T., Shahid, S., Sorribas, S., Guillouzer, C. L., Clet, G., Tellez, C., et al. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201505352 · Cited by 289

Reverse osmosis molecular differentiation of organic liquids using carbon molecular sieve membranes

Koh, D.-Y., McCool, B. A., Deckman, H. W., & Lively, R. P. (2016) · Science · doi:10.1126/science.aaf1343 · Cited by 288

A Chemical Route to Activation of Open Metal Sites in the Copper-Based Metal–Organic Framework Materials HKUST-1 and Cu-MOF-2

Kim, H. K., Yun, W. S., Kim, M.-B., Kim, J. Y., Bae, Y.-S., Lee, J., & Jeong, N. C. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06637 · Cited by 265

Modulated UiO-66-Based Mixed-Matrix Membranes for CO2 Separation

Anjum, M. W., Vermoortele, F., Khan, A. L., Bueken, B., Vos, D. E. D., & Vankelecom, I. F. J. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b08964 · Cited by 263

Carbon Dioxide-Oxygen Separation: Facilitated Transport of Carbon Dioxide across a Liquid Film

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Formation of Ultrathin, Continuous Metal–Organic Framework Membranes on Flexible Polymer Substrates

Hou, J., Sutrisna, P. D., Zhang, Y., & Chen, V. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201511340 · Cited by 258

The diffusion time lag in polymer membranes containing adsorptive fillers

Paul, D. R., & Kemp, D. R. (1973) · Journal of Polymer Science: Polymer Symposia · doi:10.1002/polc.5070410109 · Cited by 246

Supported carbon molecular sieve membranes based on a phenolic resin

Centeno, T. A., & Fuertes, A. B. (1999) · Journal of Membrane Science · doi:10.1016/s0376-7388(99)00083-6 · Cited by 241

Zeolites and their synthesis

Barrer, R. M. (1981) · Zeolites · doi:10.1016/s0144-2449(81)80001-2 · Cited by 240

The Behavior of Flexible MIL-53(Al) upon CH4and CO2Adsorption

Boutin, A., Coudert, F.-X., Springuel-Huet, M.-A., Neimark, A. V., Férey, G., & Fuchs, A. H. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp108710h · Cited by 237

Vanadium-Node-Functionalized UiO-66: A Thermally Stable MOF-Supported Catalyst for the Gas-Phase Oxidative Dehydrogenation of Cyclohexene

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A highly permeable graphene oxide membrane with fast and selective transport nanochannels for efficient carbon capture

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