The DOI matches its Crossref record; 46 of the 46 references it cites were found in a registry or an index.
3D Printing of Highly Stretchable, Shape-Memory, and Self-Healing Elastomer toward Novel 4D Printing
Abstract
The three-dimensional (3D) printing of flexible and stretchable materials with smart functions such as shape memory (SM) and self-healing (SH) is highly desirable for the development of future 4D printing technology for myriad applications, such as soft actuators, deployable smart medical devices, and flexible electronics. Here, we report a novel ink that can be used for the 3D printing of highly stretchable, SM, and SH elastomer via UV-light-assisted direct-ink-write printing. An ink containing urethane diacrylate and a linear semicrystalline polymer is developed for the 3D printing of a semi-interpenetrating polymer network elastomer that can be stretched by up to 600%. The 3D-printed complex structures show interesting functional properties, such as high strain SM and SM -assisted SH capability. We demonstrate that such a 3D-printed SM elastomer has the potential application for biomedical devices, such as vascular repair devices. This research paves a new way for the further development of novel 4D printing, soft robotics, and biomedical devices.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Autonomic healing of polymer composites
White, S. R., Sottos, N. R., Geubelle, P. H., Moore, J. S., Kessler, M. R., Sriram, S. R., Brown, E. N., & Viswanathan, S. (2001) · Nature · doi:10.1038/35057232 · Cited by 4,575
A Thermally Re-mendable Cross-Linked Polymeric Material
Chen, X., Dam, M. A., Ono, K., Mal, A., Shen, H., Nutt, S. R., Sheran, K., & Wudl, F. (2002) · Science · doi:10.1126/science.1065879 · Cited by 2,645
Ultralight, ultrastiff mechanical metamaterials
Zheng, X., Lee, H., Weisgraber, T. H., Shusteff, M., DeOtte, J., Duoss, E. B., Kuntz, J. D., Biener, M. M., Ge, Q., Jackson, J. A., et al. (2014) · Science · doi:10.1126/science.1252291 · Cited by 2,308
Light-induced shape-memory polymers
Lendlein, A., Jiang, H., Jünger, O., & Langer, R. (2005) · Nature · doi:10.1038/nature03496 · Cited by 2,006
Recent advances in 3D printing of biomaterials
Chia, H. N., & Wu, B. M. (2015) · Journal of Biological Engineering · doi:10.1186/s13036-015-0001-4 · Cited by 1,734
A highly stretchable autonomous self-healing elastomer
Li, C.-H., Wang, C., Keplinger, C., Zuo, J.-L., Jin, L., Sun, Y., Zheng, P., Cao, Y., Lissel, F., Linder, C., et al. (2016) · Nature Chemistry · doi:10.1038/nchem.2492 · Cited by 1,496
Zhao, Q., Qi, H. J., & Xie, T. (2015) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2015.04.001 · Cited by 1,409
Self-citationTunable polymer multi-shape memory effect
Xie, T. (2010) · Nature · doi:10.1038/nature08863 · Cited by 1,380
Progress in Additive Manufacturing and Rapid Prototyping
Kruth, J.-P., Leu, M. C., & Nakagawa, T. (1998) · CIRP Annals · doi:10.1016/s0007-8506(07)63240-5 · Cited by 1,331
Momeni, F., M.Mehdi Hassani.N, S., Liu, X., & Ni, J. (2017) · Materials & Design · doi:10.1016/j.matdes.2017.02.068 · Cited by 1,165
Direct 3D Printing of Shear‐Thinning Hydrogels into Self‐Healing Hydrogels
Highley, C. B., Rodell, C. B., & Burdick, J. A. (2015) · Advanced Materials · doi:10.1002/adma.201501234 · Cited by 1,043
3D Printing of Shape Memory Polymers for Flexible Electronic Devices
Zarek, M., Layani, M., Cooperstein, I., Sachyani, E., Cohn, D., & Magdassi, S. (2016) · Advanced Materials · doi:10.1002/adma.201503132 · Cited by 903
Catalyst-free room-temperature self-healing elastomers based on aromatic disulfide metathesis
Rekondo, A., Martin, R., Ruiz de Luzuriaga, A., Cabañero, G., Grande, H. J., & Odriozola, I. (2014) · Mater. Horiz. · doi:10.1039/c3mh00061c · Cited by 901
Heat‐ or Water‐Driven Malleability in a Highly Recyclable Covalent Network Polymer
Taynton, P., Yu, K., Shoemaker, R. K., Jin, Y., Qi, H. J., & Zhang, W. (2014) · Advanced Materials · doi:10.1002/adma.201400317 · Cited by 890
Self-citationActive materials by four-dimension printing
Ge, Q., Qi, H. J., & Dunn, M. L. (2013) · Applied Physics Letters · doi:10.1063/1.4819837 · Cited by 785
Self-citationSelf-Repairing Oxetane-Substituted Chitosan Polyurethane Networks
Ghosh, B., & Urban, M. W. (2009) · Science · doi:10.1126/science.1167391 · Cited by 713
Direct 4D Printing Via Active Composite Materials
Ding, Z., Yuan, C., Peng, X., Wang, T., Qi, H. J., & Dunn, M. L. (2017) · Science Advances · doi:10.1126/sciadv.1602890 · Cited by 692
Self-citationSequential Self-Folding Structures by 3D Printed Digital Shape Memory Polymers
Mao, Y., Yu, K., Isakov, M. S., Wu, J., Dunn, M. L., & Jerry Qi, H. (2015) · Scientific Reports · doi:10.1038/srep13616 · Cited by 510
Self-citationWei, H., Zhang, Q., Yao, Y., Liu, L., Liu, Y., & Leng, J. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b12824 · Cited by 504
Recyclable 3D printing of vitrimer epoxy
Shi, Q., Yu, K., Kuang, X., Mu, X., Dunn, C. K., Dunn, M. L., Wang, T., & Jerry Qi, H. (2017) · Materials Horizons · doi:10.1039/c7mh00043j · Cited by 460
Self-citationSelf‐Healing Materials with Interpenetrating Microvascular Networks
Hansen, C. J., Wu, W., Toohey, K. S., Sottos, N. R., White, S. R., & Lewis, J. A. (2009) · Advanced Materials · doi:10.1002/adma.200900588 · Cited by 434
Shape Memory Assisted Self-Healing Coating
Luo, X., & Mather, P. T. (2013) · ACS Macro Letters · doi:10.1021/mz400017x · Cited by 412
Wax‐Protected Catalyst Microspheres for Efficient Self‐Healing Materials
Rule, J. D., Brown, E. N., Sottos, N. R., White, S. R., & Moore, J. S. (2005) · Advanced Materials · doi:10.1002/adma.200400607 · Cited by 405
Multi-shape active composites by 3D printing of digital shape memory polymers
Wu, J., Yuan, C., Ding, Z., Isakov, M., Mao, Y., Wang, T., Dunn, M. L., & Qi, H. J. (2016) · Scientific Reports · doi:10.1038/srep24224 · Cited by 399
Self-citationLinear/Network Poly(ε-caprolactone) Blends Exhibiting Shape Memory Assisted Self-Healing (SMASH)
Rodriguez, E. D., Luo, X., & Mather, P. T. (2011) · ACS Applied Materials & Interfaces · doi:10.1021/am101012c · Cited by 381
Shape Memory Polymers for Body Motion Energy Harvesting and Self‐Powered Mechanosensing
Liu, R., Kuang, X., Deng, J., Wang, Y., Wang, A. C., Ding, W., Lai, Y., Chen, J., Wang, P., Lin, Z., et al. (2018) · Advanced Materials · doi:10.1002/adma.201705195 · Cited by 359
Self-citation3D printed reversible shape changing components with stimuli responsive materials
Mao, Y., Ding, Z., Yuan, C., Ai, S., Isakov, M., Wu, J., Wang, T., Dunn, M. L., & Qi, H. J. (2016) · Scientific Reports · doi:10.1038/srep24761 · Cited by 348
Self-citationGao, G., Du, G., Sun, Y., & Fu, J. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b00704 · Cited by 331
Self‐Healing Supramolecular Block Copolymers
Hentschel, J., Kushner, A. M., Ziller, J., & Guan, Z. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201204840 · Cited by 309
3D printed microfluidic devices with integrated versatile and reusable electrodes
Erkal, J. L., Selimovic, A., Gross, B. C., Lockwood, S. Y., Walton, E. L., McNamara, S., Martin, R. S., & Spence, D. M. (2014) · Lab Chip · doi:10.1039/c4lc00171k · Cited by 287
Lafont, U., van Zeijl, H., & van der Zwaag, S. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am301879z · Cited by 260
Restoration of Large Damage Volumes in Polymers
White, S. R., Moore, J. S., Sottos, N. R., Krull, B. P., Santa Cruz, W. A., & Gergely, R. C. R. (2014) · Science · doi:10.1126/science.1251135 · Cited by 258
Continuous Self‐Healing Life Cycle in Vascularized Structural Composites
Patrick, J. F., Hart, K. R., Krull, B. P., Diesendruck, C. E., Moore, J. S., White, S. R., & Sottos, N. R. (2014) · Advanced Materials · doi:10.1002/adma.201400248 · Cited by 257
Reduced time as a unified parameter determining fixity and free recovery of shape memory polymers
Yu, K., Ge, Q., & Qi, H. J. (2014) · Nature Communications · doi:10.1038/ncomms4066 · Cited by 256
Self-citationA Rapid and Efficient Self‐Healing Thermo‐Reversible Elastomer Crosslinked with Graphene Oxide
Wang, C., Liu, N., Allen, R., Tok, J. B. ‐., Wu, Y., Zhang, F., Chen, Y., & Bao, Z. (2013) · Advanced Materials · doi:10.1002/adma.201302962 · Cited by 247
Kuang, X., Liu, G., Dong, X., Liu, X., Xu, J., & Wang, D. (2015) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.27655 · Cited by 181
Self-citationYang, K., Grant, J. C., Lamey, P., Joshi‐Imre, A., Lund, B. R., Smaldone, R. A., & Voit, W. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201700318 · Cited by 176
Preparation and Characterization of Shape Memory Elastomeric Composites
Luo, X., & Mather, P. T. (2009) · Macromolecules · doi:10.1021/ma9015888 · Cited by 158
Novel Biodegradable Shape‐Memory Elastomers with Drug‐Releasing Capabilities
Serrano, M. C., Carbajal, L., & Ameer, G. A. (2011) · Advanced Materials · doi:10.1002/adma.201004566 · Cited by 154
Kuang, X., Liu, G., Dong, X., & Wang, D. (2016) · Macromolecular Materials and Engineering · doi:10.1002/mame.201500425 · Cited by 118
Self-citationTriple-shape memory epoxy based on Diels–Alder adduct molecular switch
Kuang, X., Liu, G., Dong, X., & Wang, D. (2015) · Polymer · doi:10.1016/j.polymer.2015.12.033 · Cited by 103
Self-citationAppuhamillage, G. A., Reagan, J. C., Khorsandi, S., Davidson, J. R., Voit, W., & Smaldone, R. A. (2017) · Polymer Chemistry · doi:10.1039/c7py00310b · Cited by 97
Digital manufacture of shape changing components
Yu, K., Dunn, M. L., & Qi, H. J. (2015) · Extreme Mechanics Letters · doi:10.1016/j.eml.2015.07.005 · Cited by 76
Self-citationTwo-way shape memory property and its structural origin of cross-linked poly(ε-caprolactone)
Huang, M., Dong, X., Wang, L., Zhao, J., Liu, G., & Wang, D. (2014) · RSC Advances · doi:10.1039/c4ra09385b · Cited by 68
3D Printed Silicones with Shape Memory
Wu, A. S., Small, W., Bryson, T. M., Cheng, E., Metz, T. R., Schulze, S. E., Duoss, E. B., & Wilson, T. S. (2017) · Scientific Reports · doi:10.1038/s41598-017-04663-z · Cited by 66
Temperature and molecular weight dependence of fracture behaviour of polypropylene films
Bruno Fayolle, C., Tcharkhtchi, A., & Jacques Verdu, C. (2004) · Polymer Testing · doi:10.1016/j.polymertesting.2004.04.013 · Cited by 28
Cited by
Advances in 4D Printing: Materials and Applications
Kuang, X., Roach, D. J., Wu, J., Hamel, C. M., Ding, Z., Wang, T., Dunn, M. L., & Qi, H. J. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201805290 · Cited by 1,095
Self-citationRoach, D. J., Yuan, C., Kuang, X., Li, V. C.-F., Blake, P., Romero, M. L., Hammel, I., Yu, K., & Qi, H. J. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b04401 · Cited by 319
Self-citation3D printing of functional microrobots
Li, J., & Pumera, M. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01062f · Cited by 303
Mechanical Models, Structures, and Applications of Shape-Memory Polymers and Their Composites
Xin, X., Liu, L., Liu, Y., & Leng, J. (2019) · Acta Mechanica Solida Sinica · doi:10.1007/s10338-019-00103-9 · Cited by 115
Milazzo, M., & Libonati, F. (2022) · Advanced Intelligent Systems · doi:10.1002/aisy.202100278 · Cited by 43
Metadata
- Authors
- Kuang, X., Chen, K., Dunn, C. K., Wu, J., Li, V. C. F., & Qi, H. J.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-02-19
- Volume
- 10
- Issue
- 8
- Pages
- 7381-7388
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2790554408
- Cited by
- 523
- References
- 46
- FWCI
- 28.22
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.