Activation of Carbonyl-Containing Molecules with Solid Lewis Acids in Aqueous Media

Hard and Soft Acids and Bases

Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475

Chemical Routes for the Transformation of Biomass into Chemicals

Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970

The Path Forward for Biofuels and Biomaterials

Ragauskas, A. J., Williams, C. K., Davison, B. H., Britovsek, G., Cairney, J., Eckert, C. A., Frederick, W. J., Hallett, J. P., Leak, D. J., Liotta, C. L., et al. (2006) · Science · doi:10.1126/science.1114736 · Cited by 5,741

Solvents and Solvent Effects in Organic Chemistry

Reichardt, C., & Welton, T. (2010) · Wiley eBooks · doi:10.1002/9783527632220 · Cited by 4,280

Electronegativity: The density functional viewpoint

Parr, R. G., Donnelly, R. A., Levy, M., & Palke, W. E. (1978) · The Journal of Chemical Physics · doi:10.1063/1.436185 · Cited by 3,404

Liquid‐Phase Catalytic Processing of Biomass‐Derived Oxygenated Hydrocarbons to Fuels and Chemicals

Chheda, J. N., Huber, G. W., & Dumesic, J. A. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200604274 · Cited by 2,342

Catalytic conversion of biomass to biofuels

Alonso, D. M., Bond, J. Q., & Dumesic, J. A. (2010) · Green Chemistry · doi:10.1039/c004654j · Cited by 2,333

Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates

Román-Leshkov, Y., Barrett, C. J., Liu, Z. Y., & Dumesic, J. A. (2007) · Nature · doi:10.1038/nature05923 · Cited by 2,259

Organic Reactions in Aqueous Media with a Focus on Carbon−Carbon Bond Formations: A Decade Update

Li, C.-J. (2005) · Chemical Reviews · doi:10.1021/cr030009u · Cited by 2,244

The Donor-Acceptor Approach to Molecular Interactions

Gutmann, V. (1978) · Springer eBooks · doi:10.1007/978-1-4615-8825-2 · Cited by 2,187

Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural

Zhao, H., Holladay, J. E., Brown, H., & Zhang, Z. C. (2007) · Science · doi:10.1126/science.1141199 · Cited by 1,997

Phase Modifiers Promote Efficient Production of Hydroxymethylfurfural from Fructose

Román-Leshkov, Y., Chheda, J. N., & Dumesic, J. A. (2006) · Science · doi:10.1126/science.1126337 · Cited by 1,670

Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals

Binder, J. B., & Raines, R. T. (2009) · Journal of the American Chemical Society · doi:10.1021/ja808537j · Cited by 1,490

Recent advances in the concept of hard and soft acids and bases

Pearson, R. G. (1987) · Journal of Chemical Education · doi:10.1021/ed064p561 · Cited by 1,410

Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides

Chheda, J. N., Román-Leshkov, Y., & Dumesic, J. A. (2007) · Green Chem. · doi:10.1039/b611568c · Cited by 1,175

Lewis Acids: From Conventional Homogeneous to Green Homogeneous and Heterogeneous Catalysis

Corma, A., & García, H. (2003) · Chemical Reviews · doi:10.1021/cr030680z · Cited by 1,155

Biomass for renewable energy, fuels, and chemicals

(1999) · Choice Reviews Online · doi:10.5860/choice.36-4508 · Cited by 1,100

Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations

Corma, A., Nemeth, L. T., Renz, M., & Valencia, S. (2001) · Nature · doi:10.1038/35086546 · Cited by 1,013

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water

Moliner, M., Román-Leshkov, Y., & Davis, M. E. (2010) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1002358107 · Cited by 998

Lactic acid: recent advances in products, processes and technologies — a review

Datta, R., & Henry, M. (2006) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.1486 · Cited by 973

Heterogeneous Catalysts for Liquid-Phase Oxidations: Philosophers' Stones or Trojan Horses?

Sheldon, R. A., Wallau, M., Arends, I. W. C. E., & Schuchardt, U. (1998) · Accounts of Chemical Research · doi:10.1021/ar9700163 · Cited by 964

Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts

Holm, M. S., Saravanamurugan, S., & Taarning, E. (2010) · Science · doi:10.1126/science.1183990 · Cited by 912

Hard and soft acids and bases—The evolution of a chemical concept

Pearson, R. G. (1990) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(90)85016-l · Cited by 886

Catalytic routes for the conversion of biomass into liquid hydrocarbon transportation fuels

Serrano-Ruiz, J. C., & Dumesic, J. A. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00436g · Cited by 850

Ionic Liquid-Mediated Formation of 5-Hydroxymethylfurfural—A Promising Biomass-Derived Building Block

Zakrzewska, M. E., Bogel-Łukasik, E., & Bogel-Łukasik, R. (2011) · Chemical Reviews · doi:10.1021/cr100171a · Cited by 800

Mechanism of formation of 5-(hydroxymethyl)-2-furaldehyde from d-fructose and sucrose

Antal, M. J., Mok, W. S. L., & Richards, G. N. (1990) · Carbohydrate Research · doi:10.1016/0008-6215(90)84096-d · Cited by 786

Development of Novel Lewis Acid Catalysts for Selective Organic Reactions in Aqueous Media

Kobayashi, S., & Manabe, K. (2002) · Accounts of Chemical Research · doi:10.1021/ar000145a · Cited by 771

Mechanism of Glucose Isomerization Using a Solid Lewis Acid Catalyst in Water

Román‐Leshkov, Y., Moliner, M., Labinger, J. A., & Davis, M. E. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201004689 · Cited by 725

5‐Hydroxymethylfurfural (HMF). A Review Focussing on its Manufacture

Kuster, B. F. M. (1990) · Starch - Stärke · doi:10.1002/star.19900420808 · Cited by 684

Biomass for Renewable Energy, Fuels, and Chemicals

(1998) · Elsevier eBooks · doi:10.1016/b978-0-12-410950-6.x5000-4 · Cited by 679

“One-Pot” Synthesis of 5-(Hydroxymethyl)furfural from Carbohydrates using Tin-Beta Zeolite

Nikolla, E., Román-Leshkov, Y., Moliner, M., & Davis, M. E. (2011) · ACS Catalysis · doi:10.1021/cs2000544 · Cited by 674

Lewis Acids as Catalysts in Oxidation Reactions: From Homogeneous to Heterogeneous Systems

Corma, A., & García, H. (2002) · Chemical Reviews · doi:10.1021/cr010333u · Cited by 669

Furans in polymer chemistry

Gandini, A. (1997) · Progress in Polymer Science · doi:10.1016/s0079-6700(97)00004-x · Cited by 668

Recent Catalytic Advances in the Chemistry of Substituted Furans from Carbohydrates and in the Ensuing Polymers

Moreau, C., Belgacem, M. N., & Gandini, A. (2004) · Topics in Catalysis · doi:10.1023/b:toca.0000013537.13540.0e · Cited by 589

Nb2O5·nH2O as a Heterogeneous Catalyst with Water-Tolerant Lewis Acid Sites

Nakajima, K., Baba, Y., Noma, R., Kitano, M., Kondo, J. N., Hayashi, S., & Hara, M. (2011) · Journal of the American Chemical Society · doi:10.1021/ja110482r · Cited by 577

Converting carbohydrates to bulk chemicals and fine chemicals over heterogeneous catalysts

Climent, M. J., Corma, A., & Iborra, S. (2011) · Green Chemistry · doi:10.1039/c0gc00639d · Cited by 574

Biotechnological Production of Lactic Acid and Its Recent Applications

Wee, Y., Kim, J., & Ryu, H. (2006) · DOAJ (DOAJ: Directory of Open Access Journals) · Cited by 566

Solid Superacids

Arata, K. (1990) · Advances in Catalysis · doi:10.1016/s0360-0564(08)60365-x · Cited by 563

Molecular and industrial aspects of glucose isomerase

Bhosale, S. H., Rao, M. B., & Deshpande, V. (1996) · Microbiological Reviews · doi:10.1128/mmbr.60.2.280-300.1996 · Cited by 544

Synthesis, chemistry and applications of 5-hydroxymethyl-furfural and its derivatives

Lewkowski, J. (2001) · Arkivoc · doi:10.3998/ark.5550190.0002.102 · Cited by 496

Efficient conversion of glucose into 5-hydroxymethylfurfural catalyzed by a common Lewis acid SnCl4 in an ionic liquid

Hu, S., Zhang, Z., Song, J., Zhou, Y., & Han, B. (2009) · Green Chemistry · doi:10.1039/b914601f · Cited by 476

Solvent Effects on Fructose Dehydration to 5-Hydroxymethylfurfural in Biphasic Systems Saturated with Inorganic Salts

Román-Leshkov, Y., & Dumesic, J. A. (2009) · Topics in Catalysis · doi:10.1007/s11244-008-9166-0 · Cited by 469

A New Hypothesis Regarding the Surface Acidity of Binary Metal Oxides

Tanabe, K., Sumiyoshi, T., Shibata, K., Kiyoura, T., & Kitagawa, J. (1974) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.47.1064 · Cited by 464

Oxyfunctionalization of alkanes with hydrogen peroxide on titanium silicalite

Huybrechts, D. R. C., Bruycker, L. D., & Jacobs, P. A. (1990) · Nature · doi:10.1038/345240a0 · Cited by 436

Single-step conversion of cellulose to 5-hydroxymethylfurfural (HMF), a versatile platform chemical

Su, Y., Brown, H. M., Huang, X., Zhou, X.-D., Amonette, J. E., & Zhang, Z. C. (2009) · Applied Catalysis A: General · doi:10.1016/j.apcata.2009.04.002 · Cited by 436

Efficient Catalytic System for the Selective Production of 5‐Hydroxymethylfurfural from Glucose and Fructose

Yong, G., Zhang, Y., & Ying, J. Y. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803207 · Cited by 430

Design of solid acid catalysts for aqueous-phase dehydration of carbohydrates: The role of Lewis and Brønsted acid sites

Weingarten, R., Tompsett, G. A., Conner, W. C., & Huber, G. W. (2011) · Journal of Catalysis · doi:10.1016/j.jcat.2011.01.013 · Cited by 424

The Composition and Conformation of Sugars in Solution

Angyal, S. J. (1969) · Angewandte Chemie International Edition in English · doi:10.1002/anie.196901571 · Cited by 422

Dehydration of fructose to 5-hydroxymethylfurfural over H-mordenites

Moreau, C., Durand, R., Razigade, S., Duhamet, J., Faugeras, P., Rivalier, P., Ros, P., & Avignon, G. (1996) · Applied Catalysis A: General · doi:10.1016/0926-860x(96)00136-6 · Cited by 413

Dehydration of fructose to 5-hydroxymethylfurfural in sub- and supercritical acetone

Bicker, M., Hirth, J., & Vogel, H. (2003) · Green Chemistry · doi:10.1039/b211468b · Cited by 407

Lewis Acid Catalysts Stable in Water. Correlation between Catalytic Activity in Water and Hydrolysis Constants and Exchange Rate Constants for Substitution of Inner-Sphere Water Ligands

Kobayashi, S., Nagayama, S., & Busujima, T. (1998) · Journal of the American Chemical Society · doi:10.1021/ja980715q · Cited by 378

Reactions of titanium silicalite with protic molecules and hydrogen peroxide

Bellussi, G. (1992) · Journal of Catalysis · doi:10.1016/0021-9517(92)90199-r · Cited by 374

Dehydration of xylose into furfural over micro-mesoporous sulfonic acid catalysts

Dias, A. S., Pillinger, M., & Valente, A. A. (2005) · Journal of Catalysis · doi:10.1016/j.jcat.2004.11.016 · Cited by 353

Titanium silicalites

Notari, B. (1993) · Catalysis Today · doi:10.1016/0920-5861(93)85029-y · Cited by 344

A one-pot reaction for biorefinery: combination of solid acid and base catalysts for direct production of 5-hydroxymethylfurfural from saccharides

Takagaki, A., Ohara, M., Nishimura, S., & Ebitani, K. (2009) · Chemical Communications · doi:10.1039/b914087e · Cited by 341

Determination of the catalytically active oxidation Lewis acid sites in Sn-beta zeolites, and their optimisation by the combination of theoretical and experimental studies

BORONAT, M., CONCEPCION, P., CORMA, A., RENZ, M., & VALENCIA, S. (2005) · Journal of Catalysis · doi:10.1016/j.jcat.2005.05.023 · Cited by 339

Conversion of fructose to 5-hydroxymethylfurfural using ionic liquids prepared from renewable materials

Hu, S., Zhang, Z., Zhou, Y., Han, B., Fan, H., Li, W., Song, J., & Xie, Y. (2008) · Green Chemistry · doi:10.1039/b810392e · Cited by 332

Production of titanium containing molecular sieves and their application in catalysis

Perego, C., Carati, A., Ingallina, P., Mantegazza, M. A., & Bellussi, G. (2001) · Applied Catalysis A: General · doi:10.1016/s0926-860x(01)00797-9 · Cited by 312

The Conversion of Fructose and Glucose in Acidic Media: Formation of Hydroxymethylfurfural

van Dam, H. E., Kieboom, A. P. G., & van Bekkum, H. (1986) · Starch - Stärke · doi:10.1002/star.19860380308 · Cited by 312

Effect of water on sulfuric acid catalyzed esterification

Liu, Y., Lotero, E., & Goodwin, J. G. (2005) · Journal of Molecular Catalysis A Chemical · doi:10.1016/j.molcata.2005.09.049 · Cited by 311

Efficient process for conversion of fructose to 5-hydroxymethylfurfural with ionic liquids

Qi, X., Watanabe, M., Aida, T. M., & Smith, Jr. (2009) · Green Chemistry · doi:10.1039/b905975j · Cited by 297

Selective oxidation of glycerol on a platinum-bismuth catalyst

Kimura, H., Tsuto, K., Wakisaka, T., Kazumi, Y., & Inaya, Y. (1993) · Applied Catalysis A: General · doi:10.1016/0926-860x(90)80011-3 · Cited by 295

Zeolite‐Catalyzed Isomerization of Triose Sugars

Taarning, E., Saravanamurugan, S., Spangsberg Holm, M., Xiong, J., West, R. M., & Christensen, C. H. (2009) · ChemSusChem · doi:10.1002/cssc.200900099 · Cited by 276

Selective and Shape-Selective Baeyer–Villiger Oxidations of Aromatic Aldehydes and Cyclic Ketones with Sn-Beta Zeolites and H2O2

Renz, M., Blasco, T., Corma, A., Fornés, V., Jensen, R., & Nemeth, L. (2002) · Chemistry - A European Journal · doi:10.1002/1521-3765(20021018)8:20<4708::aid-chem4708>3.0.co;2-u · Cited by 270

Cellulose hydrothermal conversion promoted by heterogeneous Brønsted and Lewis acids: Remarkable efficiency of solid Lewis acids to produce lactic acid

Chambon, F., Rataboul, F., Pinel, C., Cabiac, A., Guillon, E., & Essayem, N. (2011) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2011.04.009 · Cited by 263

Fermentation of Glucose to Lactic Acid Coupled with Reactive Extraction: A Review

Wasewar, K. L., Yawalkar, A. A., Moulijn, J. A., & Pangarkar, V. G. (2004) · Industrial & Engineering Chemistry Research · doi:10.1021/ie049963n · Cited by 261

Acid‐Catalyzed Conversion of Sugars and Furfurals in an Ionic‐Liquid Phase

Sievers, C., Musin, I., Marzialetti, T., Valenzuela Olarte, M. B., Agrawal, P. K., & Jones, C. W. (2009) · ChemSusChem · doi:10.1002/cssc.200900092 · Cited by 255

Mechanism of the Meerwein−Ponndorf−Verley−Oppenauer (MPVO) Redox Equilibrium on Sn− and Zr−Beta Zeolite Catalysts

Boronat, M., Corma, A., & Renz, M. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp063249x · Cited by 245

Dehydration of d-fructose to hydroxymethylfurfural in sub- and supercritical fluids

Bicker, M., Kaiser, D., Ott, L., & Vogel, H. (2005) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2005.04.004 · Cited by 243

Conversion of mono/di/polysaccharides into furan compounds using 1-alkyl-3-methylimidazolium ionic liquids

Lima, S., Neves, P., Antunes, M. M., Pillinger, M., Ignat’ev, N. V., & Valente, A. A. (2009) · Applied Catalysis A General · doi:10.1016/j.apcata.2009.04.049 · Cited by 238

Alkaline degradation of glucose: effect of initial concentration of reactants

Yang, B. Y., & Montgomery, R. (1996) · Carbohydrate Research · doi:10.1016/0008-6215(95)00294-4 · Cited by 235

Catalytical conversion of carbohydrates in subcritical water: A new chemical process for lactic acid production

Bicker, M., Endres, S., Ott, L., & Vogel, H. (2005) · Journal of Molecular Catalysis A Chemical · doi:10.1016/j.molcata.2005.06.017 · Cited by 235

Selective preparation of furfural from xylose over microporous solid acid catalysts

Moreau, C., Durand, R., Peyron, D., Duhamet, J., & Rivalier, P. (1998) · Industrial Crops and Products · doi:10.1016/s0926-6690(97)00037-x · Cited by 226

Zeolite H-USY for the production of lactic acid and methyl lactate from C3-sugars

West, R. M., Holm, M. S., Saravanamurugan, S., Xiong, J., Beversdorf, Z., Taarning, E., & Christensen, C. H. (2009) · Journal of Catalysis · doi:10.1016/j.jcat.2009.10.023 · Cited by 225

Use of renewables for the production of chemicals: Glycerol oxidation over carbon supported gold catalysts

Demirel, S., Lehnert, K., Lucas, M., & Claus, P. (2007) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2005.11.036 · Cited by 224

Direct conversion of inulin to 5-hydroxymethylfurfural in biorenewable ionic liquids

Hu, S., Zhang, Z., Zhou, Y., Song, J., Fan, H., & Han, B. (2009) · Green Chemistry · doi:10.1039/b822328a · Cited by 217

Lewis Acid Catalysis of a Diels−Alder Reaction in Water

Otto, S., Bertoncin, F., & Engberts, J. B. F. N. (1996) · Journal of the American Chemical Society · doi:10.1021/ja960318k · Cited by 217

Syntheses of 5-hydroxymethylfurfural and levoglucosan by selective dehydration of glucose using solid acid and base catalysts

Ohara, M., Takagaki, A., Nishimura, S., & Ebitani, K. (2010) · Applied Catalysis A: General · doi:10.1016/j.apcata.2010.05.040 · Cited by 201

Selective saccharides dehydration to 5-hydroxymethyl-2-furaldehyde by heterogeneous niobium catalysts

Carlini, C., Giuttari, M., Maria Raspolli Galletti, A., Sbrana, G., Armaroli, T., & Busca, G. (1999) · Applied Catalysis A: General · doi:10.1016/s0926-860x(99)00064-2 · Cited by 199

Mechanistic insights on the conversion of sugars into 5-hydroxymethylfurfural

Binder, J. B., Cefali, A. V., Blank, J. J., & Raines, R. T. (2010) · Energy & Environmental Science · doi:10.1039/b923961h · Cited by 191

Direct conversion of glucose to 5-(hydroxymethyl)furfural in ionic liquids with lanthanide catalysts

Ståhlberg, T., Sørensen, M. G., & Riisager, A. (2010) · Green Chemistry · doi:10.1039/b916354a · Cited by 188

Zeolite-catalysed conversion of C3 sugars to alkyl lactates

Pescarmona, P. P., Janssen, K. P. F., Delaet, C., Stroobants, C., Houthoofd, K., Philippaerts, A., De Jonghe, C., Paul, J. S., Jacobs, P. A., & Sels, B. F. (2010) · Green Chemistry · doi:10.1039/b921284a · Cited by 183

Green Chemicals from d-glucose: Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions

Rasrendra, C. B., Makertihartha, I. G. B. N., Adisasmito, S., & Heeres, H. J. (2010) · Topics in Catalysis · doi:10.1007/s11244-010-9570-0 · Cited by 180

Tin-catalyzed conversion of trioses to alkyl lactates in alcohol solution

Hayashi, Y., & Sasaki, Y. (2005) · Chemical Communications · doi:10.1039/b501964h · Cited by 178

Isomerization of glucose into fructose in the presence of cation-exchanged zeolites and hydrotalcites

Moreau, C., Durand, R., Roux, A., & Tichit, D. (2000) · Applied Catalysis A General · doi:10.1016/s0926-860x(99)00435-4 · Cited by 177

One pot production of 5-hydroxymethylfurfural with high yield from cellulose by a Brønsted–Lewis–surfactant-combined heteropolyacid catalyst

Zhao, S., Cheng, M., Li, J., Tian, J., & Wang, X. (2011) · Chemical Communications · doi:10.1039/c0cc04444j · Cited by 176

Selective conversion of trioses to lactates over Lewis acid heterogeneous catalysts

Li, L., Stroobants, C., Lin, K., Jacobs, P. A., Sels, B. F., & Pescarmona, P. P. (2011) · Green Chemistry · doi:10.1039/c0gc00923g · Cited by 170

Heterogeneous catalysts based on vanadyl phosphate for fructose dehydration to 5-hydroxymethyl-2-furaldehyde

Carlini, C., Patrono, P., Galletti, A. M. R., & Sbrana, G. (2004) · Applied Catalysis A General · doi:10.1016/j.apcata.2004.07.026 · Cited by 169

The influence of the initial and catalyst concentrations on the dehydration of d-fructose

Kuster, B. F. M., & S. van der Baan, H. (1977) · Carbohydrate Research · doi:10.1016/s0008-6215(00)84806-5 · Cited by 168

Glucose Activation by Transient Cr2+ Dimers

Pidko, E. A., Degirmenci, V., van Santen, R. A., & Hensen, E. J. M. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000250 · Cited by 168

Selective Catalytic Oxidation of Glycerol to Dihydroxyacetone

Painter, R. M., Pearson, D., & Waymouth, R. M. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201004063 · Cited by 161

Principles of Descriptive Inorganic Chemistry

Wulfsberg, G. P. (1987) · Cited by 160

Metal Ion Roles and the Movement of Hydrogen during Reaction Catalyzed by D-Xylose Isomerase: A Joint X-Ray and Neutron Diffraction Study

Kovalevsky, A. Y., Hanson, L., Fisher, S. Z., Mustyakimov, M., Mason, S. A., Trevor Forsyth, V., Blakeley, M. P., Keen, D. A., Wagner, T., Carrell, H. L., et al. (2010) · Structure · doi:10.1016/j.str.2010.03.011 · Cited by 160

Integrating enzymatic and acid catalysis to convert glucose into 5-hydroxymethylfurfural

Huang, R., Qi, W. D., Su, R., & He, Z. (2009) · Chemical Communications · doi:10.1039/b921306f · Cited by 157

Ionic Liquid−Water Mixtures: Enhanced Kw for Efficient Cellulosic Biomass Conversion

Zhang, Y., Du, H., Qian, X., & Chen, E. Y. ‐. (2010) · Energy & Fuels · doi:10.1021/ef1000198 · Cited by 155

The Lobry de Bruyn-Alberda van Ekenstein Transformation and Related Reactions

Angyal, S. J. (2001) · Topics in current chemistry · doi:10.1007/3-540-44422-x_1 · Cited by 151

Dehydration reactions of fructose in non‐aqueous media

Brown, D. W., Floyd, A. J., Kinsman, R. G., & Roshanhyphen;Ali, Y. (1982) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.5030320730 · Cited by 147

One-pot electrocatalytic oxidation of glycerol to DHA

Ciriminna, R., Palmisano, G., Pina, C. D., Rossi, M., & Pagliaro, M. (2006) · Tetrahedron Letters · doi:10.1016/j.tetlet.2006.07.123 · Cited by 139

Catalytic Conversion of Dihydroxyacetone to Lactic Acid Using Metal Salts in Water

Rasrendra, C. B., Fachri, B. A., Makertihartha, I. G. B. N., Adisasmito, S., & Heeres, H. J. (2011) · ChemSusChem · doi:10.1002/cssc.201000457 · Cited by 135

Catalytic Activity of Lanthanide(III) Ions for the Dehydration of Hexose to 5-Hydroxymethyl-2-furaldehyde in Water

Seri, K., Inoue, Y., & Ishida, H. (2001) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.74.1145 · Cited by 134

Enolisation and isomerisation of monosaccharides in aqueous, alkaline solution

de Wit, G., Kieboom, A. P. G., & van Bekkum, H. (1979) · Carbohydrate Research · doi:10.1016/s0008-6215(00)84773-4 · Cited by 133

Sn-Beta zeolite as diastereoselective water-resistant heterogeneous Lewis-acid catalyst for carbon–carbon bond formation in the intramolecular carbonyl–ene reaction

Corma, A., & Renz, M. (2004) · Chemical Communications · doi:10.1039/b313738d · Cited by 129

The Dehydration of d -Fructose to 5-Hydroxymethyl-2-furaldehyde

Nakamura, Y., & Morikawa, S.-I. (1980) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.53.3705 · Cited by 128

Computational and EXAFS Study of the Nature of the Ti(IV) Active Sites in Mesoporous Titanosilicate Catalysts

Sinclair, P. E., Sankar, G., Catlow, C. R. A., Thomas, J. M., & Maschmeyer, T. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp9623960 · Cited by 126

Water Resistant, Catalytically Active Nb and Ta Isolated Lewis Acid Sites, Homogeneously Distributed by Direct Synthesis in a Beta Zeolite

Corma, A., Xamena, F. X. L. I., Prestipino, C., Renz, M., & Valencia, S. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp902375n · Cited by 126

Tantalum compounds as heterogeneous catalysts for saccharide dehydration to 5-hydroxymethylfurfural

Yang, F., Liu, Q., Yue, M., Bai, X., & Du, Y. (2011) · Chemical Communications · doi:10.1039/c0cc05138a · Cited by 125

Molecular Aspects of Glucose Dehydration by Chromium Chlorides in Ionic Liquids

Zhang, Y., Pidko, E. A., & Hensen, E. J. M. (2011) · Chemistry - A European Journal · doi:10.1002/chem.201003645 · Cited by 121

Selective Catalytic Oxidation of Glycerol to Dihydroxyacetone

Painter, R. M., Pearson, D., & Waymouth, R. M. (2010) · Angewandte Chemie · doi:10.1002/ange.201004063 · Cited by 120

Acid-catalyzed degradation of d-fructose

Shaw, P. E., Tatum, J. H., & Berry, R. E. (1967) · Carbohydrate Research · doi:10.1016/s0008-6215(00)80500-5 · Cited by 112

Dehydration of butanol to butene over solid acid catalysts in high water environments

West, R. M., Braden, D. J., & Dumesic, J. A. (2009) · Journal of Catalysis · doi:10.1016/j.jcat.2008.12.009 · Cited by 111

Highly Efficient Catalytic Activity of Lanthanide(III) Ions for Conversion of Saccharides to 5-Hydroxymethyl-2-furfural in Organic Solvents

Seri, K., Inoue, Y., & Ishida, H. (2000) · Chemistry Letters · doi:10.1246/cl.2000.22 · Cited by 109

Novel Enzymatic Mechanisms in Carbohydrate Metabolism

He, X., Agnihotri, G., & Liu, H. (2000) · Chemical Reviews · doi:10.1021/cr9902998 · Cited by 109

Xylose Isomerase in Substrate and Inhibitor Michaelis States: Atomic Resolution Studies of a Metal-Mediated Hydride Shift,

Fenn, T. D., Ringe, D., & Petsko, G. A. (2004) · Biochemistry · doi:10.1021/bi049812o · Cited by 108

Mechanistic Imperatives for Aldose−Ketose Isomerization in Water: Specific, General Base- and Metal Ion-Catalyzed Isomerization of Glyceraldehyde with Proton and Hydride Transfer

Nagorski, R. W., & Richard, J. P. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003433a · Cited by 108

Transformations of sugars in alkaline solutions

Isbell, H. S., Frush, H. L., Wade, C. W. R., & Hunter, C. E. (1969) · Carbohydrate Research · doi:10.1016/s0008-6215(00)82132-1 · Cited by 107

The preparation of 5-chloromethylfurfuraldehyde from high fructose corn syrup and other carbohydrates

Szmant, H. H., & Chundury, D. D. (1981) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.503310128 · Cited by 105

A Multisite Molecular Mechanism for Baeyer–Villiger Oxidations on Solid Catalysts Using Environmentally Friendly H2O2 as Oxidant

Boronat, M., Corma, A., Renz, M., Sastre, G., & Viruela, P. M. (2005) · Chemistry - A European Journal · doi:10.1002/chem.200500184 · Cited by 104

Solid-state phosphorus-31 NMR of a chemisorbed phosphonium ion in HY zeolite: observation of proton-phosphorus-31 coupling in the solid-state

Rothwell, W. P., Shen, W., & Lunsford, J. H. (1984) · Journal of the American Chemical Society · doi:10.1021/ja00320a048 · Cited by 102

Effect of Borate on the Alkali-catalyzed Isomerization of Sugars1

Mendicino, J. F. (1960) · Journal of the American Chemical Society · doi:10.1021/ja01503a055 · Cited by 100

Hydrothermal catalytic conversion of biomass for lactic acid production

Kong, L., Li, G., Wang, H., He, W., & Fang, L. (2007) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.1797 · Cited by 98

Theoretical Study of 1,2-Hydride Shift Associated with the Isomerization of Glyceraldehyde to Dihydroxy Acetone by Lewis Acid Active Site Models

Assary, R. S., & Curtiss, L. A. (2011) · The Journal of Physical Chemistry A · doi:10.1021/jp204371g · Cited by 96

The Acid-Base-Catalyzed Conversion of Aldohexose into 5-(Hydroxymethyl)-2-furfural2

Mednick, M. L. (1962) · The Journal of Organic Chemistry · doi:10.1021/jo01049a013 · Cited by 88

Theoretical insights on the mechanism of alkene epoxidation by H2O2 with titanium silicalite

Neurock, M., & Manzer, L. E. (1996) · Chemical Communications · doi:10.1039/cc9960001133 · Cited by 85

The preparation of 5-hydroxymethylfurfuraldehyde from high fructose corn syrup and other carbohydrates

Szmant, H. H., & Chundury, D. D. (1981) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.280310119 · Cited by 85

Enthalpy and Entropy Changes by Formation of Different Types of Complexes

Ahrland, S. (1967) · Helvetica Chimica Acta · doi:10.1002/hlca.19670500138 · Cited by 84

Recent Contributions to the Preparation of Polymers Derived from Renewable Resources

Gandini, A., & Belgacem, M. N. (2002) · Journal of Polymers and the Environment · doi:10.1023/a:1021172130748 · Cited by 80

TRANSITION METAL CATALYSTS. III. NATURE OF THE ACTIVE SITE IN ORGANOMETALLIC CATALYSTS

Carrick, W. L., Karol, F. J., Karapinka, G. L., & Smith, J. J. (1960) · Journal of the American Chemical Society · doi:10.1021/ja01491a056 · Cited by 79

Direct dehydration polycondensation of lactic acid catalyzed by water‐stable Lewis acids

Takasu, A., Narukawa, Y., & Hirabayashi, T. (2006) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.21639 · Cited by 75

Nouvelle méthode de préparation du 5-hydroxyméthyl-2-furaldéhyde par action de sels d'ammonium ou d'immonium sur les mono-, oligo- et poly-saccharides. Accès direct aux 5-halogénométhyl-2-furaldéhydes

Fayet, C., & Gelas, J. (1983) · Carbohydrate Research · doi:10.1016/0008-6215(83)88406-7 · Cited by 71

Complex formation in protic and aprotic media

Ahrland, S. (1979) · Pure and Applied Chemistry · doi:10.1351/pac197951102019 · Cited by 70

Selective conversion of D-fructose to 5-hydroxymethyl-2-furancarboxaldehyde using a water-solvent-ion-exchange resin triphasic system

Rigal, L., Gaset, A., & Gorrichon, J. (1981) · Industrial & Engineering Chemistry Product Research and Development · doi:10.1021/i300004a025 · Cited by 62

Tracer studies of acid-catalyzed reactions. Part 10.—Deuterium exchange and isomerization of cyclic olefins over alumina

Hightower, J. W., & Hall, W. K. (1970) · Transactions of the Faraday Society · doi:10.1039/tf9706600477 · Cited by 62

Synthesis and Characterization of Mesoporous Ta−W Oxides as Strong Solid Acid Catalysts

Tagusagawa, C., Takagaki, A., Iguchi, A., Takanabe, K., Kondo, J. N., Ebitani, K., Tatsumi, T., & Domen, K. (2010) · Chemistry of Materials · doi:10.1021/cm903767n · Cited by 58

3-DEOXYHEXOSONES

Anet, E. (1960) · Journal of the American Chemical Society · doi:10.1021/ja01491a055 · Cited by 47

Tin–Tungsten Mixed Oxide as Efficient Heterogeneous Catalyst for Conversion of Saccharides to Furan Derivatives

Yamaguchi, K., Sakurada, T., Ogasawara, Y., & Mizuno, N. (2011) · Chemistry Letters · doi:10.1246/cl.2011.542 · Cited by 43

A Comparative Study of Structural, Acidic and Hydrophilic Properties of Sn−BEA with Ti−BEA Using Periodic Density Functional Theory

Shetty, S. G., Kulkarni, B. S., Kanhere, D. G., Goursot, A., & Pal, S. (2008) · The Journal of Physical Chemistry B · doi:10.1021/jp709846s · Cited by 42

Isomerisation of aldoses in pyridine in the presence of aluminium oxide

Ekeberg, D., Morgenlie, S., & Stenstrøm, Y. (2005) · Carbohydrate Research · doi:10.1016/j.carres.2004.12.006 · Cited by 29

Preparation of 5‐Hydroxymethylfurfural Part II. Dehydration of Fructose in a Tube Reactor Using Polyethyleneglycol as Solvent

Kuster, B. F. M., & Laurens, J. (1977) · Starch - Stärke · doi:10.1002/star.19770290507 · Cited by 29

A High-Throughput Experimentation Study of the Synthesis of Lactates with Solid Acid Catalysts

Pescarmona, P. P., Janssen, K. P. F., Stroobants, C., Molle, B., Paul, J. S., Jacobs, P. A., & Sels, B. F. (2009) · Topics in Catalysis · doi:10.1007/s11244-009-9433-8 · Cited by 23

CCI.—The constitution of the disaccharides. Part XIII. The γ-fructose residue in sucrose

Haworth, W. N., Hirst, E. L., & Nicholson, V. S. (1927) · Journal of the Chemical Society (Resumed) · doi:10.1039/jr9270001513 · Cited by 19

Hydroxyapatite Supported Lewis Acid Catalysts for the Transformation of Trioses in Alcohols

Zhang, Z., & Zhao, Z. K. (2011) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(10)60162-3 · Cited by 12

31P NMR Chemical Shifts of Phosphorus Probes as Reliable and Practical Acidity Scales for Solid and Liquid Catalysts

Zheng, A., Liu, S.-B., & Deng, F. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00289 · Cited by 365

Defect‐Mediated Ordering of Condensed Water Structures in Microporous Zeolites

Bukowski, B. C., Bates, J. S., Gounder, R., & Greeley, J. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201908151 · Cited by 59