Recent advances on polyoxometalate-based molecular and composite materials

Transformation of Carbon Dioxide

Sakakura, T., Choi, J.-C., & Yasuda, H. (2007) · Chemical Reviews · doi:10.1021/cr068357u · Cited by 3,853

Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines

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Lanthanide-Based Luminescent Hybrid Materials

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Polyoxometalates: Building Blocks for Functional Nanoscale Systems

Long, D., Tsunashima, R., & Cronin, L. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200902483 · Cited by 2,273

Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices

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Polyoxometalates in Medicine

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Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications

Dolbecq, A., Dumas, E., Mayer, C. R., & Mialane, P. (2010) · Chemical Reviews · doi:10.1021/cr1000578 · Cited by 1,755

Making Plastics from Carbon Dioxide: Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO 2

Darensbourg, D. J. (2007) · Chemical Reviews · doi:10.1021/cr068363q · Cited by 1,593

Homogeneous catalysis by transition metal oxygen anion clusters

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A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals

Yin, Q., Tan, J. M., Besson, C., Geletii, Y. V., Musaev, D. G., Kuznetsov, A. E., Luo, Z., Hardcastle, K. I., & Hill, C. L. (2010) · Science · doi:10.1126/science.1185372 · Cited by 1,438

Splitting Water with Cobalt

Artero, V., Chavarot‐Kerlidou, M., & Fontecave, M. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201007987 · Cited by 1,393

Designed Hybrid Organic−Inorganic Nanocomposites from Functional Nanobuilding Blocks

Sanchez, C., Soler-Illia, G. J. D. A. A., Ribot, F., Lalot, T., Mayer, C. R., & Cabuil, V. (2001) · Chemistry of Materials · doi:10.1021/cm011061e · Cited by 1,240

Discrete Metal‐Based Catalysts for the Copolymerization of CO2 and Epoxides: Discovery, Reactivity, Optimization, and Mechanism

Coates, G. W., & Moore, D. R. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460442 · Cited by 1,154

Cobalt catalysts for the coupling of CO2and epoxides to provide polycarbonates and cyclic carbonates

Lu, X.-B., & Darensbourg, D. J. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15142h · Cited by 1,112

The synthesis of organic carbonates from carbon dioxide

Sakakura, T., & Kohno, K. (2009) · Chemical Communications · doi:10.1039/b819997c · Cited by 1,067

Copolymerization of carbon dioxide and epoxide

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Energy Resources and Global Development

Chow, J., Kopp, R. J., & Portney, P. R. (2003) · Science · doi:10.1126/science.1091939 · Cited by 969

Surface nano-architecture of a metal–organic framework

Makiura, R., Motoyama, S., Umemura, Y., Yamanaka, H., Sakata, O., & Kitagawa, H. (2010) · Nature Materials · doi:10.1038/nmat2769 · Cited by 899

Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

Proust, A., Thouvenot, R., & Gouzerh, P. (2008) · Chemical Communications · doi:10.1039/b715502f · Cited by 898

Mononuclear Lanthanide Single-Molecule Magnets Based on Polyoxometalates

AlDamen, M. A., Clemente-Juan, J. M., Coronado, E., Martí-Gastaldo, C., & Gaita-Ariño, A. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801659m · Cited by 863

Where Water Is Oxidized to Dioxygen: Structure of the Photosynthetic Mn 4 Ca Cluster

Yano, J., Kern, J., Sauer, K., Latimer, M. J., Pushkar, Y., Biesiadka, J., Loll, B., Saenger, W., Messinger, J., Zouni, A., et al. (2006) · Science · doi:10.1126/science.1128186 · Cited by 804

Catalysts for CO 2 /epoxide copolymerisation

Kember, M. R., Buchard, A., & Williams, C. K. (2011) · Chem. Commun. · doi:10.1039/c0cc02207a · Cited by 797

Reactive Applications of Cyclic Alkylene Carbonates

Clements, J. H. (2003) · Industrial & Engineering Chemistry Research · doi:10.1021/ie020678i · Cited by 784

Efficient water oxidation catalysts based on readily available iron coordination complexes

Fillol, J. L., Codolà, Z., Garcia-Bosch, I., Gómez, L., Pla, J. J., & Costas, M. (2011) · Nature Chemistry · doi:10.1038/nchem.1140 · Cited by 784

Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms

Klaus, S., Lehenmeier, M. W., Anderson, C. E., & Rieger, B. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.12.002 · Cited by 710

Cyclometalated Iridium(III) Aquo Complexes: Efficient and Tunable Catalysts for the Homogeneous Oxidation of Water

McDaniel, N. D., Coughlin, F. J., Tinker, L. L., & Bernhard, S. (2008) · Journal of the American Chemical Society · doi:10.1021/ja074478f · Cited by 610

Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [γ-SiW10O36]8−: A Totally Inorganic Oxygen-Evolving Catalyst

Sartorel, A., Carraro, M., Scorrano, G., Zorzi, R. D., Geremia, S., McDaniel, N. D., Bernhard, S., & Bonchio, M. (2008) · Journal of the American Chemical Society · doi:10.1021/ja077837f · Cited by 599

Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

Hull, J. F., Balcells, D., Blakemore, J. D., Incarvito, C. D., Eisenstein, O., Brudvig, G. W., & Crabtree, R. H. (2009) · Journal of the American Chemical Society · doi:10.1021/ja901270f · Cited by 594

An All‐Inorganic, Stable, and Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation

Geletii, Y. V., Botar, B., Kögerler, P., Hillesheim, D. A., Musaev, D. G., & Hill, C. L. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200705652 · Cited by 592

Efficient water oxidation at carbon nanotube–polyoxometalate electrocatalytic interfaces

Toma, F. M., Sartorel, A., Iurlo, M., Carraro, M., Parisse, P., Maccato, C., Rapino, S., Gonzalez, B. R., Amenitsch, H., Da Ros, T., et al. (2010) · Nature Chemistry · doi:10.1038/nchem.761 · Cited by 503

Copolymerization of CO2 and Epoxides Catalyzed by Metal Salen Complexes

Darensbourg, D. J., Mackiewicz, R. M., Phelps, A. L., & Billodeaux, D. R. (2004) · Accounts of Chemical Research · doi:10.1021/ar030240u · Cited by 479

Polyoxometalates: introduction to a class of inorganic compounds and their biomedical applications

Hasenknopf, B. (2005) · Frontiers in Bioscience · doi:10.2741/1527 · Cited by 459

Deep desulfurization of diesel fuel using ionic liquids: current status and future challenges

Kulkarni, P. S., & Afonso, C. A. M. (2010) · Green Chemistry · doi:10.1039/c002113j · Cited by 459

Copolymerization of carbon dioxide and epoxide

Sugimoto, H., & Inoue, S. (2004) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.20319 · Cited by 380

Water Oxidation Catalyzed by Strong Carbene‐Type Donor‐Ligand Complexes of Iridium

Lalrempuia, R., McDaniel, N. D., Müller‐Bunz, H., Bernhard, S., & Albrecht, M. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201005260 · Cited by 371

Efficient Light-Driven Carbon-Free Cobalt-Based Molecular Catalyst for Water Oxidation

Huang, Z., Luo, Z., Geletii, Y. V., Vickers, J. W., Yin, Q., Wu, D., Hou, Y., Ding, Y., Song, J., Musaev, D. G., et al. (2011) · Journal of the American Chemical Society · doi:10.1021/ja109681d · Cited by 358

Homogeneous Light-Driven Water Oxidation Catalyzed by a Tetraruthenium Complex with All Inorganic Ligands

Geletii, Y. V., Huang, Z., Hou, Y., Musaev, D. G., Lian, T., & Hill, C. L. (2009) · Journal of the American Chemical Society · doi:10.1021/ja901373m · Cited by 352

Layer-by-Layer Assembly and UV Photoreduction of Graphene–Polyoxometalate Composite Films for Electronics

Li, H., Pang, S., Wu, S., Feng, X., Müllen, K., & Bubeck, C. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201594k · Cited by 325

Catalytic hydrogen production at cobalt centres

Losse, S., Vos, J. G., & Rau, S. (2010) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.06.004 · Cited by 314

Self-Assembly of Organic−Inorganic Hybrid Amphiphilic Surfactants with Large Polyoxometalates as Polar Head Groups

Zhang, J., Song, Y.-F., Cronin, L., & Liu, T. (2008) · Journal of the American Chemical Society · doi:10.1021/ja805644a · Cited by 305

Integrated three-dimensional microelectromechanical devices from processable carbon nanotube wafers

Hayamizu, Y., Yamada, T., Mizuno, K., Davis, R. C., Futaba, D. N., Yumura, M., & Hata, K. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2008.98 · Cited by 285

Desulfurization and Denitrogenation Process for Light Oils Based on Chemical Oxidation followed by Liquid−Liquid Extraction

Shiraishi, Y., Tachibana, K., Hirai, T., & Komasawa, I. (2002) · Industrial & Engineering Chemistry Research · doi:10.1021/ie010618x · Cited by 265

Ionic liquids containing carboxyl acid moieties grafted onto silica: Synthesis and application as heterogeneous catalysts for cycloaddition reactions of epoxide and carbon dioxide

Han, L., Choi, H.-J., Choi, S.-J., Liu, B., & Park, D.-W. (2011) · Green Chemistry · doi:10.1039/c0gc00612b · Cited by 260

Toward Nanodevices: Synthesis and Characterization of the Nanoporous Surfactant-Encapsulated Keplerate (DODA)40(NH4)2[(H2O)n⊂Mo132O372(CH3COO)30(H2O)72]

Volkmer, D., Du Chesne, A., Kurth, D. G., Schnablegger, H., Lehmann, P., Koop, M. J., & Müller, A. (2000) · Journal of the American Chemical Society · doi:10.1021/ja992350v · Cited by 243

Polyoxometalates as Inhibitors of the Aggregation of Amyloid β Peptides Associated with Alzheimer’s Disease

Geng, J., Li, M., Ren, J., Wang, E., & Qu, X. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201007067 · Cited by 238

pH-Responsive, Bolaamphiphile-Based Smart Metallo-Hydrogels as Potential Dye-Adsorbing Agents, Water Purifier, and Vitamin B12 Carrier

Ray, S., Das, A. K., & Banerjee, A. (2007) · Chemistry of Materials · doi:10.1021/cm062672f · Cited by 235

Oxidative desulfurization of dibenzothiophene with molecular oxygen using emulsion catalysis

Lü, H., Gao, J., Jiang, Z., Yang, Y., Song, B., & Li, C. (2007) · Chem. Commun. · doi:10.1039/b610504a · Cited by 233

Structural Modifications of Mononuclear Ruthenium Complexes: A Combined Experimental and Theoretical Study on the Kinetics of Ruthenium‐Catalyzed Water Oxidation

Tong, L., Duan, L., Xu, Y., Privalov, T., & Sun, L. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201005141 · Cited by 193

Carbon dioxide‐based copolymers: Environmental benefits of PPC, an industrially viable catalyst

Qin, Y., & Wang, X. (2010) · Biotechnology Journal · doi:10.1002/biot.201000134 · Cited by 185

Oxidative Desulfurization Using Polyoxometalates

Komintarachat, C., & Trakarnpruk, W. (2006) · Industrial & Engineering Chemistry Research · doi:10.1021/ie051199x · Cited by 184

Application of the Langmuir–Blodgett Technique to Polyoxometalates: Towards New Magnetic Films

Clemente‐León, M., Mingotaud, C., Agricole, B., Gómez‐Garcia, C. J., Coronado, E., & Delhaès, P. (1997) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199711141 · Cited by 184

Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)2N(CH3)2]5[IMo6O24]

Lü, H., Zhang, Y., Jiang, Z., & Li, C. (2010) · Green Chemistry · doi:10.1039/c0gc00271b · Cited by 182

A New Class of Surfactants with Multinuclear, Inorganic Head Groups

Landsmann, S., Lizandara-Pueyo, C., & Polarz, S. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1011178 · Cited by 179

Water‐Tolerant, Highly Active Solid Acid Catalysts Composed of the Keggin‐Type Polyoxometalate H3PW12O40 Immobilized in Hydrophobic Nanospaces of Organomodified Mesoporous Silica

Inumaru, K., Ishihara, T., Kamiya, Y., Okuhara, T., & Yamanaka, S. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200702478 · Cited by 178

Micropatterned Surfaces with Covalently Grafted Unsymmetrical Polyoxometalate-Hybrid Clusters Lead to Selective Cell Adhesion

Song, Y., McMillan, N., Long, D., Kane, S., Malm, J., Riehle, M. O., Pradeep, C. P., Gadegaard, N., & Cronin, L. (2009) · Journal of the American Chemical Society · doi:10.1021/ja807091v · Cited by 171

Polyoxometalate-Modified Carbon Nanotubes: New Catalyst Support for Methanol Electro-oxidation

Pan, D., Chen, J., Tao, W., Nie, L., & Yao, S. (2006) · Langmuir · doi:10.1021/la053171w · Cited by 156

Highly Efficient Extraction and Oxidative Desulfurization System Using Na7H2LaW10O36⋅32 H2O in [bmim]BF4 at Room Temperature

Xu, J., Zhao, S., Chen, W., Wang, M., & Song, Y. (2012) · Chemistry - A European Journal · doi:10.1002/chem.201102754 · Cited by 156

Water‐Tolerant, Highly Active Solid Acid Catalysts Composed of the Keggin‐Type Polyoxometalate H3PW12O40 Immobilized in Hydrophobic Nanospaces of Organomodified Mesoporous Silica

Inumaru, K., Ishihara, T., Κamiya, Y., Okuhara, T., & Yamanaka, S. (2007) · Angewandte Chemie · doi:10.1002/ange.200702478 · Cited by 156

Magnetic Nanocrescents as Controllable Surface‐Enhanced Raman Scattering Nanoprobes for Biomolecular Imaging

Liu, G. L., Lu, Y., Kim, J., Doll, J. C., & Lee, L. P. (2005) · Advanced Materials · doi:10.1002/adma.200501064 · Cited by 155

Spontaneous assembly and real-time growth of micrometre-scale tubular structures from polyoxometalate-based inorganic solids

Ritchie, C., Cooper, G. J. T., Song, Y., Streb, C., Yin, H., Parenty, A. D. C., MacLaren, D. A., & Cronin, L. (2009) · Nature Chemistry · doi:10.1038/nchem.113 · Cited by 154

Hydrophilic Macroionic Solutions: What Happens When Soluble Ions Reach the Size of Nanometer Scale?

Liu, T. (2009) · Langmuir · doi:10.1021/la902917q · Cited by 140

CO2 Coordination by Inorganic Polyoxoanion in Water

Gao, G., Li, F., Xu, L., Liu, X., & Yang, Y. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801560t · Cited by 124

Desulfurization by oxidation combined with extraction using acidic room-temperature ionic liquids

Yansheng, C., Li, C., Qingzhu, J., Qingshan, L., Peifang, Y., Xiumei, L., & Welz‐Biermann, U. (2011) · Green Chemistry · doi:10.1039/c0gc00745e · Cited by 124

Solid Materials as Sources for Synthetically Useful Singlet Oxygen

Wahlen, J., Vos, D. E. D., Jacobs, P. A., & Alsters, P. L. (2004) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200303224 · Cited by 121

Micelles and Vesicles Formed by Polyoxometalate–Block Copolymer Composites

Bu, W., Uchida, S., & Mizuno, N. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200904116 · Cited by 109

Surfactant‐Encapsulated Polyoxometalates as Immobilized Supramolecular Catalysts for Highly Efficient and Selective Oxidation Reactions

Qi, W., Wang, Y., Li, W., & Wu, L. (2010) · Chemistry - A European Journal · doi:10.1002/chem.200902261 · Cited by 108

Kinetics and mechanism for oxidative desulfurization of fuels catalyzed by peroxo-molybdenum amino acid complexes in water-immiscible ionic liquids

Zhu, W., Li, H., Gu, Q., Wu, P., Zhu, G., Yan, Y., & Chen, G. (2010) · Journal of Molecular Catalysis A Chemical · doi:10.1016/j.molcata.2010.12.003 · Cited by 99

Intermediates in the hydrodesulfurization of 4,6-dimethyl-dibenzothiophene over Pd/-AlO

Niquille-Röthlisberger, A., & Prins, R. (2005) · Journal of Catalysis · doi:10.1016/j.jcat.2005.08.007 · Cited by 97

Direct synthesis of cyclic carbonates from olefins and CO2 catalyzed by a MoO2(acac)2-quaternary ammonium salt system

Chen, F., Dong, T., Xu, T., Li, X., & Hu, C. (2011) · Green Chemistry · doi:10.1039/c1gc15549k · Cited by 95

Micelle Directed Synthesis of Polyoxometalate Nanoparticles and Their Improved Catalytic Activity for the Aerobic Oxidation of Sulfides

Maayan, G., Popovitz‐Biro, R., & Neumann, R. (2006) · Journal of the American Chemical Society · doi:10.1021/ja060696h · Cited by 91

Zinc Porphyrin Tweezer in Host-Guest Complexation: Determination of Absolute Configurations of Primary Monoamines by Circular Dichroism

Huang, X., Borhan, B., Rickman, B. H., Nakanishi, K., & Berova, N. D. (2000) · Chemistry - A European Journal · doi:10.1002/(sici)1521-3765(20000117)6:2<385::aid-chem385>3.0.co;2-a · Cited by 89

Air-channel fabrication for microelectromechanical systems via sacrificial photosensitive polycarbonates

Jayachandran, J. P., Reed, H. A., Zhen, H., et al. (2003) · Journal of Microelectromechanical Systems · doi:10.1109/jmems.2003.809963 · Cited by 80

Molecular Design of Polyoxometalate-Based Compounds for Environmentally-Friendly Functional Group Transformations: From Molecular Catalysts to Heterogeneous Catalysts

Mizuno, N., Yamaguchi, K., & Kamata, K. (2011) · Catalysis Surveys from Asia · doi:10.1007/s10563-011-9111-2 · Cited by 74

Vertical devices of self-assembled hybrid organic/inorganic monolayers based on tungsten polyoxometalates

Makarona, E., Kapetanakis, E., Velessiotis, D., Douvas, A. M., Argitis, P., Normand, P., Gotszalk, T. P., Woszczyna, M., & Glezos, N. (2008) · Microelectronic Engineering · doi:10.1016/j.mee.2008.01.020 · Cited by 68

Photoreduction of99Tc Pertechnetate by Nanometer-Sized Metal Oxides: New Strategies for Formation and Sequestration of Low-Valent Technetium

Burton‐Pye, B. P., Radivojevic, I., McGregor, D., Mbomekalle, I. M., Lukens, W. W., & Francesconi, L. C. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2060929 · Cited by 64

Identification of a Polyoxometalate Inhibitor of the DNA Binding Activity of Sox2

Narasimhan, K., Pillay, S., Ahmad, N. R. B., Bikádi, Z., Hazai, E., Yan, L., Kolatkar, P. R., Pervushin, K. V., & Jauch, R. (2011) · ACS Chemical Biology · doi:10.1021/cb100432x · Cited by 56

Cation mediated self-assembly of inorganic cluster anion building blocks

Wang, Y., & Weinstock, I. A. (2010) · Dalton Transactions · doi:10.1039/c0dt00166j · Cited by 50

Inhibition of amyloid-β protein fibrillization upon interaction with polyoxometalates nanoclusters

Zhou, Y., Li, Z., Han, F., Zhang, G., Ma, Y., Yao, J., Keita, B., de Oliveira, P., & Nadjo, L. (2010) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2010.11.068 · Cited by 39

Catalytic applications of layered double hydroxides: recent advances and perspectives

Fan, G., Li, F., Evans, D. G., & Duan, X. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00160e · Cited by 1,762

Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation

Kärkäs, M. D., Verho, O., Johnston, E. V., & Åkermark, B. (2014) · Chemical Reviews · doi:10.1021/cr400572f · Cited by 1,376

Heterogeneous Catalysis by Polyoxometalates in Metal–Organic Frameworks

Samaniyan, M., Mirzaei, M., Khajavian, R., Eshtiagh-Hosseini, H., & Streb, C. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b03439 · Cited by 389

Functional Carbon Nitride Materials in Photo‐Fenton‐Like Catalysis for Environmental Remediation

Lin, J., Tian, W., Guan, Z., Zhang, H., Duan, X., Wang, H., Sun, H., Fang, Y., Huang, Y., & Wang, S. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202201743 · Cited by 303

Design of Single-Atom Catalysts and Tracking Their Fate Using Operando and Advanced X-ray Spectroscopic Tools

Sarma, B. B., Maurer, F., Doronkin, D. E., & Grunwaldt, J.-D. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00495 · Cited by 291