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Mesoporous materials and electrochemistry

Walcarius, Alain·2013·Chemical Society Reviews

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Abstract

Ordered mesoporous materials prepared by the template route have attracted increasing interest from the electrochemists community due to their plenty of unique properties and functionalities that can be effectively exploited in electrochemical devices. This review will cover the whole field of the intersection between electrochemistry and ordered mesoporous materials. The latter are either electronically insulating (silica and some other metal oxides, as well as silica-based organic-inorganic hybrid materials), semi-conducting (metal oxides), or conducting (metals, carbons). The three main intersection areas are: (1) the development/use of electrochemical methods to characterize the properties of mesoporous materials (i.e., charge and mass transfer processes); (2) the generation of mesostructured solids by electro-assisted deposition using appropriate templates; and (3) the application of these novel materials for electrochemical purposes. The most common devices to date are based on a bulk composite or thin film configuration and the resulting electrodes modified with such mesoporous materials have been successfully applied in various fields, including mainly electrochemical sensing and biosensing as well as energy conversion and storage (620 references).

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Porous Metals from Colloidal Templates
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Nanostructured Gold Colloid Electrodes
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Electrochemical Synthesis of Mesoporous Pt–Au Binary Alloys with Tunable Compositions for Enhancement of Electrochemical Performance
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Mesoporous Silicate Materials in Sensing
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Mercury(II) Ion Adsorption Behavior in Thiol-Functionalized Mesoporous Silica Microspheres
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Lithium Intercalation into Mesoporous Anatase with an Ordered 3D Pore Structure
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Electrochemical Sensor for Detecting Ultratrace Nitroaromatic Compounds Using Mesoporous SiO2-Modified Electrode
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Enzyme-functionalized mesoporous silica for bioanalytical applications
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Rate of Access to the Binding Sites in Organically Modified Silicates. 3. Effect of Structure and Density of Functional Groups in Mesoporous Solids Obtained by the Co-Condensation Route
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From molecular chemistry to hybrid nanomaterials. Design and functionalization
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Oriented Mesoporous Silica Films Obtained by Electro-Assisted Self-Assembly (EASA)
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Platinum and platinum–ruthenium nanoparticles supported on ordered mesoporous carbon and their electrocatalytic performance for fuel cell reactions
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Ordered mesoporous carbons (OMC) as supports of electrocatalysts for direct methanol fuel cells (DMFC): Effect of carbon precursors of OMC on DMFC performances
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Mesostructured Silica Supports for Functional Materials and Molecular Machines
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Functionalized Sol–Gel Coatings for Optical Applications
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Hybrid Inorganic–Organic Mesoporous Materials
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Mesoporous silica-based electrochemical sensor for sensitive determination of environmental hormone bisphenol A
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Conductive Mesocellular Silica–Carbon Nanocomposite Foams for Immobilization, Direct Electrochemistry, and Biosensing of Proteins
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The preparation and characterisation of H1-e palladium films with a regular hexagonal nanostructure formed by electrochemical deposition from lyotropic liquid crystalline phases
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Mesoporous Silica Applications
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Ordered porous thin films in electrochemical analysis
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Synthesis of Mesoporous Pt Films with Tunable Pore Sizes from Aqueous Surfactant Solutions
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Colloidal Crystal Templating to Produce Hierarchically Porous LiFePO4 Electrode Materials for High Power Lithium Ion Batteries
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Analytical Chemistry with Silica Sol-Gels: Traditional Routes to New Materials for Chemical Analysis
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Tailored Mesostructuring and Biofunctionalization of Gold for Increased Electroactivity
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Highly ordered mesoporous carbons as electrode material for the construction of electrochemical dehydrogenase- and oxidase-based biosensors
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Biosensing applications of clay-modified electrodes: a review
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Highly ordered mesoporous Cr2O3materials with enhanced performance for gas sensors and lithium ion batteries
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A High-Performance Supercapacitor/Battery Hybrid Incorporating Templated Mesoporous Electrodes
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Rate of Access to the Binding Sites in Organically Modified Silicates. 1. Amorphous Silica Gels Grafted with Amine or Thiol Groups
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Highly Organized Mesoporous TiO2 Films with Controlled Crystallinity: A Li‐Insertion Study
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Ordered Macroporous Bimetallic Nanostructures: Design, Characterization, and Applications
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Ruthenium Polypyridyl Sensitisers in Dye Solar Cells Based on Mesoporous TiO2
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Ordered Mesoporous α‐Fe 2 O 3 (Hematite) Thin‐Film Electrodes for Application in High Rate Rechargeable Lithium Batteries
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Complex Nanostructures from Materials based on Metal–Organic Frameworks for Electrochemical Energy Storage and Conversion
Guan, B. Y., Yu, X. Y., Wu, H. B., & Lou, X. W. (. (2017) · Advanced Materials · doi:10.1002/adma.201703614 · Cited by 733
Engineering Ordered and Nonordered Porous Noble Metal Nanostructures: Synthesis, Assembly, and Their Applications in Electrochemistry
Zhu, C., Du, D., Eychmüller, A., & Lin, Y. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00255 · Cited by 672
Designing 3D Highly Ordered Nanoporous CuO Electrodes for High-Performance Asymmetric Supercapacitors
Moosavifard, S. E., El-Kady, M. F., Rahmanifar, M. S., Kaner, R. B., & Mousavi, M. F. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/am508816t · Cited by 409
New insight into the synthesis of large-pore ordered mesoporous materials
Wei, J., Sun, Z., Luo, W., Li, Y., Elzatahry, A. A., Al-Enizi, A. M., Deng, Y., & Zhao, D. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11411 · Cited by 336
Hierarchically porous nickel–cobalt phosphide nanoneedle arrays loaded micro-carbon spheres as an advanced electrocatalyst for overall water splitting application
Hoa, V. H., Tran, D. T., Le, H. T., Kim, N. H., & Lee, J. H. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.04.017 · Cited by 124

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Authors: Walcarius, A.
Venue: Chemical Society Reviews
Publisher: Royal Society of Chemistry (RSC)
Published: 2013
Volume: 42
Issue: 9
Pages: 4098
ISSN: 0306-0012 (ISSN-L)
1460-4744
DOI: 10.1039/c2cs35322a
OpenAlex: W1968580777
Cited by: 623
References: 292
FWCI: 2.67
Type: journal article
Language: en
Open access: closed

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Mesoporous materials and electrochemistry

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