The surface chemistry of metal–organic frameworks

Functional Porous Coordination Polymers

Kitagawa, S., Kitaura, R., & Noro, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200300610 · Cited by 11,071

Selective gas adsorption and separation in metal–organic frameworks

Li, J.-R., Kuppler, R. J., & Zhou, H.-C. (2009) · Chemical Society Reviews · doi:10.1039/b802426j · Cited by 8,932

Metal-organic framework materials as catalysts

Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969

Introduction to Metal–Organic Frameworks

Zhou, H.-C., Long, J. R., & Yaghi, O. M. (2012) · Chemical Reviews · doi:10.1021/cr300014x · Cited by 7,720

Carbon Dioxide Capture in Metal–Organic Frameworks

Sumida, K., Rogow, D. L., Mason, J. A., McDonald, T. M., Bloch, E. D., Herm, Z. R., Bae, T.-H., & Long, J. R. (2012) · Chemical Reviews · doi:10.1021/cr2003272 · Cited by 6,408

Metal–Organic Frameworks for Separations

Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323

Hybrid porous solids: past, present, future

Férey, G. (2008) · Chem. Soc. Rev. · doi:10.1039/b618320b · Cited by 5,822

Hydrogen storage in metal–organic frameworks

Murray, L. J., Dincă, M., & Long, J. R. (2009) · Chemical Society Reviews · doi:10.1039/b802256a · Cited by 4,532

Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging

Horcajada, P., Chalati, T., Serre, C., Gillet, B., Sebrie, C., Baati, T., Eubank, J. F., Heurtaux, D., Clayette, P., Kreuz, C., et al. (2010) · Nature Materials · doi:10.1038/nmat2608 · Cited by 4,260

Metal–Organic Frameworks in Biomedicine

Horcajada, P., Gref, R., Baati, T., Allan, P. K., Maurin, G., Couvreur, P., Férey, G., Morris, R. E., & Serre, C. (2012) · Chemical Reviews · doi:10.1021/cr200256v · Cited by 4,168

Metal–Organic Frameworks (MOFs)

Zhou, H.-C. “., & Kitagawa, S. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs90059f · Cited by 4,125

Hydrogen Storage in Metal–Organic Frameworks

Suh, M. P., Park, H. J., Prasad, T. K., & Lim, D.-W. (2012) · Chemical Reviews · doi:10.1021/cr200274s · Cited by 3,689

Engineering Metal Organic Frameworks for Heterogeneous Catalysis

Corma, A., García, H., & Llabrés i Xamena, F. X. (2010) · Chemical Reviews · doi:10.1021/cr9003924 · Cited by 3,478

Enantioselective catalysis with homochiral metal–organic frameworks

Ma, L., Abney, C., & Lin, W. (2009) · Chemical Society Reviews · doi:10.1039/b807083k · Cited by 3,109

Applications of metal–organic frameworks in heterogeneous supramolecular catalysis

Liu, J., Chen, L., Cui, H., Zhang, J., Zhang, L., & Su, C.-Y. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00094c · Cited by 2,894

The pervasive chemistry of metal–organic frameworks

Long, J. R., & Yaghi, O. M. (2009) · Chemical Society Reviews · doi:10.1039/b903811f · Cited by 2,394

Gold Nanoparticles for Biology and Medicine

Giljohann, D. A., Seferos, D. S., Daniel, W. L., Massich, M. D., Patel, P. C., & Mirkin, C. A. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200904359 · Cited by 2,356

Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks

Cohen, S. M. (2012) · Chemical Reviews · doi:10.1021/cr200179u · Cited by 2,336

Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery

Della Rocca, J., Liu, D., & Lin, W. (2011) · Accounts of Chemical Research · doi:10.1021/ar200028a · Cited by 2,087

Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks

Li, J.-R., Ma, Y., McCarthy, M. C., Sculley, J., Yu, J., Jeong, H.-K., Balbuena, P. B., & Zhou, H.-C. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2011.02.012 · Cited by 2,019

Postsynthetic modification of metal–organic frameworks

Wang, Z., & Cohen, S. M. (2009) · Chemical Society Reviews · doi:10.1039/b802258p · Cited by 1,973

Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites

Bloch, E. D., Queen, W. L., Krishna, R., Zadrozny, J. M., Brown, C. M., & Long, J. R. (2012) · Science · doi:10.1126/science.1217544 · Cited by 1,928

Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks

Deng, H., Doonan, C. J., Furukawa, H., Ferreira, R. B., Towne, J., Knobler, C. B., Wang, B., & Yaghi, O. M. (2010) · Science · doi:10.1126/science.1181761 · Cited by 1,917

Metal–Organic Frameworks: Opportunities for Catalysis

Farrusseng, D., Aguado, S., & Pinel, C. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200806063 · Cited by 1,888

Modulated Synthesis of Zr‐Based Metal–Organic Frameworks: From Nano to Single Crystals

Schaate, A., Roy, P., Godt, A., Lippke, J., Waltz, F., Wiebcke, M., & Behrens, P. (2011) · Chemistry – A European Journal · doi:10.1002/chem.201003211 · Cited by 1,701

Gas Storage in Nanoporous Materials

Morris, R. E., & Wheatley, P. S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200703934 · Cited by 1,622

Postsynthetic Modifications of Iron-Carboxylate Nanoscale Metal−Organic Frameworks for Imaging and Drug Delivery

Taylor-Pashow, K. M. L., Della Rocca, J., Xie, Z., Tran, S., & Lin, W. (2009) · Journal of the American Chemical Society · doi:10.1021/ja906198y · Cited by 1,522

MOF-based electronic and opto-electronic devices

Stavila, V., Talin, A. A., & Allendorf, M. D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00096j · Cited by 1,330

Metal–Organic Framework Thin Films: From Fundamentals to Applications.

Bétard, A., & Fischer, R. A. (2012) · Chemical Reviews · doi:10.1021/cr200167v · Cited by 1,186

Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr)

Vermoortele, F., Bueken, B., Le Bars, G., Van de Voorde, B., Vandichel, M., Houthoofd, K., Vimont, A., Daturi, M., Waroquier, M., Van Speybroeck, V., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405078u · Cited by 1,110

Chemistry of coordination space of porous coordination polymers

Kitagawa, S., & Matsuda, R. (2007) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2007.07.009 · Cited by 978

Metal Organic Framework Catalysis: Quo vadis?

Gascon, J., Corma, A., Kapteijn, F., & Llabrés i Xamena, F. X. (2014) · ACS Catalysis · doi:10.1021/cs400959k · Cited by 960

Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering

Cravillon, J., Nayuk, R., Springer, S., Feldhoff, A., Huber, K., & Wiebcke, M. (2011) · Chemistry of Materials · doi:10.1021/cm103571y · Cited by 916

Step-by-Step Route for the Synthesis of Metal−Organic Frameworks

Shekhah, O., Wang, H., Kowarik, S., Schreiber, F., Paulus, M., Tolan, M., Sternemann, C., Evers, F., Zacher, D., Fischer, R. A., et al. (2007) · Journal of the American Chemical Society · doi:10.1021/ja076210u · Cited by 910

Thin films of metal–organic frameworks

Zacher, D., Shekhah, O., Wöll, C., & Fischer, R. A. (2009) · Chemical Society Reviews · doi:10.1039/b805038b · Cited by 893

Adsorptive separation on metal–organic frameworks in the liquid phase

Van de Voorde, B., Bueken, B., Denayer, J., & De Vos, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00006d · Cited by 874

Nanoscale Coordination Polymers for Platinum-Based Anticancer Drug Delivery

Rieter, W. J., Pott, K. M., Taylor, K. M. L., & Lin, W. (2008) · Journal of the American Chemical Society · doi:10.1021/ja803383k · Cited by 803

Metal–Organic Frameworks from Edible Natural Products

Smaldone, R. A., Forgan, R. S., Furukawa, H., Gassensmith, J. J., Slawin, A. M. Z., Yaghi, O. M., & Stoddart, J. F. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201002343 · Cited by 781

Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth

Tsuruoka, T., Furukawa, S., Takashima, Y., Yoshida, K., Isoda, S., & Kitagawa, S. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200901177 · Cited by 708

Manganese-Based Nanoscale Metal−Organic Frameworks for Magnetic Resonance Imaging

Taylor, K. M. L., Rieter, W. J., & Lin, W. (2008) · Journal of the American Chemical Society · doi:10.1021/ja803777x · Cited by 657

Mechanized Silica Nanoparticles: A New Frontier in Theranostic Nanomedicine

Ambrogio, M. W., Thomas, C. R., Zhao, Y.-L., Zink, J. I., & Stoddart, J. F. (2011) · Accounts of Chemical Research · doi:10.1021/ar200018x · Cited by 604

Metal–organic framework growth at functional interfaces: thin films and composites for diverse applications

Bradshaw, D., Garai, A., & Huo, J. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15276a · Cited by 599

Surface Modification and Functionalization of Nanoscale Metal-Organic Frameworks for Controlled Release and Luminescence Sensing

Rieter, W. J., Taylor, K. M. L., & Lin, W. (2007) · Journal of the American Chemical Society · doi:10.1021/ja073506r · Cited by 588

Shape-Memory Nanopores Induced in Coordination Frameworks by Crystal Downsizing

Sakata, Y., Furukawa, S., Kondo, M., Hirai, K., Horike, N., Takashima, Y., Uehara, H., Louvain, N., Meilikhov, M., Tsuruoka, T., et al. (2013) · Science · doi:10.1126/science.1231451 · Cited by 581

Controlled Multiscale Synthesis of Porous Coordination Polymer in Nano/Micro Regimes

Diring, S., Furukawa, S., Takashima, Y., Tsuruoka, T., & Kitagawa, S. (2010) · Chemistry of Materials · doi:10.1021/cm101778g · Cited by 527

Nucleic Acid–Metal Organic Framework (MOF) Nanoparticle Conjugates

Morris, W., Briley, W. E., Auyeung, E., Cabezas, M. D., & Mirkin, C. A. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503215w · Cited by 478

Morphology Design of Porous Coordination Polymer Crystals by Coordination Modulation

Umemura, A., Diring, S., Furukawa, S., Uehara, H., Tsuruoka, T., & Kitagawa, S. (2011) · Journal of the American Chemical Society · doi:10.1021/ja204233q · Cited by 465

Selective adsorption of ethylene over ethane and propylene over propane in the metal–organic frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn)

Geier, S. J., Mason, J. A., Bloch, E. D., Queen, W. L., Hudson, M. R., Brown, C. M., & Long, J. R. (2013) · Chemical Science · doi:10.1039/c3sc00032j · Cited by 443

Solvent‐Assisted Linker Exchange: An Alternative to the De Novo Synthesis of Unattainable Metal–Organic Frameworks

Karagiaridi, O., Bury, W., Mondloch, J. E., Hupp, J. T., & Farha, O. K. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201306923 · Cited by 427

Metal–biomolecule frameworks (MBioFs)

Imaz, I., Rubio-Martínez, M., An, J., Solé-Font, I., Rosi, N. L., & Maspoch, D. (2011) · Chemical Communications · doi:10.1039/c1cc11202c · Cited by 426

Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework

Gassensmith, J. J., Furukawa, H., Smaldone, R. A., Forgan, R. S., Botros, Y. Y., Yaghi, O. M., & Stoddart, J. F. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206525x · Cited by 392

Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach

Tanabe, K. K., Wang, Z., & Cohen, S. M. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801848j · Cited by 386

Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications

Burrows, A. D. (2011) · CrystEngComm · doi:10.1039/c0ce00568a · Cited by 374

Formate modulated solvothermal synthesis of ZIF-8 investigated using time-resolved in situ X-ray diffraction and scanning electron microscopy

Cravillon, J., Schröder, C. A., Bux, H., Rothkirch, A., Caro, J., & Wiebcke, M. (2012) · CrystEngComm · doi:10.1039/c1ce06002c · Cited by 368

Urea Metal–Organic Frameworks as Effective and Size-Selective Hydrogen-Bond Catalysts

Roberts, J. M., Fini, B. M., Sarjeant, A. A., Farha, O. K., Hupp, J. T., & Scheidt, K. A. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2108118 · Cited by 325

Surface Chemistry of Metal–Organic Frameworks at the Liquid–Solid Interface

Zacher, D., Schmid, R., Wöll, C., & Fischer, R. A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201002451 · Cited by 318

Trapping Metal-Organic Framework Nanocrystals: An in-Situ Time-Resolved Light Scattering Study on the Crystal Growth of MOF-5 in Solution

Hermes, S., Witte, T., Hikov, T., Zacher, D., Bahnmüller, S., Langstein, G., Huber, K., & Fischer, R. A. (2007) · Journal of the American Chemical Society · doi:10.1021/ja068835i · Cited by 303

Improvement of hydrothermal stability of zeolitic imidazolate frameworks

Liu, X., Li, Y., Ban, Y., Peng, Y., Jin, H., Bux, H., Xu, L., Caro, J., & Yang, W. (2013) · Chemical Communications · doi:10.1039/c3cc45308a · Cited by 295

“Clickable” Metal−Organic Framework

Goto, Y., Sato, H., Shinkai, S., & Sada, K. (2008) · Journal of the American Chemical Society · doi:10.1021/ja7114053 · Cited by 287

Polymer-Modified Gadolinium Metal-Organic Framework Nanoparticles Used as Multifunctional Nanomedicines for the Targeted Imaging and Treatment of Cancer

Rowe, M. D., Thamm, D. H., Kraft, S. L., & Boyes, S. G. (2009) · Biomacromolecules · doi:10.1021/bm900043e · Cited by 286

Combining Coordination Modulation with Acid–Base Adjustment for the Control over Size of Metal–Organic Frameworks

Guo, H., Zhu, Y., Wang, S., Su, S., Zhou, L., & Zhang, H. (2012) · Chemistry of Materials · doi:10.1021/cm202593h · Cited by 286

Bio-functionalization of metal–organic frameworks by covalent protein conjugation

Jung, S., Kim, Y., Kim, S.-J., Kwon, T.-H., Huh, S., & Park, S. (2011) · Chemical Communications · doi:10.1039/c0cc03288c · Cited by 255

Phosphorescent Nanoscale Coordination Polymers as Contrast Agents for Optical Imaging

Liu, D., Huxford, R. C., & Lin, W. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201008277 · Cited by 254

Introduction of Functionalized Mesopores to Metal–Organic Frameworks via Metal–Ligand–Fragment Coassembly

Park, J., Wang, Z. U., Sun, L.-B., Chen, Y.-P., & Zhou, H.-C. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3085884 · Cited by 246

Metal–Organic Framework@Microporous Organic Network: Hydrophobic Adsorbents with a Crystalline Inner Porosity

Chun, J., Kang, S., Park, N., Park, E. J., Jin, X., Kim, K.-D., Seo, H. O., Lee, S. M., Kim, H. J., Kwon, W. H., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500362w · Cited by 232

Substitution reactions in metal–organic frameworks and metal–organic polyhedra

Han, Y., Li, J.-R., Xie, Y., & Guo, G. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00033a · Cited by 221

Kinetics and mechanism of metal–organic framework thin film growth: systematic investigation of HKUST-1 deposition on QCM electrodes

Stavila, V., Volponi, J., Katzenmeyer, A. M., Dixon, M. C., & Allendorf, M. D. (2012) · Chemical Science · doi:10.1039/c2sc20065a · Cited by 195

Electric Field-Induced Assembly of Monodisperse Polyhedral Metal–Organic Framework Crystals

Yanai, N., Sindoro, M., Yan, J., & Granick, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja309361d · Cited by 188

Armored MOFs: Enforcing Soft Microporous MOF Nanocrystals with Hard Mesoporous Silica

Li, Z., & Zeng, H. C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja409675j · Cited by 184

The controlled regulation of morphology and size of HKUST-1 by “coordination modulation method”

Wang, F., Guo, H., Chai, Y., Li, Y., & Liu, C. (2013) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2013.02.023 · Cited by 180

Lipid-coated nanoscale coordination polymers for targeted delivery of antifolates to cancer cells

Huxford, R. C., deKrafft, K. E., Boyle, W. S., Liu, D., & Lin, W. (2012) · Chem. Sci. · doi:10.1039/c1sc00499a · Cited by 177

Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO2 over N2

蒋冬梅, Burrows, A. D., & Edler, K. J. (2011) · CrystEngComm · doi:10.1039/c1ce06274c · Cited by 161

Covalent surface modification of a metal–organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition

Gadzikwa, T., Lu, G., Stern, C. L., Wilson, S. R., Hupp, J. T., & Nguyen, S. T. (2008) · Chemical Communications · doi:10.1039/b805101a · Cited by 161

Rational Synthesis of Metal–Organic Framework Nanocubes and Nanosheets Using Selective Modulators and Their Morphology-Dependent Gas-Sorption Properties

Pham, M.-H., Vuong, G.-T., Fontaine, F.-G., & Do, T.-O. (2012) · Crystal Growth & Design · doi:10.1021/cg300297p · Cited by 161

Coordinatively Immobilized Monolayers on Porous Coordination Polymer Crystals

Kondo, M., Furukawa, S., Hirai, K., & Kitagawa, S. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201001063 · Cited by 148

Directional Self‐Assembly of a Colloidal Metal–Organic Framework

Yanai, N., & Granick, S. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201109132 · Cited by 143

Heteroepitaxial Growth of Isoreticular Metal−Organic Frameworks and Their Hybrid Films

Yoo, Y., & Jeong, H. (2010) · Crystal Growth & Design · doi:10.1021/cg9013027 · Cited by 118

A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal–organic framework UiO-67

Siu, P. W., Brown, Z. J., Farha, O. K., Hupp, J. T., & Scheidt, K. A. (2013) · Chemical Communications · doi:10.1039/c3cc47177b · Cited by 104

Tuning the aspect ratio of NH 2 -MIL-53(Al) microneedles and nanorodsvia coordination modulation

Chin, J. M., Chen, E. Y., Menon, A. G., Tan, H. Y., Hor, T. S. A., Schreyer, M. K., & Xu, J. (2012) · CrystEngComm · doi:10.1039/c2ce26586a · Cited by 95

Multi Variant Surface Mounted Metal–Organic Frameworks

Liu, B., Tu, M., Zacher, D., & Fischer, R. A. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201202996 · Cited by 70

Programmed functionalization of SURMOFs via liquid phase heteroepitaxial growth and post-synthetic modification

Tu, M., Wannapaiboon, S., & Fischer, R. A. (2013) · Dalton Transactions · doi:10.1039/c3dt51457a · Cited by 52

MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration

Szilágyi, P. Á., Lutz, M., Gascón, J., Juan‐Alcañiz, J., van Esch, J. H., Kapteijn, F., Geerlings, H., Dam, B., & van de Krol, R. (2013) · CrystEngComm · doi:10.1039/c3ce40653a · Cited by 47

Size-controlled indium(iii)–benzenedicarboxylate hexagonal rods and their transformation to In2O3 hollow structures

Jin, L., Liu, Q., & Sun, W. (2013) · CrystEngComm · doi:10.1039/c3ce40113h · Cited by 44

Metal–organic frameworks for membrane-based separations

Denny, M. S., Moreton, J. C., Benz, L., & Cohen, S. M. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.78 · Cited by 820

Application of zirconium MOFs in drug delivery and biomedicine

Abánades Lázaro, I., & Forgan, R. S. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.09.009 · Cited by 678

Mesopore‐Rich Fe–N–C Catalyst with FeN4–O–NC Single‐Atom Sites Delivers Remarkable Oxygen Reduction Reaction Performance in Alkaline Media

Peng, L., Yang, J., Yang, Y., Qian, F., Wang, Q., Sun‐Waterhouse, D., Shang, L., Zhang, T., & Waterhouse, G. I. N. (2022) · Advanced Materials · doi:10.1002/adma.202202544 · Cited by 478

Positioning metal-organic framework nanoparticles within the context of drug delivery – A comparison with mesoporous silica nanoparticles and dendrimers

Wuttke, S., Lismont, M., Escudero, A., Rungtaweevoranit, B., & Parak, W. J. (2017) · Biomaterials · doi:10.1016/j.biomaterials.2017.01.025 · Cited by 286