Recent advances in nanostructured transition metal phosphides: synthesis and energy-related applications

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Heterogeneous photocatalyst materials for water splitting

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Powering the planet: Chemical challenges in solar energy utilization

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Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction

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Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces

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Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts

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Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction

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Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0–14

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Review on recent progress of nanostructured anode materials for Li-ion batteries

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Ni2P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni2P nanoparticles

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Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction

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Catalysts for Hydrogen Evolution from the [NiFe] Hydrogenase to the Ni 2 P(001) Surface: The Importance of Ensemble Effect

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Aprotic and Aqueous Li–O2 Batteries

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Nanoscaled Metal Borides and Phosphides: Recent Developments and Perspectives

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Molybdenum Phosphosulfide: An Active, Acid‐Stable, Earth‐Abundant Catalyst for the Hydrogen Evolution Reaction

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On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper

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Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends

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A Cost‐Effective 3D Hydrogen Evolution Cathode with High Catalytic Activity: FeP Nanowire Array as the Active Phase

Jiang, P., Liu, Q., Liang, Y., Tian, J., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201406848 · Cited by 885

The Synthesis of Nanostructured Ni5P4 Films and their Use as a Non‐Noble Bifunctional Electrocatalyst for Full Water Splitting

Ledendecker, M., Krick Calderón, S., Papp, C., Steinrück, H., Antonietti, M., & Shalom, M. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502438 · Cited by 858

Self‐Supported Cu3P Nanowire Arrays as an Integrated High‐Performance Three‐Dimensional Cathode for Generating Hydrogen from Water

Tian, J., Liu, Q., Cheng, N., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403842 · Cited by 848

Electrodeposited Cobalt‐Phosphorous‐Derived Films as Competent Bifunctional Catalysts for Overall Water Splitting

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Closely Interconnected Network of Molybdenum Phosphide Nanoparticles: A Highly Efficient Electrocatalyst for Generating Hydrogen from Water

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Transition metal phosphide hydroprocessing catalysts: A review

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Highly Active and Stable Catalysts of Phytic Acid-Derivative Transition Metal Phosphides for Full Water Splitting

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Bifunctional Nickel Phosphide Nanocatalysts Supported on Carbon Fiber Paper for Highly Efficient and Stable Overall Water Splitting

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Synthesis, Characterization, and Properties of Metal Phosphide Catalysts for the Hydrogen-Evolution Reaction

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Monodispersed nickel phosphide nanocrystals with different phases: synthesis, characterization and electrocatalytic properties for hydrogen evolution

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Simultaneous H2 Generation and Biomass Upgrading in Water by an Efficient Noble‐Metal‐Free Bifunctional Electrocatalyst

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The Synthesis of Nanostructured Ni5P4 Films and their Use as a Non‐Noble Bifunctional Electrocatalyst for Full Water Splitting

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Monodisperse Nanoparticles of Ni and NiO: Synthesis, Characterization, Self‐Assembled Superlattices, and Catalytic Applications in the Suzuki Coupling Reaction

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Extraordinarily efficient photocatalytic hydrogen evolution in water using semiconductor nanorods integrated with crystalline Ni2P cocatalysts

Sun, Z., Zheng, H., Li, J., & Du, P. (2015) · Energy & Environmental Science · doi:10.1039/c5ee01310k · Cited by 571

Hydrodeoxygenation of guaiacol as model compound for pyrolysis oil on transition metal phosphide hydroprocessing catalysts

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Tailoring deposition and morphology of discharge products towards high-rate and long-life lithium-oxygen batteries

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One‐Step Synthesis of Self‐Supported Nickel Phosphide Nanosheet Array Cathodes for Efficient Electrocatalytic Hydrogen Generation

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Efficient Water Oxidation Using CoMnP Nanoparticles

Li, D., Baydoun, H., Verani, C. N., & Brock, S. L. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01543 · Cited by 523

Physicochemical Evaluation of the Hot‐Injection Method, a Synthesis Route for Monodisperse Nanocrystals

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Nanostructured Co2P Electrocatalyst for the Hydrogen Evolution Reaction and Direct Comparison with Morphologically Equivalent CoP

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Nanocrystalline Ni5P4: a hydrogen evolution electrocatalyst of exceptional efficiency in both alkaline and acidic media

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Anion-exchange synthesis of nanoporous FeP nanosheets as electrocatalysts for hydrogen evolution reaction

Xu, Y., Wu, R., Zhang, J., Shi, Y., & Zhang, B. (2013) · Chemical Communications · doi:10.1039/c3cc43107j · Cited by 465

Surface Chemistry in Cobalt Phosphide-Stabilized Lithium–Sulfur Batteries

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Metal-organic frameworks derived porous core/shellCoP@C polyhedrons anchored on 3D reduced graphene oxide networks as anode for sodium-ion battery

Ge, X., Li, Z., & Yin, L. (2017) · Nano Energy · doi:10.1016/j.nanoen.2016.11.055 · Cited by 457

In Situ Transformation of Hydrogen-Evolving CoP Nanoparticles: Toward Efficient Oxygen Evolution Catalysts Bearing Dispersed Morphologies with Co-oxo/hydroxo Molecular Units

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Ni12P5 Nanoparticles as an Efficient Catalyst for Hydrogen Generation via Electrolysis and Photoelectrolysis

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Ultrahigh‐Performance Pseudocapacitor Electrodes Based on Transition Metal Phosphide Nanosheets Array via Phosphorization: A General and Effective Approach

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Converting Metals into Phosphides: A General Strategy for the Synthesis of Metal Phosphide Nanocrystals

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Uncovering the Nature of Active Species of Nickel Phosphide Catalysts in High-Performance Electrochemical Overall Water Splitting

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Self-Supported FeP Nanorod Arrays: A Cost-Effective 3D Hydrogen Evolution Cathode with High Catalytic Activity

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Evaluating the Stability of Co2P Electrocatalysts in the Hydrogen Evolution Reaction for Both Acidic and Alkaline Electrolytes

Zhang, Y., Gao, L., Hensen, E. J. M., & Hofmann, J. P. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00514 · Cited by 416

Recent advances in understanding of the mechanism and control of Li2O2formation in aprotic Li–O2batteries

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Easily-prepared dinickel phosphide (Ni2P) nanoparticles as an efficient and robust electrocatalyst for hydrogen evolution

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Highly Selective and Sharp Volcano-type Synergistic Ni2Pt@ZIF-8-Catalyzed Hydrogen Evolution from Ammonia Borane Hydrolysis

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NiP2nanosheet arrays supported on carbon cloth: an efficient 3D hydrogen evolution cathode in both acidic and alkaline solutions

Jiang, P., Liu, Q., & Sun, X. (2014) · Nanoscale · doi:10.1039/c4nr04866k · Cited by 400

Low temperature synthesis of ternary metal phosphides using plasma for asymmetric supercapacitors

Liang, H., Xia, C., Jiang, Q., Gandi, A. N., Schwingenschlögl, U., & Alshareef, H. N. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.04.007 · Cited by 368

Energy in World History

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Rational Design of Three-Dimensional Graphene Encapsulated with Hollow FeP@Carbon Nanocomposite as Outstanding Anode Material for Lithium Ion and Sodium Ion Batteries

Wang, X., Chen, K., Wang, G., Liu, X., & Wang, H. (2017) · ACS Nano · doi:10.1021/acsnano.7b06625 · Cited by 359

Core-shell structured CoP/FeP porous microcubes interconnected by reduced graphene oxide as high performance anodes for sodium ion batteries

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Anion and cation substitution in transition-metal oxides nanosheets for high-performance hybrid supercapacitors

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The oxygen evolution reaction enabled by transition metal phosphide and chalcogenide pre-catalysts with dynamic changes

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Fe–P: A New Class of Electroactive Catalyst for Oxygen Reduction Reaction

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Generalized Synthesis of Metal Phosphide Nanorods via Thermal Decomposition of Continuously Delivered Metal−Phosphine Complexes Using a Syringe Pump

Park, J., Koo, B., Yoon, K. Y., Hwang, Y., Kang, M., Park, J.-G., & Hyeon, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0427496 · Cited by 307

Desulfurization Reactions on Ni2P(001) and α-Mo2C(001) Surfaces: Complex Role of P and C Sites

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Regulating the polysulfide redox conversion by iron phosphide nanocrystals for high-rate and ultrastable lithium-sulfur battery

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Efficient Activation of Li2S by Transition Metal Phosphides Nanoparticles for Highly Stable Lithium–Sulfur Batteries

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CoP Nanosheet Arrays Supported on a Ti Plate: An Efficient Cathode for Electrochemical Hydrogen Evolution

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Boosting Visible‐Light‐Driven Photocatalytic Hydrogen Evolution with an Integrated Nickel Phosphide–Carbon Nitride System

Indra, A., Acharjya, A., Menezes, P. W., Merschjann, C., Hollmann, D., Schwarze, M., Aktas, M., Friedrich, A., Lochbrunner, S., Thomas, A., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201611605 · Cited by 293

High-Performance Flexible Solid-State Asymmetric Supercapacitors Based on Bimetallic Transition Metal Phosphide Nanocrystals

Zhang, N., Li, Y., Xu, J., Li, J., Wei, B., Ding, Y., Amorim, I., Thomas, R., Thalluri, S. M., Liu, Y., et al. (2019) · ACS Nano · doi:10.1021/acsnano.9b04810 · Cited by 292

Tungsten Phosphide Nanorod Arrays Directly Grown on Carbon Cloth: A Highly Efficient and Stable Hydrogen Evolution Cathode at All pH Values

Pu, Z., Liu, Q., Asiri, A. M., & Sun, X. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am5060178 · Cited by 290

Engineering of Carbon‐Based Electrocatalysts for Emerging Energy Conversion: From Fundamentality to Functionality

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Sub-1.1 nm ultrathin porous CoP nanosheets with dominant reactive {200} facets: a high mass activity and efficient electrocatalyst for the hydrogen evolution reaction

Zhang, C., Huang, Y., Yu, Y., Zhang, J., Zhuo, S., & Zhang, B. (2017) · Chemical Science · doi:10.1039/c6sc05687c · Cited by 273

Mechanistic Understanding of Metal Phosphide Host for Sulfur Cathode in High-Energy-Density Lithium–Sulfur Batteries

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Ternary Ni–Co–P nanoparticles as noble-metal-free catalysts to boost the hydrolytic dehydrogenation of ammonia-borane

Hou, C.-C., Li, Q., Wang, C.-J., Peng, C.-Y., Chen, Q.-Q., Ye, H.-F., Fu, W.-F., Che, C.-M., López, N., & Chen, Y. (2017) · Energy & Environmental Science · doi:10.1039/c7ee01553d · Cited by 267

X-ray Photoelectron and Absorption Spectroscopy of Metal-Rich Phosphides M2P and M3P (M = Cr−Ni)

Blanchard, P. E. R., Grosvenor, A. P., Cavell, R. G., & Mar, A. (2008) · Chemistry of Materials · doi:10.1021/cm802123a · Cited by 261

A Flexible Electrode Based on Iron Phosphide Nanotubes for Overall Water Splitting

Yan, Y., Xia, B. Y., Ge, X., Liu, Z., Fisher, A., & Wang, X. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201503777 · Cited by 260

Integrating Hydrogen Production with Aqueous Selective Semi‐Dehydrogenation of Tetrahydroisoquinolines over a Ni2P Bifunctional Electrode

Huang, C., Huang, Y., Liu, C., Yu, Y., & Zhang, B. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201903327 · Cited by 260

Deoxygenation of methyl laurate as a model compound to hydrocarbons on transition metal phosphide catalysts

Chen, J., Shi, H., Li, L., & Li, K. (2014) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2013.08.026 · Cited by 259

Co–Fe Mixed Metal Phosphide Nanocubes with Highly Interconnected-Pore Architecture as an Efficient Polysulfide Mediator for Lithium–Sulfur Batteries

Chen, Y., Zhang, W., Zhou, D., Tian, H., Su, D., Wang, C., Stockdale, D., Kang, F., Li, B., & Wang, G. (2019) · ACS Nano · doi:10.1021/acsnano.9b01079 · Cited by 257

Solution-Phase Synthesis of Single-Crystalline Iron Phosphide Nanorods/Nanowires

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Studies of the synthesis of transition metal phosphides and their activity in the hydrodeoxygenation of a biofuel model compound

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Electrochemical Reactivity and Design of NiP2 Negative Electrodes for Secondary Li-Ion Batteries

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High-Efficiency Electrochemical Hydrogen Evolution Catalyzed by Tungsten Phosphide Submicroparticles

Xing, Z., Liu, Q., Asiri, A. M., & Sun, X. (2015) · ACS Catalysis · doi:10.1021/cs5014943 · Cited by 238

MoP is a novel, noble-metal-free cocatalyst for enhanced photocatalytic hydrogen production from water under visible light

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MoP Nanoparticles Supported on Indium‐Doped Porous Carbon: Outstanding Catalysts for Highly Efficient CO2 Electroreduction

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Dispersed Nickel Cobalt Oxyphosphide Nanoparticles Confined in Multichannel Hollow Carbon Fibers for Photocatalytic CO2 Reduction

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Nanostructured Ni2P as a Robust Catalyst for the Hydrolytic Dehydrogenation of Ammonia–Borane

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Phytic acid-derivative transition metal phosphides encapsulated in N,P-codoped carbon: an efficient and durable hydrogen evolution electrocatalyst in a wide pH range

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Cobalt Phosphide Nanowires: Efficient Nanostructures for Fluorescence Sensing of Biomolecules and Photocatalytic Evolution of Dihydrogen from Water under Visible Light

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Trioctylphosphine: A General Phosphorus Source for the Low-Temperature Conversion of Metals into Metal Phosphides

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Surface reconstruction of cobalt phosphide nanosheets by electrochemical activation for enhanced hydrogen evolution in alkaline solution

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Phytic Acid-Assisted Formation of Hierarchical Porous CoP/C Nanoboxes for Enhanced Lithium Storage and Hydrogen Generation

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Selective Transfer Semihydrogenation of Alkynes with H2O (D2O) as the H (D) Source over a Pd‐P Cathode

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A Cobalt‐Based Amorphous Bifunctional Electrocatalysts for Water‐Splitting Evolved from a Single‐Source Lazulite Cobalt Phosphate

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Efficient Water Splitting Catalyzed by Cobalt Phosphide‐Based Nanoneedle Arrays Supported on Carbon Cloth

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Synthesis and characterization of silica-supported transition-metal phosphides as HDN catalysts

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Vapor–solid synthesis of monolithic single-crystalline CoP nanowire electrodes for efficient and robust water electrolysis

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Cobalt Phosphide Modified Titanium Oxide Nanophotocatalysts with Significantly Enhanced Photocatalytic Hydrogen Evolution from Water Splitting

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A Hierarchical MoP Nanoflake Array Supported on Ni Foam: A Bifunctional Electrocatalyst for Overall Water Splitting

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Operando Spectroscopic Analysis of CoP Films Electrocatalyzing the Hydrogen-Evolution Reaction

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Dibenzothiophene hydrodesulfurization activity and surface sites of silica-supported MoP, Ni2P, and NiMoP catalysts

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Integrating cobalt phosphide and cobalt nitride-embedded nitrogen-rich nanocarbons: high-performance bifunctional electrocatalysts for oxygen reduction and evolution

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Potential-tuned selective electrosynthesis of azoxy-, azo- and amino-aromatics over a CoP nanosheet cathode

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Integrating Hydrogen Production with Aqueous Selective Semi‐Dehydrogenation of Tetrahydroisoquinolines over a Ni2P Bifunctional Electrode

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Engineering Cobalt Phosphide (CoP) Thin Film Catalysts for Enhanced Hydrogen Evolution Activity on Silicon Photocathodes

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Phosphorus and phosphide nanomaterials for sodium-ion batteries

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Honeycomb-Like Interconnected Network of Nickel Phosphide Heteronanoparticles with Superior Electrochemical Performance for Supercapacitors

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Evaluation of transition metal phosphides supported on ordered mesoporous materials as catalysts for phenol hydrodeoxygenation

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High-performance Li–S battery cathode with catalyst-like carbon nanotube-MoP promoting polysulfide redox

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Synthesis and Characterization of Discrete Nickel Phosphide Nanoparticles: Effect of Surface Ligation Chemistry on Catalytic Hydrodesulfurization of Thiophene

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Metal–organic framework-derived nickel phosphides as efficient electrocatalysts toward sustainable hydrogen generation from water splitting

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Topochemical Synthesis of Two‐Dimensional Transition‐Metal Phosphides Using Phosphorene Templates

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Robustly photogenerating H2 in water using FeP/CdS catalyst under solar irradiation

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Highly Defective Fe-Based Oxyhydroxides from Electrochemical Reconstruction for Efficient Oxygen Evolution Catalysis

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Unique Fe2P Nanoparticles Enveloped in Sandwichlike Graphited Carbon Sheets as Excellent Hydrogen Evolution Reaction Catalyst and Lithium-Ion Battery Anode

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Synthesis of MnP Nanocrystals by Treatment of Metal Carbonyl Complexes with Phosphines: A New, Versatile Route to Nanoscale Transition Metal Phosphides

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Graphene and cobalt phosphide nanowire composite as an anode material for high performance lithium-ion batteries

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A robust and efficient catalyst of Cd x Zn 1−x Se motivated by CoP for photocatalytic hydrogen evolution under sunlight irradiation

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Mechanistic Insights into Surface Chemical Interactions between Lithium Polysulfides and Transition Metal Oxides

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Deoxygenation of Palmitic Acid on Unsupported Transition-Metal Phosphides

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Stability and electronic structure of the Co–P compounds from first-principle calculations

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Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel

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Synthesis of FeP 2 /C nanohybrids and their performance for hydrogen evolution reaction

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CoP nanoarray: a robust non-noble-metal hydrogen-generating catalyst toward effective hydrolysis of ammonia borane

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Cobalt phosphide nanoparticles film growth on carbon cloth: A high-performance cathode for electrochemical hydrogen evolution

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Ruthenium-Catalyzed Ammonia Borane Dehydrogenation: Mechanism and Utility

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Triphenyl Phosphite as the Phosphorus Source for the Scalable and Cost-Effective Production of Transition Metal Phosphides

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Metal-Dependent Interplay between Crystallization and Phosphorus Diffusion during the Synthesis of Metal Phosphide Nanoparticles

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Phosphorus-Rich Copper Phosphide Nanowires for Field-Effect Transistors and Lithium-Ion Batteries

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Fabrication of Metallic Nickel–Cobalt Phosphide Hollow Microspheres for High-Rate Supercapacitors

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Programmable Synthesis of Multimetallic Phosphide Nanorods Mediated by Core/Shell Structure Formation and Conversion

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Highly efficient hydrolysis of ammonia borane by anion (-OH, F-, Cl-)-tuned interactions between reactant molecules and CoP nanoparticles.

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The Predominance of Hydrogen Evolution on Transition Metal Sulfides and Phosphides under CO2 Reduction Conditions: An Experimental and Theoretical Study

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Aminophosphines as Versatile Precursors for the Synthesis of Metal Phosphide Nanocrystals

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Tungsten diphosphide nanorods as an efficient catalyst for electrochemical hydrogen evolution

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A Facile Molecular Precursor Route to Metal Phosphide Nanoparticles and Their Evaluation as Hydrodeoxygenation Catalysts

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A 3D free-standing thin film based on N, P-codoped hollow carbon fibers embedded with MoP quantum dots as high efficient oxygen electrode for Li-O2 batteries

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Low-Temperature Solvothermal Synthesis of Phosphorus-Rich Transition-Metal Phosphides

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Boosted Reactivity of Ammonia Borane Dehydrogenation over Ni/Ni2P Heterostructure

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Highly Efficient Photocatalytic System Constructed from CoP/Carbon Nanotubes or Graphene for Visible‐Light‐Driven CO2 Reduction

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High-Surface-Area and Porous Co2P Nanosheets as Cost-Effective Cathode Catalysts for Li–O2 Batteries

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Phosphorus vacancies enriched Ni2P nanosheets as efficient electrocatalyst for high-performance Li–O2 batteries

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The synthesis and investigation of ruthenium phosphide catalysts

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Hydrodenitrogenation of Quinoline Catalyzed by MCM-41-Supported Nickel Phosphides

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Hydrodeoxygenation of gamma-valerolactone on transition metal phosphide catalysts

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General Method for Synthesis Transition‐Metal Phosphide/Nitrogen and Phosphide Doped Carbon Materials with Yolk‐Shell Structure for Oxygen Reduction Reaction

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Metal phosphide modified CdxZn1−xS solid solutions as a highly active visible-light photocatalyst for hydrogen evolution

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Cubic Co-Co prussian blue MOF-based transition metal phosphide as an efficient catalyst for visible light-driven water oxidation

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MoP Nanoflakes as Efficient Electrocatalysts for Rechargeable Li–O2 Batteries

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Planar penta-transition metal phosphide and arsenide as narrow-gap semiconductors with ultrahigh carrier mobility

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CoO x (OH) y /C nanocomposites in situ derived from Na 4 Co 3 (PO 4 ) 2 P 2 O 7 as sustainable electrocatalysts for water splitting

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DFT Study on the Mechanism of the Water Gas Shift Reaction Over NixPyCatalysts: The Role of P

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An Exceptionally Efficient Co−Co2P@N, P‐Codoped Carbon Hybrid Catalyst for Visible Light‐Driven CO2‐to‐CO Conversion

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Low-Cost Nickel Phosphide as an Efficient Bifunctional Cathode Catalyst for Li-O2 Batteries

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Rational Design of Transition Metal Phosphide‐Based Electrocatalysts for Hydrogen Evolution

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Noble Metal Phosphides: Robust Electrocatalysts toward Hydrogen Evolution Reaction

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