Strategies to suppress hydrogen evolution for highly selective electrocatalytic nitrogen reduction: challenges and perspectives

Combining theory and experiment in electrocatalysis: Insights into materials design

Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114

How a century of ammonia synthesis changed the world

Erisman, J. W., Sutton, M. A., Galloway, J., Klimont, Z., & Winiwarter, W. (2008) · Nature Geoscience · doi:10.1038/ngeo325 · Cited by 4,607

“Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries

Suo, L., Borodin, O., Gao, T., Olguin, M., Ho, J., Fan, X., Luo, C., Wang, C., & Xu, K. (2015) · Science · doi:10.1126/science.aab1595 · Cited by 3,821

Beyond fossil fuel–driven nitrogen transformations

Chen, J. G., Crooks, R. M., Seefeldt, L. C., Bren, K. L., Bullock, R. M., Darensbourg, M. Y., Holland, P. L., Hoffman, B., Janik, M. J., Jones, A. K., et al. (2018) · Science · doi:10.1126/science.aar6611 · Cited by 2,441

Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity

van Deelen, T. W., Hernández Mejía, C., & de Jong, K. P. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0364-x · Cited by 2,349

A roadmap to the ammonia economy

MacFarlane, D. R., Cherepanov, P. V., Choi, J., Suryanto, B. H. R., Hodgetts, R. Y., Bakker, J. M., Ferrero Vallana, F. M., & Simonov, A. N. (2020) · Joule · doi:10.1016/j.joule.2020.04.004 · Cited by 1,926

Efficient Visible Light Nitrogen Fixation with BiOBr Nanosheets of Oxygen Vacancies on the Exposed {001} Facets

Li, H., Shang, J., Ai, Z., & Zhang, L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03105 · Cited by 1,778

Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia

Suryanto, B. H. R., Du, H.-L., Wang, D., Chen, J., Simonov, A. N., & MacFarlane, D. R. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0252-4 · Cited by 1,654

Catalysts for nitrogen reduction to ammonia

Foster, S. L., Bakovic, S. I. P., Duda, R. D., Maheshwari, S., Milton, R. D., Minteer, S. D., Janik, M. J., Renner, J. N., & Greenlee, L. F. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0092-7 · Cited by 1,633

A theoretical evaluation of possible transition metal electro-catalysts for N2reduction

Skúlason, E., Bligaard, T., Gudmundsdóttir, S., Studt, F., Rossmeisl, J., Abild-Pedersen, F., Vegge, T., Jónsson, H., & Nørskov, J. K. (2012) · Phys. Chem. Chem. Phys. · doi:10.1039/c1cp22271f · Cited by 1,609

Challenges in reduction of dinitrogen by proton and electron transfer

van der Ham, C. J. M., Koper, M. T. M., & Hetterscheid, D. G. H. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00085d · Cited by 1,583

A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements

Andersen, S. Z., Čolić, V., Yang, S., Schwalbe, J. A., Nielander, A. C., McEnaney, J. M., Enemark-Rasmussen, K., Baker, J. G., Singh, A. R., Rohr, B. A., et al. (2019) · Nature · doi:10.1038/s41586-019-1260-x · Cited by 1,554

CO 2 electrolysis to multicarbon products at activities greater than 1 A cm −2

García de Arquer, F. P., Dinh, C.-T., Ozden, A., Wicks, J., McCallum, C., Kirmani, A. R., Nam, D.-H., Gabardo, C., Seifitokaldani, A., Wang, X., et al. (2020) · Science · doi:10.1126/science.aay4217 · Cited by 1,517

Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH3) under ambient conditions

Guo, C., Ran, J., Vasileff, A., & Qiao, S.-Z. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02220d · Cited by 1,463

Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center

Yandulov, D. V., & Schrock, R. R. (2003) · Science · doi:10.1126/science.1085326 · Cited by 1,433

Recent Advances and Challenges of Electrocatalytic N2Reduction to Ammonia

Qing, G., Ghazfar, R., Jackowski, S. T., Habibzadeh, F., Ashtiani, M. M., Chen, C.-P., Smith, M. R., & Hamann, T. W. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00659 · Cited by 1,323

A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions

Cui, X., Tang, C., & Zhang, Q. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201800369 · Cited by 1,314

Oxygen Vacancy‐Mediated Photocatalysis of BiOCl: Reactivity, Selectivity, and Perspectives

Li, H., Li, J., Ai, Z., Jia, F., & Zhang, L. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201705628 · Cited by 1,207

Electrochemical Reduction of N2 under Ambient Conditions for Artificial N2 Fixation and Renewable Energy Storage Using N2/NH3 Cycle

Bao, D., Zhang, Q., Meng, F., Zhong, H., Shi, M., Zhang, Y., Yan, J., Jiang, Q., & Zhang, X. (2017) · Advanced Materials · doi:10.1002/adma.201604799 · Cited by 1,164

Tackling the Activity and Selectivity Challenges of Electrocatalysts toward the Nitrogen Reduction Reaction via Atomically Dispersed Biatom Catalysts

Guo, X., Gu, J., Lin, S., Zhang, S., Chen, Z., & Huang, S. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b13349 · Cited by 1,151

Efficient Ammonia Electrosynthesis from Nitrate on Strained Ruthenium Nanoclusters

Li, J., Zhan, G., Yang, J., Quan, F., Mao, C., Liu, Y., Wang, B., Lei, F., Li, L., Chan, A. W. M., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c00418 · Cited by 1,108

Boron-Doped Graphene for Electrocatalytic N2 Reduction

Yu, X., Han, P., Wei, Z., Huang, L., Gu, Z., Peng, S., Ma, J., & Zheng, G. (2018) · Joule · doi:10.1016/j.joule.2018.06.007 · Cited by 1,000

How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully

Tang, C., & Qiao, S.-Z. (2019) · Chemical Society Reviews · doi:10.1039/c9cs00280d · Cited by 993

Electrochemical Ammonia Synthesis—The Selectivity Challenge

Singh, A. R., Rohr, B. A., Schwalbe, J. A., Cargnello, M., Chan, K., Jaramillo, T. F., Chorkendorff, I., & Nørskov, J. K. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03035 · Cited by 971

Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction

Tao, H., Choi, C., Ding, L.-X., Jiang, Z., Han, Z., Jia, M., Fan, Q., Gao, Y., Wang, H., Robertson, A. W., et al. (2019) · Chem · doi:10.1016/j.chempr.2018.10.007 · Cited by 944

Design principles for hydrogen evolution reaction catalyst materials

Strmcnik, D., Lopes, P. P., Genorio, B., Stamenkovic, V. R., & Markovic, N. M. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.017 · Cited by 917

Au Sub‐Nanoclusters on TiO2 toward Highly Efficient and Selective Electrocatalyst for N2 Conversion to NH3 at Ambient Conditions

Shi, M., Bao, D., Wulan, B., Li, Y., Zhang, Y., Yan, J., & Jiang, Q. (2017) · Advanced Materials · doi:10.1002/adma.201606550 · Cited by 917

Achieving a Record‐High Yield Rate of 120.9 for N2 Electrochemical Reduction over Ru Single‐Atom Catalysts

Geng, Z., Liu, Y., Kong, X., Li, P., Li, K., Liu, Z., Du, J., Shu, M., Si, R., & Zeng, J. (2018) · Advanced Materials · doi:10.1002/adma.201803498 · Cited by 913

Electrochemical nitrogen fixation and utilization: theories, advanced catalyst materials and system design

Guo, W., Zhang, K., Liang, Z., Zou, R., & Xu, Q. (2019) · Chemical Society Reviews · doi:10.1039/c9cs00159j · Cited by 882

Promoting nitrogen electroreduction to ammonia with bismuth nanocrystals and potassium cations in water

Hao, Y.-C., Guo, Y., Chen, L.-W., Shu, M., Wang, X.-Y., Bu, T.-A., Gao, W.-Y., Zhang, N., Su, X., Feng, X., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0241-7 · Cited by 860

Atomic site electrocatalysts for water splitting, oxygen reduction and selective oxidation

Zhao, D., Zhuang, Z., Cao, X., Zhang, C., Peng, Q., Chen, C., & Li, Y. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00869a · Cited by 860

Ambient ammonia synthesis via palladium-catalyzed electrohydrogenation of dinitrogen at low overpotential

Wang, J., Yu, L., Hu, L., Chen, G., Xin, H., & Feng, X. (2018) · Nature Communications · doi:10.1038/s41467-018-04213-9 · Cited by 803

Recent progress towards the electrosynthesis of ammonia from sustainable resources

Shipman, M. A., & Symes, M. D. (2017) · Catalysis Today · doi:10.1016/j.cattod.2016.05.008 · Cited by 762

Molybdenum Carbide Nanodots Enable Efficient Electrocatalytic Nitrogen Fixation under Ambient Conditions

Cheng, H., Ding, L., Chen, G., Zhang, L., Xue, J., & Wang, H. (2018) · Advanced Materials · doi:10.1002/adma.201803694 · Cited by 758

Morphology and surface chemistry engineering toward PH-universal catalysts for hydrogen evolution at high current density

Luo, Y., Tang, L., Khan, U., Yu, Q., Cheng, H.-M., Zou, X., & Liu, B. (2019) · Nature Communications · doi:10.1038/s41467-018-07792-9 · Cited by 713

Suppression of Hydrogen Evolution Reaction in Electrochemical N2 Reduction Using Single-Atom Catalysts: A Computational Guideline

Choi, C., Back, S., Kim, N.-Y., Lim, J., Kim, Y.-H., & Jung, Y. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b00905 · Cited by 703

Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions

Luo, Y., Chen, G.-F., Ding, L., Chen, X., Ding, L.-X., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.09.011 · Cited by 699

Electride support boosts nitrogen dissociation over ruthenium catalyst and shifts the bottleneck in ammonia synthesis

Kitano, M., Kanbara, S., Inoue, Y., Kuganathan, N., Sushko, P. V., Yokoyama, T., Hara, M., & Hosono, H. (2015) · Nature Communications · doi:10.1038/ncomms7731 · Cited by 691

Conversion of Dinitrogen to Ammonia by FeN3-Embedded Graphene

Li, X.-F., Li, Q.-K., Cheng, J., Liu, L., Yan, Q., Wu, Y., Zhang, X.-H., Wang, Z.-Y., Qiu, Q., & Luo, Y. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b04778 · Cited by 691

Ammonia Synthesis at Atmospheric Pressure

Marnellos, G., & Stoukides, M. (1998) · Science · doi:10.1126/science.282.5386.98 · Cited by 665

Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation

Han, L., Liu, X., Chen, J., Lin, R., Liu, H., Lü, F., Bak, S., Liang, Z., Zhao, S., Stavitski, E., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201811728 · Cited by 662

Competition between CO2 Reduction and Hydrogen Evolution on a Gold Electrode under Well-Defined Mass Transport Conditions

Goyal, A., Marcandalli, G., Mints, V. A., & Koper, M. T. M. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b10061 · Cited by 637

Ammonia Electrosynthesis with High Selectivity under Ambient Conditions via a Li+ Incorporation Strategy

Chen, G.-F., Cao, X., Wu, S., Zeng, X., Ding, L.-X., Zhu, M., & Wang, H. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b04393 · Cited by 626

Electrocatalytic Synthesis of Ammonia at Room Temperature and Atmospheric Pressure from Water and Nitrogen on a Carbon‐Nanotube‐Based Electrocatalyst

Chen, S., Perathoner, S., Ampelli, C., Mebrahtu, C., Su, D., & Centi, G. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201609533 · Cited by 615

Electrocatalytic Reduction of Nitrogen: From Haber-Bosch to Ammonia Artificial Leaf

Martín, A. J., Shinagawa, T., & Pérez-Ramírez, J. (2019) · Chem · doi:10.1016/j.chempr.2018.10.010 · Cited by 608

Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids

Zhou, F., Azofra, L. M., Ali, M., Kar, M., Simonov, A. N., McDonnell-Worth, C., Sun, C., Zhang, X., & MacFarlane, D. R. (2017) · Energy & Environmental Science · doi:10.1039/c7ee02716h · Cited by 607

Electrocatalytic Nitrogen Reduction at Low Temperature

Deng, J., Iñiguez, J. A., & Liu, C. (2018) · Joule · doi:10.1016/j.joule.2018.04.014 · Cited by 590

Photon-Driven Nitrogen Fixation: Current Progress, Thermodynamic Considerations, and Future Outlook

Medford, A. J., & Hatzell, M. C. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00439 · Cited by 588

Engineering water dissociation sites in MoS2 nanosheets for accelerated electrocatalytic hydrogen production

Zhang, J., Wang, T., Liu, P., Liu, S., Dong, R., Zhuang, X., Chen, M., & Feng, X. (2016) · Energy & Environmental Science · doi:10.1039/c6ee01786j · Cited by 580

Boosted Electrocatalytic N2 Reduction to NH3 by Defect‐Rich MoS2 Nanoflower

Li, X., Li, T., Ma, Y., Wei, Q., Qiu, W., Guo, H., Shi, X., Zhang, P., Asiri, A. M., Chen, L., et al. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201801357 · Cited by 576

Defect engineering in earth-abundant electrocatalysts for CO2 and N2 reduction

Wang, Q., Lei, Y., Wang, D., & Li, Y. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03781g · Cited by 574

Two-Dimensional Mosaic Bismuth Nanosheets for Highly Selective Ambient Electrocatalytic Nitrogen Reduction

Li, L., Tang, C., Xia, B., Jin, H., Zheng, Y., & Qiao, S.-Z. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00366 · Cited by 570

Molybdenum-catalysed ammonia production with samarium diiodide and alcohols or water

Ashida, Y., Arashiba, K., Nakajima, K., & Nishibayashi, Y. (2019) · Nature · doi:10.1038/s41586-019-1134-2 · Cited by 565

Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles

Yang, X., Nash, J., Anibal, J., Dunwell, M., Kattel, S., Stavitski, E., Attenkofer, K., Chen, J. G., Yan, Y., & Xu, B. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b08379 · Cited by 553

Ammonia Synthesis Under Ambient Conditions: Selective Electroreduction of Dinitrogen to Ammonia on Black Phosphorus Nanosheets

Zhang, L., Ding, L., Chen, G., Yang, X., & Wang, H. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201813174 · Cited by 534

Nitrogen Vacancies on 2D Layered W2N3: A Stable and Efficient Active Site for Nitrogen Reduction Reaction

Jin, H., Li, L., Liu, X., Tang, C., Xu, W., Chen, S., Song, L., Zheng, Y., & Qiao, S. (2019) · Advanced Materials · doi:10.1002/adma.201902709 · Cited by 531

Greatly Improving Electrochemical N 2 Reduction over TiO 2 Nanoparticles by Iron Doping

Wu, T., Zhu, X., Xing, Z., Mou, S., Li, C., Qiao, Y., Liu, Q., Luo, Y., Shi, X., Zhang, Y., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201911153 · Cited by 499

New recipe produces ammonia from air, water, and sunlight

Service, R. F. (2014) · Science · doi:10.1126/science.345.6197.610 · Cited by 496

Advances in Electrocatalytic N2 Reduction—Strategies to Tackle the Selectivity Challenge

Chen, G., Ren, S., Zhang, L., Cheng, H., Luo, Y., Zhu, K., Ding, L., & Wang, H. (2019) · Small Methods · doi:10.1002/smtd.201800337 · Cited by 491

Identification and elimination of false positives in electrochemical nitrogen reduction studies

Choi, J., Suryanto, B. H. R., Wang, D., Du, H.-L., Hodgetts, R. Y., Ferrero Vallana, F. M., MacFarlane, D. R., & Simonov, A. N. (2020) · Nature Communications · doi:10.1038/s41467-020-19130-z · Cited by 483

Electrochemical synthesis of ammonia at atmospheric pressure and low temperature in a solid polymer electrolyte cell

Kordali, V., Kyriacou, G., & Lambrou, C. (2000) · Chemical Communications · doi:10.1039/b004885m · Cited by 475

Computational Screening of Efficient Single‐Atom Catalysts Based on Graphitic Carbon Nitride (g‐C3N4) for Nitrogen Electroreduction

Chen, Z., Zhao, J., Cabrera, C. R., & Chen, Z. (2019) · Small Methods · doi:10.1002/smtd.201800368 · Cited by 475

Metal-organic framework-derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N2 and H2O in alkaline electrolytes

Mukherjee, S., Cullen, D. A., Karakalos, S., Liu, K., Zhang, H., Zhao, S., Xu, H., More, K. L., Wang, G., & Wu, G. (2018) · Nano Energy · doi:10.1016/j.nanoen.2018.03.059 · Cited by 474

Electrocatalytic Oxidation of Glycerol to Formic Acid by CuCo2O4 Spinel Oxide Nanostructure Catalysts

Han, X., Sheng, H., Yu, C., Walker, T. W., Huber, G. W., Qiu, J., & Jin, S. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01498 · Cited by 445

Modulating Local CO2 Concentration as a General Strategy for Enhancing C−C Coupling in CO2 Electroreduction

Tan, Y. C., Lee, K. B., Song, H., & Oh, J. (2020) · Joule · doi:10.1016/j.joule.2020.03.013 · Cited by 442

Synthesis of ammonia directly from air and water at ambient temperature and pressure

Lan, R., Irvine, J. T. S., & Tao, S. (2013) · Scientific Reports · doi:10.1038/srep01145 · Cited by 416

Favoring the unfavored: Selective electrochemical nitrogen fixation using a reticular chemistry approach

Lee, H. K., Koh, C. S. L., Lee, Y. H., Liu, C., Phang, I. Y., Han, X., Tsung, C.-K., & Ling, X. Y. (2018) · Science Advances · doi:10.1126/sciadv.aar3208 · Cited by 411

Electroreduction of N2 to Ammonia at Ambient Conditions on Mononitrides of Zr, Nb, Cr, and V: A DFT Guide for Experiments

Abghoui, Y., Garden, A. L., Howalt, J. G., Vegge, T., & Skúlason, E. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b01918 · Cited by 400

Efficient H2 Evolution Coupled with Oxidative Refining of Alcohols via A Hierarchically Porous Nickel Bifunctional Electrocatalyst

You, B., Liu, X., Liu, X., & Sun, Y. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00876 · Cited by 392

Recent progress in electrocatalytic nitrogen reduction

Guo, X., Du, H., Qu, F., & Li, J. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta11201k · Cited by 384

Doping strain induced bi-Ti3+ pairs for efficient N2 activation and electrocatalytic fixation

Cao, N., Chen, Z., Zang, K., Xu, J., Zhong, J., Luo, J., Xu, X., & Zheng, G. (2019) · Nature Communications · doi:10.1038/s41467-019-10888-5 · Cited by 374

Carbon‐Based Metal‐Free Catalysts for Electrocatalytic Reduction of Nitrogen for Synthesis of Ammonia at Ambient Conditions

Zhao, S., Lu, X., Wang, L., Gale, J., & Amal, R. (2019) · Advanced Materials · doi:10.1002/adma.201805367 · Cited by 373

Recent Progress on Electrocatalyst and Photocatalyst Design for Nitrogen Reduction

Li, M., Huang, H., Low, J., Gao, C., Long, R., & Xiong, Y. (2019) · Small Methods · doi:10.1002/smtd.201800388 · Cited by 358

Rational Design of Fe–N/C Hybrid for Enhanced Nitrogen Reduction Electrocatalysis under Ambient Conditions in Aqueous Solution

Wang, Y., Cui, X., Zhao, J., Jia, G., Gu, L., Zhang, Q., Meng, L., Shi, Z., Zheng, L., Wang, C., et al. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b03802 · Cited by 345

Nitrogen Fixation Reaction Derived from Nanostructured Catalytic Materials

Wang, S., Ichihara, F., Pang, H., Chen, H., & Ye, J. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201803309 · Cited by 334

A physical catalyst for the electrolysis of nitrogen to ammonia

Song, Y., Johnson, D., Peng, R., Hensley, D. K., Bonnesen, P. V., Liang, L., Huang, J., Yang, F., Zhang, F., Qiao, R., et al. (2018) · Science Advances · doi:10.1126/sciadv.1700336 · Cited by 333

Rare Earth Single-Atom Catalysts for Nitrogen and Carbon Dioxide Reduction

Liu, J., Kong, X., Zheng, L., Guo, X., Liu, X., & Shui, J. (2020) · ACS Nano · doi:10.1021/acsnano.9b08835 · Cited by 327

Nitrogen‐Doped Porous Carbon Supported Nonprecious Metal Single‐Atom Electrocatalysts: from Synthesis to Application

Guo, J., Huo, J., Liu, Y., Wu, W., Wang, Y., Wu, M., Liu, H., & Wang, G. (2019) · Small Methods · doi:10.1002/smtd.201900159 · Cited by 326

Accelerated Dinitrogen Electroreduction to Ammonia via Interfacial Polarization Triggered by Single-Atom Protrusions

Li, J., Chen, S., Quan, F., Zhan, G., Jia, F., Ai, Z., & Zhang, L. (2020) · Chem · doi:10.1016/j.chempr.2020.01.013 · Cited by 322

MoO3 nanosheets for efficient electrocatalytic N2 fixation to NH3

Han, J., Ji, X., Ren, X., Cui, G., Li, L., Xie, F., Wang, H., Li, B., & Sun, X. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta03974g · Cited by 319

Metal‐Free Fluorine‐Doped Carbon Electrocatalyst for CO2 Reduction Outcompeting Hydrogen Evolution

Xie, J., Zhao, X., Wu, M., Li, Q., Wang, Y., & Yao, J. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201802055 · Cited by 318

Photoelectrochemical Synthesis of Ammonia on the Aerophilic-Hydrophilic Heterostructure with 37.8% Efficiency

Zheng, J., Lyu, Y., Qiao, M., Wang, R., Zhou, Y., Li, H., Chen, C., Li, Y., Zhou, H., Jiang, S. P., et al. (2019) · Chem · doi:10.1016/j.chempr.2018.12.003 · Cited by 318

Enabling electrochemical reduction of nitrogen to ammonia at ambient conditions through rational catalyst design

Abghoui, Y., Garden, A. L., Hlynsson, V. F., Björgvinsdóttir, S., Ólafsdóttir, H., & Skúlason, E. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp04838e · Cited by 315

MoS2 Polymorphic Engineering Enhances Selectivity in the Electrochemical Reduction of Nitrogen to Ammonia

Suryanto, B. H. R., Wang, D., Azofra, L. M., Harb, M., Cavallo, L., Jalili, R., Mitchell, D. R. G., Chatti, M., & MacFarlane, D. R. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.8b02257 · Cited by 315

Boosting selective nitrogen reduction to ammonia on electron-deficient copper nanoparticles

Lin, Y.-X., Zhang, S.-N., Xue, Z.-H., Zhang, J.-J., Su, H., Zhao, T.-J., Zhai, G.-Y., Li, X.-H., Antonietti, M., & Chen, J.-S. (2019) · Nature Communications · doi:10.1038/s41467-019-12312-4 · Cited by 311

Water Durable Electride Y5Si3: Electronic Structure and Catalytic Activity for Ammonia Synthesis

Lu, Y., Li, J., Tada, T., Toda, Y., Ueda, S., Yokoyama, T., Kitano, M., & Hosono, H. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b00124 · Cited by 306

Ambient Electrochemical Ammonia Synthesis with High Selectivity on Fe/Fe Oxide Catalyst

Hu, L., Khaniya, A., Wang, J., Chen, G., Kaden, W. E., & Feng, X. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b02585 · Cited by 302

Conversion of dinitrogen to ammonia on Ru atoms supported on boron sheets: a DFT study

Liu, C., Li, Q., Zhang, J., Jin, Y., MacFarlane, D. R., & Sun, C. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta08219g · Cited by 294

Theoretical Screening of Single Transition Metal Atoms Embedded in MXene Defects as Superior Electrocatalyst of Nitrogen Reduction Reaction

Li, L., Wang, X., Guo, H., Yao, G., Yu, H., Tian, Z., Li, B., & Chen, L. (2019) · Small Methods · doi:10.1002/smtd.201900337 · Cited by 291

Single or Double: Which Is the Altar of Atomic Catalysts for Nitrogen Reduction Reaction?

Chen, Z. W., Yan, J., & Jiang, Q. (2019) · Small Methods · doi:10.1002/smtd.201800291 · Cited by 290

Computational Evaluation of Electrocatalytic Nitrogen Reduction on TM Single-, Double-, and Triple-Atom Catalysts (TM = Mn, Fe, Co, Ni) Based on Graphdiyne Monolayers

Ma, D., Zeng, Z., Liu, L., Huang, X., & Jia, Y. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b05250 · Cited by 289

In Situ Infrared Spectroscopy Reveals Persistent Alkalinity near Electrode Surfaces during CO2 Electroreduction

Yang, K., Kas, R., & Smith, W. A. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07000 · Cited by 288

Generating Defect‐Rich Bismuth for Enhancing the Rate of Nitrogen Electroreduction to Ammonia

Wang, Y., Shi, M., Bao, D., Meng, F., Zhang, Q., Zhou, Y., Liu, K., Zhang, Y., Wang, J., Chen, Z., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201903969 · Cited by 278

Vacancy Engineering of Iron‐Doped W18O49 Nanoreactors for Low‐Barrier Electrochemical Nitrogen Reduction

Tong, Y., Guo, H., Liu, D., Yan, X., Su, P., Liang, J., Zhou, S., Liu, J., Lu, G. Q. (., & Dou, S. X. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202002029 · Cited by 278

Nanoporous Gold Embedded ZIF Composite for Enhanced Electrochemical Nitrogen Fixation

Yang, Y., Wang, S., Wen, H., Ye, T., Chen, J., Li, C., & Du, M. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201909770 · Cited by 274

Electrochemical Synthesis of NH3 at Low Temperature and Atmospheric Pressure Using a γ-Fe2O3 Catalyst

Kong, J., Lim, A., Yoon, C., Jang, J. H., Ham, H. C., Han, J., Nam, S., Kim, D., Sung, Y.-E., Choi, J., et al. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b02890 · Cited by 272

Increasing stability, efficiency, and fundamental understanding of lithium-mediated electrochemical nitrogen reduction

Andersen, S. Z., Statt, M. J., Bukas, V. J., Shapel, S. G., Pedersen, J. B., Krempl, K., Saccoccio, M., Chakraborty, D., Kibsgaard, J., Vesborg, P. C. K., et al. (2020) · Energy & Environmental Science · doi:10.1039/d0ee02246b · Cited by 272

Double-atom catalysts: transition metal dimer-anchored C2N monolayers as N2 fixation electrocatalysts

Zhang, X., Chen, A., Zhang, Z., & Zhou, Z. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta07683a · Cited by 270

Aqueous electrocatalytic N2 reduction under ambient conditions

Cao, N., & Zheng, G. (2018) · Nano Research · doi:10.1007/s12274-018-1987-y · Cited by 257

Electrocatalytically Active Fe‐(O‐C2)4 Single‐Atom Sites for Efficient Reduction of Nitrogen to Ammonia

Zhang, S., Jin, M., Shi, T., Han, M., Sun, Q., Lin, Y., Ding, Z., Zheng, L. R., Wang, G., Zhang, Y., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202005930 · Cited by 251

Rational Electrode–Electrolyte Design for Efficient Ammonia Electrosynthesis under Ambient Conditions

Suryanto, B. H. R., Kang, C. S. M., Wang, D., Xiao, C., Zhou, F., Azofra, L. M., Cavallo, L., Zhang, X., & MacFarlane, D. R. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00487 · Cited by 248

Electrochemical Nitrogen Reduction: Identification and Elimination of Contamination in Electrolyte

Li, L., Tang, C., Yao, D., Zheng, Y., & Qiao, S.-Z. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b01573 · Cited by 243

Enabling Effective Electrocatalytic N2 Conversion to NH3 by the TiO2 Nanosheets Array under Ambient Conditions

Zhang, R., Ren, X., Shi, X., Xie, F., Zheng, B., Guo, X., & Sun, X. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b06647 · Cited by 242

Tuning the Catalytic Preference of Ruthenium Catalysts for Nitrogen Reduction by Atomic Dispersion

Yu, B., Li, H., White, J., Donne, S., Yi, J., Xi, S., Fu, Y., Henkelman, G., Yu, H., Chen, Z., et al. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201905665 · Cited by 232

Strategies toward Selective Electrochemical Ammonia Synthesis

Singh, A. R., Rohr, B. A., Statt, M. J., Schwalbe, J. A., Cargnello, M., & Nørskov, J. K. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02245 · Cited by 223

Onset potentials for different reaction mechanisms of nitrogen activation to ammonia on transition metal nitride electro-catalysts

Abghoui, Y., & Skúlason, E. (2017) · Catalysis Today · doi:10.1016/j.cattod.2016.11.047 · Cited by 220

Dramatically Enhanced Ambient Ammonia Electrosynthesis Performance by In‐Operando Created Li–S Interactions on MoS2 Electrocatalyst

Liu, Y., Han, M., Xiong, Q., Zhang, S., Zhao, C., Gong, W., Wang, G., Zhang, H., & Zhao, H. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201803935 · Cited by 208

High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium

Cheng, H., Cui, P., Wang, F., Ding, L., & Wang, H. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201910658 · Cited by 206

Understanding the Electrocatalytic Interface for Ambient Ammonia Synthesis

Hu, L., Xing, Z., & Feng, X. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.9b02679 · Cited by 202

Hierarchical Cobalt Phosphide Hollow Nanocages toward Electrocatalytic Ammonia Synthesis under Ambient Pressure and Room Temperature

Guo, W., Liang, Z., Zhao, J., Zhu, B., Cai, K., Zou, R., & Xu, Q. (2018) · Small Methods · doi:10.1002/smtd.201800204 · Cited by 200

Atomically Dispersed Single Ni Site Catalysts for Nitrogen Reduction toward Electrochemical Ammonia Synthesis Using N2 and H2O

Mukherjee, S., Yang, X., Shan, W., Samarakoon, W., Karakalos, S., Cullen, D. A., More, K., Wang, M., Feng, Z., Wang, G., et al. (2020) · Small Methods · doi:10.1002/smtd.201900821 · Cited by 200

Recent Advanced Materials for Electrochemical and Photoelectrochemical Synthesis of Ammonia from Dinitrogen: One Step Closer to a Sustainable Energy Future

Yan, Z., Ji, M., Xia, J., & Zhu, H. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902020 · Cited by 191

Reversible Nitrogen Fixation Based on a Rechargeable Lithium-Nitrogen Battery for Energy Storage

Ma, J.-L., Bao, D., Shi, M.-M., Yan, J.-M., & Zhang, X.-B. (2017) · Chem · doi:10.1016/j.chempr.2017.03.016 · Cited by 190

Enhanced Electrocatalytic N2 Reduction via Partial Anion Substitution in Titanium Oxide–Carbon Composites

Qin, Q., Zhao, Y., Schmallegger, M., Heil, T., Schmidt, J., Walczak, R., Gescheidt‐Demner, G., Jiao, H., & Oschatz, M. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201906056 · Cited by 190

Electronically Coupled SnO2 Quantum Dots and Graphene for Efficient Nitrogen Reduction Reaction

Chu, K., Liu, Y.-P., Li, Y.-B., Wang, J., & Zhang, H. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b08055 · Cited by 190

The Difficulty of Proving Electrochemical Ammonia Synthesis

Kibsgaard, J., Nørskov, J. K., & Chorkendorff, I. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b02286 · Cited by 190

Crystal‐Phase‐Engineered PdCu Electrocatalyst for Enhanced Ammonia Synthesis

Tong, W., Huang, B., Wang, P., Li, L., Shao, Q., & Huang, X. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201913122 · Cited by 189

Greatly Enhanced Electrocatalytic N2 Reduction on TiO2 via V Doping

Wu, T., Kong, W., Zhang, Y., Xing, Z., Zhao, J., Wang, T., Shi, X., Luo, Y., & Sun, X. (2019) · Small Methods · doi:10.1002/smtd.201900356 · Cited by 186

Proton transfer dynamics control the mechanism of O2 reduction by a non-precious metal electrocatalyst

Tse, E. C. M., Barile, C. J., Kirchschlager, N. A., Li, Y., Gewargis, J. P., Zimmerman, S. C., Hosseini, A., & Gewirth, A. A. (2016) · Nature Materials · doi:10.1038/nmat4636 · Cited by 183

Tuning the Electron Localization of Gold Enables the Control of Nitrogen‐to‐Ammonia Fixation

Zheng, J., Lyu, Y., Qiao, M., Veder, J. P., Marco, R. D., Bradley, J., Wang, R., Li, Y., Huang, A., Jiang, S. P., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201909477 · Cited by 183

ZIF‐Induced d‐Band Modification in a Bimetallic Nanocatalyst: Achieving Over 44 % Efficiency in the Ambient Nitrogen Reduction Reaction

Sim, H. Y. F., Chen, J. R. T., Koh, C. S. L., Lee, H. K., Han, X., Phan‐Quang, G. C., Pang, J. Y., Lay, C. L., Pedireddy, S., Phang, I. Y., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202006071 · Cited by 182

A Highly Efficient Metal‐Free Electrocatalyst of F‐Doped Porous Carbon toward N2 Electroreduction

Liu, Y., Li, Q., Guo, X., Kong, X., Ke, J., Chi, M., Li, Q., Geng, Z., & Zeng, J. (2020) · Advanced Materials · doi:10.1002/adma.201907690 · Cited by 172

N2 Electroreduction to NH3 by Selenium Vacancy‐Rich ReSe2 Catalysis at an Abrupt Interface

Lai, F., Zong, W., He, G., Xu, Y., Huang, H., Weng, B., Rao, D., Martens, J. A., Hofkens, J., Parkin, I. P., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202003129 · Cited by 172

Electrochemical ammonia synthesis through N2 and H2O under ambient conditions: Theory, practices, and challenges for catalysts and electrolytes

Xu, H., Ithisuphalap, K., Li, Y., Mukherjee, S., Lattimer, J., Soloveichik, G., & Wu, G. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.104469 · Cited by 170

Nitrogen electroreduction performance of transition metal dimers embedded into N-doped graphene: a theoretical prediction

Li, H., Zhao, Z., Cai, Q., Yin, L., & Zhao, J. (2020) · Journal of Materials Chemistry A · doi:10.1039/c9ta13599e · Cited by 160

Atomic Structure Modification for Electrochemical Nitrogen Reduction to Ammonia

Chen, X., Guo, Y., Du, X., Zeng, Y., Chu, J., Gong, C., Huang, J., Fan, C., Wang, X., & Xiong, J. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903172 · Cited by 159

The rapid electrochemical activation of MoTe2 for the hydrogen evolution reaction

McGlynn, J. C., Dankwort, T., Kienle, L., Bandeira, N. A. G., Fraser, J. P., Gibson, E. K., Cascallana-Matías, I., Kamarás, K., Symes, M. D., Miras, H. N., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-12831-0 · Cited by 158

Carbon‐Nanoplated CoS@TiO2 Nanofibrous Membrane: An Interface‐Engineered Heterojunction for High‐Efficiency Electrocatalytic Nitrogen Reduction

Liu, Y., Chen, X., Yu, J., & Ding, B. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201912733 · Cited by 155

A General Strategy to Glassy M‐Te (M = Ru, Rh, Ir) Porous Nanorods for Efficient Electrochemical N2 Fixation

Wang, J., Huang, B., Ji, Y., Sun, M., Wu, T., Yin, R., Zhu, X., Li, Y., Shao, Q., & Huang, X. (2020) · Advanced Materials · doi:10.1002/adma.201907112 · Cited by 151

Ambient NH 3 synthesis via electrochemical reduction of N 2 over cubic sub-micron SnO 2 particles

Zhang, L., Ren, X. Z., Luo, Y., Shi, X., Asiri, A. M., Li, T., & Sun, X. (2018) · Chemical Communications · doi:10.1039/c8cc06524a · Cited by 142

Understanding the influence of the electrochemical double-layer on heterogeneous electrochemical reactions

Dunwell, M., Yan, Y. S., & Xu, B. (2018) · Current Opinion in Chemical Engineering · doi:10.1016/j.coche.2018.05.003 · Cited by 140

Single molybdenum center supported on N-doped black phosphorus as an efficient electrocatalyst for nitrogen fixation

Ou, P., Zhou, X. Y., Meng, F., Chen, C., Chen, Y., & Song, J. J. (2019) · Nanoscale · doi:10.1039/c9nr02586c · Cited by 132

Communication—Electrochemical Reduction of Nitrogen to Ammonia in 2-Propanol under Ambient Temperature and Pressure

Kim, K., Lee, N., Yoo, C., Kim, J., Yoon, H. C., & Han, J. (2016) · Journal of The Electrochemical Society · doi:10.1149/2.0231607jes · Cited by 127

Bionic Design of a Mo(IV)-Doped FeS 2 Catalyst for Electroreduction of Dinitrogen to Ammonia

Wang, H., Wang, J., Zhang, R., Cheng, C., Qiu, K., Yang, Y., Mao, J., Liu, H., Du, M., Dong, C., et al. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c00271 · Cited by 122

Electrochemical Synthesis of Ammonia from Nitrogen Under Mild Conditions: Current Status and Challenges

Yao, Y., Wang, J., Shahid, U. B., Gu, M. D., Wang, H., Li, H., & Shao, M. (2020) · Electrochemical Energy Reviews · doi:10.1007/s41918-019-00061-3 · Cited by 120

Electrochemical Synthesis of Ammonia from N 2 and H 2 O under Ambient Conditions Using Pore-Size-Controlled Hollow Gold Nanocatalysts with Tunable Plasmonic Properties

Nazemi, M., & El‐Sayed, M. A. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b02188 · Cited by 119

Ta 2 + -mediated ammonia synthesis from N 2 and H 2 at ambient temperature

Geng, C., Li, J., Weiske, T., & Schwarz, H. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1814610115 · Cited by 115

Single-Metal Atom Anchored on Boron Monolayer (β 12 ) as an Electrocatalyst for Nitrogen Reduction into Ammonia at Ambient Conditions: A First-Principles Study

(2019) · doi:10.1021/acs.jpcc.8b11696 · Cited by 113

Electrochemical Synthesis of Ammonia from Water and Nitrogen in Ethylenediamine under Ambient Temperature and Pressure

Kim, K., Yoo, C., Kim, J., Yoon, H. C., & Han, J. (2016) · Journal of The Electrochemical Society · doi:10.1149/2.0741614jes · Cited by 108

A theoretical study of the effect of a non-aqueous proton donor on electrochemical ammonia synthesis

Zhang, L., Sharada, S. M., Singh, A. R., Rohr, B. A., Su, Y., Qiao, L. J., & Nørskov, J. K. (2018) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp05484j · Cited by 108

Amorphous Sn/Crystalline SnS2 Nanosheets via In Situ Electrochemical Reduction Methodology for Highly Efficient Ambient N2 Fixation

Li, P., Fu, W., Zhuang, P., Cao, Y., Tang, C. L., Watson, A. B., Dong, P. T., Shen, J., & Ye, M. (2019) · Small · doi:10.1002/smll.201902535 · Cited by 105

Atomic Modulation, Structural Design, and Systematic Optimization for Efficient Electrochemical Nitrogen Reduction

Huang, Y., Babu, D. D., Peng, Z., & Wang, Y. (2020) · Advanced Science · doi:10.1002/advs.201902390 · Cited by 105

Boosted Electrocatalytic N2 Reduction on Fluorine-Doped SnO2 Mesoporous Nanosheets

Liu, Y., Li, Y., Zhang, H., & Chu, K. (2019) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.9b01823 · Cited by 102

Single vs double atom catalyst for N2 activation in nitrogen reduction reaction: A DFT perspective

Qian, Y., Liu, Y., Zhao, Y., Zhang, X., & Yu, G. (2020) · EcoMat · doi:10.1002/eom2.12014 · Cited by 99

Crystal‐Phase‐Engineered PdCu Electrocatalyst for Enhanced Ammonia Synthesis

Wu, T. S., Huang, B., Wang, P., Li, L., Shao, Q., & Huang, X. (2019) · Angewandte Chemie · doi:10.1002/ange.201913122 · Cited by 94

Photocatalytic and electrocatalytic approaches towards atmospheric nitrogen reduction to ammonia under ambient conditions

John, J., Lee, D., & Sim, U. (2019) · Nano Convergence · doi:10.1186/s40580-019-0182-5 · Cited by 90

Theoretical Screening of Single-Atom-Embedded MoSSe Nanosheets for Electrocatalytic N 2 Fixation

Li, L., Li, B., Guo, Q., & Li, B. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b02657 · Cited by 88

Theoretical study on double-atom catalysts supported with graphene for electroreduction of nitrogen into ammonia

Yang, W., Huang, H., Ding, X., Ding, Z., Wu, C., Gates, I. D., & Gao, Z. (2020) · Electrochimica Acta · doi:10.1016/j.electacta.2020.135667 · Cited by 83

Role of H 2 O in CO 2 Electrochemical Reduction As Studied in a Water-in-Salt System

Dong, Q., Zhang, X., He, D., Lang, C., & Wang, D. (2019) · ACS Central Science · doi:10.1021/acscentsci.9b00519 · Cited by 82

Design of a High-Performance Electrocatalyst for N2 Conversion to NH3 by Trapping Single Metal Atoms on Stepped CeO2

Qi, J., Gao, L., Wei, F., Wan, Q., & Lin, S. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b15570 · Cited by 82

Long-term electrocatalytic N 2 fixation by MOF-derived Y-stabilized ZrO 2 : insight into the deactivation mechanism

Luo, S., Li, X., Wang, M., Zhang, X., Gao, W., Su, S., Liu, G., & Luo, M. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta01154a · Cited by 79

Promoting photocatalytic nitrogen fixation with alkali metal cations and plasmonic nanocrystals

Bu, T.-A., Hao, Y., Gao, W., Su, X., Chen, L., Zhang, N., & Yin, A. (2019) · Nanoscale · doi:10.1039/c9nr02502b · Cited by 75

Ti 3+ self-doped TiO 2−x nanowires for efficient electrocatalytic N 2 reduction to NH 3

Li, B., Zhu, X., Wang, J., Xing, R., Liu, Q., Shi, X., Luo, Y., Liu, S., Niu, X., & Sun, X. (2019) · Chemical Communications · doi:10.1039/c9cc08971c · Cited by 63

Strain induced rich planar defects in heterogeneous WS 2 /WO 2 enable efficient nitrogen fixation at low overpotential

Ling, Y., Kazim, F. M. D., Ma, S., Zhang, Q., Qu, K., Wang, Y., Xiao, S., Cai, W., & Yang, Z. (2020) · Journal of Materials Chemistry A · doi:10.1039/c9ta13812a · Cited by 61

Nitrogen-carbon layer coated nickel nanoparticles for efficient electrocatalytic reduction of carbon dioxide

Tan, D., Cui, C., Shi, J., Luo, Z., Zhang, B., Tan, X., Han, B., Zheng, L., Zhang, J., & Zhang, J. (2019) · Nano Research · doi:10.1007/s12274-019-2372-1 · Cited by 57

Quantifying Losses and Assessing the Photovoltage Limits in Metal–Insulator–Semiconductor Water Splitting Systems

Hemmerling, J. R., Quinn, J., & Linic, S. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903354 · Cited by 56

Core@shell structured Au@SnO2 nanoparticles with improved N2 adsorption/activation and electrical conductivity for efficient N2 fixation

Wang, P., Ji, Y., Shao, Q., Li, Y., & Huang, X. (2019) · 中国科学通报：英文版 · doi:10.1016/j.scib.2019.12.019 · Cited by 51

Synergistic Promotion of the Electrochemical Reduction of Nitrogen to Ammonia by Phosphorus and Potassium

Zhang, Q., Liu, B., Yu, L., Bei, Y., & Tang, B. (2019) · ChemCatChem · doi:10.1002/cctc.201901519 · Cited by 47

Photoactive Earth‐Abundant Iron Pyrite Catalysts for Electrocatalytic Nitrogen Reduction Reaction

Chang, C., Li, S., Chou, H., Lee, Y., Patil, S. B., Lin, Y., Chang, C., Chang, Y. J., & Wang, D. (2019) · Small · doi:10.1002/smll.201904723 · Cited by 47

Turning Water from a Hindrance to the Promotor of Preferential Electrochemical Nitrogen Reduction

Koh, C. S. L., Lee, H. K., Sim, H. Y. F., Han, X., Phan‐Quang, G. C., & Ling, X. Y. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.9b05313 · Cited by 46

Selective Electrochemical Nitrogen Reduction Driven by Hydrogen Bond Interactions at Metal–Ionic Liquid Interfaces

Ortuño, M. Á., Hollóczki, O., Kirchner, B., & López, N. (2019) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b03409 · Cited by 45

Support effect boosting the electrocatalytic N 2 reduction activity of Ni 2 P/N,P-codoped carbon nanosheet hybrids

Yuan, M., Zhang, H., Gao, D., He, H., Sun, Y. F., Lu, P., Dilpazir, S., Li, Q., Zhou, L., Li, S., et al. (2020) · Journal of Materials Chemistry A · doi:10.1039/c9ta09920d · Cited by 45

Electrochemical synthesis of ammonia by zirconia-based catalysts at ambient conditions

Xian, H., Wang, Q. L., Yu, G., Wang, H., Li, Y., Wang, Y., & Li, T. (2019) · Applied Catalysis A General · doi:10.1016/j.apcata.2019.05.025 · Cited by 40

Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride

Yang, X., Kattel, S. P., Nash, J., Chang, X., Lee, J. H., Yan, Y. S., Chen, J. G., & Xu, B. (2019) · Angewandte Chemie · doi:10.1002/ange.201906449 · Cited by 34

Ultrasmall V 8 C 7 nanoparticles embedded in conductive carbon for efficient electrocatalytic N 2 reduction toward ambient NH 3 production

Feng, J., Zhu, X., Chen, Q., Xiong, W., Chen, X., Luo, Y., Alshehri, A. A., Alzahrani, K. A., Jiang, Z., & Li, W. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta09439c · Cited by 30

Boosted electrochemical ammonia synthesis by high-percentage metallic transition metal dichalcogenide quantum dots

Zhang, J., Ling, C., Zang, W., Li, X., Huang, S., Li, X. L., Yan, D., Kou, Z., Liu, L., Wang, J., et al. (2020) · Nanoscale · doi:10.1039/d0nr01409e · Cited by 30

Investigation of N2-fixation on polyaniline electrodes in methanol by electrochemical impedance spectroscopy

Köleli, F., Röpke, D., Aydın, R., & Röpke, T. (2010) · Journal of Applied Electrochemistry · doi:10.1007/s10800-010-0250-3 · Cited by 22

Can sustainable ammonia synthesis pathways compete with fossil-fuel based Haber–Bosch processes?

Wang, M., Khan, M. A., Mohsin, I., Wicks, J., Ip, A. H., Sumon, K. Z., Dinh, C.-T., Sargent, E. H., Gates, I. D., & Kibria, M. G. (2021) · Energy & Environmental Science · doi:10.1039/d0ee03808c · Cited by 518

Tailored catalyst microenvironments for CO2 electroreduction to multicarbon products on copper using bilayer ionomer coatings

Kim, C., Bui, J. C., Luo, X., Cooper, J. K., Kusoglu, A., Weber, A. Z., & Bell, A. T. (2021) · Nature Energy · doi:10.1038/s41560-021-00920-8 · Cited by 473

Review of Carbon Support Coordination Environments for Single Metal Atom Electrocatalysts (SACS)

Song, W., Xiao, C., Ding, J., Huang, Z., Yang, X., Zhang, T., Mitlin, D., & Hu, W. (2024) · Advanced Materials · doi:10.1002/adma.202301477 · Cited by 373