Cited by 305Ionic liquids properties and applicationsBiofuel production and bioconversionCatalysis for Biomass Conversion

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Deep Eutectic Solvents for Pretreatment, Extraction, and Catalysis of Biomass and Food Waste

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Kalhor, Payam, Ghandi, Khashayar·2019·Molecules

DOI 10.3390/molecules24224012PMC PMC6891572

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Abstract

Valorization of lignocellulosic biomass and food residues to obtain valuable chemicals is essential to the establishment of a sustainable and biobased economy in the modern world. The latest and greenest generation of ionic liquids (ILs) are deep eutectic solvents (DESs) and natural deep eutectic solvents (NADESs); these have shown great promise for various applications and have attracted considerable attention from researchers who seek versatile solvents with pretreatment, extraction, and catalysis capabilities in biomass- and biowaste-to-bioenergy conversion processes. The present work aimed to review the use of DESs and NADESs in the valorization of biomass and biowaste as pretreatment or extraction solvents or catalysis agents.

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Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
Huber, G. W., Iborra, S., & Corma, A. (2006) · Chemical Reviews · doi:10.1021/cr068360d · Cited by 7,810
Deep Eutectic Solvents (DESs) and Their Applications
Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378
Novel solvent properties of choline chloride/urea mixturesElectronic supplementary information (ESI) available: spectroscopic data. See http://www.rsc.org/suppdata/cc/b2/b210714g/
Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340
Untitled work
(2011) · FAO eBooks · Cited by 3,368
Natural Deep Eutectic Solvents – Solvents for the 21st Century
Paiva, A., Craveiro, R., Aroso, I., Martins, M., Reis, R. L., & Duarte, A. R. C. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc500096j · Cited by 2,458
Deconstruction of lignocellulosic biomass with ionic liquids
Brandt, A., Gräsvik, J., Hallett, J. P., & Welton, T. (2013) · Green Chemistry · doi:10.1039/c2gc36364j · Cited by 1,557
Bimetallic catalysts for upgrading of biomass to fuels and chemicals
Alonso, D. M., Wettstein, S. G., & Dumesic, J. A. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35188a · Cited by 1,420
Are Natural Deep Eutectic Solvents the Missing Link in Understanding Cellular Metabolism and Physiology?
Choi, Y. H., van Spronsen, J., Dai, Y., Verberne, M., Hollmann, F., Arends, I. W. C. E., Witkamp, G.-J., & Verpoorte, R. (2011) · Plant Physiology · doi:10.1104/pp.111.178426 · Cited by 1,368
Catalytic Conversion of Carbohydrates to Initial Platform Chemicals: Chemistry and Sustainability
Mika, L. T., Cséfalvay, E., & Németh, Á. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00395 · Cited by 1,342
Insights into the Nature of Eutectic and Deep Eutectic Mixtures
Martins, M. A. R., Pinho, S. P., & Coutinho, J. A. P. (2018) · Journal of Solution Chemistry · doi:10.1007/s10953-018-0793-1 · Cited by 1,235
Deep Eutectic Solvents: Physicochemical Properties and Gas Separation Applications
García, G., Aparicio, S., Ullah, R., & Atilhan, M. (2015) · Energy & Fuels · doi:10.1021/ef5028873 · Cited by 1,112
A review of ionic liquids: Applications towards catalytic organic transformations
Vekariya, R. L. (2016) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2016.11.123 · Cited by 1,046
Insights into the synthesis and properties of deep eutectic solvents based on cholinium chloride and carboxylic acids
Florindo, C., Oliveira, F. S., Rebelo, L. P. N., Fernandes, A. M., & Marrucho, I. M. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc500439w · Cited by 977
Green Carbon Science: Scientific Basis for Integrating Carbon Resource Processing, Utilization, and Recycling
He, M., Sun, Y., & Han, B. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209384 · Cited by 942
Glycerol eutectics as sustainable solvent systems
Abbott, A. P., Harris, R. C., Ryder, K. S., D’Agostino, C., Gladden, L. F., & Mantle, M. D. (2010) · Green Chemistry · doi:10.1039/c0gc00395f · Cited by 899
Eutectic‐Based Ionic Liquids with Metal‐Containing Anions and Cations
Abbott, A. P., Barron, J. C., Ryder, K. S., & Wilson, D. (2007) · Chemistry - A European Journal · doi:10.1002/chem.200601738 · Cited by 798
A Review of Ionic Liquids, Their Limits and Applications
Ghandi, K. (2014) · Green and Sustainable Chemistry · doi:10.4236/gsc.2014.41008 · Cited by 771
Self-citation
Facile fractionation of lignocelluloses by biomass-derived deep eutectic solvent (DES) pretreatment for cellulose enzymatic hydrolysis and lignin valorization
Shen, X., Wen, J., Mei, Q., Chen, X., Sun, D., Yuan, T., & Sun, R. (2018) · Green Chemistry · doi:10.1039/c8gc03064b · Cited by 767
Extraction techniques with deep eutectic solvents
Cunha, S. C., & Fernandes, J. O. (2018) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2018.05.001 · Cited by 760
Unique low-molecular-weight lignin with high purity extracted from wood by deep eutectic solvents (DES): a source of lignin for valorization
Álvarez-Vasco, C., Ma, R., Quintero, M., Guo, M., Geleynse, S. C., Ramasamy, K. K., Wolcott, M. P., & Zhang, X. (2016) · Green Chemistry · doi:10.1039/c6gc01007e · Cited by 734
Deep eutectic solvents for the production and application of new materials
Tomé, L. I. N., Baião, V., da Silva, W., & Brett, C. M. A. (2017) · Applied Materials Today · doi:10.1016/j.apmt.2017.11.005 · Cited by 718
Household-level dynamics of food waste production and related beliefs, attitudes, and behaviours in Guelph, Ontario
Parizeau, K., von Massow, M., & Martin, R. (2015) · Waste Management · doi:10.1016/j.wasman.2014.09.019 · Cited by 636
The peculiar effect of water on ionic liquids and deep eutectic solvents
Ma, C., Laaksonen, A., Liu, C., Lü, X., & Ji, X. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00325d · Cited by 606
Ether- and alcohol-functionalized task-specific ionic liquids: attractive properties and applications
Tang, S., Baker, G. A., & Zhao, H. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15362a · Cited by 594
Molecular motion and ion diffusion in choline chloride based deep eutectic solvents studied by 1H pulsed field gradient NMR spectroscopy
D’Agostino, C., Harris, R. C., Abbott, A. P., Gladden, L. F., & Mantle, M. D. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp22554e · Cited by 578
Application of Hole Theory to Define Ionic Liquids by their Transport Properties
Abbott, A. P., Harris, R. C., & Ryder, K. S. (2007) · The Journal of Physical Chemistry B · doi:10.1021/jp0671998 · Cited by 576
Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities
Satlewal, A., Agrawal, R., Bhagia, S., Sangoro, J. R., & Ragauskas, A. J. (2018) · Biotechnology Advances · doi:10.1016/j.biotechadv.2018.08.009 · Cited by 572
Natural deep eutectic solvent mediated pretreatment of rice straw: bioanalytical characterization of lignin extract and enzymatic hydrolysis of pretreated biomass residue
Kumar, A. K., Parikh, B. S., & Pravakar, M. (2016) · Environmental Science and Pollution Research · doi:10.1007/s11356-015-4780-4 · Cited by 571
Applications of deep eutectic solvents in biotechnology and bioengineering—Promises and challenges
Mbous, Y. P. V., Hayyan, M., Hayyan, A., Wong, W. F., Hashim, M. A., & Looi, C. Y. (2016) · Biotechnology Advances · doi:10.1016/j.biotechadv.2016.11.006 · Cited by 565
Multiple hydrogen bond coordination in three-constituent deep eutectic solvents enhances lignin fractionation from biomass
Xia, Q., Liu, Y., Meng, J., Cheng, W., Chen, W., Liu, S., Li, P., Li, J., & Yu, H. (2018) · Green Chemistry · doi:10.1039/c8gc00900g · Cited by 558
Phenolic Hydrogen Bond Donors in the Formation of Non-Ionic Deep Eutectic Solvents: The Quest for Type V DES
Abranches, D. O., Martins, M. A. R., Silva, L. P., Schaeffer, N., Pinho, S. P., & Coutinho, J. A. P. (2019) · Chemical Communications · doi:10.1039/c9cc04846d · Cited by 550 · cited 1×
“Finally, non-ionic compounds can be used to make mixtures with decreased freezing points to establish a new class, type V, of DESs [101].”
Background
Design of improved deep eutectic solvents using hole theory
Abbott, A. P., Capper, G., & Gray, S. (2006) · ChemPhysChem · doi:10.1002/cphc.200500489 · Cited by 545
Efficient Cleavage of Lignin–Carbohydrate Complexes and Ultrafast Extraction of Lignin Oligomers from Wood Biomass by Microwave‐Assisted Treatment with Deep Eutectic Solvent
Liu, Y., Chen, W., Xia, Q., Guo, B., Wang, Q., Liu, S., Li, P., Li, J., & Yu, H. (2017) · ChemSusChem · doi:10.1002/cssc.201601795 · Cited by 544
Extraction of polyphenolic antioxidants from orange peel waste using deep eutectic solvents
Ozturk, B., Parkinson, C., & Gonzalez-Miquel, M. (2018) · Separation and Purification Technology · doi:10.1016/j.seppur.2018.05.052 · Cited by 542
Freeze-Drying of Aqueous Solutions of Deep Eutectic Solvents: A Suitable Approach to Deep Eutectic Suspensions of Self-Assembled Structures
Gutiérrez, M. C., Ferrer, M. L., Mateo, C. R., & del Monte, F. (2009) · Langmuir · doi:10.1021/la900552b · Cited by 540
Recent developments in deep eutectic solvents in chemical sciences
Tang, B., & Row, K. H. (2013) · Monatshefte für Chemie - Chemical Monthly · doi:10.1007/s00706-013-1050-3 · Cited by 538
Facile pretreatment of lignocellulosic biomass using deep eutectic solvents
Zhang, C., Xia, S., & Ma, P. (2016) · Bioresource Technology · doi:10.1016/j.biortech.2016.07.026 · Cited by 531
Comprehensive evaluation of deep eutectic solvents in extraction of bioactive natural products
Duan, L., Dou, L.-L., Guo, L., Li, P., & Liu, E.-H. (2016) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.6b00091 · Cited by 519
Densities and Viscosities of (Choline Chloride + Urea) Deep Eutectic Solvent and Its Aqueous Mixtures in the Temperature Range 293.15 K to 363.15 K
Yadav, A., & Pandey, S. (2014) · Journal of Chemical & Engineering Data · doi:10.1021/je5001796 · Cited by 498
Enhanced extraction of bioactive natural products using tailor-made deep eutectic solvents: Application to flavonoid extraction from Flos sophorae
Nam, M. W., Zhao, J., Lee, M. S., Jeong, J. H., & Lee, J. (2015) · Green Chemistry · doi:10.1039/c4gc01556h · Cited by 467
The critical role of heterogeneous catalysis in lignocellulosic biomass conversion
Lin, Y., & Huber, G. W. (2008) · Energy & Environmental Science · doi:10.1039/b814955k · Cited by 462
Deep eutectic solvents for polysaccharides processing. A review
Zdanowicz, M., Wilpiszewska, K., & Spychaj, T. (2018) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2018.07.078 · Cited by 460
Novel choline-chloride-based deep-eutectic-solvents with renewable hydrogen bond donors: levulinic acid and sugar-based polyols
Maugeri, Z., & de María, P. D. (2011) · RSC Advances · doi:10.1039/c1ra00630d · Cited by 444
Enhancing cellulose accessibility of corn stover by deep eutectic solvent pretreatment for butanol fermentation
Xu, G., Ding, J.-C., Han, R., Dong, J., & Ni, Y. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2015.11.002 · Cited by 424
Natural designer solvents for greening analytical chemistry
Espino, M., de los Ángeles Fernández, M., Gomez, F. J. V., & Silva, M. F. (2016) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2015.11.006 · Cited by 418
Application of natural deep eutectic solvents to the extraction of anthocyanins from Catharanthus roseus with high extractability and stability replacing conventional organic solvents
Dai, Y., Rozema, E., Verpoorte, R., & Choi, Y. H. (2016) · Journal of Chromatography A · doi:10.1016/j.chroma.2016.01.037 · Cited by 416
Extraction of phenolic compounds from virgin olive oil by deep eutectic solvents (DESs)
García, A., Rodríguez-Juan, E., Rodríguez-Gutiérrez, G., Rios, J. J., & Fernández-Bolaños, J. (2016) · Food Chemistry · doi:10.1016/j.foodchem.2015.10.131 · Cited by 409
Natural deep eutectic solvents as beneficial extractants for enhancement of plant extracts bioactivity
Radošević, K., Ćurko, N., Gaurina Srček, V., Cvjetko Bubalo, M., Tomašević, M., Kovačević Ganić, K., & Radojčić Redovniković, I. (2016) · LWT · doi:10.1016/j.lwt.2016.05.037 · Cited by 404
Green Solvents in Carbohydrate Chemistry: From Raw Materials to Fine Chemicals
Farrán, M. Á., Cai, C., Sandoval, M., Xu, Y., Liu, J., Hernáiz, M. J., & Linhardt, R. J. (2015) · Chemical Reviews · doi:10.1021/cr500719h · Cited by 401
Deep eutectic solvent pretreatment and subsequent saccharification of corncob
Procentese, A., Johnson, E. E., Ward, V. C. A., Campanile, A. G., Wood, J. A., Marzocchella, A., & Rehmann, L. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2015.05.053 · Cited by 398
Green Processing of Lignocellulosic Biomass and Its Derivatives in Deep Eutectic Solvents
Tang, X., Zuo, M., Li, Z., Liu, H., Xiong, C., Zeng, X., Sun, Y., Hu, L., Liu, S., Lei, T., et al. (2017) · ChemSusChem · doi:10.1002/cssc.201700457 · Cited by 380
Hydrothermal liquefaction of mixed-culture algal biomass from wastewater treatment system into bio-crude oil
Chen, W.-T., Zhang, Y., Zhang, J., Yu, G., Schideman, L. C., Zhang, P., & Minarick, M. (2014) · Bioresource Technology · doi:10.1016/j.biortech.2013.10.111 · Cited by 379
Densities of ammonium and phosphonium based deep eutectic solvents: Prediction using artificial intelligence and group contribution techniques
Shahbaz, K., Baroutian, S., Mjalli, F. S., Hashim, M. A., & AlNashef, I. M. (2011) · Thermochimica Acta · doi:10.1016/j.tca.2011.10.010 · Cited by 377
Deep eutectic solvents’ ability to solubilize lignin, cellulose, and hemicellulose; thermal stability; and density
Lynam, J. G., Kumar, N., & Wong, M. J. (2017) · Bioresource Technology · doi:10.1016/j.biortech.2017.04.079 · Cited by 376
Biomass pretreatment using deep eutectic solvents from lignin derived phenols
Kim, K. H., Dutta, T., Sun, J., Simmons, B., & Singh, S. (2018) · Green Chemistry · doi:10.1039/c7gc03029k · Cited by 373
Green and efficient extraction of rutin from tartary buckwheat hull by using natural deep eutectic solvents
Huang, Y., Feng, F., Jiang, J., Qiao, Y., Wu, T., Voglmeir, J., & Chen, Z.-G. (2017) · Food Chemistry · doi:10.1016/j.foodchem.2016.11.013 · Cited by 366
Natural deep eutectic solvents and ultrasound-assisted extraction: Green approaches for extraction of wine lees anthocyanins
Bosiljkov, T., Dujmić, F., Bubalo, M. C., Hribar, J., Vidrih, R., Brnčić, M., Zlatić, E., Redovniković, I. R., & Jokić, S. (2016) · Food and Bioproducts Processing · doi:10.1016/j.fbp.2016.12.005 · Cited by 365
Ionic Liquids Based upon Metal Halide/Substituted Quaternary Ammonium Salt Mixtures
Abbott, A. P., Capper, G., Davies, D. L., & Rasheed, R. (2004) · Inorganic Chemistry · doi:10.1021/ic049931s · Cited by 364
Anaerobic digestion without biogas?
Kleerebezem, R., Joosse, B., Rozendal, R. A., & van Loosdrecht, M. C. M. (2015) · Reviews in Environmental Science and Bio/Technology · doi:10.1007/s11157-015-9374-6 · Cited by 358
Densities and dynamic viscosities of (choline chloride+glycerol) deep eutectic solvent and its aqueous mixtures in the temperature range (283.15–363.15)K
Yadav, A., Trivedi, S., Rai, R., & Pandey, S. (2014) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2014.01.028 · Cited by 341
Ultrafast fractionation of lignocellulosic biomass by microwave-assisted deep eutectic solvent pretreatment
Chen, Z., & Wan, C. (2018) · Bioresource Technology · doi:10.1016/j.biortech.2017.11.066 · Cited by 337
Degradation of Deep-Eutectic Solvents Based on Choline Chloride and Carboxylic Acids
Rodriguez, N. R., van den Bruinhorst, A., Kollau, L. J. B. M., Kroon, M. C., & Binnemans, K. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b01378 · Cited by 337
Effect of functional groups in acid constituent of deep eutectic solvent for extraction of reactive lignin
Tan, Y. T., Ngoh, G. C., & Chua, A. S. M. (2019) · Bioresource Technology · doi:10.1016/j.biortech.2019.02.010 · Cited by 328
Electrochemistry in Deep Eutectic Solvents
Nkuku, C. A., & LeSuer, R. J. (2007) · The Journal of Physical Chemistry B · doi:10.1021/jp075794j · Cited by 318
Acidic Deep Eutectic Solvents As Hydrolytic Media for Cellulose Nanocrystal Production
Sirviö, J. A., Visanko, M., & Liimatainen, H. (2016) · Biomacromolecules · doi:10.1021/acs.biomac.6b00910 · Cited by 314
Natural deep eutectic solvents (DES) for fractionation of waste lignocellulosic biomass and its cascade conversion to value-added bio-based chemicals
Mamilla, J. L. K., Novak, U., Grilc, M., & Likozar, B. (2018) · Biomass and Bioenergy · doi:10.1016/j.biombioe.2018.12.002 · Cited by 308
Polarity-dependent extraction of flavonoids from citrus peel waste using a tailor-made deep eutectic solvent
Xu, M., Ran, L., Chen, N., Fan, X., Ren, D., & Yi, L. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.124970 · Cited by 299
Static Relative Dielectric Permittivities of Ionic Liquids at 25 °C
Huang, M., Jiang, Y., Padmanabhan, S., Driver, G. W., & Weingärtner, H. (2011) · Journal of Chemical & Engineering Data · doi:10.1021/je101184s · Cited by 291
Effective extraction of flavonoids from Lycium barbarum L. fruits by deep eutectic solvents-based ultrasound-assisted extraction
Ali, M. C., Chen, J., Zhang, H., Li, Z., Zhao, L., & Qiu, H. (2019) · Talanta · doi:10.1016/j.talanta.2019.05.012 · Cited by 284
Contribution of Deep Eutectic Solvents for Biomass Processing: Opportunities, Challenges, and Limitations
Vigier, K. D. O., Châtel, G., & Jérôme, F. (2015) · ChemCatChem · doi:10.1002/cctc.201500134 · Cited by 282
The characterisation and treatment of food waste for improvement of biogas production during anaerobic digestion – A review
Bong, C. P. C., Lim, L. Y., Lee, C. T., Klemeš, J. J., Ho, C. S., & Ho, W. S. (2017) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2017.10.199 · Cited by 281
Application of natural deep eutectic solvents for extraction and determination of phenolics in Cajanus cajan leaves by ultra performance liquid chromatography
Wei, Z., Qi, X., Li, T., Luo, M., Wang, W., Zu, Y., & Fu, Y. (2015) · Separation and Purification Technology · doi:10.1016/j.seppur.2015.05.015 · Cited by 274
Insight into the structure-function relationships of deep eutectic solvents during rice straw pretreatment
Hou, X., Li, A., Lin, K.-P., Wang, Y., Kuang, Z.-Y., & Cao, S. (2017) · Bioresource Technology · doi:10.1016/j.biortech.2017.10.019 · Cited by 268
Short-time deep eutectic solvent pretreatment for enhanced enzymatic saccharification and lignin valorization
Guo, Z., Zhang, Q., You, T., Zhang, X., Xu, F., & Wu, Y. (2019) · Green Chemistry · doi:10.1039/c9gc00704k · Cited by 266
Water-based woody biorefinery
Amidon, T. E., & Liu, S. (2009) · Biotechnology Advances · doi:10.1016/j.biotechadv.2009.04.012 · Cited by 265
Molecular Dynamic Simulations and Vibrational Analysis of an Ionic Liquid Analogue
Perkins, S. L., Painter, P. C., & Colina, C. M. (2013) · The Journal of Physical Chemistry B · doi:10.1021/jp404619x · Cited by 259
Novel approaches mediated by tailor-made green solvents for the extraction of phenolic compounds from agro-food industrial by-products
Fernández, M. D. L. Á., Espino, M., Gomez, F. J. V., & Silva, M. F. (2018) · Food Chemistry · doi:10.1016/j.foodchem.2017.06.150 · Cited by 257
Application of ionic liquids and deep eutectic solvents in biodiesel production: A review
Troter, D. Z., Todorović, Z. B., Djokic-Stojanovic, D., Stamenković, O. S., & Veljković, V. B. (2016) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2016.04.011 · Cited by 256
Pretreatment of wheat straw using basic ethanolamine-based deep eutectic solvents for improving enzymatic hydrolysis
Zhao, Z., Chen, X., Ali, M. F., Abdeltawab, A. A., Yakout, S. M., & Yu, G. (2018) · Bioresource Technology · doi:10.1016/j.biortech.2018.05.016 · Cited by 252
Cellulose solvent-based pretreatment for enhanced second-generation biofuel production: a review
Satari, B., Karimi, K., & Kumar, R. (2018) · Sustainable Energy & Fuels · doi:10.1039/c8se00287h · Cited by 250
Novel lactic acid-based natural deep eutectic solvents: Efficiency in the ultrasound-assisted extraction of antioxidant polyphenols from common native Greek medicinal plants
Bakirtzi, C., Triantafyllidou, K., & Makris, D. P. (2016) · Journal of Applied Research on Medicinal and Aromatic Plants · doi:10.1016/j.jarmap.2016.03.003 · Cited by 245
Hydrothermal Treatment of Protein, Polysaccharide, and Lipids Alone and in Mixtures
Teri, G., Luo, L., & Savage, P. E. (2014) · Energy & Fuels · doi:10.1021/ef501760d · Cited by 243
O-Acetylation of cellulose and monosaccharides using a zinc based ionic liquid
Abbott, A. P., Bell, T. J., Handa, S., & Stoddart, B. (2005) · Green Chemistry · doi:10.1039/b511691k · Cited by 241
The application of deep eutectic solvent ionic liquids for environmentally-friendly dissolution and recovery of precious metals
Jenkin, G. R. T., Al-Bassam, A. Z. M., Harris, R. C., Abbott, A. P., Smith, D. J., Holwell, D. A., Chapman, R. J., & Stanley, C. J. (2015) · Minerals Engineering · doi:10.1016/j.mineng.2015.09.026 · Cited by 236
Multi-functioning deep eutectic solvents as extraction and storage media for bioactive natural products that are readily applicable to cosmetic products
Jeong, K. M., Ko, J., Zhao, J., Jin, Y., Yoo, D. E., Han, S. Y., & Lee, J. (2017) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2017.03.038 · Cited by 235
Co-liquefaction of swine manure and mixed-culture algal biomass from a wastewater treatment system to produce bio-crude oil
Chen, W.-T., Zhang, Y., Zhang, J., Schideman, L., Yu, G., Zhang, P., & Minarick, M. (2014) · Applied Energy · doi:10.1016/j.apenergy.2014.04.068 · Cited by 233
Green and efficient extraction of polysaccharides from brown seaweed by adding deep eutectic solvent in subcritical water hydrolysis
Saravana, P. S., Cho, Y.-N., Woo, H.-C., & Chun, B. (2018) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2018.07.151 · Cited by 227
High-Solid Lignocellulose Processing Enabled by Natural Deep Eutectic Solvent for Lignin Extraction and Industrially Relevant Production of Renewable Chemicals
Chen, Z., Bai, X., A, L., & Wan, C. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b02541 · Cited by 221
Tailoring and recycling of deep eutectic solvents as sustainable and efficient extraction media
Jeong, K. M., Lee, M. S., Nam, M. W., Zhao, J., Jin, Y., Lee, D.-K., Kwon, S. W., Jeong, J. H., & Lee, J. (2015) · Journal of Chromatography A · doi:10.1016/j.chroma.2015.10.083 · Cited by 219
Deep eutectic solvent pretreatment enabling full utilization of switchgrass
Chen, Z., Reznicek, W. D., & Wan, C. (2018) · Bioresource Technology · doi:10.1016/j.biortech.2018.04.058 · Cited by 214
Facile Extraction of Wheat Straw by Deep Eutectic Solvent (DES) to Produce Lignin Nanoparticles
Lou, R., Ma, R., Lin, K.-T., Ahamed, A., & Zhang, X. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b05816 · Cited by 212
Electropolishing of stainless steels in a choline chloride based ionic liquid: an electrochemical study with surface characterisation using SEM and atomic force microscopy
Abbott, A. P., Capper, G., McKenzie, K. J., Glidle, A., & Ryder, K. S. (2006) · Physical Chemistry Chemical Physics · doi:10.1039/b607763n · Cited by 208
Fast and green extraction and separation of main bioactive flavonoids from Radix Scutellariae
Wei, Z.-F., Wang, X.-Q., Peng, X., Wang, W., Zhao, C.-J., Zu, Y.-G., & Fu, Y.-J. (2015) · Industrial Crops and Products · doi:10.1016/j.indcrop.2014.10.013 · Cited by 205
Evaluation of new natural deep eutectic solvents for the extraction of isoflavones from soy products
Bajkacz, S., & Adamek, J. (2017) · Talanta · doi:10.1016/j.talanta.2017.02.065 · Cited by 204
Halogenation reactions in biodegradable solvent: Efficient bromination of substituted 1-aminoanthra-9,10-quinone in deep eutectic solvent (choline chloride : urea)
Phadtare, S. B., & Shankarling, G. S. (2010) · Green Chemistry · doi:10.1039/b923589b · Cited by 200
Selective Extraction of Collagen Peptides with High Purity from Cod Skins by Deep Eutectic Solvents
Bai, C., Wei, Q., & Ren, X. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b01439 · Cited by 199
One-pot production of chitin with high purity from lobster shells using choline chloride–malonic acid deep eutectic solvent
Ping, Z., Gu, Z., Hong, S., & Lian, H. (2017) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2017.09.001 · Cited by 193
Cellulose Nanofibrils from Nonderivatizing Urea-Based Deep Eutectic Solvent Pretreatments
Li, P., Sirviö, J. A., Haapala, A., & Liimatainen, H. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b13625 · Cited by 192
Polyol-Based Deep Eutectic Solvents for Extraction of Natural Polyphenolic Antioxidants from Chlorella vulgaris
Mahmood, W. M. A. W., Lorwirachsutee, A., Theodoropoulos, C., & González‐Miquel, M. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b05642 · Cited by 191
Synergistic and Antagonistic Interactions during Hydrothermal Liquefaction of Soybean Oil, Soy Protein, Cellulose, Xylose, and Lignin
Lu, J., Liu, Z., Zhang, Y., & Savage, P. E. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b03156 · Cited by 190
Deep eutectic solvent-based extraction and fabrication of chitin films from crustacean waste
Saravana, P. S., Ho, T. C., Chae, S.-J., Cho, Y., Park, J., Lee, H.-J., & Chun, B. (2018) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2018.05.018 · Cited by 190
Water absorption by deep eutectic solvents
Chen, Y., Yu, D., Chen, W., Fu, L. Y., & Mu, T. (2019) · Physical Chemistry Chemical Physics · doi:10.1039/c8cp07383j · Cited by 189
Deep eutectic solvents as efficient solvent system for the extraction of κ-carrageenan from Kappaphycus alvarezii
Das, A. K., Sharma, M., Mondal, D., & Prasad, K. (2016) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2015.09.114 · Cited by 187
Pre-treatment and extraction techniques for recovery of added value compounds from wastes throughout the agri-food chain
Arshadi, M., Attard, T. M., Bogel‐Łukasik, R., Brnčić, M., Lopes, A. M. D. C., Finell, M., Geladi, P. L. M., Gerschenson, L. N., Göğüş, F., Herrero, M., et al. (2016) · Green Chemistry · doi:10.1039/c6gc01389a · Cited by 186
Application of natural deep eutectic solvents for the “green”extraction of vanillin from vanilla pods
Guízar‐González, C., Mustafa, N. R., Wilson, E. G., Verpoorte, R., & Choi, Y. H. (2017) · Flavour and Fragrance Journal · doi:10.1002/ffj.3425 · Cited by 186
Green and Facile Production of Chitin from Crustacean Shells Using a Natural Deep Eutectic Solvent
Huang, W., Zhao, D., Guo, N., Xue, C., & Mao, X. (2018) · Journal of Agricultural and Food Chemistry · doi:10.1021/acs.jafc.8b03847 · Cited by 182
Novel binary eutectic mixtures based on imidazole
Hou, Y. W., Gu, Y., Zhang, S., Yang, F., Ding, H., & Shan, Y. (2008) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2008.07.009 · Cited by 181
Aqueous ionic liquids and deep eutectic solvents for cellulosic biomass pretreatment and saccharification
Xia, S., Baker, G. A., Li, H., Ravula, S., & Zhao, H. (2013) · RSC Advances · doi:10.1039/c3ra46149a · Cited by 178
Ternary deep eutectic solvents for effective biomass deconstruction at high solids and low enzyme loadings
Chen, Z., Jacoby, W. A., & Wan, C. (2019) · Bioresource Technology · doi:10.1016/j.biortech.2019.01.126 · Cited by 178
Quantum Chemical Insight into the Interactions and Thermodynamics Present in Choline Chloride Based Deep Eutectic Solvents
Wagle, D. V., Deakyne, C. A., & Baker, G. A. (2016) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.6b04750 · Cited by 177
Room Temperature Ionic Liquids Meet Biomolecules: A Microscopic View of Structure and Dynamics
Benedetto, A., & Ballone, P. (2015) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.5b01385 · Cited by 176
Efficient continuous synthesis of high purity deep eutectic solvents by twin screw extrusion
Crawford, D. E., Wright, L. A., James, S. L., & Abbott, A. P. (2016) · Chemical Communications · doi:10.1039/c5cc09685e · Cited by 174
Pretreatment of oil palm trunk in deep eutectic solvent and optimization of enzymatic hydrolysis of pretreated oil palm trunk
Zulkefli, S., Abdulmalek, E., & Rahman, M. B. A. (2017) · Renewable Energy · doi:10.1016/j.renene.2017.01.037 · Cited by 171
The environmental biorefinery: State-of-the-art on the production of hydrogen and value-added biomolecules in mixed-culture fermentation
Moscoviz, R., Trably, E., Bernet, N., & Carrère, H. (2018) · Green Chemistry · doi:10.1039/c8gc00572a · Cited by 171
Hexafluoroisopropanol-based hydrophobic deep eutectic solvents for dispersive liquid-liquid microextraction of pyrethroids in tea beverages and fruit juices
Deng, W., Yu, L., Li, X., Chen, J., Wang, X., Deng, Z., & Xiao, Y. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2018.09.048 · Cited by 168
High-pressure density measurements for choline chloride: Urea deep eutectic solvent and its aqueous mixtures at T= (298.15 to 323.15) K and up to 50 MPa
Leron, R. B., & Li, M. (2012) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2012.05.008 · Cited by 167
Using Deep Eutectic Solvents for the Removal of Glycerol from Palm Oil-Based Biodiesel
Shahbaz, K., Mjalli, F. S., Hashim, M. A., & AlNashef, I. M. (2010) · Journal of Applied Sciences · doi:10.3923/jas.2010.3349.3354 · Cited by 165
A new processing route for cleaner production of biodiesel fuel using a choline chloride based deep eutectic solvent
Hayyan, A., Hashim, M. A., Hayyan, M., Mjalli, F. S., & AlNashef, I. M. (2013) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2013.08.031 · Cited by 165
Physicochemical transformation of rice straw after pretreatment with a deep eutectic solvent of choline chloride/urea
Pan, M., Zhao, G., Ding, C., Wu, B., Lian, Z., & Lian, H. (2017) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2017.08.088 · Cited by 163
Pretreatment and hydrolysis of lignocellulosic wastes for butanol production: Challenges and perspectives
Amiri, H., & Karimi, K. (2018) · Bioresource Technology · doi:10.1016/j.biortech.2018.08.117 · Cited by 162
Glycerol Hydrogen-Bonding Network Dominates Structure and Collective Dynamics in a Deep Eutectic Solvent
Faraone, A., Wagle, D. V., Baker, G. A., Novak, E. C., Ohl, M., Reuter, D., Lunkenheimer, P., Loidl, A., & Mamontov, E. (2018) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.7b11224 · Cited by 159
Acid and Deep Eutectic Solvent (DES) extraction of pectin from pomelo (Citrus grandis (L.) Osbeck) peels
Liew, S. Q., Ngoh, G. C., Yusoff, R. B., & Teoh, W. H. (2017) · Biocatalysis and Agricultural Biotechnology · doi:10.1016/j.bcab.2017.11.001 · Cited by 156
Deep Eutectic Solvents pretreatment of agro-industrial food waste
Procentese, A., Raganati, F., Olivieri, G., Russo, M. E., Rehmann, L., & Marzocchella, A. (2018) · Biotechnology for Biofuels · doi:10.1186/s13068-018-1034-y · Cited by 156
High-purity lignin isolated from poplar wood meal through dissolving treatment with deep eutectic solvents
Chen, Y., Zhang, L., Yu, J., Lu, Y., Jiang, B., Fan, Y., & Wang, Z. (2019) · Royal Society Open Science · doi:10.1098/rsos.181757 · Cited by 154
An approach for the rationalization of melting temperature for deep eutectic solvents from DFT
García, G., Atilhan, M., & Aparício, S. (2015) · Chemical Physics Letters · doi:10.1016/j.cplett.2015.06.017 · Cited by 151
Characterization of Food Waste and Its Digestate as Feedstock for Thermochemical Processing
Opatokun, S. A., Kan, T., Shoaibi, A. A., Srinivasakannan, C., & Strezov, V. (2015) · Energy & Fuels · doi:10.1021/acs.energyfuels.5b02183 · Cited by 149
Enhanced Protein Extraction from Oilseed Cakes Using Glycerol–Choline Chloride Deep Eutectic Solvents: A Biorefinery Approach
Grudniewska, A., de Melo, E. M., Chan, A. T., Gniłka, R., Boratyński, F., & Matharu, A. S. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b04359 · Cited by 149
Novel dihydrogen-bonding deep eutectic solvents: Pretreatment of rice straw for butanol fermentation featuring enzyme recycling and high solvent yield
Xing, W., Xu, G., Dong, J., Han, R., & Ni, Y. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.09.176 · Cited by 146
Highly efficient extraction of anthocyanins from grape skin using deep eutectic solvents as green and tunable media
Jeong, K. M., Zhao, J., Jin, Y., Heo, S. R., Han, S. Y., Yoo, D. E., & Lee, J. (2015) · Archives of Pharmacal Research · doi:10.1007/s12272-015-0678-4 · Cited by 145
Bio-Oil from Hydro-Liquefaction of Bagasse in Supercritical Ethanol
Chumpoo, J., & Prasassarakich, P. (2010) · Energy & Fuels · doi:10.1021/ef901241e · Cited by 142
Enhanced and green extraction polyphenols and furanocoumarins from Fig (Ficus carica L.) leaves using deep eutectic solvents
Wang, T., Jiao, J., Gai, Q., Wang, P., Guo, N., Niu, L., & Fu, Y. (2017) · Journal of Pharmaceutical and Biomedical Analysis · doi:10.1016/j.jpba.2017.07.002 · Cited by 139
Ultrasound and deep eutectic solvent (DES): A novel blend of techniques for rapid and energy efficient synthesis of oxazoles
Singh, B. S., Lobo, H. R., Pinjari, D. V., Jarag, K. J., Pandit, A. B., & Shankarling, G. S. (2012) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2012.06.003 · Cited by 137
Efficient extraction of proanthocyanidin from Ginkgo biloba leaves employing rationally designed deep eutectic solvent-water mixture and evaluation of the antioxidant activity
Cao, J., Chen, L., Li, M., Cao, F., Zhao, L., & Su, E. (2018) · Journal of Pharmaceutical and Biomedical Analysis · doi:10.1016/j.jpba.2018.06.007 · Cited by 136
Deep Extractive Desulfurization with Arenium Ion Deep Eutectic Solvents
Tang, X., Zhang, Y.-F., Li, J.-J., Zhu, Y., Qing, D., & Deng, Y.-X. (2015) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.5b00291 · Cited by 135
Green and efficient extraction of different types of bioactive alkaloids using deep eutectic solvents
Jiang, Z., Wang, L.-J., Gao, Z., Zhuang, B., Yin, Q., & Liu, E. (2018) · Microchemical Journal · doi:10.1016/j.microc.2018.10.057 · Cited by 132
Influence of Thermophysical Properties of Ionic Liquids in Chemical Process Design
França, J. M. P., de Castro, C. A. N., Lopes, M. M., & Nunes, V. M. B. (2009) · Journal of Chemical & Engineering Data · doi:10.1021/je900107t · Cited by 130
Acid and Alkali Catalyzed Hydrothermal Liquefaction of Dairy Manure Digestate and Food Waste
Posmanik, R., Martinez, C. M., Cantero‐Tubilla, B., Cantero, D. A., Sills, D. L., Cocero, M. J., & Tester, J. W. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b04359 · Cited by 129
Ethanol Production from Food Waste at High Solids Content with Vacuum Recovery Technology
Huang, H., Qureshi, N., Chen, M., Liu, W., & Singh, V. (2015) · Journal of Agricultural and Food Chemistry · doi:10.1021/jf5054029 · Cited by 127
Potential use of pure and diluted choline chloride-based deep eutectic solvent in delignification of oil palm fronds
New, E. K., Wu, T. Y., Lee, C. B. T. L., Poon, Z. Y., Loow, Y.-L., Foo, L. Y. W., Procentese, A., Siow, L. F., Teoh, W. H., Daud, N. N. N., et al. (2018) · Process Safety and Environmental Protection · doi:10.1016/j.psep.2018.11.015 · Cited by 126
Charge Spreading in Deep Eutectic Solvents
Zahn, S., Kirchner, B., & Mollenhauer, D. (2016) · ChemPhysChem · doi:10.1002/cphc.201600348 · Cited by 125
Effective separation, recovery and recycling of deep eutectic solvent after biomass fractionation with membrane-based methodology
Liang, X., Fu, Y., & Chang, J. (2018) · Separation and Purification Technology · doi:10.1016/j.seppur.2018.08.021 · Cited by 124
How Do Animals Survive Extreme Temperature Amplitudes? The Role of Natural Deep Eutectic Solvents
Gertrudes, A., Craveiro, R., Eltayari, Z. S. F., Reis, R. L., Paiva, A., & Duarte, A. R. C. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b01707 · Cited by 123
Direct conversion of shrimp shells to O -acylated chitin with antibacterial and anti-tumor effects by natural deep eutectic solvents
Feng, M., Lü, X., Zhang, J., Li, Y., Shi, C., Lü, L., & Zhang, S. (2018) · Green Chemistry · doi:10.1039/c8gc02506a · Cited by 123
Comparison of deep eutectic solvents (DES) on pretreatment of oil palm empty fruit bunch (OPEFB): Cellulose digestibility, structural and morphology changes
Thi, S., & Lee, K. M. (2019) · Bioresource Technology · doi:10.1016/j.biortech.2019.03.065 · Cited by 121
Low-energy biomass pretreatment with deep eutectic solvents for bio-butanol production
Procentese, A., Raganati, F., Olivieri, G., Russo, M. E., Rehmann, L., & Marzocchella, A. (2017) · Bioresource Technology · doi:10.1016/j.biortech.2017.06.143 · Cited by 118
Towards green analysis of virgin olive oil phenolic compounds: Extraction by a natural deep eutectic solvent and direct spectrophotometric detection
Paradiso, V. M., Clemente, A., Summo, C., Pasqualone, A., & Caponio, F. (2016) · Food Chemistry · doi:10.1016/j.foodchem.2016.05.082 · Cited by 117
Sequential ultrasonication and deep eutectic solvent pretreatment to remove lignin and recover xylose from oil palm fronds
Ong, V. Z., Wu, T. Y., Lee, C. B. T. L., Cheong, N. W. R., & Shak, K. P. Y. (2019) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2019.05.015 · Cited by 117
Imidazole-based deep eutectic solvents for starch dissolution and plasticization
Zdanowicz, M., Spychaj, T., & Mąka, H. (2015) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2015.12.036 · Cited by 115
Understanding the peculiar effect of water on the physicochemical properties of choline chloride based deep eutectic solvents theoretically and experimentally
Kuddushi, M., Nangala, G. S., Rajput, S. M., Ijardar, S. P., & Malek, N. I. (2019) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2019.01.053 · Cited by 112
Enhanced and Selective Lipid Extraction from the Microalga P. tricornutum by Dimethyl Carbonate and Supercritical CO2 Using Deep Eutectic Solvents and Microwaves as Pretreatment
Tommasi, E., Cravotto, G., Galletti, P., Grillo, G., Mazzotti, M., Sacchetti, G., Samorì, C., Tabasso, S., Tacchini, M., & Tagliavini, E. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b02074 · Cited by 110
Growth of ZnO Nanostructures with Controllable Morphology Using a Facile Green Antisolvent Method
Dong, J.-Y., Hsu, Y., Wong, D. S., & Lu, S. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp102396f · Cited by 107
Deep Eutectic Solvent Aqueous Solutions as Efficient Media for the Solubilization of Hardwood Xylans
Morais, E. S., Mendonça, P. V., Coelho, J. F. J., Freire, M. G., Freire, C. S. R., Coutinho, J. A. P., & Silvestre, A. J. D. (2018) · ChemSusChem · doi:10.1002/cssc.201702007 · Cited by 106
Conversion of sunflower stalk based cellulose to the valuable products using choline chloride based deep eutectic solvents
Sert, M., Arslanoğlu, A., & Ballice, L. (2017) · Renewable Energy · doi:10.1016/j.renene.2017.10.083 · Cited by 103
Reviving Pretreatment Effectiveness of Deep Eutectic Solvents on Lignocellulosic Date Palm Residues by Prior Recalcitrance Reduction
Fang, C., Thomsen, M. H., Frankær, C. G., Brudecki, G. P., Schmidt, J. E., & AlNashef, I. M. (2017) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.6b04733 · Cited by 102
Biomass conversion to bio-oil using sub-critical water: Study of model compounds for food processing waste
Posmanik, R., Cantero, D. A., Malkani, A. S., Sills, D. L., & Tester, J. W. (2016) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2016.09.004 · Cited by 100
Characterization of the solid products from hydrothermal liquefaction of waste feedstocks from food and agricultural industries
Cantero‐Tubilla, B., Cantero, D. A., Martínez, C. M., Tester, J. W., Walker, L. P., & Posmanik, R. (2017) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2017.07.009 · Cited by 99
Ionic conductivity of deep eutectic solvents: the role of orientational dynamics and glassy freezing
Reuter, D., Binder, C., Lunkenheimer, P., & Loidl, A. (2019) · Physical Chemistry Chemical Physics · doi:10.1039/c9cp00742c · Cited by 99
Natural deep eutectic solvents in combination with ultrasonic energy as a green approach for solubilisation of proteins: application to gluten determination by immunoassay
Lores, H., Romero, V., Costas, I., Bendicho, C., & Lavilla, I. (2017) · Talanta · doi:10.1016/j.talanta.2016.10.078 · Cited by 96
Dynamic Solvent Control of a Reaction in Ionic Deep Eutectic Solvents: Time-Resolved Fluorescence Measurements of Reactive and Nonreactive Dynamics in (Choline Chloride + Urea) Melts
Das, A., & Biswas, R. (2015) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.5b04936 · Cited by 94
A kinetic study on microwave-assisted conversion of cellulose and lignocellulosic waste into hydroxymethylfurfural/furfural
Lacerda, V. D. S., López-Sotelo, J. B., Corrêa-Guimarães, A., Hernández-Navarro, S., Sánchez‐Báscones, M., Navas-Gracia, L. M., Martín‐Ramos, P., Pérez‐Lebeña, E., & Martín‐Gil, J. (2014) · Bioresource Technology · doi:10.1016/j.biortech.2014.12.089 · Cited by 93
Cellulosic ethanol production from green solvent-pretreated rice straw
Kumar, A. K., Parikh, B. S., Shah, E., Liu, L. Z., & Cotta, M. A. (2016) · Biocatalysis and Agricultural Biotechnology · doi:10.1016/j.bcab.2016.04.008 · Cited by 93
A highly efficient synthesis of dithiocarbamates in green reaction media
Azizi, N., & Gholibeglo, E. (2012) · RSC Advances · doi:10.1039/c2ra20615c · Cited by 92
Dielectric Relaxations of (Acetamide + Electrolyte) Deep Eutectic Solvents in the Frequency Window, 0.2 ≤ ν/GHz ≤ 50: Anion and Cation Dependence
Mukherjee, K., Das, A., Choudhury, S., Barman, A., & Biswas, R. (2015) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.5b01502 · Cited by 91
Application of deep eutectic solvent in ultrasound-assisted emulsification microextraction of quercetin from some fruits and vegetables
Kanberoğlu, G. S., Yılmaz, E., & Soylak, M. (2019) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2019.01.130 · Cited by 91
An automated homogeneous liquid-liquid microextraction based on deep eutectic solvent for the HPLC-UV determination of caffeine in beverages
Shishov, A., Volodina, N., Nechaeva, D., Gagarinova, S., & Bulatov, A. (2019) · Microchemical Journal · doi:10.1016/j.microc.2018.10.014 · Cited by 90
Volumetric properties of solutions of choline chloride + glycerol deep eutectic solvent with water, methanol, ethanol, or iso-propanol
Kim, K.-S., & Park, B. H. (2018) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2018.01.087 · Cited by 89
Optimization of thermo-chemical pretreatment and enzymatic hydrolysis of kitchen wastes
Vavouraki, A. I., Volioti, V., & Kornaros, M. E. (2013) · Waste Management · doi:10.1016/j.wasman.2013.09.027 · Cited by 88
High-pressure volumetric properties of choline chloride–ethylene glycol based deep eutectic solvent and its mixtures with water
Leron, R. B., & Li, M. (2012) · Thermochimica Acta · doi:10.1016/j.tca.2012.07.024 · Cited by 88
Zinc-based deep eutectic solvent-mediated hydroxylation and demethoxylation of lignin for the production of wood adhesive
Hong, S., Lian, H., Sun, X., Pan, D., Carranza, A., Pojman, J. A., & Mota-Morales, J. D. (2016) · RSC Advances · doi:10.1039/c6ra18290a · Cited by 85
Deep Eutectic Solvent-Based Microwave-Assisted Method for Extraction of Hydrophilic and Hydrophobic Components from Radix Salviae miltiorrhizae
Chen, J., Liu, M., Wang, Q., Du, H., & Zhang, L. (2016) · Molecules · doi:10.3390/molecules21101383 · Cited by 85
Production of fuel ethanol and methane from garbage by high-efficiency two-stage fermentation process
Koike, Y., An, M.-Z., Tang, Y., Syo, T., Osaka, N., Morimura, S., & Kida, K. (2009) · Journal of Bioscience and Bioengineering · doi:10.1016/j.jbiosc.2009.06.007 · Cited by 81
Catalytic hydrothermal liquefaction of Euglena sp. microalgae over zeolite catalysts for the production of bio-oil
Zhang, B., Lin, Q., Zhang, Q., Wu, K., Pu, W., Yang, M., & Wu, Y. (2017) · RSC Advances · doi:10.1039/c6ra28747f · Cited by 81
Deacidification of palm oil using betaine monohydrate-based natural deep eutectic solvents
Zahrina, I., Nasikin, M., Krisanti, E., & Mulia, K. (2018) · Food Chemistry · doi:10.1016/j.foodchem.2017.07.132 · Cited by 81
Deep eutectic solvent (DES) as both solvent and catalyst for oxidation of furfural to maleic acid and fumaric acid
Ni, Y., Bi, Z., Su, H., & Yan, L. (2019) · Green Chemistry · doi:10.1039/c8gc04022b · Cited by 80
Comparison of three deep eutectic solvents and 1-ethyl-3-methylimidazolium acetate in the pretreatment of lignocellulose: effect on enzyme stability, lignocellulose digestibility and one-pot hydrolysis
Wahlström, R., Hiltunen, J., Sirkka, M. P. D. S. N., Vuoti, S., & Kruus, K. (2016) · RSC Advances · doi:10.1039/c6ra11719h · Cited by 79
Subcritical water extraction enhancement by adding deep eutectic solvent for extracting xanthone from mangosteen pericarps
Machmudah, S., Lestari, S. D., Widiyastuti, Wahyudiono, Kanda, H., Winardi, S., & Goto, M. (2018) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2017.06.012 · Cited by 79
Highly Efficient Extraction of Antioxidant Polyphenols from Olea europaea Leaves Using an Eco-friendly Glycerol/Glycine Deep Eutectic Solvent
Athanasiadis, V., Grigorakis, S., Lalas, S. I., & Makris, D. P. (2017) · Waste and Biomass Valorization · doi:10.1007/s12649-017-9997-7 · Cited by 79
Hydrothermal liquefaction of de-oiled Jatropha curcas cake using Deep Eutectic Solvents (DESs) as catalysts and co-solvents
Alhassan, Y., Kumar, N. R., & Bugaje, I. M. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2015.07.116 · Cited by 77
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5 of the 247 references couldn’t be matched to a known paper.

Research works printed but not linked: 2

Tan, 2013, Synthesis of polypyrrole/cellulose composites in ionic liquids, Appl. Polym. Compos., 1, 125
Wang, 2018, Deep eutectic solvent-based microwave-assisted extraction of maicalin from scutellaria baicalensis georgi, J. Chem., 223, 3233

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The peculiar effect of water on ionic liquids and deep eutectic solvents
Ma, C., Laaksonen, A., Liu, C., Lü, X., & Ji, X. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00325d · Cited by 606
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Authors: Kalhor, P., & Ghandi, K.
Affiliations: Tsinghua University (CN)
University of Guelph (CA)
Corresponding author: Ghandi, Khashayar
ORCID: Kalhor, Payam
Ghandi, Khashayar
Venue: Molecules
Publisher: MDPI AG
Published: 2019-11-06
Volume: 24
Issue: 22
Pages: 4012
ISSN: 1420-3049 (ISSN-L)
DOI: 10.3390/molecules24224012
PMC: PMC6891572
OpenAlex: W2983067886
Cited by: 305
References: 247
Citations by year: 2026: 35 · 2025: 49 · 2024: 51 · 2023: 51 · 2022: 54 · 2021: 40 · 2020: 24
FWCI: 1.34
Type: journal article
Language: en
Open access: gold
dx.doi.org
Licence: cc-by
creativecommons.org/licenses/by/4.0/ (vor)
Locations: Molecules (publishedVersion, cc-by)
Europe PMC (PubMed Central) (publishedVersion, cc-by)
PubMed Central (publishedVersion, cc-by)
PubMed (publishedVersion)
DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders: Natural Sciences and Engineering Research Council of Canada (NA)
Topics: Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
Physical Sciences › Chemical Engineering › Catalysis › Catalysis for Biomass Conversion
Keywords: deep eutectic solvents, natural deep eutectic solvents, lignocellulosic biomass, food waste, biomass pretreatment, extraction, catalysis, biomass waste valorization, bioenergy conversion, green solvents
MeSH terms: Catalysis, Food, Lignin, Models, Molecular, Refuse Disposal, Solvents, Molecular Structure, Biomass, Chemical Phenomena

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Deep Eutectic Solvents for Pretreatment, Extraction, and Catalysis of Biomass and Food Waste

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