The DOI matches its Crossref record; 120 of the 121 references it cites were found in a registry or an index; 23 of the 162 sources its claims cite were checked for support.
Chromium Remediation from Tannery Wastewater in Arequipa, Peru: Local Experiences and Prospects for Sustainable Solutions
Open accessAbstract
The release of tannery wastewater contributes to chromium (Cr) pollution globally. Herein, we conduct a novel consolidation of research from the Arequipa region of southern Peru that integrates university theses written in Spanish alongside peer-reviewed journal articles. The objective is to provide a place-based complement to existing research in English scientific journals focused on effective tools for Cr treatment from tannery wastewater. Our consolidation categorized a total of 75 publications (70 theses and five peer-reviewed) into five distinct strategies for Cr treatment: adsorption (twenty-three studies), phytoremediation (eighteen studies), bioremediation (thirteen studies), electrocoagulation (five studies), and other techniques (fifteen studies). This synthesis highlighted potentially promising approaches that could be sustainably tailored to regional resources and waste products. This includes sorptive materials derived from food waste such as native achiote peels (B. orellana) and avocado seeds (P. americana) either used directly or as a feedstock for biochar. Other technologies include phytoremediation using microalgae and resident vascular plants and microbial bioremediation that capitalizes on indigenous bacteria and fungi. Promise was also discerned in studies that incorporated a combination of abiotic and biotic mechanisms tailored toward the region, such as infiltration using selective and bioactive materials, wetlands, solar distillation, iron-based coagulation and flocculation, and bioreactors. These findings provide a sustainable complement to prior global investigations for effective attenuation strategies by adding novel materials and techniques that could be further explored to assess the viability of implementation at pilot and larger scales. These promising technologies and the ability to tailor sustainable treatments toward local resources highlight the opportunity to prioritize the treatment of tannery wastewater to ensure a cleaner environment by informing policy makers, academics, and industry on technologies that could be adopted for implementation in the region.
Overview
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Written from the paper’s full text.
TL;DR
This place-based synthesis consolidates 75 publications (70 Spanish-language theses and five peer-reviewed articles) on chromium removal from tannery wastewater in the Arequipa region of southern Peru, categorizing them into five treatment strategies. It identifies locally available, waste-derived sorbents and nature-based approaches as promising, sustainable options while noting that inconsistent reporting prevents direct comparison of removal efficiencies.
Key findings
- Of 75 publications, strategies broke down as adsorption (23 studies), phytoremediation (18), bioremediation (13), electrocoagulation (5), and other techniques (15); 38 experiments targeted total Cr (CrT), 48 targeted Cr(VI), and 12 targeted Cr(III) (98 experiments total, as some studied more than one species).
- Reported removals included ~98% Cr(VI) by the macrophyte *I. cernua* in 5 days, 99% Cr(VI) by olive seed in 30 min, Cr(VI) to below detection by achiote peel in 5 min and avocado seed in 15 min, 89% total Cr (34.8 to 3.82 mg/L) by *C. aquaticus*, 96% Cr(III) by *Penicillium* sp. (99% when combined with microalgae, zeolite, and activated carbon), and 99% CrT by a bio-sand filter in 46 min.
- Adsorption results trended toward greater effectiveness under acidic conditions (pH 1.1–6; R² = 0.99 for CrT, 0.50 for Cr(VI), 0.99 for Cr(III)), whereas infiltration-type studies trended toward higher efficiency at higher pH (R² = 0.20 for Cr(VI), 0.94 for CrT).
- Field context: the April 2023 RSIP effluent averaged above 10 mg/L total Cr at an estimated 31 L/s, exceeding Peru's 0.5 mg/L MCL for total Cr (and 0.1 mg/L for Cr(VI)); sediments at RSIP and the Aashuayco Ravine ranged 3750–9220 mg/kg against a 1000 mg/kg MCL.
Methods
- Design: a novel consolidation of regional research integrating Spanish-language university theses with peer-reviewed journal articles, intended as a place-based complement to English-language global reviews.
- Data: 75 publications (70 theses — 9 graduate, 61 undergraduate — and five peer-reviewed articles) on Cr removal from tannery wastewater in Arequipa, identified through Google Scholar, Scopus, and Web of Science; theses came largely from Chemistry/Chemical Engineering (21%) and Environmental Engineering (25%), followed by Biology (15%), Biotechnology (11%), and Pharmacy (8%).
- Analysis: studies were categorized into five treatment groups, with removal percentages, pH, temperature, treatment time, and particle size tabulated and compared qualitatively and via regression against pH; a field visit to RSIP effluent was conducted in April 2023.
Limitations
- Stated by the paper: there was no consistent approach across studies regarding pH, temperature, or treatment time, making direct comparisons of removal efficiency and rates challenging; authors preferred reporting percent removal rather than mass-normalized units (e.g., mg/kg) or adsorption isotherms, hindering global benchmarking; only six phytoremediation studies documented both Cr removal and pH; the small number of electrocoagulation studies (five) made pH patterns hard to discern; and 2023–2024 publications (four and one, respectively) were not formally tallied due to lag between thesis completion and repository availability.
- Evident from the text: several key results rest on single studies or small numbers of theses, many of which are not peer-reviewed; costs of transporting and applying waste-derived sorbents are "currently unknown"; and the synthesis is region-specific, so the authors frame findings as trajectories for further pilot-scale testing rather than demonstrated implementations.
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Claims the paper makes
23 of 162 cited sources checked · 6 supported · 1 flagged · accuracy not yet measured
- Premisecitation
When not properly treated, the discharge of tannery wastewater results in elevated levels of Cr in the receiving waters.
“When not properly treated, the discharge of tannery wastewater results in elevated levels of Cr in the receiving waters [3].”
Quote in the paperSubstantial claim1 of 1 sources checked- cites [3] Ghezzi, L., Mugnaioli, E., Perchiazzi, N., Duce, C., Pelosi, C., Zamponi, E., Pollastri, S., Campanella, B., Onor, M., and Abdellatief, M. (2023). Hexavalent chromium release over time from a pyrolyzed Cr-bearing tannery sludge. Sci. Rep., 13. source
The Introduction states that excess chromium remains in tanning liquor and is usually removed by treatment. It does not say that discharge of inadequately treated tannery wastewater raises chromium levels in receiving waters; the paper studies chromium release from treated sludge instead. No page numbers are available in our copy. (LLM, conf=0.79)
Experimental — accuracy not yet measured
- Premisecitation
Source waters in a tributary to the Chili River that transits through RSIP exceeded Peru's maximum contaminant limit of 0.5 mg/L for total Cr.
“These source waters exceeded Peru's maximum contaminant limits (MCLs) of 0.5 mg/L [34], which were established for surface water effluents from industrial sectors such as materials manufacturing, beverage industries, and tanneries.”
Quote in the paperSubstantial claim1 of 3 sources checked- cites [29] 2017, Estudio de la contaminación por cromo (Cr) en el río Chili y Parque Industrial Río Seco (PIRS), Arequipa, Perú. 2015–2016, Veritas
- cites [33] Tejada-Meza, K., Arenazas-Rodríguez, A., Garcia-Chevesich, P.A., Flores-Farfan, C., Morales-Paredes, L., Romero-Mariscal, G., Ticona-Quea, J., Vanzin, G., and Sharp, J.O. (2023). Acute Ecotoxicity Potential of Untreated Tannery Wastewater Release in Arequipa, Southern Peru. Sustainability, 15. source
Section 4.1 reports 10.4 ± 0.4 mg/L total chromium in the sampled RSIP effluent and says it exceeds Peru’s maximum admissible concentration. The Abstract identifies the receiving creek as a tributary of the Chili River. The paper does not establish a 0.5 mg/L limit or report that chromium in the tributary’s source waters, rather than the sampled effluent, exceeded it. (LLM, conf=0.86)
Experimental — accuracy not yet measured - cites [34] (2025, January 22). DS 010-2023-MINAM. [Ministerio del Medio Ambiente] Aprueban los Límites Máximos Permisibles para Efluentes de las Actividades de Curtido y Adobo de Cuero, Así Como Adobo y Teñido de Pieles. Available online: https://www.gob.pe/institucion/minam/normas-legales/4561259-010-2023-minam.
- Premisecitation
Tejada-Meza et al.'s findings on adverse effects of RSIP's tannery wastewaters on bioindicator species reinforce concerns about Cr pollution.
“Tejada-Meza et al.'s [33] recent findings on the adverse effects of RSIP's tannery wastewaters on bioindicator species reinforce these concerns.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites [33] Tejada-Meza, K., Arenazas-Rodríguez, A., Garcia-Chevesich, P.A., Flores-Farfan, C., Morales-Paredes, L., Romero-Mariscal, G., Ticona-Quea, J., Vanzin, G., and Sharp, J.O. (2023). Acute Ecotoxicity Potential of Untreated Tannery Wastewater Release in Arequipa, Southern Peru. Sustainability, 15. source
- Premisecitation
Bejarano-Meza et al. used magnetic iron-based nanoparticles synthesized with O. europea bone extract to remove nearly all detectable Cr(VI) from RSIP's tannery effluents.
“Finally, Bejarano-Meza et al. [45] used magnetic iron-based nanoparticles synthesized with O. europea bone extract to remove nearly all detectable Cr(VI) from RSIP's tannery effluents.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites [45] Bejarano-Meza, M., Deza-Carrasco, F.E., Salinas-Herrera, S., Flores-Calla, S., and Jimenez-Pacheco, H.G. (2024). Evaluation of Cr(VI) Removal from Tanning Effluents Using Magnetic Nanoparticles of Fe3O4 Synthesized with Olea europaea Bone Extract. Molecules, 29. source
The Experimental Procedure (§3.1) says the effluent samples came from a tannery in Río Seco Industrial Park. The Introduction describes synthesis using Olea europaea bone extract, and Results (§2.4) reports Cr(VI) removal of 85% from tanning effluent and 100% from retanning effluent. Thus, “nearly all” overstates the result for the tanning sample. (LLM, conf=0.84)
Experimental — accuracy not yet measured
- Findingcitation
The locally cultivated microalga species D. quadricauda was not previously documented in the international literature for Cr removal from tannery wastewater.
“The locally cultivated microalga species D. quadricauda [67] was not previously documented in the international literature for this application, as summarized in the literature review on microalgal applications toward contaminant remediation by Jácome-Pilco et al. [164].”
Quote in the paperNot a substantial claim1 of 2 sources checked- cites [67] Paredes Arenazas, W.G. (2021). Determinación de la Bioabsorción de Cromo VI de Efluentes del Parque Industrial de Rio Seco (PIRS) Mediante la Microalga Desmodesmus quadricauda. [Bachelor’s Thesis, Universidad Católica Santa María].
- cites [164] Ballesteros, 2021, Microalgas en el tratamiento de aguas residuales generadas en industrias de curtiembres, Ciencia y Tecnología source
The sections “Géneros y especies de microalgas en la industria de curtiembres” and “Remoción de cromo hexavalente y total (Cr)” discuss other microalgae used for chromium removal, but do not mention D. quadricauda. Searches for its name and for a statement that its use was previously undocumented found no such passage. A review’s omission of a species does not establish its absence from the international literature; page numbers were not available in our copy. (LLM, conf=0.72)
Experimental — accuracy not yet measured
- Premisecitation
Tanning industries (such as those operating in RSIP in Arequipa) generate effluents that can have highly variable pH values (between 2 and 9) due to the chemical processes involved in transforming animal hides into leather, which include the use of acids, bases, and other chemicals.
“Tanning industries (such as those operating in RSIP in Arequipa) generate effluents that can have highly variable pH values (between 2 and 9) due to the chemical processes involved in transforming animal hides into leather, which include the use of acids, bases, and other chemicals [124].”
Quote in the paperSubstantial claim1 of 1 sources checked- cites [124] Bhardwaj, 2023, Tannery effluent treatment and its environmental impact: A review of current practices and emerging technologies, Water Qual. Res. J. source
Split into 2 atoms — 1 confirmed, 1 partially supported, 0 disputed, 0 misattributed, 0 unverifiable. Expand the claim to see per-atom verdicts.
Experimental — accuracy not yet measured
- Premisecitation
Treatment with magnetite nanoparticles achieved below detection (BD) removal of Cr(VI) at pH not reported, 3 weeks [100].
“| Cr(VI) | Magnetite nanoparticles | BD | NA | NA | 3 weeks | [100] |”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites [100] Ruiz Marcelo, M. (2018). Eficiencia de Nanopartículas de Magnetita en la Reducción del Cromo Hexavalente a Cromo Trivalente en el Suelo del Parque Industrial de Río Seco (PIRS), Cerro Colorado–Arequipa. [Bachelor’s Thesis, Universidad Cesar Vallejo]. source
The Abstract reports that magnetite nanoparticles reduced Cr(VI) in soil over three weeks. It reports efficiencies of 99.93–99.96% for the most effective treatment, but does not say the final Cr(VI) concentrations were below detection; that part of the table entry is unsupported. (LLM, conf=0.87)
Experimental — accuracy not yet measured
- Findingown data
A large portion of the theses came from the faculties of Chemistry and Chemical Engineering (21%) and Environmental Engineering (25%), followed by Biology (15%), Biotechnology (11%), and Pharmacy (8%).
“A large portion of the theses came from the faculties of Chemistry and Chemical Engineering (21%) and Environmental Engineering (25%), followed by Biology (15%), Biotechnology (11%), and Pharmacy (8%).”
Quote in the paperNot a substantial claim - Findingown data
Various plant adsorbents with porous sizes ranging from 75 to 350 μm were found with capacities to absorb Cr.
“In terms of adsorption techniques, various plant adsorbents (leaves, fruits, seeds, tubers, shells, etc.) with a variety of porous sizes ranging from 75 to 350 µm were found with the capacities to absorb Cr.”
Quote in the paperNot a substantial claim - Findingreasoning
Promising results (at least 95% removal) were obtained using materials such as sawdust, Peruvian potatoes, corn crown, rice peel, and olive pits.
“Promising results (at least 95% removal) were obtained using materials such as sawdust, Peruvian potatoes, corn crown, rice peel, and olive pits (see Table 2).”
Quote in the paperSubstantial claim - Findingown data
Numerous techniques to remove or remediate residual Cr content of tannery wastewaters were found in this synthesis, categorized into five main groups: adsorption, phytoremediation, bioremediation, electrocoagulation, and other methods.
“Numerous techniques to remove or remediate the residual Cr content of tannery wastewaters were found in this synthesis.These techniques were categorized into five main groups: adsorption, phytoremediation, bioremediation, electrocoagulation, and a catch-all collection of other methods.”
Quote in the paperSubstantial claim - Findingown data
There are 70 Spanish-written theses (9 graduate, 61 undergraduate) focusing on Cr removal in the Arequipa Region.
“There is however a wealth of additional knowledge contained within 70 Spanish-written graduate (9) or undergraduate (61) theses focusing on Cr removal in the Arequipa Region.”
Quote in the paperSubstantial claim - Findingnone given
Alvarez and Vilca obtained their results in a shorter time (only five minutes), compared to the rest of the electrocoagulation experiments.
“However, the authors obtained their results in a shorter time (only five minutes), compared to the rest of the experiments.”
Quote in the paperNot a substantial claim - Findingown data
The extent of Cr removal in adsorption studies ranged from a low of 12% (lemon pectin) to removal rendering Cr non-detectable (achiote peel, avocado seed, and pea pods).
“The extent of removal ranged from a low of 12% (lemon pectin) to removal rendering Cr non-detectable (achiote peel, avocado seed, and pea pods).”
Quote in the paperNot a substantial claim - Findingown data
A total of 13 studies focused on microbial bioremediation (fungi and bacteria) for the treatment of Cr species from tannery wastewaters were found in Arequipa.
“A total of 13 studies focused on microbial bioremediation (fungi and bacteria) for the treatment of Cr species from tannery wastewaters were found in Arequipa (Table 4a,b).”
Quote in the paperNot a substantial claim - Findingcitation
Considering only studies with sufficient additional information beyond removal extent, particularly promising results were obtained using infiltration approaches.
“Considering only studies with sufficient additional information beyond removal extent, and besides the already mentioned peer-review studies done by Herrera-Yari et al. [43] and Bejarano-Meza et al. [45], particularly promising results were obtained using infiltration approaches.”
Quote in the paperNot a substantial claim - Findingnone given
There was no consistent approach across studies regarding key parameters such as pH, temperature, or treatment time.
“Notably, there was no consistent approach across studies regarding key parameters such as pH, temperature, or treatment time.”
Quote in the paperSubstantial claim - Findingnone given
A total of 18 phytoremediation-associated studies were found for the Arequipa Region.
“A total of 18 phytoremediation-associated studies were found for the Arequipa Region.”
Quote in the paperNot a substantial claim - Findingreasoning
A clear correlation between Cr removal species and pH was harder to discern in bioremediation studies because of the limited number of experiments documenting both variables and a presumed requisite of appropriate and likely circumneutral pH constraints for effective microbial growth.
“Unlike in the sorptive studies, a clear correlation between Cr removal species and pH was harder to discern because of the limited number of experiments documenting both variables and a presumed requisite of appropriate and likely circumneutral pH constraints for effective microbial growth.”
Quote in the paperNot a substantial claim - Findingown data
Five studies in the Arequipa Region evaluated electrocoagulation, applying electrical current with voltages between 0 and 40 volts and intensities between 0 and 60 amps to treat different Cr species from tannery wastewaters.
“Five studies in the Arequipa Region evaluated electrocoagulation (see Table 5), in which the authors applied electrical current with voltages between 0 and 40 volts and intensities between 0 and 60 amps to treat different Cr species from tannery wastewaters.”
Quote in the paperNot a substantial claim - Findingcitation
Near-complete removal of Cr was obtained using a system approach that integrated fungi with adsorption-based technologies.
“Near-complete removal of Cr was also obtained using a system approach that integrated fungi with adsorption-based technologies (Table 4b).”
Quote in the paperNot a substantial claim - Findingnone given
A total of 23 publications focused on the application of different absorbents to remove Cr from tannery wastewaters were found in the Arequipa Region.
“A total of 23 publications focused on the application of different absorbents to remove Cr from tannery wastewaters were found in the Arequipa Region.”
Quote in the paperNot a substantial claim - Findingcitation
Rojas used diatoms in wetlands to obtain 125 mg/g Cr removal in Arequipa.
“Similarly, Rojas [107] used diatoms in wetlands to obtain an impressive 125 mg/g Cr removal in Arequipa.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [107] Rojas Tamata, K. (2016). Remoción de arsénico (V) y Cromo (VI) Presente en Lechos Acuáticos Mediante el Uso de Tierra de Diatomeas Recubierta con Sales de Hierro. [Master’s Thesis, Universidad Católica Santa María].
- Findingcitation
Laura and Salinas applied aluminum electrodes to remove all Cr species to below detection limits from tannery wastewater in only 30 min.
“A highlight was led by Laura and Salinas [95], who applied aluminum electrodes (locally the most common method) to remove all Cr species to below detection limits from tannery wastewater in only 30 min.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [95] Laura Benavides, S.L., and Salinas Rondon, J.O. (2020). Eficiencia en la Remoción del Contenido de Cromo III por Electrocoagulación en Las Aguas Residuales de Curtiembre del Parque Industrial de Río Seco. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Findingcitation
Another effective waste product identified in this synthesis is olive seed.
“Another effective waste product identified in this synthesis is olive seed.”
Quote in the paperNot a substantial claim - Findingreasoning
Our synthesis adds locally abundant freshwater river shrimp (P.serratus) to the body of knowledge on shrimp carapace waste material for metal removal.
“Though shrimp carapace waste material has been studied for metal removal in India and Saudi Arabia [149,150], our synthesis adds locally abundant freshwater river shrimp (P.serratus) to this body of knowledge.”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [149] Arulkumar, 2012, Rapid removal of chromium from aqueous solution using novel prawn shell activated carbon, Chem. Eng. J. source
- cites [150] Elwakeel, 2018, Efficient retention of Chromate from industrial wastewater onto a green magnetic polymer based on shrimp peels, J. Polym. Environ. source
- Findingnone given
The Arequipa studies identified other vascular plant species not previously studied for Cr removal from tannery wastewaters, including Buddleja sp., I. cernua, N. aquaticum, H. macrophylla, C. murale, E. montevidensis, B. salicifolia, T. integrifolia, C. ruizianus, and I. cernua.
“The Arequipa studies identified other vascular plant species not previously studied for Cr removal from tannery wastewaters, including Buddleja sp., I. cernua, N. aquaticum, H. macrophylla, C. murale, E. montevidensis, B. salicifolia, T. integrifolia, C. ruizianus, and I. cernua.”
Quote in the paperNot a substantial claim - Findingown data
Analogous variability was confirmed in our place-based analysis across sites in the region.
“Analogous variability was confirmed in our place-based analysis across sites in the region.”
Quote in the paperSubstantial claim - Findingcitation
The results collectively suggest that more acidic waters tend to eliminate more Cr (in all forms) during sorption applications.
“As previously discussed in Section 3.1 and depicted in Figure 4, the results collectively suggest that more acidic waters tend to eliminate more Cr (in all forms) during sorption applications, agreeing with studies developed for wastewaters in other parts of the world [132].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [132] Anah, 2017, Influence of pH on Cr(VI) ions removal from aqueous solutions using carboxymethyl cellulose-based hydrogel as adsorbent: IOP conference series, Earth Environ. Sci.
- Findingown data
In this literature review, a total of 75 studies (70 theses and five peer-reviewed, most in Spanish) evaluating different techniques to remove Cr species from polluted tannery wastewaters were found for the Arequipa Region.
“In this literature review, a total of 75 (70 theses and five peer-reviewed, most of them in Spanish) studies evaluating different techniques to remove Cr species from polluted tannery wastewaters were found for the Arequipa Region.”
Quote in the paperSubstantial claim - Findingnone given
Numerous studies identified in this synthesis were able to remove the majority of detectable Cr from polluted tannery wastewater.
“Numerous studies identified in this synthesis were able to remove the majority of detectable Cr from polluted tannery wastewater.”
Quote in the paperSubstantial claim - Findingreasoning
Promising place-based solutions included adsorption materials originated from local food waste, such as native achiote peels (B.orellana) and avocado seeds (P.americana).
“Promising place-based solutions included adsorption materials originated from local food waste, such as native achiote peels (B.orellana) and avocado seeds (P.americana).”
Quote in the paperSubstantial claim - Findingown data
Most of the surveyed experiments employing electrocoagulation resulted in nearly complete Cr removal.
“Most of the surveyed experiments employing electrocoagulation resulted in nearly complete Cr removal (Table 5).”
Quote in the paperNot a substantial claim - Findingown data
Our local place-based synthesis identified adsorption materials not previously described in the Peruvian and international literature, such as Arequipan papaya seed, sancayo cacti peel, Peruvian potato varieties, and quinoa.
“Our local place-based synthesis identified adsorption materials not previously described in the Peruvian and international literature, such as Arequipan papaya seed, sancayo cacti peel, Peruvian potato varieties, and quinoa (see Table 2).”
Quote in the paperSubstantial claim - Findingreasoning
A direct comparison is hindered by the preference of Arequipa authors to express their results in terms of percent removal as opposed to benchmarks against material mass and the establishment of adsorption isotherms, making it difficult to develop a global comparative analysis.
“A direct comparison is unfortunately hindered by the preference of Arequipa authors to express their results in terms of percent removal as opposed to benchmarks against material mass (e.g., mg/kg) and the establishment of adsorption isotherms, making it difficult to develop a global comparative analysis.”
Quote in the paperSubstantial claim - Findingcitation
Achiote peels and avocado seeds were particularly promising in terms of percent removal and time.
“Achiote peels [50] and avocado seeds [51] were particularly promising in terms of percent removal and time.”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [50] Martinez Ocsa, S.K., and Quispe Roa, Y.M. (2020). Estudio Cinético de la Remoción de Cr+6 de Aguas Usando Cáscara de Achiote. [Bachelor’s Thesis, Universidad Privada Autónoma del Sur].
- cites [51] Mollinedo Chávez, A.M., and Huanca Quispe, A. (2021). Adsorción de Cromo Hexavalente de Lechos Acuáticos Utilizando Biomasa de Pepa de Palta (Persea americana mill). [Bachelor’s Thesis, Universidad María Auxiliadora].
- Findingown data
The most promising adsorption results (>95% removal) in Arequipa were documented for plant materials (achiote peels, avocado seed, pea pods, sawdust, potatoes, corn crown and rice peel, and olive pits) that are present and, in most cases, waste products in the Arequipa Region.
“With the caveat of limited context to establish isotherms and equilibrium kinetics, the most promising adsorption results (>95% removal) were documented for plant materials (achiote peels, avocado seed, pea pods, sawdust, potatoes, corn crown and rice peel, and olive pits) that are present and, in most cases, waste products in the Arequipa Region of southern Peru (see Table 2 for details).”
Quote in the paperSubstantial claim - Premisecitation
The leather tanning process relies heavily on Cr salts.
“An example of industrial release is the leather tanning process [2], which relies heavily on Cr salts.”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [2] Arti, 2023, Analysis of heavy metals and toxicity level in the tannery effluent and the environs, Environ. Monit. Assess. source
- Premisenone given
The mobility and toxicological impact of Cr is influenced by the oxidation state.
“The mobility and toxicological impact of Cr is influenced by the oxidation state.”
Quote in the paperSubstantial claim - Interpretationreasoning
Microbial reduction of Cr(IV) to Cr(III), potentially in association with the respiration of other electron acceptors such as sulfate, seemed particularly promising.
“While mechanisms may also include bioaccumulation and sorption, microbial reduction of Cr(IV) to Cr(III), potentially in association of the respiration of other electron acceptors such as sulfate, seemed particularly promising.”
Quote in the paperSubstantial claim - Premisecitation
Leguía and Puma used a bio-sand filter to remove 99% of CrT in 46 min.
“For example, Leguía and Puma [104] used a bio-sand filter to remove 99% of CrT in 46 min.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [104] Leguía, J., and Puma, P. (2016). Diseño de Filtros de Bioarena para Remover Metales Pesados (As, Cd, Cr, Pb y Fe) en Aguas de Uso Doméstico. [Bachelor’s Thesis, Universidad Nacional de San Agustín].
- Premisecitation
Solis treated RSIP's tannery wastewater with the fungus Penicillium sp. (2.2 g/L) under completely mixed conditions to remove 96% of Cr(III).
“Solis [90] treated RSIP's tannery wastewater with the fungus Penicillium sp.(2.2 g/L) under completely mixed conditions to remove 96% of Cr(III).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [90] Solis Pareja, C. (2020). Estrategias Basadas en Producción Más Limpia y Biorremediación para Mitigar Los Impactos Ambientales Negativos Generados Por Los Efluentes Industriales de las Curtiembres del Parque Industrial de Río Seco. [Bachelor’s Thesis, Universidad Nacional de San Agustin de Arequipa].
- Premisecitation
I. cernua was particularly promising, with 98% removal of Cr(VI) in only 5 days.
“Of these, I. cernua was particularly promising, with 98% removal of Cr(VI) in only 5 days [42].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [42] Zapana, 2020, Treatment of tannery wastewater in a pilot scale hybrid constructed wetland system in Arequipa, Peru, Int. J. Environ. Sci. Technol. source
- Premisecitation
Paz removed total Cr to below detection in 16 h using pea pods.
“for example, Paz [52] removed total Cr (CrT) to BD in 16 h using pea pods.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [52] Paz Corrales, O.A. (2020). Biorremoción de Cromo Total en Los Efluentes de Curtiembres, Empleando Vainas de Arvejas Pisum sativum L. Para Obtener Agua Categoría 3D2DS 004-2017 MINAM. en Arequipa. [Ph.D. Thesis, Universidad Nacional de San Agustín de Arequipa].
- Interpretationreasoning
When compared to international efforts, the techniques applied in Arequipa to remove Cr species from tannery wastewaters feature place-based adaptations that could be applied sustainably in the region.
“When compared to these international efforts, the techniques applied in Arequipa to remove Cr species from tannery wastewaters feature place-based adaptations that could be applied sustainably in the region.”
Quote in the paperSubstantial claim - Premisecitation
Vilca and Gordillo found Cr-associated sediments in Arequipa's RSIP and the Aashuayco Ravine well in excess of the 1000 mg/kg Peruvian MCL.
“Similarly, Vilca and Gordillo [30] investigated Arequipa's RSIP and the Aashuayco Ravine for a period of three months, finding Cr associated sediments that were well in excess of the 1000 mg/kg Peruvian MCL [35].”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [30] Vilca Castro, F., and Gordillo Vilca, Y.B. (2016). Retención de Metales Pesados en Suelos y su Impacto Ambiental: Caso Aguas Residuales–Parque Industrial Río Seco. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- cites [35] (2025, January 22). DS011-2017-MINAM [Ministerio del Medio Ambiente] Aprueban Estándares de Calidad Ambiental (ECA) para Suelo. Available online: https://www.minam.gob.pe/disposiciones/decreto-supremo-n-011-2017-minam/.
- Premisecitation
Huillca used a wetland system colonized with the plant species E. montevidensis to remove Cr from polluted waters, with a bioaccumulation factor of 13.9 and 22.0 through aerial and root systems, respectively.
“Similar to the study already mentioned by Almiron et al. [41], Huillca [78] used a wetland system colonized with the plant species E. montevidensis to remove Cr from polluted waters, with a bioaccumulation factor of 13.9 and 22.0 through aerial and root systems, respectively.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [78] Huillca Mayta, D.A. (2024, October 03). Evaluación de la Capacidad Fitorremediadora de Cromo a Diferentes Concentraciones por Eleocharis montevidensis, Empleando Sistemas de Humedales Artificiales. Available online: https://hdl.handle.net/20.500.12692/74810.
- Premisecitation
When further combined with the microalga Acutodesmus dismorphus, zeolite, and activated carbon, the system achieved 99% removal.
“When further combined with the microalga Acutodesmus dismorphus, zeolite, and activated carbon, the system achieved 99% removal.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [90] Solis Pareja, C. (2020). Estrategias Basadas en Producción Más Limpia y Biorremediación para Mitigar Los Impactos Ambientales Negativos Generados Por Los Efluentes Industriales de las Curtiembres del Parque Industrial de Río Seco. [Bachelor’s Thesis, Universidad Nacional de San Agustin de Arequipa].
- Interpretationreasoning
Direct comparisons of Cr removal efficiency and rates are challenging due to inconsistent approaches across studies.
“As a result, direct comparisons of Cr removal efficiency and rates are challenging.”
Quote in the paperSubstantial claim - Interpretationreasoning
The results suggest that large amounts of Cr can be removed in short periods by adsorption.
“The results suggest that large amounts of Cr can be removed in short periods.”
Quote in the paperSubstantial claim - Interpretationreasoning
This synthesis supports a trend toward more effective sorption under acidic conditions.
“this synthesis supports a trend toward more effective sorption under acidic conditions.”
Quote in the paperSubstantial claim - Interpretationreasoning
Considering both treatment times and Cr elimination, adsorption is feasible for large-scale projects.
“Moreover, considering both treatment times and Cr elimination, adsorption is feasible for large-scale projects.”
Quote in the paperSubstantial claim - Premisecitation
Moran and Luque reported some degree of Cr pollution in the Chili River, which crosses the city of Arequipa.
“Both Moran [27] and Luque [28] reported some degree of Cr pollution in the Chili River, which crosses the city of Arequipa.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [27] Moran Medina, K.L. (2021). Comportamiento de la Concentración de Metales Pesados y Su Influencia en la Calidad del Agua, Parte Baja del Río Chili Arequipa 2017–2019. [Master’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- cites [28] Luque Zurita, D.S. (2020). Determinación de la Remanencia de Contaminación por Cromo en el Río Chili, Arequipa–Perú. [Ph.D. Thesis, Universidad Nacional de San Agustín].
- Interpretationreasoning
The average total Cr content in the RSIP effluent exceeded the Peruvian MCL of 0.5 mg/L for total Cr.
“While lower than the values reported by Aboulhassan et al. [36] in wastewaters from Moroccan tanneries, this exceeded the Peruvian MCL of 0.5 mg/L for total Cr.”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [36] Aboulhassan, 2008, Tannery effluents characterization and impacts on the marine environment, Revue des Sciences de L’eau source
- Premisecitation
Peru has documented anthropogenically sourced Cr contamination in surface water rivers throughout the country.
“The country of Peru is a clear example of documented anthropogenically sourced Cr contamination, with an unfortunate wealth of studies that have reported surface water pollution in rivers situated throughout the country (Table 1).”
Quote in the paperNot a substantial claim - Premisecitation
Herrera-Yari et al. used a solar parabolic cylindrical concentrator on synthetic RSIP tannery effluents, reducing 173 mg/L Cr(VI) to ~26 mg/L Cr(VI) (85%) to less toxic Cr(III) through photocatalytic degradation.
“Another investigation, Herrera-Yari et al. [43], used a solar parabolic cylindrical concentrator on synthetic RSIP tannery effluents, reducing 173 mg/L Cr(VI) to ~26 mg/L Cr(VI) (i.e., 85%) to less toxic Cr(III) through photocatalytic degradation.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [43] 2021, Determination of the parameters for photocatalytic degradation from Chromium hexavalent to Chromium trivalent in a solar parabolic cylindrical concentrator in a simulated sample from tanning, Environ. Technol. Innov. source
- Premisecitation
89% of Cr(VI) was removed using the bacterium P. mirabilis.
“Similarly, 89% of Cr(VI) was removed using the bacterium P. mirabilis [86].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [86] Chambi Mamani, C. (2021). Aislamiento e Identificación de Cepas Bacterianas Aisladas de Sitios Contaminados Con Efluentes de Curtiduría y Su Capacidad para Reducir CR (VI). [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Premisecitation
Lemon pectine (Citrus limon) achieved 12% removal of total chromium (CrT) at pH 5, room temperature, 15 min, particle size 180-250 μm [53].
“| Lemon pectine (Citrus limon) * | CrT | 12 | NA | 5 | RT | 15 | 180-250 µm | [53] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [53] Laura Ticona, V.E. (2018). Estudio de la Determinación de la Actividad Floculante en Aguas Provenientes del Río Chili Conteniendo As, Pb y Cr Tratados con Pectina Obtenidos a Partir de la Cáscara de Naranja, Limón y Mandarina. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Interpretationreasoning
Some adsorption results listed in Table 2 appear to be competitive with other Peruvian and international studies that have focused on testing different materials to remove Cr from tannery wastewaters using adsorption-based approaches.
“Despite the limitations of the units previously discussed and in considering the available information (i.e., % removal most commonly), some results listed in Table 2 appear to be competitive with other Peruvian and international studies that have focused on testing different materials to remove Cr from tannery wastewaters using adsorption-based approaches.”
Quote in the paperSubstantial claim - Premisecitation
Corn crown (Zea mays) and rice husk (Oryza sativa) achieved 95% removal of Cr(VI) at pH 2, room temperature, 30 min, particle size less than 0.42 mm [48].
“| Corn crown (Zea mays) and rice husk (Oryza sativa) * | Cr(VI) | 95 | NA | 2 | RT | 30 | Less than 0.42 mm | [48] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [48] Pacheco Portugal, J.D. (2019). Evaluación el Proceso de Biosorción de Cr (VI) Usando Residuos Agroindustriales de la Región Arequipa Cascarilla de Arroz y Chala de Maíz. [Bachelor’s Thesis, Universidad Católica de Santa María].
- Premisecitation
Olive fruit (Olea europaea) achieved 78% removal of Cr(VI) at pH 2 to 6, room temperature, with no reported time, particle size 250 μm [62].
“| Olive fruit (Olea europaea) | Cr(VI) | 78 | NA | 2 to 6 | RT | NA | 250 µm | [62] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [62] 2017, Evaluación de residuos agroindustriales como biofiltros: Remoción de cr (vi) en efluentes de curtiembres sintéticos, Biotecnología en el Sector Agropecuario y Agroindustrial
- Premisecitation
Coffee seed's endocarp (Coffea arabica) achieved 94% removal of Cr(VI) at pH 2, room temperature, 120 min, particle size 75-150 μm [58].
“| Coffee seed's endocarp (Coffea arabica) * Cr(VI) | 94 | NA | 2 | RT | 120 | 75-150 µm | [58] | |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [58] Apaza Amanqui, J.A., and Toribio Villanueva, I. (2019). Alternativa de Remoción de Cromo Hexavalente de Soluciones Acuosas Usando Epicarpio de Café. [Bachelor’s Thesis, Universidad Privada Autónoma del Sur].
- Premisecitation
Potato varieties (Solanum tuberosum Var. Canchan, Unica, Peruanita, and Perricholi) achieved 96% removal of Cr(VI) at pH 2, 25°C, 30 min, particle size 150-850 μm [49].
“| Canchan, Unica, Peruanita, and | Cr(VI) | 96 | NA | 2 | 25 | 30 | 150-850 µm | [49] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [49] Herrera Guillén, A.F., and Sosa Pulcha, S.E. (2018). Evaluación y Comparación de la Biosorción de Cr (VI) Usando Cáscaras de Cuatro Variedades de Papa (Solanum tuberosum). [Bachelor’s Thesis, Universidad Católica de Santa María].
- Premisecitation
Egg shells achieved 73% removal of Cr(VI) at pH 5, room temperature, 15 min, with no reported particle size [63].
“| Egg shells * | Cr(VI) | 73 | NA | 5 | RT | 15 | NA | [63] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [63] Aguaro Quispe, J.G., and Onofre Huaracha, E.E. (2018). Investigación para Controlar en las Aguas Residuales Industriales la Contaminación Con Cromo, Usando Cascara de Huevo Calcinado, en Soluciones Sintéticas y Posterior Aplicación a las Aguas Contaminadas Reales. [Bachelor’s Thesis, Universidad Nacional de San Agustin de Arequipa].
- Premisecitation
Shrimp skeleton (Palaemon serratus) achieved 52% removal of Cr(III) at pH 5, 19°C, with no reported time or particle size [56].
“| Shrimp skeleton (Palaemon serratus) * | Cr(III) | 52 | NA | 5 | 19 | NA | NA | [56] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [56] Delgado Requena, A.F. (2021). Evaluación del Efecto del Quitosano Sobre Las Concentraciones de Cromo y Los Parámetros Fisicoquímicos en Efluentes de Curtiembre. [Bachelor’s Thesis, Tesis Universidad Católica de Santa María].
- Premisecitation
Portada demonstrated 74% Cr(III) removal from tannery wastewaters through chemical precipitation in only 30 min in Puno (southern Peru).
“However, Portada [121] demonstrated 74% Cr(III) removal from tannery wastewaters through chemical precipitation in only 30 min in Puno (southern Peru).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [121] Portada Mamani, A. (2016). Tratamiento de las Aguas Residuales del Proceso de Curtido en Pieles Por Procesos Físico-Químico de la Curtiembre de la Facultad de Ingeniería Química de la Universidad Nacional del Altiplano. [Bachelor’s Thesis, Universidad Nacional del Altiplano].
- Premisecitation
Shrimp skeleton (Palaemon serratus) achieved 46% removal of Cr(VI) at pH 5, 19°C, with no reported time or particle size [56].
“| Shrimp skeleton (Palaemon serratus) * | Cr(VI) | 46 | NA | 5 | 19 | NA | NA | [56] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [56] Delgado Requena, A.F. (2021). Evaluación del Efecto del Quitosano Sobre Las Concentraciones de Cromo y Los Parámetros Fisicoquímicos en Efluentes de Curtiembre. [Bachelor’s Thesis, Tesis Universidad Católica de Santa María].
- Premisecitation
Metallic iron nanoparticles using Eucalyptus sp. leaves achieved 93% removal of Cr(VI) at pH 3 to 5, room temperature, 60 min, particle size 180 nm [59].
“| Metallic iron nanoparticles using Eucalyptus sp. Leaves * | Cr(VI) | 93 | NA | 3 to 5 | RT | 60 | 180 nm | [59] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [59] Cañazaca Davila, C.M., and Ccama Larico, W.E.Y. (2017). Biosíntesis de Nanopartículas de Hierro Cero Valente (nzvi) Usando Hojas de Eucalipto (Eucalyptus sp.) Para la Remoción de Cromo Hexavalente. [Bachelor’s Thesis, Universidad Nacional de San Agustin de Arequipa].
- Premisecitation
Orange pectine (Citrus × sinensis) achieved 18% removal of total chromium (CrT) at pH 5, room temperature, 15 min, particle size 180-250 μm [53].
“| Orange pectine (Citrus × sinensis) * | CrT | 18 | NA | 5 | RT | 15 | 180-250 µm | [53] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [53] Laura Ticona, V.E. (2018). Estudio de la Determinación de la Actividad Floculante en Aguas Provenientes del Río Chili Conteniendo As, Pb y Cr Tratados con Pectina Obtenidos a Partir de la Cáscara de Naranja, Limón y Mandarina. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Premisecitation
Olive seed (Olea europaea) achieved 99% removal of Cr(VI) at pH 2, room temperature, 30 min, particle size 70-160 nm [47].
“| Olive seed (Olea europaea) * | Cr(VI) | 99 | NA | 2 | RT | 30 | 70-160 nm | [47] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [47] Deza Carrasco, F.E., and Salinas Herrera, S.C. (2022). Evaluación del Porcentaje de Remoción de CR (VI) Proveniente de Efluentes de Curtido Empleando Nanopartículas de Magnetita (Fe3O4) Sintetizadas con Extracto de Hueso de Olea Europaea. [Bachelor’s Thesis, Universidad Católica de Santa María].
- Interpretationnone given
Despite an abundance of societal interest and documented efforts from local scientists to remove Cr from tannery wastewaters at RSIP, those or other initiatives have not been adopted to address ongoing, industry-sourced Cr pollution in Arequipa.
“Despite an abundance of societal interest and documented efforts from local scientists to remove Cr from tannery wastewaters at RSIP, it is evident that those or other initiatives have not been adopted to address ongoing, industry-sourced Cr pollution in Arequipa.”
Quote in the paperNot a substantial claim- Rests on an assumption: Cr pollution from tannery wastewater is a problem in the Arequipa Region of southern Peru.
- Interpretationreasoning
The use of agricultural waste, such as unprocessed adsorbents or via conversion to biochar, emerged more broadly as a promising approach for large-scale applications in the region due to local availability and rapid treatment times.
“The use of agricultural waste, such as unprocessed adsorbents or via conversion to biochar, emerged more broadly as a promising approach for large-scale applications in the region due to local availability and rapid treatment times.”
Quote in the paperSubstantial claim- Rests on an assumption: Local food waste products are locally abundant in Arequipa.
- Premisecitation
Wheat (Triticum sp.) achieved 86% removal of Cr(VI) at pH 2, 45°C, 180 min, particle size 200 μm and 125 μm [60].
“| Wheat (Triticum sp.) | Cr(VI) | 86 | NA | 2 | 45 | 180 | 200 µm and 125 µm | [60] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [60] Cabrera Navinta, G.M., and Calderon Llanqui, K. (2019). Evaluación de la Remoción de Cromo (VI) Con Biomasa Modificada de Residuos de Trigo (Triticum aestivum) en Aguas Residuales Provenientes de Las Zonas del Parque Industrial del Rio Seco y Uchumayo. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Premisecitation
Olive seed (Olea europaea) achieved 68% removal of Cr(III) at pH 4, room temperature, 9 min, particle size 250 μm [55].
“| Olive seed (Olea europaea) * | Cr(III) | 68 | NA | 4 | RT | 9 | 250 µm | [55] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [55] Rosas, Y.E. (2019). Caracterización y Remoción de Cromo (III) de Aguas Residuales de Curtiembres del Parque Industrial de Rio Seco Utilizando Hueso de Olivo (Olea europea) Procesado Como Biosorbente. [Bachelor’s Thesis, Tesis Universidad Nacional de San Agustín de Arequipa, Escuela Profesional de Ingeniería Química].
- Interpretationcitation
Electrocoagulation is expensive compared to other approaches due to infrastructure, energy, and other operational costs.
“Hence, despite the promise of nearly complete removal in relatively short periods of time, electrocoagulation is expensive compared to other approaches due to infrastructure, energy, and other operational costs [204].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [204] Mazumder, 2020, Electric field assisted membrane separation for oily wastewater with a novel and cost-effective electrocoagulation and electroflotation enhanced membrane module (ECEFMM), Chem. Eng. Process. -Process Intensif. source
- Premisecitation
Pea pods (Pisum sativum) achieved below detection (BD) removal of total chromium (CrT) at pH 1.1, room temperature, 960 min, with no reported particle size [52].
“| Pea pods (Pisum sativum) * | CrT | BD | NA | 1.1 | RT | 960 | NA | [52] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [52] Paz Corrales, O.A. (2020). Biorremoción de Cromo Total en Los Efluentes de Curtiembres, Empleando Vainas de Arvejas Pisum sativum L. Para Obtener Agua Categoría 3D2DS 004-2017 MINAM. en Arequipa. [Ph.D. Thesis, Universidad Nacional de San Agustín de Arequipa].
- Interpretationreasoning
These bioremediation results entailing greater than 97% attenuation of Cr species from tannery wastewater can be compared with other Peruvian and international research.
“These results entailing greater than 97% attenuation of Cr species from tannery wastewater can be compared with other Peruvian and international research.”
Quote in the paperNot a substantial claim - Premisecitation
Achiote peel (Bixa orellana) achieved below detection (BD) removal of Cr(VI) at pH 2, room temperature, 5 min, particle size 75-150 μm [50].
“| Achiote peel (Bixa orellana) * | Cr(VI) | BD | NA | 2 | RT | 5 | 75-150 µm | [50] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [50] Martinez Ocsa, S.K., and Quispe Roa, Y.M. (2020). Estudio Cinético de la Remoción de Cr+6 de Aguas Usando Cáscara de Achiote. [Bachelor’s Thesis, Universidad Privada Autónoma del Sur].
- Premisecitation
Treatment with magnetic iron-based nanoparticles achieved 100% removal of Cr(VI) at pH 2, 30 min [45].
“| Cr(VI) | Magnetic iron-based nanoparticles | 100 | NA | 2 | 30 min | [45] * |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [45] *
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Premisecitation
Treatment with photovoltaic reduction UV/TiO2 achieved 85% removal of Cr(VI) at pH 3.8, 4 h [43].
“| Cr(VI) | Photovoltaic reduction UV/TiO 2 | 85 | NA | 3.8 | 4 h | [43] * |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [43] *
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Premisecitation
Electrocoagulation with aluminum electrodes achieved 99% removal of total chromium (CrT) at pH 3.2, intensity 0.095 A, 44 min [96].
“| CrT | 99 | Aluminum electrodes | 3.2 | NA | 0.095 | 44 | [96] |”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [96] Challco Hihui, A.V. (2022). Electrocoagulación Acoplada a un Sistema de Microfiltración Membrana/Adsorbente en el Tratamiento de Efluentes Residuales Provenientes del Curtido de Pieles en Una Industria de Curtido del Parque Industrial Río Seco. [Master’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Premisecitation
Treatment with diatoms coated with FeCl3 achieved 125 mg/g removal of total chromium (CrT) at pH 6, 4.5 h [107].
“| CrT | Diatoms coated with FeCl 3 | NA | 125 mg/g | 6 | 4.5 h | [107] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [107] Rojas Tamata, K. (2016). Remoción de arsénico (V) y Cromo (VI) Presente en Lechos Acuáticos Mediante el Uso de Tierra de Diatomeas Recubierta con Sales de Hierro. [Master’s Thesis, Universidad Católica Santa María].
- Premisecitation
Treatment with ionic exchange resins achieved 93% removal of Cr(VI) at pH 3-5, 30 min [109].
“| Cr(VI) | Ionic exchange resins | 93 | NA | 3-5 | 30 min | [109] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [109] Ojeda Castro, C.C. (2023). Adsorción de Cromo (VI) en Efluente Simulado de Curtiembre Con Resina de Intercambio Iónico para la Reducción de Riesgo quíMico. [Bachelor’s Thesis, Universidad Tecnológica del Perú].
- Premisecitation
Treatment with solar distillation achieved below detection (BD) removal of Cr(VI) at pH not reported, 3 days [99].
“| Cr(VI) | Solar distillation | BD | NA | NA | 3 days | [99] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [99] Anahua Apaza, Z.J., and Pacheco Gonzáles, W.Y. (2021). Sistema de Destilación Por Concentración Solar para la Remoción del Cr+6 de Los Efluentes de Curtiembres en Arequipa, Río Seco. [Bachelor’s Thesis, Universidad Cesar Vallejo].
- Premisecitation
Treatment with ionic exchange resins achieved 93% removal of Cr(VI) with 0.15 mg/L removal at pH 3, 30 min [47].
“| Cr(VI) | Ionic exchange resins | 93 | 0.15 mg/L | 3 | 30 min | [47] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [47] Deza Carrasco, F.E., and Salinas Herrera, S.C. (2022). Evaluación del Porcentaje de Remoción de CR (VI) Proveniente de Efluentes de Curtido Empleando Nanopartículas de Magnetita (Fe3O4) Sintetizadas con Extracto de Hueso de Olea Europaea. [Bachelor’s Thesis, Universidad Católica de Santa María].
- Premisecitation
Electrocoagulation with aluminum electrodes achieved 99% removal of Cr(VI) at pH 5.9, voltage 40 V, intensity 14 A, 45 min [98].
“| Cr(VI) | 99 | Aluminum electrodes | 5.9 | 40 | 14 | 45 | [98] |”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [98] Aguilar Ruelas, B., and Soto Miranda, A.E. (2021). Eficiencia y Rentabilidad de la Aplicación del Tratamiento por Electrocoagulación para la Reducción del Cromo Hexavalente en Las Aguas Residuales de Curtiembre. [Bachelor’s Thesis, Universidad Cesar Vallejo].
- Premisecitation
Treatment with zeolite and perlite achieved below detection (BD) removal of total chromium (CrT) at 'Basic' pH, 8 h [105].
“| CrT | Zeolite and perlite | BD | NA |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [105] Paye Masco, B.I., and Gómez Castañeda, B. (2021). Estudio Comparativo de Adsorción de Cromo de Efluente de Curtiembre del Parque Industrial Río Seco, Arequipa Mediante dos Materiales Adsorbentes Obtenidos a Partir de Precursores Naturales (Perlita Expandida y Zeolita Agrícola). [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Premisecitation
Electrocoagulation with aluminum electrodes achieved below detection (BD) removal of Cr(III) at pH 4, voltage 0-12 V, intensity 0-50 A, 30 min [96].
“| Cr(III) | BD | Aluminum electrodes | 4 | 0-12 | 0-50 | 30 | [96] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [96] Challco Hihui, A.V. (2022). Electrocoagulación Acoplada a un Sistema de Microfiltración Membrana/Adsorbente en el Tratamiento de Efluentes Residuales Provenientes del Curtido de Pieles en Una Industria de Curtido del Parque Industrial Río Seco. [Master’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Premisecitation
Treatment with artificial wetlands with S. americanus, E. montevidensis, and H. bonariensis achieved 99% removal of total chromium (CrT) at pH 7-9, 6 days [101].
“| CrT | Artificial wetlands with S. americanus, E. montevidensis, and H. bonariensis | 99 | NA | 7-9 | 6 days | [101] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [101] Lima Coasaca, R. (2021). Efecto del Tiempo de Retención hidrÁulico (TRH) Sobre un Sistema de Humedales Artificiales (Flujo Subsuperficial+ Flujo Superficial) Plantados Con Scirpus americanus, Elecharis montevidensis e Hydrocotyle bonariensis para Tratamiento de Efluentes Brutos. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Premisecitation
Electrocoagulation with iron anodes and aluminum cathodes achieved below detection (BD) removal of Cr(III) at pH 5, voltage 3-20 V, intensity 0-60 A, 90 min [97].
“| Cr(III) | BD | Iron anodes and aluminum cathodes | 5 | 3-20 | 0-60 | 90 | [97] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [97] Juarez Calderon, C.A., and Osorio Casquina, G.V. (2019). Determinación de los Parámetros Electroquímicos Óptimos para la Remoción de Cromo (III) y DQO en Aguas de Curtido a Traves del Proceso de Electrocoagulación en un Reactor de Recirculación. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Premisecitation
Treatment with Cu nanoparticles and copper oxide achieved 15 mg/L removal of Cr(VI) at pH 2, time not reported [110].
“| Cr(VI) | Cu nanoparticles and copper oxide | NA | 15 mg/L | 2 | NA | [110] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [110] Tejada Dongo, P. (2017). Síntesis Por Método Anternativo “Verde” de Nanopartículas de Cu a Traves de Extracto Acuoso de Subproductos Industriales de Vitis vinifera L.(Uva) y Su Inmovilización en Memebranas de PVC y Determinacipon de Su Capacidad para la Adsorción de Cr (VI). [Ph.D. Dissertation, Universidad Católica de Santa María].
- Premisecitation
Activated charcoal from rice husk (Oryza sativa) achieved an adsorption capacity of 53 mg/g for Cr(VI) at pH 2, 20°C, 240 min, with surface area 690 m2/g [66].
“| Activated charcoal from rice husk (Oryza sativa) * | Cr(VI) | NA | 53 | 2 | 20 | 240 | Surface 690 m 2 /g area | [66] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [66] Manrique Pino, P.L. (2014). Optimización de la Producción de Carbón Activado a Partir de Cascarilla de Arroz y Su Uso en la Adsorción de Cromo (VI). [Bachelor’s Thesis, Universidad Católica de Santa María].
- Premisecitation
Treatment with a shrimp cephalothorax biofilter (C. caementarius) achieved 0.7-0.9 mg/kg removal of total chromium (CrT) at acid pH, time not reported [108].
“| CrT | Shrimp cephalothorax biofilter (C. caementarius) | NA | 0.7-0.9 mg/kg | Acid | NA | [108] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [108] Monroy Piérola, C.R. (2018). Niveles de Metales Pesados Cromo, Arsénico, Plomo y Mercurio en Cefalotorax de Cryphiops caementarius (Camarón) en Los Ríos Ocoña, Majes y Tambo. [Bachelor’s Thesis, Universidad Católica Santa María].
- Premisecitation
Treatment with a bio-sand filter achieved 99% removal of total chromium (CrT) at pH 8-9, 46 min [104].
“| CrT | Bio-sand filter | 99 | NA | 8-9 | 46 min | [104] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [104] Leguía, J., and Puma, P. (2016). Diseño de Filtros de Bioarena para Remover Metales Pesados (As, Cd, Cr, Pb y Fe) en Aguas de Uso Doméstico. [Bachelor’s Thesis, Universidad Nacional de San Agustín].
- Premisecitation
Treatment with a sandy-loam soil filter achieved 9220 mg/kg removal of total chromium (CrT) at pH 6.9-7.2, time not reported [30].
“| CrT | Sandy-loam soil filter | NA | 9220 mg/kg | 6.9-7.2 | NA | [30] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [30] Vilca Castro, F., and Gordillo Vilca, Y.B. (2016). Retención de Metales Pesados en Suelos y su Impacto Ambiental: Caso Aguas Residuales–Parque Industrial Río Seco. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Premisecitation
Treatment with polymer (Floerger AN 910) and FeCl3 coagulant achieved 96% removal of Cr(VI) at pH 6, time not reported [102].
“| Cr(VI) | Polymer (Floerger AN 910) and FeCl 3 coagulant | 96 | NA | 6 | NA | [102] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [102] Chávez Segura, L.M., and Alpaca Rodríguez, Y.A. (2014). Acción Coagulante–Floculante del Cloruro Férrico y el Polímero Aniónico Floerger An 910, en el Tratamiento Químico del Agua Residual de la Laguna de Estabilización del Parque Industrial Río Seco (Pirs). [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Premisecitation
Treatment with sodium bentonite filters achieved 94% removal of Cr(VI) at pH 4, 30 min [103].
“| Cr(VI) | Sodium bentonite filters | 94 | NA | 4 | 30 min | [103] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [103] Rendón Velarde, R.B. (2020). Adsorción y Desorción de Cromo (VI) en un Medio Adsorbente (Bentonita), Aplicando un Proceso Zero Waste. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- Probably not a substantial claim. 29
- It may state two separate claims as one. 60
- The quote only partly states this claim. 1
Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.
Findingown dataWhile Tejada-Meza et al. reported that the pH of the RSIP's tannery effluents was 8.2 ± 0.4 during their analysis window, this may not be constant because of the changing quality (color/smell) of the surface water effluent observed by our team during the field visit, most likely a result of upstream dumping.
“While Tejada-Meza et al. [33] reported that the pH of the RSIP's tannery effluents was 8.2 ± 0.4 during their analysis window, this may not be constant because of the changing quality (color/smell) of the surface water effluent observed by our team during the field visit (see Section 1 for details), most likely a result of upstream dumping.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites [33] Tejada-Meza, K., Arenazas-Rodríguez, A., Garcia-Chevesich, P.A., Flores-Farfan, C., Morales-Paredes, L., Romero-Mariscal, G., Ticona-Quea, J., Vanzin, G., and Sharp, J.O. (2023). Acute Ecotoxicity Potential of Untreated Tannery Wastewater Release in Arequipa, Southern Peru. Sustainability, 15. source
Split into 2 atoms — 0 confirmed, 0 partially supported, 2 disputed, 0 misattributed, 0 unverifiable. Expand the claim to see per-atom verdicts.
Checked by a reasoning model — may be wrong.
Experimental — accuracy not yet measured
Probably not a substantial claim. The paper’s conclusions may not depend on it.
PremisecitationThe release of tannery wastewater contributes to chromium pollution globally.
“The release of tannery wastewater contributes to chromium (Cr) pollution globally.”
Quote in the paperNot a substantial claim1 of 2 sources checked- cites [2] Arti, 2023, Analysis of heavy metals and toxicity level in the tannery effluent and the environs, Environ. Monit. Assess. source
- cites [3] Ghezzi, L., Mugnaioli, E., Perchiazzi, N., Duce, C., Pelosi, C., Zamponi, E., Pollastri, S., Campanella, B., Onor, M., and Abdellatief, M. (2023). Hexavalent chromium release over time from a pyrolyzed Cr-bearing tannery sludge. Sci. Rep., 13. source
The Introduction (page unavailable) says chromium tanning is used in more than 80% of global leather production, that excess chromium remains in tanning liquor, and that leather manufacturing poses environmental threats. It does not say that tannery wastewater is released or that such releases cause chromium pollution globally; its focus is chromium-bearing sludge. (LLM, conf=0.79)
Experimental — accuracy not yet measured
Probably not a substantial claim. The paper’s conclusions may not depend on it.
PremisecitationChromium bioaccumulates in animal tissues and organs.
“and bioaccumulates in animal tissues and organs [7].”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites [7] Tejada-Purizaca, T.R., Garcia-Chevesich, P.A., Ticona-Quea, J., Martínez, G., Martínez, K., Morales-Paredes, L., Romero-Mariscal, G., Arenazas-Rodríguez, A., Vanzin, G., and Sharp, J.O. (2024). Heavy Metal Bioaccumulation in Peruvian Food and Medicinal Products. Foods, 13. source
Section 2.3 reports chromium among the metals analyzed in river fish, and describes metal bioaccumulation in fish tissues and organs. It does not establish specifically that chromium bioaccumulates in animal organs; its organ-specific examples concern other metals. (LLM, conf=0.82)
Experimental — accuracy not yet measured
It may state two separate claims as one.
PremisecitationNanotechnology is a common method used to treat Cr from wastewater, but only two studies used this technique in Arequipa.
“Nanotechnology, for example, is a common method used to treat Cr from wastewater [113,117,118], but only two studies [100,110] used this technique in Arequipa.”
Quote in the paperNot a substantial claim2 of 5 sources checked- cites [113] Mitra, 2017, Removal of chromium from industrial effluents using nanotechnology: A review, Nanotechnol. Environ. Eng. source
- cites [117] Njimou, 2025, Eco-friendly chitin-MnO2-alginate nanobiocomposite spheres for enhanced heavy metal removal from wastewater: Inorganic chemistry communications, Inorg. Chem. Commun. source
- cites [118] Xing, 2022, A comprehensive review on emerging natural and tailored materials for chromium-contaminated water treatment and environmental remediation, J. Environ. Chem. Eng. source
- cites [100] Ruiz Marcelo, M. (2018). Eficiencia de Nanopartículas de Magnetita en la Reducción del Cromo Hexavalente a Cromo Trivalente en el Suelo del Parque Industrial de Río Seco (PIRS), Cerro Colorado–Arequipa. [Bachelor’s Thesis, Universidad Cesar Vallejo]. source
- cites [110] Tejada Dongo, P. (2017). Síntesis Por Método Anternativo “Verde” de Nanopartículas de Cu a Traves de Extracto Acuoso de Subproductos Industriales de Vitis vinifera L.(Uva) y Su Inmovilización en Memebranas de PVC y Determinacipon de Su Capacidad para la Adsorción de Cr (VI). [Ph.D. Dissertation, Universidad Católica de Santa María].
It may state two separate claims as one.
PremisecitationThe average total Cr content in the RSIP effluent was above 10 mg/L, with a flow estimate of 31 L/s at the time of the visit.
“As reported by Tejada-Meza et al. [33], the average total Cr content in this effluent was above 10 mg/L, with a flow estimate of 31 L/s at the time of the visit.”
Quote in the paperSubstantial claim1 of 1 sources checked- cites [33] Tejada-Meza, K., Arenazas-Rodríguez, A., Garcia-Chevesich, P.A., Flores-Farfan, C., Morales-Paredes, L., Romero-Mariscal, G., Ticona-Quea, J., Vanzin, G., and Sharp, J.O. (2023). Acute Ecotoxicity Potential of Untreated Tannery Wastewater Release in Arequipa, Southern Peru. Sustainability, 15. source
Section 3.1 reports chromium at 10.4 ± 0.4 mg Cr/L in the RSIP effluent, supporting the claim that its average exceeded 10 mg/L. Section 4.3 describes a flow of approximately 30 L/s, not 31 L/s, and does not tie that estimate to the time of a visit. (LLM, conf=0.88)
Experimental — accuracy not yet measured
It may state two separate claims as one.
FindingcitationParticular highlights for Cr removal included solar distillation, magnetic iron nanoparticles, artificial wetlands, iron-based coagulation-incorporating polymers, and infiltration systems.
“Particular highlights for Cr removal included solar distillation [99], magnetic iron nanoparticles [100], artificial wetlands [101], iron-based coagulation-incorporating polymers [102], and infiltration systems [30,103,104].”
Quote in the paperNot a substantial claim1 of 3 sources checked- cites [99] Anahua Apaza, Z.J., and Pacheco Gonzáles, W.Y. (2021). Sistema de Destilación Por Concentración Solar para la Remoción del Cr+6 de Los Efluentes de Curtiembres en Arequipa, Río Seco. [Bachelor’s Thesis, Universidad Cesar Vallejo].
- cites [100] Ruiz Marcelo, M. (2018). Eficiencia de Nanopartículas de Magnetita en la Reducción del Cromo Hexavalente a Cromo Trivalente en el Suelo del Parque Industrial de Río Seco (PIRS), Cerro Colorado–Arequipa. [Bachelor’s Thesis, Universidad Cesar Vallejo]. source
- cites [101] Lima Coasaca, R. (2021). Efecto del Tiempo de Retención hidrÁulico (TRH) Sobre un Sistema de Humedales Artificiales (Flujo Subsuperficial+ Flujo Superficial) Plantados Con Scirpus americanus, Elecharis montevidensis e Hydrocotyle bonariensis para Tratamiento de Efluentes Brutos. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
It may state two separate claims as one.
FindingcitationPromising examples included the microalgae D. quadricauda, Chlorella sp., and Espirulina sp., and the vascular plants I. cernua and N. aquaticum.
“Promising examples included the microalgae D. quadricauda [67], Chlorella sp., and Espirulina sp.[68], and the vascular plants I. cernua and N. aquaticum [40,67].”
Quote in the paperNot a substantial claim1 of 3 sources checked- cites [67] Paredes Arenazas, W.G. (2021). Determinación de la Bioabsorción de Cromo VI de Efluentes del Parque Industrial de Rio Seco (PIRS) Mediante la Microalga Desmodesmus quadricauda. [Bachelor’s Thesis, Universidad Católica Santa María].
- cites [68] Sumalave Cutire, C.L. (2022). Biosorción de Cromo de Efluentes de la Industria Textil Mediante el Uso de Microalgas en la Ciudad de Arequipa. [Bachelor’s Thesis, Universidad Cesar Vallejo].
- cites [40] Huerta Alata, M., Alvarez-Risco, A., Torres, L.S., Moran, K., Pilares, D., Carling, G., Paredes, B., Del-Aguila-Arcentales, S., and Yáñez, J.A. (2023). Evaluation of Environmental Contamination by Toxic Elements in Agricultural Soils and Their Health Risks in the City of Arequipa, Peru. Sustainability, 15. source
The Method of Analysis (§2.2) describes measurements in agricultural soil, and the References include a study of aquatic macrophytes, but neither passage identifies I. cernua or N. aquaticum as promising examples. Searches for those names and the listed microalgae found no passage in our copy addressing the claim. (LLM, conf=0.77)
Experimental — accuracy not yet measured
Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.
FindingcitationThe pH values tested in phytoremediation studies, when available, correspond to neutral conditions, which may facilitate plant growth.
“Furthermore, it is pertinent to note that the pH values tested, when available, correspond to neutral conditions, which may facilitate plant growth [69].”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites [69] Kaiwen, 2020, Effects of salt concentration, pH, and their interaction on plant growth, nutrient uptake, and photochemistry of alfalfa (Medicago sativa) leaves, Plant Signal. Behav. source
The available copy contains a Results and analysis heading for plant growth (section 2.1), but no findings or tested pH values. Searches for neutral pH, pH 7, and growth under neutral versus alkaline conditions returned only headings and links, so the copy does not establish whether neutral conditions facilitated growth or characterize pH values in phytoremediation studies. (LLM, conf=0.72)
Experimental — accuracy not yet measured
Probably not a substantial claim.
PremisecitationSeveral global reviews on how different techniques are used to treat CrT, Cr(III), and/or Cr(VI) from tannery wastewaters already exist.
“Several global reviews on how different techniques are used to treat CrT, Cr(III), and/or Cr(VI) from tannery wastewaters already exist [111][112][113][114][115][116].”
Quote in the paperSubstantial claim2 of 3 sources checked- cites [111] Alam, 2020, An overview of chromium removal techniques from tannery effluent, Appl. Water Sci. source
- cites [112] Owlad, 2009, Removal of hexavalent chromium-contaminated water and wastewater: A review, Water Air Soil Pollut. source
- cites [113] Mitra, 2017, Removal of chromium from industrial effluents using nanotechnology: A review, Nanotechnol. Environ. Eng. source
The Introduction reviews several techniques for removing Cr(VI) from industrial effluents, and “Chromium in industrial effluents” identifies tanneries as one source of those effluents (page numbers unavailable). The review is not specifically about tannery wastewater, and the cited passages do not establish treatment of total chromium (CrT) or Cr(III) as treatment targets. (LLM, conf=0.86)
Experimental — accuracy not yet measured
Probably not a substantial claim.
PremisecitationInternational studies provide a strong precedent for the need to further evaluate various treatment methods for tannery wastewaters, including coagulation and flocculation, electrochemical treatments, ion exchange, membrane filtration, electrodialysis, photocatalysis, and biological treatments.
“International studies provide a strong precedent for the need to further evaluate various treatment methods for tannery wastewaters, including coagulation and flocculation, electrochemical treatments such as electro-flotation and electro-oxidation (distinct from electrocoagulation presented herein), ion exchange, membrane filtration, electrodialysis, photocatalysis, and biological treatments (e.g.”
Quote in the paperSubstantial claim2 of 10 sources checked- cites [111] Alam, 2020, An overview of chromium removal techniques from tannery effluent, Appl. Water Sci. source
The Introduction lists membrane filtration, electro-flotation, electro-oxidation, ion exchange and electrodialysis for chromium removal from tannery wastewater. The Coagulation and flocculation section and Abstract also address coagulation/flocculation and biological processes. The passages do not establish photocatalysis as one of the reviewed tannery-wastewater treatments, so the full list is not supported by this source. (LLM, conf=0.83)
Experimental — accuracy not yet measured - cites [112] Owlad, 2009, Removal of hexavalent chromium-contaminated water and wastewater: A review, Water Air Soil Pollut. source
- cites [113] Mitra, 2017, Removal of chromium from industrial effluents using nanotechnology: A review, Nanotechnol. Environ. Eng. source
The Introduction (page unavailable) discusses membrane filtration and electrokinetic treatment of Cr(VI) in industrial effluents, and ‘Conventional processes for chromium remediation’ discusses electrochemical addition of iron and bacterial remediation. The paper therefore supports evaluating some treatment approaches, but its focus is chromium in industrial effluents, not tannery wastewater treatment generally; the cited passages do not support the full list, including coagulation and flocculation, electro-flotation, electro-oxidation, and electrodialysis. (LLM, conf=0.85)
Experimental — accuracy not yet measured - cites [114] Kumar, 2021, A review on accessible techniques for removal of hexavalent chromium and divalent nickel from industrial wastewater: Recent research and future outlook, J. Clean. Prod. source
- cites [115] GracePavithra, 2019, A review on cleaner strategies for chromium industrial wastewater: Present research and future perspective, J. Clean. Prod. source
- cites [116] Whitacre, 2012, Strategies for chromium bioremediation of tannery effluent, Reviews of Environmental Contamination and Toxicology
- cites [117] Njimou, 2025, Eco-friendly chitin-MnO2-alginate nanobiocomposite spheres for enhanced heavy metal removal from wastewater: Inorganic chemistry communications, Inorg. Chem. Commun. source
- cites [118] Xing, 2022, A comprehensive review on emerging natural and tailored materials for chromium-contaminated water treatment and environmental remediation, J. Environ. Chem. Eng. source
- cites [119] Ramakrishnaiah, 2012, Hexavalent chromium removal from industrial watsewater by chemical precipitation method, Int. J. Eng. Res. Appl.
- cites [120] Peng, 2020, Removal of chromium from wastewater by membrane filtration, chemical precipitation, ion exchange, adsorption electrocoagulation, electrochemical reduction, electrodialysis, electrodeionization, photocatalysis and nanotechnology: A review, Environ. Chem. Lett. source
It may state two separate claims as one.
PremisecitationSorption applications can be tailored toward specific metals with capability for recovery, regeneration, and reuse, contributing to cost-effectiveness and providing a more environmentally benign alternative to chemical dosing.
“They can be further tailored toward specific metals with the capability for recovery, regeneration, and reuse, which can contribute to cost-effectiveness and provide a more environmentally benign alternative to chemical dosing [127-131].”
Quote in the paperNot a substantial claim2 of 5 sources checked- cites [127] Habineza, 2017, Heavy metal removal from wastewaters by agricultural waste low-cost adsorbents: Hindrances of adsorption technology to the large scale industrial application—A review, Desalin. Water Treat source
The abstract (p. 1) describes agricultural-waste adsorbents as promising for heavy-metal removal and says the review covers biosorbent regeneration and desorption. It does not establish that sorption can be tailored to specific metals, that metals and adsorbents can be recovered and reused cost-effectively, or that it is environmentally preferable to chemical dosing. The abstract also says economic evaluations are missing. (LLM, conf=0.79)
Experimental — accuracy not yet measured - cites [128] Ali, 2006, Advances in water treatment by adsorption technology, Nat. Protoc. source
- cites [129] Rashid, 2021, A state-of-the-art review on wastewater treatment techniques: The effectiveness of adsorption method, Environ. Sci. Pollut. Res. source
- cites [130] Fu, 2011, Removal of heavy metal ions from wastewaters: A review, J. Environ. Manag. source
- cites [131] Younas, F., Mustafa, A., Farooqi, Z.U.R., Wang, X., Younas, S., Mohy-Ud-Din, W., Hameed, M.A., Abrar, M.M., Maitlo, A.A., and Noreen, S. (2021). Current and emerging adsorbent technologies for wastewater treatment: Trends, limitations, and environmental implications. Water, 13. source
Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.
PremisecitationElectrocoagulation presents several advantages for metal extraction from contaminated waters, notably high efficiency and rapid removal.
“Electrocoagulation presents several advantages for metal extraction from contaminated waters, notably high efficiency, and rapid removal [202].”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites [202] Ruiz, 2005, La electrocoagulación: Una alternativa para el tratamiento de aguas residuales, Revista Lasallista de investigación
The Electrocoagulación section says the process is used for wastewater containing chromium, lead, or mercury, and the advantages list describes high effectiveness across a broad range of contaminants. That list says the resulting flocs can be separated rapidly by filtration, but it does not establish rapid removal of metals specifically. (LLM, conf=0.84)
Experimental — accuracy not yet measured
Probably not a substantial claim. The paper’s conclusions may not depend on it.
Findingnone givenFifteen additional studies implemented technologies that are less clearly linked into the above classifications.
“Fifteen additional studies implemented technologies that are less clearly linked into the above classifications (Table 6).”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
Findingown dataIn April 2023, the research team observed RSIP effluent downstream of processing activities that changed colors over time and had an unpleasant smell.
“In April 2023, our research team observed RSIP effluent downstream of processing activities.This tributary to the Chili River (Figure 1) is a small unlined surface water course that changed colors over time (from green to brown, most likely a reflection of upstream industrial dumping), with an unpleasant smell.”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
Findingown dataThe published university theses related to Cr removal applied to wastewater from tanneries increased in number within the last decade with a potential lull during and after the COVID-19 pandemic.
“The published university theses related to Cr removal applied to wastewater from tanneries increased in number within the last decade with a potential lull during and after the COVID-19 pandemic (Figure 2).”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
Findingown dataBoth microalgae and vascular plants showed a high propensity to remove Cr from polluted tannery wastewater.
“Both microalgae (Table 3a) and vascular plants (Table 3b) showed a high propensity to remove Cr from polluted tannery wastewater.”
Quote in the paperSubstantial claimIt may state two separate claims as one.
FindingcitationAll adsorption experiments were conducted under acidic conditions with a pH between 1.1 and 6, which is lower than what was found using other treatment methods or reported by other studies conducted with RSIP tannery effluents.
“Finally, it is worth noting that all these adsorption experiments were conducted under acidic conditions with a pH between 1.1 and 6), which is lower than what was found using other treatment methods, or than reported by other studies conducted with RSIP tannery effluents [31]).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [31] 2019, Concentración de metales pesados: Cromo, cadmio y plomo en los sedimentos superficiales en el río Coata, Perú, Rev. Boliv. Química
It may state two separate claims as one.
FindingcitationThe most promising results, when considering both removal extent and treatment time, were obtained using the bacterium P. mirabilis or the fungus S. cerevisiae, which eliminated nearly 90% of Cr(VI) in 36 and 48 h, respectively.
“The most promising results, when considering both removal extent and treatment time, were obtained using the bacterium P. mirabilis [86] or the fungus S. cerevisiae [91], which eliminated nearly 90% of Cr(VI) in 36 and 48 h, respectively.”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [86] Chambi Mamani, C. (2021). Aislamiento e Identificación de Cepas Bacterianas Aisladas de Sitios Contaminados Con Efluentes de Curtiduría y Su Capacidad para Reducir CR (VI). [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- cites [91] Fernandez Chiara, J.G., and Guzman Ponce, K.S. (2019). Bioadsorción de Cromo (VI) con Saccharomyces cerevisiae Inmovilizada, Como Residuo de la Elaboración de la Cerveza, para Su Aplicación en Biorremediación de Aguas Contaminadas de la Industria del Curtido. [Bachelor’s Thesis, Universidad Católica de Santa María].
It may state two separate claims as one.
FindingreasoningThe limited number of electrocoagulation studies was conducted across a range of acidic pH values, which made it difficult to discern if there were any patterns between Cr removal and pH.
“This limited number of studies was conducted across a range of acidic pH values, which made it difficult to discern if there were any patterns between Cr removal and pH.”
Quote in the paperNot a substantial claimProbably not a substantial claim. The paper’s conclusions may not depend on it.
Findingnone givenThe peer-reviewed publications about Cr removal from tannery wastewater in Arequipa summarized in this paper are derived mostly from English journals.
“However, the peer-reviewed publications about Cr removal from tannery wastewater in Arequipa summarized above are derived mostly from English journals.”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
Findingown dataOf the 75 publications found in this synthesis, 38 experiments focused on treating total Cr, 48 on Cr(VI), and 12 on Cr(III) (98 experiments in total).
“Of the total number of publications found in this synthesis (75), 38 experiments focused on treating total Cr (CrT), 48 on Cr(VI), and 12 on Cr(III) (98 experiments in total, as some studies analyzed more than one Cr species).”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
FindingcitationLaura and Salinas removed Cr(III) to below detection in 30 min and no clear effects from voltage, intensity, or time on pollutant removal capacity were detected.
“Laura and Salinas [95] removed Cr(III) to BD in 30 min and no clear effects from voltage, intensity, or time on pollutant removal capacity were detected.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [95] Laura Benavides, S.L., and Salinas Rondon, J.O. (2020). Eficiencia en la Remoción del Contenido de Cromo III por Electrocoagulación en Las Aguas Residuales de Curtiembre del Parque Industrial de Río Seco. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
It may state two separate claims as one.
Findingown dataOnly six phytoremediation-based studies found in this synthesis documented both Cr removal (%) and pH, and no clear pattern was identified in terms of removal capacity and pH values (R2 = 0.14 for CrT).
“Moreover, since only six phytoremediation-based studies found in this synthesis documented both Cr removal (%) and pH, no clear pattern was identified in terms of removal capacity and pH values (R 2 = 0.14 for CrT).”
Quote in the paperNot a substantial claimProbably not a substantial claim. The paper’s conclusions may not depend on it.
FindingreasoningStudies from Arequipa indicate that the acidity of treated tannery wastewater from RSIP can vary, likely due to a combination of upstream dumping practices and specific adjustments for treatment methods.
“Additionally, studies from Arequipa indicate that the acidity of treated tannery wastewater from RSIP can vary, likely due to a combination of upstream dumping practices combined with specific adjustments for treatment methods, which can alter pH levels to differing extents (Figure 3).”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
FindingcitationMost electrocoagulation experiments obtained high removal yields in all Cr species, except for Alvarez and Vilca, who applied a graphite anode and nickel-covered metal cathode, resulting in low treatment capacity for CrT.
“Most experiments obtained high removal yields in all Cr species, except for Alvarez and Vilca [94], who applied a graphite anode and nickel-covered metal cathode, resulting in low treatment capacity for CrT.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [94] Alvarez Samayani, D.A., and Vilca Vilca, K.H. (2021). Recuperación Electrolítica de Cromo a Partir de la Viruta Residual de Cuero Procedente de Las Curtiembres del Parque Industrial Río Seco. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
It may state two separate claims as one.
FindingreasoningUnlike applied sorptive technologies, these studies tended toward increased efficiency at higher pH values (R2 = 0.20 and 0.94 for Cr(VI) and CrT, respectively), suggesting a potential interaction between multiple attenuation mechanisms.
“Unlike applied sorptive technologies, these studies tended toward increased efficiency at higher pH values (R 2 = 0.20 and 0.94 for Cr(VI) and CrT, respectively), suggesting a potential interaction between multiple attenuation mechanisms.”
Quote in the paperNot a substantial claimProbably not a substantial claim. The paper’s conclusions may not depend on it.
Findingnone givenThe associated costs of transporting and applying waste-product adsorbents are currently unknown.
“However, while the use of waste products could be economically compelling, the associated costs of transporting and the application of these materials are currently unknown.”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
Findingown dataThe main technical approaches evaluated were adsorption (twenty-three studies), phytoremediation (eighteen studies), microbial bioremediation (thirteen studies), electrocoagulation (five studies), and a broader catch-all category (fifteen studies).
“The main technical approaches evaluated were adsorption (twenty-three studies), phytoremediation (eighteen studies), microbial bioremediation (thirteen studies), electrocoagulation (five studies), and a broader catch-all category, often combining multiple attenuation mechanisms, which did not cleanly fall into those other categories (fifteen studies).”
Quote in the paperSubstantial claimProbably not a substantial claim. The paper may give no reason why it holds. It may state two separate claims as one.
Findingnone givenOther locally promising technologies included phytoremediation using certain microalgae and vascular plants, and bioremediation using bacteria and fungi.
“Other locally promising technologies included phytoremediation using certain microalgae and vascular plants, and bioremediation using bacteria and fungi.”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
FindingcitationPromising results within the Arequipa-specific literature to remove Cr species through bioremediation came from the use of unspecified sulfate-reducing bacteria, the fungi Penicillium sp. and A. niger, and the combination of filamentous fungi with activated charcoal.
“Promising results within the Arequipa-specific literature to remove Cr species through bioremediation (Table 4a,b) came from the use of unspecified sulfate-reducing bacteria [83], the fungi Penicillium sp.[90] and A. niger [88], and the combination of filamentous fungi with activated charcoal [89].”
Quote in the paperSubstantial claim0 of 3 sources checked- cites [83] Loaiza Alejandro, R.E. (2022). Biorremediación de Sulfatos, Sulfuros y Cromo en un Reactor de Biopelícula por Lotes de Secuenciación Anaeróbica (ASBBR) Empacado Con Bacterias Sulfato Reductoras. [Bachelor’s Thesis, Universidad Nacional de San Agustin de Arequipa].
- cites [90] Solis Pareja, C. (2020). Estrategias Basadas en Producción Más Limpia y Biorremediación para Mitigar Los Impactos Ambientales Negativos Generados Por Los Efluentes Industriales de las Curtiembres del Parque Industrial de Río Seco. [Bachelor’s Thesis, Universidad Nacional de San Agustin de Arequipa].
- cites [88] Aymara Uscamayta, C.G. (2018). Biorremoción de Metales Ecotóxicos Mediante Cepas Fúngicas Nativas Aisladas de Efluentes Industriales en un Sistema de Biorreactores en Serie de Agitación Continua. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa]. source
It may state two separate claims as one.
FindingcitationBased on percent removal, promising results from Arequipa for phytoremediation were achieved with I. cernua and N. aquaticum, and D. quadricauda, with further promise in other Peruvian regions using P. persica.
“Based on percent removal, promising results from Arequipa (Table 3a,b) were achieved with I. cernua and N. aquaticum [72], and D. quadricauda [67], with further promise in other Peruvian regions that are using P. persica [158].”
Quote in the paperSubstantial claim0 of 3 sources checked- cites [72] Pineda Zapana, J.S. (2019). Evaluación del Potencial de Fitorremediación de Isolepis cernua y Nasturtium aquaticum para el Tratamiento Secundario de Efluentes de Curtiembre del Parque Industrial Rio Seco en Arequipa. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- cites [67] Paredes Arenazas, W.G. (2021). Determinación de la Bioabsorción de Cromo VI de Efluentes del Parque Industrial de Rio Seco (PIRS) Mediante la Microalga Desmodesmus quadricauda. [Bachelor’s Thesis, Universidad Católica Santa María].
- cites [158] Flores Rodríguez, W.H. (2014). Cinética de la Biosorción de Cromo Hexavalente en Solución Acuosa Por Biomasa de Hueso de Prunus Pérsica (Durazno). [Bachelor’s Thesis, Universidad Nacional del Altiplano].
It may state two separate claims as one.
Findingnone givenPromising Arequipa results were obtained using infiltration-type strategies in geomedia such as biosand filters (99% of CrT in 46 min), sodium bentonite filters (94% Cr(VI) in 30 min), and zeolite with perlite (CrT to BD in eight hours).
“Promising Arequipa results were also obtained using infiltration-type strategies in geomedia such as biosand filters (99% of CrT in 46 min), sodium bentonite filters (94% Cr(VI) in 30 min), and zeolite with perlite (CrT to BD in eight hours), as listed in Table 6.”
Quote in the paperSubstantial claimIt may state two separate claims as one.
FindingcitationIn our synthesis, Lima removed 99% of Cr using constructed wetlands in Arequipa; this is analogous but superior to the 85% removal obtained by Kong et al. in constructed wetlands in China.
“In our synthesis, Lima [101] removed 99% of Cr using constructed wetlands in Arequipa; this is analogous but superior to the 85% removal obtained by Kong et al. [209] in constructed wetlands in China.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [101] Lima Coasaca, R. (2021). Efecto del Tiempo de Retención hidrÁulico (TRH) Sobre un Sistema de Humedales Artificiales (Flujo Subsuperficial+ Flujo Superficial) Plantados Con Scirpus americanus, Elecharis montevidensis e Hydrocotyle bonariensis para Tratamiento de Efluentes Brutos. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- cites [209] Kong, 2020, Removal of Cr(VI) from wastewater by artificial zeolite spheres loaded with nano Fe–Al bimetallic oxide in constructed wetland, Chemosphere source
It may state two separate claims as one.
FindingcitationMass-normalized removal from Arequipa included 2.2 mg/g with sawdust and 4.3 mg/g with banana peel.
“Mass-normalized removal from Arequipa included 2.2 mg/g with sawdust [57] and 4.3 mg/g with banana peel [141].”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [57] Cárdenas, S., and Ortega, J. (2015). Modelamiento y Simulación de una Columna de Adsorción de Lecho Fijo para la Remoción de Cr (VI) de Soluciones Acuosas Utilizando Aserrín Como Adsorbente. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- cites [141] Pari Luque, Y.P. (2020). Biosorción del Cromo Hexavalente en Soluciones Acuosas Utilizando Biomasa de Cáscara de Plátano (Musa acuminata Colla). [Master’s Thesis, Universidad Nacional del Altiplano].
It may state two separate claims as one.
PremisereasoningChromium can damage aquatic ecosystems and decrease soil fertility.
“Chromium can also damage aquatic ecosystems and decrease soil fertility where analogous oxidative and DNA damage can increase mortality in Cr-sensitive microorganisms.”
Quote in the paperNot a substantial claimProbably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.
PremisecitationChromium affects plant enzyme activity and photosynthesis, causing hindered growth and reduced yields.
“Chromium also affects plant enzyme activity and photosynthesis, causing hindered growth and reduced yields [6]”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [6] Ao, 2022, Chromium biogeochemical behaviour in soil-plant systems and remediation strategies: A critical review, J. Hazard. Mater. source
Probably not a substantial claim. The paper’s conclusions may not depend on it. The paper may give no reason why it holds. It may state two separate claims as one.
Premisenone givenExposure to Cr(VI) in humans has been associated with allergic dermal reactions; when inhaled, it causes respiratory complications, irritation, bleeding from the nose, and potentially lung cancer.
“Exposure to Cr(VI) in humans has been associated with allergic dermal reactions; when inhaled, it causes respiratory complications, irritation, bleeding from the nose, and potentially lung cancer.”
Quote in the paperNot a substantial claimProbably not a substantial claim. The paper’s conclusions may not depend on it. The paper may give no reason why it holds.
Premisenone givenCr(III) can be oxidized to the more toxic hexavalent chromium (Cr(VI)) phase in the presence of organic matter under mildly acidic conditions.
“It can also be oxidized to the more toxic hexavalent chromium (Cr(VI)) phase in the presence of organic matter under mildly acidic conditions.”
Quote in the paperNot a substantial claimProbably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.
PremisecitationChromium pollution is widespread globally, with a prominence in Latin American countries.
“Chromium pollution is widespread globally [8][9][10][11][12][13], with a prominence in Latin American countries [4,[14][15][16][17][18][19].”
Quote in the paperNot a substantial claim0 of 3 sources checked- cites [8] Yanuar, 2021, Analysis of biofilms as a biomonitoring agent for Cr(VI) pollution in Cokro River, Malang Regency, AIP Conf. Proc. source
- cites [9] He, 2020, Source identification of chromium in the sediments of the Xiaoqing River and Laizhou Bay: A chromium stable isotope perspective, Environ. Pollut. source
Checked before — its earlier verdict is held back until a new check runs.
- cites [10] Majnoni, 2015, Assessment of Cd, Cr and Pb Pollution in Sediment and Water of Gheshlagh River, Iran, in September 2013, Iran. J. Toxicol. source
Probably not a substantial claim. The paper’s conclusions may not depend on it.
PremisecitationShort-term human exposure to trivalent chromium (Cr(III)) causes irritation of the eyes and respiratory tract.
“Although considered less toxic, short-term human exposure to trivalent chromium (Cr(III)) causes irritation of the eyes and respiratory tract [4].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [4] 2010, Descripción de la nocividad del cromo proveniente de la industria curtiembre y de las posibles formas de removerlo, Rev. Ing. Univ. Medellín
It may state two separate claims as one.
PremisecitationCr(VI) ingestion can cause ulcers, weakening of the immune system, damage to the kidneys and liver, and genetic mutations.
“Cr(VI) ingestion can cause ulcers, weakening of the immune system, damage to the kidneys and liver, and genetic mutations [5].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [5] Montoya, 2010, Plomo, cromo III y cromo VI y sus efectos sobre la salud humana, Revista Ciencia y Tecnología para la Salud Visual y Ocular source
It may state two separate claims as one.
PremisecitationZapana-Huarache and colleagues designed and tested the filamentous fungus P. citrinum, which removed 80% of influent Cr(VI).
“Zapana-Huarache and colleagues [44] designed and tested the application of the filamentous fungus P. citrinum, which removed 80% of influent Cr(VI).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [44] Gonza, 2020, Design and testing of a cost-efficient bioremediation system for tannery effluents using native chromium-resistant filamentous fungi, Int. J. Environ. Sci. Technol. source
It may state two separate claims as one.
PremisecitationAuthors have used chemical precipitation of Cr(VI) worldwide in tannery wastewater, but no Arequipa-specific studies were found using this method.
“Similarly, authors have used chemical precipitation of Cr (VI) worldwide in tannery wastewater [119,120], but no Arequipa-specific studies were found using this method.”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [119] Ramakrishnaiah, 2012, Hexavalent chromium removal from industrial watsewater by chemical precipitation method, Int. J. Eng. Res. Appl.
- cites [120] Peng, 2020, Removal of chromium from wastewater by membrane filtration, chemical precipitation, ion exchange, adsorption electrocoagulation, electrochemical reduction, electrodialysis, electrodeionization, photocatalysis and nanotechnology: A review, Environ. Chem. Lett. source
Probably not a substantial claim. The paper’s conclusions may not depend on it. The paper may give no reason why it holds.
Interpretationnone givenFor local waste materials, there are further potential economic advantages with respect to material acquisition and transport.
“For local waste materials, there are further potential economic advantages with respect to material acquisition and transport.”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
PremisecitationAchiote peels seem to be particularly efficient, with rapid removal of detectable Cr(VI) in only 5 min, while avocado seeds were used to eliminate detectable Cr(VI) in 15 min.
“Achiote peels [50] seem to be particularly efficient, with rapid removal of detectable Cr(VI) in only 5 min, while avocado seeds [51] were used to eliminate detectable Cr(VI) in 15 min.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [50] Martinez Ocsa, S.K., and Quispe Roa, Y.M. (2020). Estudio Cinético de la Remoción de Cr+6 de Aguas Usando Cáscara de Achiote. [Bachelor’s Thesis, Universidad Privada Autónoma del Sur].
- cites [51] Mollinedo Chávez, A.M., and Huanca Quispe, A. (2021). Adsorción de Cromo Hexavalente de Lechos Acuáticos Utilizando Biomasa de Pepa de Palta (Persea americana mill). [Bachelor’s Thesis, Universidad María Auxiliadora].
It may state two separate claims as one.
InterpretationreasoningThe discharge of inadequately treated tannery wastewater by companies in RSIP has exacerbated the Cr environmental challenge and efforts to mitigate the Cr content of RSIP wastewater have been insufficient.
“leading to the conclusion that the discharge of inadequately treated tannery wastewater by companies in RSIP has exacerbated this environmental challenge and efforts to mitigate the Cr content of RSIP wastewater have been insufficient.”
Quote in the paperSubstantial claimIt may state two separate claims as one.
PremisecitationRoque et al. used the native bacterium C. aquaticus to attenuate 89% of the total chromium (34.8 to 3.82 mg/L) in RSIP tannery wastewater, of which ~70% was and remained Cr(III) (24.2 to 2.66 mg/L).
“In addition to these peer-reviewed research articles written in English, Roque et al. [46] (Spanish) used the native bacterium C. aquaticus to attenuate 89% of the total chromium (34.8 to 3.82 mg/L) in the RSIP tannery wastewater of which ~70% was and remained Cr(III) (24.2 to 2.66 mg/L).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [46] Roque, R.F., Prado, D., and Ruiz de Somocurcio, F. (2013, January 3–5). Biodepuración de aguas residuales industriales contaminadas con cromo III y VI utilizando microflora nativa aislada y caracterizada provenientes del Parque Industrial Rio Seco (PIRS) de la ciudad de Arequipa. Proceedings of the Memoria Segundo Encuentro de Investigadores Ambientales, Arequipa, Peru.
Probably not a substantial claim. The paper’s conclusions may not depend on it. The paper may give no reason why it holds.
Interpretationnone givenNature-inspired approaches, such as biofilters, infiltration strategies, and wetlands, likely operated with a synergy of biological and/or abiotic reduction, bioaccumulation, and sorption-based mechanisms.
“In some cases, nature-inspired approaches, such as biofilters, infiltration strategies, and wetlands, likely operated with a synergy of biological and/or abiotic reduction, bioaccumulation, and sorption-based mechanisms.”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
PremisecitationRendón used sodium bentonite filters to remove 94% of Cr(VI) in 30 min, while Paye and Gomez attenuated CrT to below detection in eight hours using a mixture of zeolite and perlite.
“Similarly, Rendón [103] used sodium bentonite filters to remove 94% of Cr(VI) in 30 min, while Paye and Gomez [105] attenuated CrT to below detection in eight hours using a mixture of zeolite and perlite.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [103] Rendón Velarde, R.B. (2020). Adsorción y Desorción de Cromo (VI) en un Medio Adsorbente (Bentonita), Aplicando un Proceso Zero Waste. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- cites [105] Paye Masco, B.I., and Gómez Castañeda, B. (2021). Estudio Comparativo de Adsorción de Cromo de Efluente de Curtiembre del Parque Industrial Río Seco, Arequipa Mediante dos Materiales Adsorbentes Obtenidos a Partir de Precursores Naturales (Perlita Expandida y Zeolita Agrícola). [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
Probably not a substantial claim. The paper’s conclusions may not depend on it.
PremisecitationArequipa is the largest leather-producing territory in Peru.
“Arequipa is the largest leather-producing territory in Peru [20].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [20] Chipana Tuma, G., Maldonado Adco, Y., Maita Villegas, J.C., Soto Rendom, K., and Durand Caceres, C.C. (2017). Curtiembres en Arequipa Desde el 2010 al 2017. [Bachelor’s Thesis, Universidad Tecnológica del Perú].
It may state two separate claims as one.
InterpretationreasoningOther phytoremediation species performed well but took weeks or months to reach results, making them less attractive for further large-scale sustainable applications.
“While other species performed well, they took weeks or months to reach results, making them less attractive for further large-scale sustainable applications.”
Quote in the paperSubstantial claimIt may state two separate claims as one.
PremisecitationZapana et al. used a pilot-scale constructed wetland system to treat RSIP's tannery wastewater, achieving ~98% removal for this industrial wastewater through bioaccumulation in macrophytes I. cernua and N. aquaticum.
“For example, Zapana et al. [42] used a pilot-scale constructed wetland system to treat RSIP's tannery wastewater.Treatment was achieved primarily through bioaccumulation in macrophytes I. cernua and N. aquaticum, achieving ~98% removal for this industrial wastewater.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [42] Zapana, 2020, Treatment of tannery wastewater in a pilot scale hybrid constructed wetland system in Arequipa, Peru, Int. J. Environ. Sci. Technol. source
It may state two separate claims as one.
PremisecitationLoaiza isolated and cultivated a sulfate-reducing bacterial consortium using a Cr2(SO4)3 solution followed by cultivation in a bioreactor containing RSIP tannery effluents, eliminating most detectable Cr(VI).
“Loaiza [83] isolated and cultivated a sulfate-reducing bacterial consortium using a Cr 2 (SO 4 ) 3 solution followed by cultivation in a bioreactor containing RSIP tannery effluents, eliminating most detectable Cr(VI).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [83] Loaiza Alejandro, R.E. (2022). Biorremediación de Sulfatos, Sulfuros y Cromo en un Reactor de Biopelícula por Lotes de Secuenciación Anaeróbica (ASBBR) Empacado Con Bacterias Sulfato Reductoras. [Bachelor’s Thesis, Universidad Nacional de San Agustin de Arequipa].
It may state two separate claims as one.
InterpretationreasoningMany bacteria- and fungi-based studies required extended treatment times to obtain efficient results, rendering them less attractive techniques for removing Cr species from tannery wastewater.
“While overall reduction/removal was laudable, many of these bacteria-and fungibased studies required extended treatment times to obtain efficient results, rendering them less attractive techniques for removing Cr species from tannery wastewater.”
Quote in the paperSubstantial claimIt may state two separate claims as one.
PremisecitationIn 2010, there were 96 tanning companies in the Arequipa Region, of which 67 were located at the Rio Seco Industrial Park (RSIP).
“In 2010, there were 96 tanning companies in the Arequipa Region, of which 67 were located at the Rio Seco Industrial Park (RSIP), in the Cerro Colorado District (Regional Ordinance 121).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Regional Ordinance 121
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
It may state two separate claims as one.
PremisecitationAdditional studies on bacterial potential for Cr removal included C. aquaticus and Streptococcus sp., and K. oxycata, with 94% (CrT) and 92% (Cr(VI)) removal (from solution), respectively.
“Additional studies on bacterial potential for Cr removal (Table 4a) included C. aquaticus and Streptococcus sp.[84], and K. oxycata [85], with 94% (CrT) and 92% (Cr(VI)) removal (from solution), respectively.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [84] Prado Salinas, D.G., and Ruiz de Somocurcio Chavez Quiroz, F. (2004). Factibilidad de Biosorción de Cromo (III y VI) en Aguas Residuales Industriales-ARI’S Contaminadas Utilizando Microflora Nativa Aislada y Caracterizada en Su Hábitat Proveniente del Parque Industrial Rio Seco-PIRS. [Bachelor’s Thesis, Universidad Católica de Santa María].
- cites [85] Cáceres Silva, G.V. (2019). Aislamiento, Caracterización e Identificación del Consorcio Microbiano Con Potencial Degradativo de Cromo. [Bachelor’s Thesis, Universidad Católica de Santa María].
It may state two separate claims as one.
PremisecitationThe application of the fungus A. niger by Aymara and the combination of native fungi and activated charcoal by Quina resulted in 97% CrT removal.
“Similarly, the application of the fungus A. niger by Aymara [88] and the combination of native fungi and activated charcoal by Quina [89] resulted in 97% CrT removal.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [88] Aymara Uscamayta, C.G. (2018). Biorremoción de Metales Ecotóxicos Mediante Cepas Fúngicas Nativas Aisladas de Efluentes Industriales en un Sistema de Biorreactores en Serie de Agitación Continua. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa]. source
- cites [89] Quina Luz, B. (2019). Tratamiento de Efluentes de Curtiembres Utilizando Hongos Nativos Filamentosos y Carbón Activado para la Remoción de Cromo Total. [Bachelor’s Thesis, Universidad Nacional de San Agustin de Arequipa].
It may state two separate claims as one.
InterpretationreasoningAchiote peels and avocado seeds represent sustainable options, where common local food waste materials could be applied in Arequipa.
“The latter two materials represent sustainable options, where common local food waste materials could be applied in Arequipa.”
Quote in the paperSubstantial claimIt may state two separate claims as one.
PremisecitationDeza and Salinas eliminated 99% of Cr(VI) in 30 min using olive seed; Pacheco and Herrera and Sosa removed the majority of Cr(VI) in the same amount of time using corn crown and potatoes, respectively.
“For example, Deza and Salinas [47] eliminated 99% of Cr(VI) in 30 min using olive seed, while Pacheco [48] and Herrera and Sosa [49] were able to remove the majority of Cr(VI) in the same amount of time using corn crown and potatoes, respectively.”
Quote in the paperNot a substantial claim0 of 3 sources checked- cites [47] Deza Carrasco, F.E., and Salinas Herrera, S.C. (2022). Evaluación del Porcentaje de Remoción de CR (VI) Proveniente de Efluentes de Curtido Empleando Nanopartículas de Magnetita (Fe3O4) Sintetizadas con Extracto de Hueso de Olea Europaea. [Bachelor’s Thesis, Universidad Católica de Santa María].
- cites [48] Pacheco Portugal, J.D. (2019). Evaluación el Proceso de Biosorción de Cr (VI) Usando Residuos Agroindustriales de la Región Arequipa Cascarilla de Arroz y Chala de Maíz. [Bachelor’s Thesis, Universidad Católica de Santa María].
- cites [49] Herrera Guillén, A.F., and Sosa Pulcha, S.E. (2018). Evaluación y Comparación de la Biosorción de Cr (VI) Usando Cáscaras de Cuatro Variedades de Papa (Solanum tuberosum). [Bachelor’s Thesis, Universidad Católica de Santa María].
Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.
PremisecitationBy 2017, more than 400 tanning companies were listed and grouped into 60 associations in the Arequipa Region; nearly 100 operated at RSIP by 2023, generating over 3000 jobs.
“However, more than 400 companies (small, medium, and large) were listed and grouped into 60 associations in 2017, of which nearly 100 operated at RSIP by 2023, generating over 3000 jobs [21].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [21] El Buho (2024, July 11). Empresarios del Cuero del Parque Industrial Denuncian Excesiva Fiscalización de OEFA, Available online: https://elbuho.pe/2023/09/empresarios-del-cuero-del-parque-industrial-denuncian-excesiva-fiscalizacion-e-incumplimiento-compromisos-del-gra/.
Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.
PremisecitationRizvi et al. used desiccated biomass comprised of P. aeruginosa, B. subtilis, and A. chroococcum to remove Cr and other metals and highlighted 96% removal by B. subtilis.
“Another common method not found is the use of dry (and presumably limited biological activity) microbial bacterial biomass for Cr adsorption, as achieved by Rizvi et al. [122] in India, who used desiccated biomass comprised of P. aeruginosa, B. subtilis, and A. chroococcum to remove Cr and other metals and highlighted 96% removal by B. subtilis.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [122] Rizvi, 2020, Biosorption of heavy metals by dry biomass of metal tolerant bacterial biosorbents: An efficient metal clean-up strategy, Environ. Monit Assess. source
It may state two separate claims as one.
PremisecitationArequipan papaya seed (Vasconcellea pubescens) achieved 78% removal of Cr(VI) at pH 2, 25°C, with no reported time or particle size [54].
“| Arequipan papaya seed (Vasconcellea pubescens) * | Cr(VI) | 78 | NA | 2 | 25 | NA | NA | [54] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [54] Córdova Pantigoso, A.M., and Medina Delgado, M.O. (2019). Biorremoción Con Semilla de Papaya Arequipeña (Vasconcellea pubescens) para Cromo Total en Efluentes de Curtiembres, Arequipa. [Bachelor’s Thesis, Universidad Católica de Santa María].
It may state two separate claims as one.
PremisecitationSorption applications that rely on water contact are straightforward to implement and can remove a diverse array of heavy metals, even at trace concentrations.
“Sorption applications that rely on water contact are straightforward is to implement and can be applied toward the removal of a diverse array of heavy metals, even at trace concentrations [126][127][128][129][130].”
Quote in the paperNot a substantial claim0 of 5 sources checked- cites [126] Chai, 2021, A review on conventional and novel materials towards heavy metal adsorption in wastewater treatment application, J. Clean. Prod. source
- cites [127] Habineza, 2017, Heavy metal removal from wastewaters by agricultural waste low-cost adsorbents: Hindrances of adsorption technology to the large scale industrial application—A review, Desalin. Water Treat source
Checked before — its earlier verdict is held back until a new check runs.
- cites [128] Ali, 2006, Advances in water treatment by adsorption technology, Nat. Protoc. source
- cites [129] Rashid, 2021, A state-of-the-art review on wastewater treatment techniques: The effectiveness of adsorption method, Environ. Sci. Pollut. Res. source
- cites [130] Fu, 2011, Removal of heavy metal ions from wastewaters: A review, J. Environ. Manag. source
Probably not a substantial claim. The paper’s conclusions may not depend on it.
Premisenone givenAdsorption is a frequently applied technique in the treatment of Cr-contaminated water.
“Adsorption is a frequently applied technique in the treatment of Cr-contaminated water.”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
PremisecitationSancayo peel (Corryocactus brevistylus) achieved 59% removal of Cr(VI) at pH 3, 30°C, 30 min, with no reported particle size [64].
“| Sancayo peel (Corryocactus brevistylus) * Cr(VI) | 59 | NA | 3 | 30 | 30 | NA | [64] | |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [64] Banda Choquihuillca, A.P., and Coaguila Coaguila, J.G. (2022). Evaluación de la Capacidad de Biorremoción de Cromo Hexavalente (Cr+6) en Aguas Contaminadas Utilizando Residuos de Cáscara de Sancayo (Corryocactus brevistylus). [Bachelor’s Thesis, Universidad Privada Autónoma del Sur].
It may state two separate claims as one.
PremisecitationArequipan papaya seed (Vasconcellea pubescens) achieved 80% removal of Cr(III) at pH 3, 25°C, with no reported time or particle size [54].
“| Arequipan papaya seed (Vasconcellea pubescens) * | Cr(III) | 80 | NA | 3 | 25 | NA | NA | [54] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [54] Córdova Pantigoso, A.M., and Medina Delgado, M.O. (2019). Biorremoción Con Semilla de Papaya Arequipeña (Vasconcellea pubescens) para Cromo Total en Efluentes de Curtiembres, Arequipa. [Bachelor’s Thesis, Universidad Católica de Santa María].
Probably not a substantial claim. It may be too vague to check against evidence. The paper’s conclusions may not depend on it. The paper may give no reason why it holds.
InterpretationreasoningThis highlights a potential synergy in sorption with biological processes for live microbial cells.
“While not directly explored, this highlights a potential synergy in sorption with biological processes for live microbial cells.”
Quote in the paperNot a substantial claimIt may state two separate claims as one. The quote only partly states this claim.
PremisecitationQuinoa (Chenopodium quinoa) achieved 55% removal of Cr(VI) at pH 'Acid', 20°C, with no reported time, particle size 450-250 μm [65].
“| Quinoa (Chenopodium quinoa) | Cr(VI) | 55 | NA |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [65] Ramirez, A. (2018). Evaluación del Proceso de Biosorción de la Inflorescencia del Chenopodium quinoa (Quinua) para la Remoción de Cromo (VI). [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
It may state two separate claims as one.
PremisecitationElectrocoagulation requires disproportionately high energy inputs, can be less efficient in highly saline or acidic waters, produces a waste sludge that necessitates dewatering and potentially hazardous disposal, and electrodes rapidly corrode.
“However, electrocoagulation requires disproportionately high energy inputs when contrasted with other engineered treatment technologies, can be less efficient in highly saline or acidic waters, produces a waste sludge that necessitates dewatering and potentially hazardous disposal, and electrodes rapidly corrode, with a need for frequent replacement [203].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [203] Guerrero, 2019, La electrocoagulación, una alternativa para el tratamiento de aguas residuales en el departamento de Nariño, Boletín Inf. CEI
Probably not a substantial claim.
InterpretationcitationThe bacterium P. mirabilis and the fungus S. cerevisiae were particularly promising for further exploration into treatment-relevant investigations that address long-term viability and large-scale applications.
“Furthermore, though some microorganisms used in Arequipa to remove Cr species from tannery wastewater are not found in the international literature, the results revealed that the bacterium P. mirabilis [86] and the fungus S. cerevisiae [91] were particularly promising for further exploration into treatment-relevant investigations that address long-term viability and large-scale applications.”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [86] Chambi Mamani, C. (2021). Aislamiento e Identificación de Cepas Bacterianas Aisladas de Sitios Contaminados Con Efluentes de Curtiduría y Su Capacidad para Reducir CR (VI). [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
- cites [91] Fernandez Chiara, J.G., and Guzman Ponce, K.S. (2019). Bioadsorción de Cromo (VI) con Saccharomyces cerevisiae Inmovilizada, Como Residuo de la Elaboración de la Cerveza, para Su Aplicación en Biorremediación de Aguas Contaminadas de la Industria del Curtido. [Bachelor’s Thesis, Universidad Católica de Santa María].
It may state two separate claims as one.
PremisecitationSawdust achieved 95% removal of Cr(VI) with adsorption capacity 2.2 mg/g at pH not reported, 60°C, 180 min, particle size 0.35 mm [57].
“| Sawdust * | Cr(VI) | 95 | 2.2 | NA | 60 | 180 | 0.35 mm | [57] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [57] Cárdenas, S., and Ortega, J. (2015). Modelamiento y Simulación de una Columna de Adsorción de Lecho Fijo para la Remoción de Cr (VI) de Soluciones Acuosas Utilizando Aserrín Como Adsorbente. [Bachelor’s Thesis, Universidad Nacional de San Agustín de Arequipa].
Probably not a substantial claim. It may state two separate claims as one.
InterpretationreasoningI. cernua seems to be the most promising phytoremediation species and should be further explored; it is a native species from southern Peru that is novel in the field of Cr removal from tannery wastewater.
“However, as previously discussed, the species that seems to be the most promising and should be further explored is I. cernua, a native species from southern Peru that is novel in the field of Cr removal from tannery wastewater.”
Quote in the paperSubstantial claimIt may state two separate claims as one.
PremisecitationAvocado seed (Persea americana) achieved below detection (BD) removal of Cr(VI) at pH 2, with no reported temperature, 15 min, particle size 75-150 μm [51].
“| Avocado seed (Persea americana) * | Cr(VI) | BD | NA | 2 | NA | 15 | 75-150 µm | [51] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [51] Mollinedo Chávez, A.M., and Huanca Quispe, A. (2021). Adsorción de Cromo Hexavalente de Lechos Acuáticos Utilizando Biomasa de Pepa de Palta (Persea americana mill). [Bachelor’s Thesis, Universidad María Auxiliadora].
Probably not a substantial claim. It may be too vague to check against evidence.
InterpretationreasoningThis unique place-based compilation of otherwise not visible research provides trajectories and opportunities that build on local understanding and acceptance of potential materials and technologies that could be appropriate for local solutions to this wastewater quality challenge.
“Rather, this unique place-based compilation of otherwise not visible research provides trajectories and opportunities that build on local understanding and acceptance of potential materials and technologies that could be appropriate for local solutions to this wastewater quality challenge.”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
PremisecitationPotato peel (Solanum tuberosum) achieved 86% removal of Cr(VI) at pH 2, with no reported temperature, 50 min, particle size <250 mm [61].
“| Potato peel (Solanum tuberosum) * | Cr(VI) | 86 | NA | 2 | NA | 50 | <250 mm | [61] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [61] Condori Ramos, P.M., and Pumacayo Gutiérrez, M.A. (2019). Evaluación de la Remediación de Aguas Contaminadas Con Cromo Empleando una Columna de Lecho Fijo con Biomasa de Cáscara de Papa “Solanum tuberosum”. [Bachelor’s Thesis, Universidad Católica de Santa María].
Probably not a substantial claim. It may be too vague to check against evidence. The paper may give no reason why it holds.
Interpretationnone givenArequipa presents a relevant test case for assessing the applicability of these methods to local tannery wastewater conditions.
“While these methods have been studied in various contexts, Arequipa presents a relevant test case for assessing their applicability to local tannery wastewater conditions.”
Quote in the paperNot a substantial claimIt may state two separate claims as one.
InterpretationreasoningEfficient techniques explored in the region were identified and were consistent with findings elsewhere using similar materials.
“Moreover, efficient techniques explored in the region were identified and were consistent with findings elsewhere using similar materials.”
Quote in the paperSubstantial claimProbably not a substantial claim. The paper’s conclusions may not depend on it.
PremisecitationIn treating Cr-contaminated tannery wastewater, adsorption eliminates Cr ions by binding them to a solid adsorbent material.
“In the specific case of treating Cr-contaminated tannery wastewater, adsorption is used to eliminate Cr ions by binding them to a solid adsorbent material [125].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [125] Shah, M.P., Couto, S.R., and Kumar, V. (2021). Chapter 11—Removal of heavy metals from coke-plant effluents by using wetlands. New Trends in Removal of Heavy Metals from Industrial Wastewater, Elsevier.
It may state two separate claims as one.
PremisecitationTreatment with constructed wetlands with Eleocharis palustris achieved 96% removal of total chromium (CrT) with 2.5 g/kg removal, pH not reported, time not reported [106].
“| CrT | Constructed wetlands with Eleocharis palustris | 96 | 2.5 g/kg | NA | NA | [106] |”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [106] Arizábal Tejada, V.K. (2018). Implementación de Humedales Artificiales para Mejorar la Calidad de Las Aguas Residuales Pre-Tratadas de la Industria del Curtido de Cuero en el Parque Industrial Rio Seco. [Bachelor’s Thesis, Universidad Católica Santa María].
The paper relies on this without support.
Spanish-language publications have received limited international visibility.
“Special emphasis is placed on Spanish-language publications, which have received limited international visibility, creating an opportunity to increase global understanding of place-based approaches toward the treatment of Cr from tannery wastewaters and foster mechanisms for local adoption.”
The paper relies on this without support.
The socioeconomic status of southern Peru favors practical treatment strategies for the removal of Cr from tannery wastewater that rely on inexpensive and easily available materials and techniques.
“The socioeconomic status of southern Peru favors practical treatment strategies for the removal of Cr from tannery wastewater that rely on inexpensive and easily available materials and techniques.”
The paper relies on this without support.
Cr pollution from tannery wastewater is a problem in the Arequipa Region of southern Peru.
“As Cr pollution from tannery wastewater is a problem in the Arequipa Region of southern Peru”
The paper relies on this without support.
Arequipa has an arid climate.
“Furthermore, Arequipa has an arid climate, which could constrain water availability.”
The paper relies on this without support.
Arequipa has high solar radiation.
“The high solar radiation present in Arequipa lends promise toward solar distillation”
The paper relies on this without support.
Local food waste products are locally abundant in Arequipa.
“adsorption materials could be applied to the region because they can be derived from locally abundant food waste products or be used as feedstocks for biochar”
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
Each contradiction between two passages listed here was confirmed by an independent check.
Studies with 95% removal are described as exceeding 95%
MinorThe discussion includes sawdust among results described as greater than 95% removal, but Table 2 reports exactly 95% for sawdust.
“the most promising adsorption results (>95% removal) were documented for plant materials (achiote peels, avocado seed, pea pods, sawdust, potatoes, corn crown and rice peel, and olive pits)”
“| Sawdust * | Cr(VI) | 95 | 2.2 | NA | 60 | 180 | 0.35 mm | [57] |”
Microbial reduction names inconsistent chromium oxidation states
MinorSection 2.3 identifies the starting species as Cr(IV), while the later description of the relevant bioremediation process identifies it as Cr(VI).
“microbial reduction of Cr(IV) to Cr(III), potentially in association of the respiration of other electron acceptors such as sulfate, seemed particularly promising.”
“Of particular relevance to bioremediation is the reduction of Cr(VI) to Cr(III) to limit mobility and toxicity [172]”
Nanotechnology count omits a listed nanoparticle study
MinorThe discussion says only two Arequipa studies used nanotechnology, citing [100] and [110]. Table 2 also lists a study of metallic iron nanoparticles, [59].
“Nanotechnology, for example, is a common method used to treat Cr from wastewater [113,117,118], but only two studies [100,110] used this technique in Arequipa.”
“| Metallic iron nanoparticles using Eucalyptus sp. Leaves * | Cr(VI) | 93 | NA | 3 to 5 | RT | 60 | 180 nm | [59] |”
Ion exchange is described as untested despite listed studies
MinorThe recommendations call ion exchange a technology not tested in the region, but Table 6 lists two ion-exchange-resin results.
“Equally important is to highlight the need to explore the application of proven and emerging treatment technologies not tested in the region, such as chemical precipitation, ion exchange, membrane filtration, trickling filters, and nanocomposite spheres.”
“| Cr(VI) | Ionic exchange resins | 93 | 0.15 mg/L | 3 | 30 min | [47] |”
Solar-distillation result names different chromium species
MinorThe discussion says the solar-distillation study reduced total chromium below detection, whereas Table 6 identifies the result as Cr(VI).
“Anahua and Pacheco [99] were able to eliminate CrT to BD using solar distillation.”
“| Cr(VI) | Solar distillation | BD | NA | NA | 3 days | [99] |”
Magnetite result names different chromium species
MinorThe discussion describes Ruiz's magnetite-nanoparticle result as removal of total chromium, while Table 6 labels the cited result as Cr(VI).
“Ruiz [100] eliminated CrT to BD using magnetite nanoparticles.”
“| Cr(VI) | Magnetite nanoparticles | BD | NA | NA | 3 weeks | [100] |”
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Metadata
- Authors
- Morales-Paredes, L. F., Garcia-Chevesich, P. A., Romero-Mariscal, G., Arenazas-Rodriguez, A., Ticona-Quea, J., Tejada-Purizaca, T. R., Vanzin, G., & Sharp, J. O.
- Affiliations
- Universidad Nacional de San Agustin de Arequipa (PE)
- Department of Civil and Environmental Engineering, Colorado School of Mines, Golden, CO 80401, USA
- Departamento Académico de Biología, Facultad de Ciencias Biológicas, Universidad Nacional de San Agustín de Arequipa, Arequipa 04000, Peru
- Colorado School of Mines (US)
- ORCID
- Venue
- Sustainability
- Publisher
- MDPI AG
- Published
- 2025-02-01
- Volume
- 17
- Issue
- 3
- Pages
- 1183
- ISSN
- 2071-1050 (ISSN-L)
- OpenAlex
- W4407108478
- Semantic Scholar
- b71b989a999c76ed4567c42b54c2f1df2e9788f9
- Cited by
- 8
- References
- 121
- Citations by year
- 2026: 2 · 2025: 6
- FWCI
- 2.97
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Sustainability (publishedVersion, cc-by)
- RePEc: Research Papers in Economics (acceptedVersion)
- Funders
- Center for Mining Sustainability
- Colorado School of Mines (USA)
- National University of San Agustin (Peru)
- Topics
- Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Chromium effects and bioremediation
- Physical Sciences › Environmental Science › Environmental Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Keywords
- chromium removal, tannery wastewater, heavy metal contamination, adsorption, phytoremediation, bioremediation, electrocoagulation, biochar, avocado seed, microalgae, indigenous bacteria, constructed wetlands, solar distillation, Arequipa
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
A language model drew the claims from the paper on 2026-11-08, under version 3 of the claim definition (model deepseek-v4.1-flash, prompt extract-v3).
A second model labelled each claim on 2026-11-08 (model jev-1.13-20260917, definition revision gold-guideline-v0.2).
Cited sources are checked with a language model’s help (gpt-6-sol).
Statistics and arithmetic are recomputed, not judged.
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