Cited by 3Soil Carbon and Nitrogen DynamicsAgricultural Science and FertilizationThermochemical Biomass Conversion Processes

Corn-cob Biochar Characterization and Application Effects to Carbon Dioxide (CO₂) Evolution in Acid Soil Added with Different Types of Fertilizers

Open access
Bulfa, Arsenio, Villegas-Pangga, Gina, Cubelo, Jose Edwin·2021·Philippine Journal of Science

Abstract

Biochar, a carbon (C) rich material produced from biomass, is an inexpensive means of removing C from the atmosphere by incorporating it into the soil, where C sinks are formed for sequestration. The slow release of carbon dioxide (CO2) from the soil is related to C sequestration, long-term storage of CO2, or other forms of C that help lessen CO2 concentration. An incubation study was conducted in a laboratory to determine the effect of corn-cob biochar (CCB) application on Luisiana clay (Orthoxic Palehumults) acidic soil. The CO2 evolution from the incubation of various mixtures of organic materials, inorganic fertilizers added with CCB was measured using a titration of hydrochloric acid (HCl). The biochar application rate was 10 t/ha, and the organic fertilizers at 5 t/ha. Results show that CCB contained essential plant elements like C, K (potassium), Si (silicon), Cu (copper), Na (sodium), and Cl (chlorine). It also possesses a large surface area and high average pore size. The CO2 evolution increased in the first two weeks with a peak at Day 2, and the amount of cumulative CO2 decreased after that in all treatments during the incubation period. Treatments with CCB showed a constant reduction in the amount of CO2

Integrity signals

Registry

Crossref · 10.56899/150.05.40

Cites

0 citation errors · 0 not checkable

Statistics

Nothing to recompute.

Claims the paper makes

13 of 37 cited sources checked · 6 supported · 1 flagged · accuracy not yet measured

  • Premisecitation
    § CO2 Evolution · p. 8

    The CO2 evolution rate was slightly lower with biochar addition within 70 days of incubation.

    “This observation was related to the findings of Jien et al. (2015), stating that the CO 2 evolution rate was slightly lower with biochar addition within 70 days of incubation.”
    Quote in the paperSubstantial claim1 of 1 sources checked
    • cites Jien et al. (2015) source

      Section 3.2 reports a slightly lower CO2 evolution rate for RHB-700 than for RHB-400—not for biochar addition versus no biochar. It says the control maintained a low rate relative to the other treatments during the 70-day incubation; section 4.1 reports higher cumulative CO2 emissions from biochar treatments than from biochar-free treatments. (LLM, conf=0.88)

      Checked by a reasoning model — may be wrong.

      Experimental — accuracy not yet measured
  • Premisecitation
    § CO2 Evolution · p. 8

    Biochar successfully captured CO2 through both surface adsorption and chemical reaction.

    “This is confirmed by Batista et al. (2018), noting that CO 2 was successfully captured by biochar related to both the surface adsorption and chemical reaction.”
    Quote in the paperSubstantial claim1 of 1 sources checked
    • cites Batista et al. (2018) source

      The Methods section on specific surface area describes nitrogen adsorption to measure biochar properties, not CO2 capture. Results and Discussion mentions possible carbon sequestration in soil but does not say biochar captured CO2 through surface adsorption or chemical reaction. Searches for CO2 capture and those mechanisms found no supporting passage in our copy; page numbers were not available. (LLM, conf=0.77)

      Experimental — accuracy not yet measured
  • Findingown data
    § Corn-cob Biochar Characterization and Application Effects to Carbon Dioxide (CO 2 ) Evolution in Acid Soil Added with Different Types of Fertilizers · p. 1

    Treatments receiving corn-cob biochar showed a steady decrease in the amount of CO2.

    “Treatments with CCB showed a constant reduction in the amount of CO 2 .”
    Quote in the paperSubstantial claim
  • Findingown data
    § Corn-cob Biochar Characterization and Application Effects to Carbon Dioxide (CO 2 ) Evolution in Acid Soil Added with Different Types of Fertilizers · p. 1

    Corn-cob biochar contained essential plant elements including carbon, potassium, silicon, copper, sodium, and chlorine.

    “Results show that CCB contained essential plant elements like C, K (potassium), Si (silicon), Cu (copper), Na (sodium), and Cl (chlorine).”
    Quote in the paperNot a substantial claim
  • Findingown data
    § Total CO2 Evolution · p. 7

    Treatments with biochar added reduced CO2 evolution during decomposition of the materials inside the incubation jars.

    “It was observed that treatments with biochar added reduced the CO 2 evolution during the decomposition of the materials inside the incubation jars.”
    Quote in the paperSubstantial claim
  • Classified as probably not a substantial claim. 51
  • May combine two claims. 39
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 2

    Biochar's effect on water infiltration varies: it reduces water movement in sandy loams and increases it in clay loam soil.

    “However, biochar has a varying effect on water infiltration by reducing the water movement along with the soil profile of sandy loams while increasing it in the clay loam soil that improves water (Blanco-Canqui 2017; Hussain et al. 2016; Surampalli et al. 2015).”
    Quote in the paperNot a substantial claim1 of 3 sources checked
    • cites Blanco-Canqui 2017 source
    • cites Hussain et al. 2016

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Surampalli et al. 2015

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 2

    Biochar can improve soil physical properties including bulk density, particle density, soil porosity, water infiltration, and water holding capacity.

    “Soil physical properties such as bulk density (BD), particle density (PD), soil porosity (SP), soil water infiltration, and water holding capacity can be improved by biochar (Blanco-Canqui 2017).”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Blanco-Canqui 2017 source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Interpretationcitation
    § Biochar Properties · p. 8

    The chemical analysis and HAABF images of corn-cob biochar agree with Wijitkosum and Jiwnok (2019), who reported that corn-cob biochar yielded the highest amount of carbon (81.35%).

    “The results of chemical analysis and HAABF images of CCB are consistent with Wijitkosum and Jiwnok (2019) study, which indicated that CCB yielded the highest amount of C (81.35%).”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Wijitkosum and Jiwnok (2019) source
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § Biochar Properties · p. 8

    The binding effect of biochar increases soil aggregation, which reduces soil losses in agriculture.

    “Also, the binding effect of biochar increases soil aggregation, which is the reason to reduce soil losses in agriculture (Jien et al. 2015).”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Jien et al. 2015 source

      Section 4.1 reports that macro-aggregates formed after biochar incorporation and that organomineral interactions stabilized soil structure. It does not establish that this aggregation reduces soil losses in agriculture; the paper’s discussion concerns stabilization of organic matter, while erosion potential appears only in reference titles. (LLM, conf=0.88)

      Experimental — accuracy not yet measured
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § CO2 Evolution · p. 7

    In a prior incubation study, the highest CO2 efflux occurred on the second day after incubation began, and biochar alone significantly reduced soil CO2 efflux on the first day.

    “These observations were similar to the incubation study of Shen et al. (2017), stating that the highest CO 2 efflux was observed on the second day after the incubation started in the soil, and amendment with biochar alone significantly decreased the soil CO 2 efflux on the first day of incubation.”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Shen et al. (2017) source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation
    § CCB Chemical Properties · p. 4

    Biochar yield varies with feedstock type because material contains labile and recalcitrant oxygen- and hydrogen-containing fractions.

    “The yielding capacity of biochar dramatically varies depending on the feedstock type because a material typically comprises labile and recalcitrant oxygen and hydrogen-containing fractions (Piash et al. 2017).”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Piash et al. 2017 source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation
    § CO2 Evolution · p. 8

    A prior study observed a significant decrease in greenhouse gas intensity from rice production when biochar was applied.

    “Thammasom et al. (2016) observed a significant decrease in the intensity of GHGs from rice production when applied with biochar.”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Thammasom et al. (2016) source
  • May combine two claims.

    Premisecitation
    § Biochar Properties · p. 8

    A high surface area, large average pore size, and high total pore volume make biochar suitable for soil amendment by capturing CO2 and other greenhouse gases, lowering soil bulk density, increasing soil moisture retention and aeration, and reducing leaching of plant nutrients from the rhizosphere.

    “The high surface area, high average pore size, and high total pore volume make biochar appropriate for soil amendment in capturing CO 2 and other GHGs, decreasing SBD, increasing soil moisture retention and aeration, and reducing leaching of plant nutrients from the rhizosphere (Wijitkosum and Jiwnok 2019; Batista et al. 2018).”
    Quote in the paperNot a substantial claim2 of 2 sources checked
    • cites Wijitkosum and Jiwnok 2019 source

      Split into 2 atoms — 1 confirmed, 1 partially supported, 0 disputed, 0 misattributed, 0 unverifiable. Expand the claim to see per-atom verdicts.

      Experimental — accuracy not yet measured
    • cites Batista et al. 2018 source

      Split into 2 atoms — 0 confirmed, 2 partially supported, 0 disputed, 0 misattributed, 0 unverifiable. Expand the claim to see per-atom verdicts.

      Experimental — accuracy not yet measured
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation
    § CCB Chemical Properties · p. 4

    Low temperature and long residence time promote biochar production.

    “Low temperature and long residence time promote the production of biochar (Miranda et al. 2012).”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Miranda et al. 2012 source

      The Introduction says pyrolysis product proportions depend on process conditions, and Section 2 describes temperatures of 600–750 °C and a one-hour heating period. Neither passage says that lower temperatures or longer residence times promote biochar production; searches for those relationships found no supporting passage in our copy. Page numbers were not available. (LLM, conf=0.72)

      Experimental — accuracy not yet measured
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 2

    Biochar application increased pH and organic matter in most degraded monoculture sites.

    “Adekiya et al. (2020) mentioned that biochar application in most degraded monoculture sites increased the pH and enhanced OM.”
    Quote in the paperNot a substantial claim1 of 1 sources checked
    • cites Adekiya et al. (2020) source

      The Results (§3.3; page unavailable) report increased soil organic matter with biochar, and the Discussion (§4; page unavailable) describes an increase in pH, although the Results except pH in 2017 from the increases relative to the control. The study examined one sandy-loam Alfisol site, not “most degraded monoculture sites”; Materials and Methods (§2.1; page unavailable) says it had been fallow for five years after cultivation of several crops. (LLM, conf=0.88)

      Experimental — accuracy not yet measured
  • May combine two claims.

    Findingown data
    § Corn-cob Biochar Characterization and Application Effects to Carbon Dioxide (CO 2 ) Evolution in Acid Soil Added with Different Types of Fertilizers · p. 1

    During incubation, CO2 evolution rose over the first two weeks, peaked on Day 2, and cumulative CO2 declined afterward in every treatment.

    “The CO 2 evolution increased in the first two weeks with a peak at Day 2, and the amount of cumulative CO 2 decreased after that in all treatments during the incubation period.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Findingnone given
    § Corn-cob Biochar Characterization and Application Effects to Carbon Dioxide (CO 2 ) Evolution in Acid Soil Added with Different Types of Fertilizers · p. 1

    Corn-cob biochar has a large surface area and a high average pore size.

    “It also possesses a large surface area and high average pore size.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § BET Analysis · p. 6

    Corn-cob biochar has a BET surface area of 10.416 m2/g, an average pore size of 21.496 Å, and an average pore volume of 0.002 cm3/g.

    “CCB has a higher surface of 10.416 m 2 g - . It also has a larger average pore size of 21.496 Å and a higher average pore volume of 0.002 cm 3 g - .”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § CCB TEM Imaging and EDS · p. 6

    EDS indicates that corn-cob biochar also contains silicon, copper, and potassium.

    “EDS also indicates the presence of other elements such as Si, Cu, and K.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § Organic Fertilizer, Rice Straw, and Gliricidia sepium leaves Chemical Properties · p. 5

    The Luisiana clay loam soil used in the incubation has pH 4.68, electrical conductivity 0.049 mS/cm, organic matter 2.75%, available phosphorus 6.24 ppm, and exchangeable potassium 0.08 cmol(+)/kg soil.

    “| pH (1:1 soil-water) | 4.68 |”
    • Also stated in: § Organic Fertilizer, Rice Straw, and Gliricidia sepium leaves Chemical Properties · p. 5 · plain
      “| Electrical conductivity (mS/cm) | 0.049 |”
    • Also stated in: § Organic Fertilizer, Rice Straw, and Gliricidia sepium leaves Chemical Properties · p. 5 · plain
      “| Organic matter (%OM) | 2.75 |”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § Soil Chemical Properties · p. 5

    Corn-cob biochar has a total potassium content of 2.70%.

    “| Corn-cob | 10.1 | 8.76 | 1.37 | 0.67 | 2.70 | 0.22 | 0.51 | 1024 | 220 | 14 | 85 |”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingnone given
    § Soil Chemical Properties · p. 4

    Soil organic matter rating is moderate at 2.75%.

    “The rating of OM in the soil is moderate at 2.75%.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § Organic Fertilizer, Rice Straw, and Gliricidia sepium leaves Chemical Properties · p. 5

    Gliricidia sepium leaves have nitrogen 3.92%, potassium 2.145%, calcium 1.14%, and total phosphorus 0.23%.

    “As expected, it was analyzed to have higher concentrations of N (3.92%), followed by K (2.145) and Ca (1.14%). However, it has a low total P (0.23%).”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § Soil Chemical Properties · p. 5

    Corn-cob biochar has a copper content of 14 ppm.

    “| Corn-cob | 10.1 | 8.76 | 1.37 | 0.67 | 2.70 | 0.22 | 0.51 | 1024 | 220 | 14 | 85 |”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § CCB Chemical Properties · p. 4

    Calcium concentration is low in corn-cob biochar.

    “Ca concentration is low, while Fe is high at 1024 ppm.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § CCB Chemical Properties · p. 4

    Copper concentration is high at 14 ppm in corn-cob biochar.

    “Mg is low, Zn is very high at 220 ppm, Cu concentration is high at 14 ppm, and Mn is observed to be high at 85 ppm.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § Biochar Production through Slow Pyrolysis by Biochar-producing Cookstove · p. 7

    T1 (soil alone) and T2 (soil plus biochar) had the lowest CO2 evolutions, 9.74 mg and 9.52 mg, respectively, with the smallest difference of 0.22 mg CO2.

    “In contrast, T 1 (soil alone) and T 2 composed of soil and biochar have the lowest evolutions with 9.74 mg and 9.52 mg, respectively, with the lowest difference of 0.22 mg CO 2 .”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § CCB Chemical Properties · p. 4

    Iron concentration is high at 1024 ppm in corn-cob biochar.

    “Ca concentration is low, while Fe is high at 1024 ppm.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § CCB Chemical Properties · p. 4

    Magnesium is low in corn-cob biochar.

    “Mg is low, Zn is very high at 220 ppm, Cu concentration is high at 14 ppm, and Mn is observed to be high at 85 ppm.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § Soil Chemical Properties · p. 5

    Corn-cob biochar has an iron content of 1024 ppm.

    “| Corn-cob | 10.1 | 8.76 | 1.37 | 0.67 | 2.70 | 0.22 | 0.51 | 1024 | 220 | 14 | 85 |”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § Soil Chemical Properties · p. 5

    Corn-cob biochar has a zinc content of 220 ppm.

    “| Corn-cob | 10.1 | 8.76 | 1.37 | 0.67 | 2.70 | 0.22 | 0.51 | 1024 | 220 | 14 | 85 |”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § CO2 Evolution · p. 7

    During the incubation, CO2 release was faster in the first 14 days, peaked on Day two, and then declined in all treatments over the 4-week period.

    “Results show that a faster rate of CO2 release was observed in the first 14 d with a peak at Day two and reduced after that in all treatments during the 4-wk incubation period.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § Total CO2 Evolution · p. 7

    Total CO2 evolution differed highly significantly among treatments (p < 0.01), ordered from T3 (65.39 mg) highest to T2 (9.52 mg) lowest.

    “The total CO 2 evolution of the treatments ordered from highest to lowest were T 3 (65.39 mg), T 4 (63.81 mg), T5 (25.99 mg), T 6 (24.09 mg), T 7 (13.18 mg), T 8 (11.95 mg), T 9 (10.48 mg), T 10 (9.20 mg), T 1 (9.74 mg), and T 2 (9.52 mg), which are highly significantly different ( p &lt; 0.01).”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § Soil Chemical Properties · p. 5

    Corn-cob biochar has a total magnesium content of 0.51%.

    “| Corn-cob | 10.1 | 8.76 | 1.37 | 0.67 | 2.70 | 0.22 | 0.51 | 1024 | 220 | 14 | 85 |”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § Soil Chemical Properties · p. 5

    Corn-cob biochar has a total calcium content of 0.22%.

    “| Corn-cob | 10.1 | 8.76 | 1.37 | 0.67 | 2.70 | 0.22 | 0.51 | 1024 | 220 | 14 | 85 |”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingnone given
    § CCB Chemical Properties · p. 4

    The resultant corn-cob biochar had higher pH and nutrient status than its original feedstock.

    “The resultant CCB had higher pH and nutrient status compared to its original feedstock.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § Soil Chemical Properties · p. 5

    Corn-cob biochar has a manganese content of 85 ppm.

    “| Corn-cob | 10.1 | 8.76 | 1.37 | 0.67 | 2.70 | 0.22 | 0.51 | 1024 | 220 | 14 | 85 |”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § Biochar Production through Slow Pyrolysis by Biochar-producing Cookstove · p. 7

    T3, composed of soil and Gliricidia sepium leaves, had the highest CO2 evolution, followed by T4, composed of soil, Gliricidia sepium leaves, and biochar, with a 1.58 mg CO2 difference.

    “with the highest CO 2 evolution is T 3 composed of soil and Gliricidia sepium leaves, followed by T 4 composed of soil, Gliricidia sepium leaves, and biochar with a 1.58 mg CO2 difference.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § CCB Chemical Properties · p. 4

    Manganese is high at 85 ppm in corn-cob biochar.

    “Mg is low, Zn is very high at 220 ppm, Cu concentration is high at 14 ppm, and Mn is observed to be high at 85 ppm.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § Soil Chemical Properties · p. 5

    Corn-cob biochar has a total nitrogen content of 1.37%.

    “| Corn-cob | 10.1 | 8.76 | 1.37 | 0.67 | 2.70 | 0.22 | 0.51 | 1024 | 220 | 14 | 85 |”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § CCB Production · p. 4

    Corn-cob biochar recovery was 1.75 kg, or 43.75%, from 4 kg biomass.

    “In this study, a recovery of 1.75 kg (43.75%) CCB from 4 kg biomass was recorded.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § CO2 Evolution · p. 7

    T3 produced the highest amount of CO2, followed by T4 and T5.

    “T3 had the highest amount of CO 2 evolved, followed by T4 and T 5 .”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § Biochar Production through Slow Pyrolysis by Biochar-producing Cookstove · p. 7

    The average CO2 evolution across all treatments was 1.42 mg, estimated as 56.81 kg CO2/ha for 2,000,000 kg soil.

    “The average CO 2 evolution from all the treatments is 1.42 mg, estimated to be 56.81 kg CO 2 /ha (2,000,000 kg soil).”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § Soil Chemical Properties · p. 5

    Corn-cob biochar has a total phosphorus content of 0.67%.

    “| Corn-cob | 10.1 | 8.76 | 1.37 | 0.67 | 2.70 | 0.22 | 0.51 | 1024 | 220 | 14 | 85 |”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § Organic Fertilizer, Rice Straw, and Gliricidia sepium leaves Chemical Properties · p. 5

    Organic fertilizer has an organic carbon content of 4.97%, total nitrogen 1.23%, total potassium 2.94%, total calcium 5.40%, total phosphorus 4.43%, and total magnesium 0.26%.

    “The OC, total N, total K, and total Ca are very high at 4.97, 1.23, 2.94, and 5.40%, respectively (Table 4). However, total P and total Mg are low at 4.43 and 0.26%, respectively.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Findingown data
    § Organic Fertilizer, Rice Straw, and Gliricidia sepium leaves Chemical Properties · p. 5

    Rice straw has total nitrogen 1.11%, total potassium 2.34%, total phosphorus 0.15%, total calcium 0.19%, and total magnesium 0.03%.

    “The total N and K are very high in rice straw at 1.11 and 2.34%, respectively. In contrast, total P, Ca, and Mg are very low at 0.15, 0.19, and 0.03%, respectively.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § CCB Chemical Properties · p. 4

    Zinc is very high at 220 ppm in corn-cob biochar.

    “Mg is low, Zn is very high at 220 ppm, Cu concentration is high at 14 ppm, and Mn is observed to be high at 85 ppm.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingown data
    § Biochar Production through Slow Pyrolysis by Biochar-producing Cookstove · p. 8

    Heating 4 kg of raw corn-cob for 1 hour produced 1.75 kg of corn-cob biochar, a 43.75% recovery, at 300-650 °C.

    “In this study, the heating time of 4-kg raw corn-cob is 1 h to produce a 1.75 kg (43.75% recovery) CCB at 300-650 °C heating temperature.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Findingcitation
    § Biochar Properties · p. 8

    HAABF images and elemental X-ray mapping of corn-cob biochar show a precise combination of fine and coarse cellulosic features related to its raw material.

    “The HAABF images and elemental X-ray mapping of CCB show the precise combination of fine and coarse cellulosic features related to its raw material (Villegas-Pangga 2021).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Villegas-Pangga 2021

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Findingown data
    § CONCLUSION · p. 8

    Corn-cob biochar retained most of the carbon and some essential plant elements from the original organic raw material.

    “The CCB retained most of the C and some essential plant elements from the original organic raw material.”
    Quote in the paperSubstantial claim
  • May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 1

    Biochar made by heating biomass under limited oxygen is highly stable and resistant to microbial decay.

    “Biochar produced by the heat treatment of biomass under limited oxygen is highly stable and resistant to microbial decay (Prayogo et al. 2014).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Prayogo et al. 2014 source
  • Classified as probably not a substantial claim. May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 1

    Pyrolysis of waste biomass into biochar is used as a soil amendment to improve soil quality, and storing biochar in soil is regarded as a way to permanently sequester carbon.

    “The pyrolysis conversion of waste biomass into biochar has attracted attention for two reasons. First, it can be used as a soil amendment for improving soil quality; second, storing biochar in soils is regarded as a means for permanently sequestering C (Lehmann et al. 2011).”
    Quote in the paperSubstantial claim0 of 1 sources checked
    • cites Lehmann et al. 2011 source
  • Classified as probably not a substantial claim. May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 1

    Biochars are carbon-rich materials that can sequester carbon in soils and improve soil properties and agronomic performance.

    “Biochars are new, C-rich materials that could sequester C in soils and improve soil properties and agronomic performance (Glaser et al. 2015).”
    Quote in the paperSubstantial claim0 of 1 sources checked
    • cites Glaser et al. 2015

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 2

    Biochar application decreases soil bulk density because biochar has low bulk density and interacts with soil particles to improve aggregation and porosity, thereby improving water holding capacity.

    “BD gradually decreases with increases in biochar applications because it has a natural low BD that can also reduce soil BD by interacting with soil particles and improving aggregation and porosity, which improves water holding capacity as a result.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 1

    Biochar application to soil can reduce CO2, CH4, and N2O.

    “Studies have shown that biochar application into the soil can reduce CO 2 , CH 4 , and N 2 O (Hussain et al. 2016).”
    Quote in the paperSubstantial claim0 of 1 sources checked
    • cites Hussain et al. 2016

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 1

    Biochar consists of recalcitrant carbon structures that prevent decomposition and lead to long-term carbon storage.

    “It is composed of recalcitrant C structures, and these properties prevent biochar from decomposition, which leads to longtime C storage (Surampalli et al. 2015).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Surampalli et al. 2015

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Premisecitation
    § Biochar Properties · p. 8

    Biochar structure can protect beneficial soil microorganisms that decompose organic materials, providing organic matter that binds soil particles and holds nutrients for plant growth.

    “This structure can protect beneficial soil microorganisms that help decompose organic materials providing OM for the soil, which binds together soil particles and holds soil nutrients for plant growth (Atkinson et al. 2010).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Atkinson et al. 2010 source
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Interpretationnone given
    § CCB Chemical Properties · p. 4

    The low total nitrogen in the resultant biochar may be attributable to the heating process.

    “Total N is low in the resultant biochar, which may be attributable to the heating process.”
    Quote in the paperNot a substantial claim
  • May combine two claims.

    Interpretationcitation
    § CO2 Evolution · p. 8

    Even over a short period, biochar addition lowers CO2 evolution, which may relate to long-term storage of atmospheric CO2 and could mitigate or delay global warming.

    “Even in a short period, biochar addition decreases CO 2 evolution, which can be related to long-term storage of atmospheric CO 2 that may mitigate or defer global warming.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § Biochar Properties · p. 8

    Light biomass materials can have larger surface areas, average pore sizes, and pore volumes than woody materials.

    “Villegas-Pangga (2021) stated that light biomass materials can have increased surface areas and average pore size plus pore volume compared to woody materials.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Villegas-Pangga (2021)

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Interpretationcitation
    § BET Analysis · p. 6

    The physical properties of corn-cob biochar shape its important role in soil and related environmental management.

    “These physical properties of CCB influence its essential function in the soil and other related environmental management strategies (Villegas-Pangga 2021).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Villegas-Pangga 2021

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 2

    Biochar stimulates plant growth and increases fertilizer efficiency, especially when mixed with organic fertilizers such as compost.

    “Recent studies have shown that biochar stimulates plant growth and increases fertilizer efficiency, especially when biochar is mixed with organic fertilizers such as compost (Schulz et al. 2013).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Schulz et al. 2013 source
  • Classified as probably not a substantial claim.

    Study design and conductreasoning
    § CO2 Measurement Setup · p. 3

    The incubation glass jar was sealed to prevent gas leakage from decomposing organic materials.

    “This glass jar was sealed to avoid leaking gasses from the decomposing organic materials.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § CCB Chemical Properties · p. 4

    Biochar generally has a very high pH and contains nutrient elements.

    “which is expected since biochar generally has a very high pH and contains nutrient elements (Villegas-Pangga 2021).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Villegas-Pangga 2021

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 2

    Biochar can act as a microbial shelter through its pore structure and maintain nutrients for microbial growth.

    “Interactions between the biochar and the microbes are that biochar can act as a microbial shelter with its pore structure and maintain nutrients for microbial growth (Zhu et al. 2017).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Zhu et al. 2017 source
  • Classified as probably not a substantial claim.

    Interpretationcitation
    § INTRODUCTION · p. 2

    Adding biochar appears to be a more efficient strategy for carbon sequestration.

    “It appears that adding biochar would be a much more efficient strategy for C sequestration.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Interpretationreasoning
    § Biochar Properties · p. 8

    The high pH of biochar may result from its high potassium content, which matches the results of this study.

    “The high pH value of biochar might result from the high K content, which coincides with the results of this study.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Interpretationcitation
    § Biochar Properties · p. 8

    The EDS result showing that corn-cob biochar is mostly carbon may influence its performance as a carbon sink in soil and as a soil amendment.

    “The EDS of CCB showing mostly C can likely influence its performance as a C sink in the soil and essential elements such as soil amendment (Villegas-Pangga 2021).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Villegas-Pangga 2021

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § CCB Chemical Properties · p. 4

    Biochar derived from plant biomass has high carbon concentration and contains macronutrients N, P, K, Ca, Mg and micronutrients Fe, Zn, Cu, Mn.

    “Since biochar is derived from plant biomass, it has a high concentration of C and contains a range of plant macronutrients like N, P, K Ca, Mg, and micronutrients such as Fe, Zn, Cu, and Mn (Naeem et al. 2017).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Naeem et al. 2017

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation
    § Biochar Properties · p. 8

    Biochar products made from different feedstocks can vary in chemical properties even when manufactured by the same process.

    “However, biochar products made from different feedstocks could vary in chemical properties, even if the same process was used to manufacture them (Villegas-Pangga 2021).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Villegas-Pangga 2021

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Interpretationreasoning
    § CCB Chemical Properties · p. 4

    The high total potassium in corn-cob biochar is due to ash components of the biochar.

    “The total P is low, while total K is high due to ash components of the biochar.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § INTRODUCTION · p. 2

    Biochar improves soil nutrient retention, including increased NH4+ and P concentrations, decreased NO3-, and reduced nutrient leaching.

    “Similarly, Surampalli et al. (2015) also state that biochar in the soil improves soil nutrient retention capacity ( e.g. increased NH 4 + and P concentrations and decreased NO 3 - in soil, reduced leaching of nutrients from the soil).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Surampalli et al. 2015

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • May combine two claims.

    Premisecitation
    § CO2 Evolution · p. 8

    Biochar addition reduces carbon loss and increases soil carbon storage.

    “Vasu (2015) revealed that the addition of biochar reduces C loss and increases soil C storage.”
    Quote in the paperSubstantial claim0 of 1 sources checked
    • cites Vasu (2015)

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Premisecitation
    § INTRODUCTION · p. 2

    Biochar addition significantly increased pH in incubated soils.

    “This is supported by also Hailegnaw et al. (2019), stating that biochar addition increased pH significantly in incubated soils.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Hailegnaw et al. (2019)

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim: may not pass S3 (load-bearing).

    Study design and conductown data
    § CO2 Measurement Setup · p. 4

    The incubation study used 10 treatments with three replicates.

    “The 10 treatments with three replicates and the amounts of added materials used in this study are shown in Table 1.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.

    Premisecitation
    § BET Analysis · p. 6

    Biochar application raises soil pH, porosity, and water holding capacity, stabilizes soil organic matter, and lowers soil bulk density and tensile strength.

    “This is confirmed by Hussain et al. (2016), noting that biochar application increases soil pH, porosity, and water holding capacity plus stabilizes soil OM through increased soil aggregation and reduced soil bulk density (SBD) and tensile strength.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Hussain et al. (2016)

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Classified as probably not a substantial claim.

    Study design and conductown data
    § Statistical Analysis · p. 4

    The experiment was arranged in a completely randomized design.

    “The data gathered in this study that was laid out in a completely randomized design were analyzed using oneway analysis of variance and least significant difference (LSD) through the Statistical Tool for Agricultural Research (STAR) 2.0 software developed by the International Rice Research Institute to determine the differences between treatment means at a 5% level of significance by L”
    Quote in the paperSubstantial claim
  • May combine two claims.

    Interpretationreasoning
    § RECOMMENDATION · p. 8

    Carbon is stored in the soil, causing organic carbon to increase, which favors crop productivity.

    “The incubation study showed that the addition of CCB into the soil reduces the CO 2 evolution; hence, C is stored in the soil, causing OC to increase in the ground that favors crop productivity.”
    Quote in the paperSubstantial claim
    • The authors state this as an assumption: Carbon was retained in the soil medium in biochar-treated soil.
73 of 73
  • The paper relies on this without support.

    A gap remains in understanding the mechanisms by which biochar amendment affects soil organic carbon retention and reduces CO2 emissions in acid soil.

    “Further understanding of the mechanisms of biochar amendment on soil organic C retention and CO 2 emission reduction in acid soil still needs to be established.”
  • The authors state this as an assumption.

    Strong soil acidity lowers available phosphorus and causes potassium deficiency in the soil.

    “It is assumed that a strongly acidic lowers available P (6.24 ppm) and makes the soil deficient in K [0.08 cmol (+)/ kg soil] (Table 3).”
  • The authors state this as an assumption.

    Incorporated biochar helps capture CO2 when added into the soil.

    “Findings such as these can be assumed that incorporated biochar helps capture CO 2 when added into the soil.”
  • The authors state this as an assumption.

    Carbon was retained in the soil medium in biochar-treated soil.

    “The low CO 2 evolution in biochar treated soil can be assumed that C was retained in the soil medium.”
  • The paper relies on this without support.

    Organic fertilizer had undergone substantial decomposition.

    “There was low CO 2 evolution observed in both T 9 and T 10 , which had organic fertilizer addition because the organic fertilizer had undergone substantial decomposition.”
5 of 5

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

Each contradiction between two passages listed here was confirmed by an independent check.

  • Per-hectare estimate uses the wrong soil-mass basis

    Major

    The results are expressed per 100 g of soil. At 1.42 mg per 100 g and 2,000,000 kg of soil per hectare, the estimate is 28.4 kg CO2/ha, not 56.81 kg CO2/ha; the latter corresponds approximately to a 50 g basis.

  • The stated highest-to-lowest order is not descending

    Minor

    The list places T10 at 9.20 mg before T1 at 9.74 mg and T2 at 9.52 mg, although it says the treatments are ordered from highest to lowest.

2 of 2

Cites

The publisher hasn’t deposited this paper’s reference list.

Research works printed but not linked: 6

  1. GREWLING T, PEECH M. 1960. Chemical soil tests. Cornell University Agricultural Experimentation Station. Bulletin 960: 34-36.
  2. J, TLUSTOŠ P. 2019. Mutual relationships of biochar and soil pH, CEC, and exchangeable base cations in a model laboratory experiment. Journal of Soils and Sediments 19(5): 2405-2416.
  3. JACKSON ML. 1958. Soil Chemical Analysis. Englewood Cliffs, NJ: Prentice Hall, Inc. p. 46-47.
  4. KI T S O N R E , MELLON MG. 1944. Colorimetric determination of phosphorus as molybdivanadophosphoric acid. Industrial &amp; Engineering Chemistry Analytical Edition 16(6): 379-383.
  5. NAEEM M, ANSARI AA, GILL SS eds. 2017. Essential Plant Nutrients: Uptake, Use Efficiency, and Management. Springer.
  6. VASU D. 2015. Effect of Biochar Addition on Soil Carbon Emission and Nitrogen Mineralization in Some Typical Indian Soils. International Journal of Emerging Research in Management &amp; Technology 2(11): 17-22.

Cited by

Sorted by citations

Authors
Bulfa, A., Villegas-Pangga, G., & Cubelo, J. E.
Affiliations
  • University of the Philippines Los Baños (PH)
  • Silliman University (PH)
Venue
Philippine Journal of Science
Published
2021-07-29
Volume
150
Issue
5
ISSN
0031-7683 (ISSN-L)
OpenAlex
W4312641117
Cited by
3
References
0
Citations by year
2025: 1 · 2023: 2
FWCI
0.28
Type
journal article
Language
en
Open access
Licence
cc-by
Locations
The Philippine journal of science (publishedVersion, cc-by)
Topics
  • Life Sciences › Agricultural and Biological Sciences › Soil Science › Soil Carbon and Nitrogen Dynamics
  • Life Sciences › Agricultural and Biological Sciences › Soil Science › Agricultural Science and Fertilization
  • Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
Keywords
corn cob biochar, CO2 evolution, carbon sequestration, acid soils, soil incubation, organic fertilizer, mineral fertilizers, biochar characterization, soil carbon

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Claims read by deepseek-v4.1-flash under definition version 3 (extract-v3) on 2026-10-01.

Classified by jev-1.13-20260917 (gold-guideline-v0.2) on 2026-10-01.

Cited sources are checked by gpt-6-sol.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review