Single Atoms and Clusters Based Nanomaterials for Hydrogen Evolution, Oxygen Evolution Reactions, and Full Water Splitting

Sultan, Siraj; Tiwari, Jitendra N.; Singh, Aditya Narayan; Zhumagali, Shynggys; Ha, Miran; Myung, Chang Woo; Thangavel, Pandiarajan; Kim, Kwang S.

doi:10.1002/aenm.201900624

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Single Atoms and Clusters Based Nanomaterials for Hydrogen Evolution, Oxygen Evolution Reactions, and Full Water Splitting

Sultan, Siraj, Tiwari, Jitendra N., Singh, Aditya Narayan, Zhumagali, Shynggys, Ha, Miran, Myung, Chang Woo, Thangavel, Pandiarajan, Kim, Kwang S.·2019·Advanced Energy Materials

DOI 10.1002/aenm.201900624

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Abstract

The sustainable and scalable production of hydrogen through hydrogen evolution reaction (HER) and oxygen through oxygen evolution reaction (OER) in water splitting demands efficient and robust electrocatalysts. Currently, state‐of‐the‐art electrocatalysts of Pt and IrO 2/RuO 2 exhibit the benchmark catalytic activity toward HER and OER, respectively. However, expanding their practical application is hindered by their exorbitant price and scarcity. Therefore, the development of alternative effective electrocatalysts for water splitting is crucial. In the last few decades, substantial effort has been devoted to the development of alternative HER/OER and water splitting catalysts based on various transition metals (including Fe, Co, Ni, Mo, and atomic Pt) which show promising catalytic activities and durability. In this review, after a brief introduction and basic mechanism of HER/OER, the authors systematically discuss the recent progress in design, synthesis, and application of single atom and cluster‐based HER/OER and water splitting catalysts. Moreover, the crucial factors that can tune the activity of catalysts toward HER/OER and water splitting such as morphology, crystal defects, hybridization of metals with nonmetals, heteroatom doping, alloying, and formation of metals inside graphitic layered materials are discussed. Finally, the existing challenges and future perspectives for improving the performance of electrocatalysts for water splitting are addressed.

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Authors: Sultan, S., Tiwari, J. N., Singh, A. N., Zhumagali, S., Ha, M., Myung, C. W., Thangavel, P., & Kim, K. S.
Venue: Advanced Energy Materials
Publisher: Wiley
Published: 2019-05-02
Volume: 9
Issue: 22
ISSN: 1614-6832 (ISSN-L)
1614-6840
DOI: 10.1002/aenm.201900624
OpenAlex: W2943354476
Cited by: 815
References: 41
FWCI: 19.58
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Funders: National Research Foundation of Korea (2010‐0020414)

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The paper: Sultan, S., Tiwari, J. N., Singh, A. N., Zhumagali, S., Ha, M., Myung, C. W., Thangavel, P., & Kim, K. S. (2019). Single Atoms and Clusters Based Nanomaterials for Hydrogen Evolution, Oxygen Evolution Reactions, and Full Water Splitting. Advanced Energy Materials. https://doi.org/10.1002/aenm.201900624

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Single Atoms and Clusters Based Nanomaterials for Hydrogen Evolution, Oxygen Evolution Reactions, and Full Water Splitting

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