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Hierarchical Mesoporous SnO2 Nanosheets on Carbon Cloth: A Robust and Flexible Electrocatalyst for CO2 Reduction with High Efficiency and Selectivity
Open accessAbstract
Electrochemical reduction of CO 2 into liquid fuels is a promising approach to achieve a carbon‐neutral energy cycle. However, conventional electrocatalysts usually suffer from low energy efficiency and poor selectivity and stability. A 3D hierarchical structure composed of mesoporous SnO 2 nanosheets on carbon cloth is proposed to efficiently and selectively electroreduce CO 2 to formate in aqueous media. The electrode is fabricated by a facile combination of hydrothermal reaction and calcination. It exhibits an unprecedented partial current density of about 45 mA cm−2 at a moderate overpotential (0.88 V) with high faradaic efficiency (87±2 %), which is even larger than most gas diffusion electrodes. Additionally, the electrode also demonstrates flexibility and long‐term stability. The superior performance is attributed to the robust and highly porous hierarchical structure, which provides a large surface area and facilitates charge and mass transfer.
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Metadata
- Authors
- Li, F., Chen, L., Knowles, G. P., MacFarlane, D. R., & Zhang, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-12-07
- Volume
- 56
- Issue
- 2
- Pages
- 505-509
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2560545729
- Cited by
- 631
- References
- 57
- FWCI
- 18.95
- Type
- journal article
- Language
- en
- Open access
- green
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