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Water depollution using metal-organic frameworks-catalyzed advanced oxidation processes: A review

Sharma, Virender K., Feng, Mingbao·2019·Journal of Hazardous Materials
DOI 10.1016/j.jhazmat.2017.09.043
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Abstract

This paper presents a review on the environmental applications of metal-organic frameworks (MOFs), which are inorganic-organic hybrid highly porous crystalline materials, prepared from metal ion/clusters and multidentate organic ligands. The emphases are made on the enhancement of the performance of advanced oxidation processes (AOPs) (photocatalysis, Fenton reaction methods, and sulfate radical (SO4-)-mediated oxidations) using MOFs materials. MOFs act as adsorption and light absorbers, leading to superior performance of photocatalytic processes. More recent examples of photocatalytic degradation of dyes are presented. Additionally, it is commonly shown that Fe-based MOFs exhibited excellent catalytic performance on the Fenton-based and SO4•--mediated oxidations of organic pollutants (e.g., dyes, phenol and pharmaceuticals). The significantly enhanced generation of reactive species such as OH and/or SO4- by both homogeneous and heterogeneous catalysis was proposed as the possible mechanism for water depollution. Based on the existing literature, the challenge and future perspectives in MOF-based AOPs are addressed.

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Metadata

Authors
Sharma, V. K., & Feng, M.
Venue
Journal of Hazardous Materials
Publisher
Elsevier BV
Published
2019-06
Volume
372
Pages
3-16
ISSN
0304-3894 (ISSN-L)
DOI
10.1016/j.jhazmat.2017.09.043
OpenAlex
W2758550818
Cited by
430
References
4
FWCI
16.04
Type
journal article
Language
en
Open access
closed
Licence
  • www.elsevier.com/tdm/userlicense/1.0/ (tdm)
  • www.elsevier.com/legal/tdmrep-license (tdm)

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Sharma, V. K., & Feng, M. (2019). Water depollution using metal-organic frameworks-catalyzed advanced oxidation processes: A review. Journal of Hazardous Materials. https://doi.org/10.1016/j.jhazmat.2017.09.043

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