Thermochemical Catalytic Liquefaction of the Marine Microalgae Dunaliella tertiolecta and Characterization of Bio-oils
Abstract
Thermochemical catalytic liquefaction (TCL) of the marine microalgae Dunaliella tertiolecta was performed in ethylene glycol acidified with H 2 SO 4 as a catalyst. The mathematical model for predicting the liquefaction yield was set up by a central composite rotatable design (CCRD) and response surface analysis (RSA). A total of 23 individual experiments were conducted to study the effect of H 2 SO 4 concentration, reaction temperature, and reaction time on the liquidation yield. From a regression analysis, the conversion yield of microalgae cells into liquid is simply expressed as a function of the operating variables by polynomial containing quadratic terms. The highest liquefaction yield of microalgae would be 97.05%, at the following optimized reaction conditions: an amount of added H 2 SO 4 of 2.4%, and a reaction temperature of 170 °C, with a 33 min reaction time. To put bio-oils into wide application, the various physical and chemical characteristics of bio-oils at the conditions of the maximum product yields were determined, and the detailed chemical compositional analysis of bio-oils was performed by various spectroscopic techniques such as Fourier transform infrared spectroscopic analysis (FT-IR), carbon-13 nuclear magnetic resonance ( 13 C NMR), and gas chromatography − mass spectrometry (GC-MS). The bio-oils were composed of benzofuranone, fatty acid methyl ester, and fatty acid hydroxyethyl ester, with a long chain from C 14 to C 18 . These bio-oils were presented as an environmentally friendly feedstock candidate for biofuels and chemicals.
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The USA and China had their first contribution in 2009.
“The USA and China had the first contribution in 2009 [41, 42] as shown in Fig. 3b.”
From Research Progress, Trends, and Future Prospects on Hydrothermal Liquefaction of Algae for Biocrude Production: A Bibliometric Analysis (2024) · cites this paper as [42]
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- Authors
- Zou, S., Wu, Y., Yang, M., Li, C., & Tong, J.
- Affiliations
- Shihezi University (CN)
- Corresponding author
- Wu, Yulong
- Yang, Mingde
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-07-16
- Volume
- 23
- Issue
- 7
- Pages
- 3753-3758
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W2077241559
- Cited by
- 150
- References
- 212
- Citations by year
- 2026: 2 · 2025: 4 · 2024: 3 · 2023: 9 · 2022: 7 · 2021: 11 · 2020: 11 · 2019: 8 · 2018: 8 · 2017: 17 · 2016: 7 · 2015: 13 · 2014: 10 · 2013: 16 · 2012: 7
- FWCI
- 4.82
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Energy & Fuels (publishedVersion)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Algal biology and biofuel production
- Physical Sciences › Engineering › Biomedical Engineering › Biodiesel Production and Applications
- Keywords
- Dunaliella tertiolecta, marine microalgae, bio-oil, sulfuric acid catalyst, ethylene glycol, bio-oil composition, fatty acid methyl esters, benzofuranone, biofuel feedstock, central composite rotatable design, response surface analysis
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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