Graphene and its electrochemistry – an update

Electric Field Effect in Atomically Thin Carbon Films

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Two-dimensional gas of massless Dirac fermions in graphene

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The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets

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A roadmap for graphene

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Detection of individual gas molecules adsorbed on graphene

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Carbon-Based Supercapacitors Produced by Activation of Graphene

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Noble metal-free hydrogen evolution catalysts for water splitting

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Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions

Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388

MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction

Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001

Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts

Guo, D., Shibuya, R., Akiba, C., Saji, S., Kondo, T., & Nakamura, J. (2016) · Science · doi:10.1126/science.aad0832 · Cited by 4,230

Review on Recent Progress in Nitrogen-Doped Graphene: Synthesis, Characterization, and Its Potential Applications

Wang, H., Maiyalagan, T., & Wang, X. (2012) · ACS Catalysis · doi:10.1021/cs200652y · Cited by 3,618

Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems

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Advanced Carbon Electrode Materials for Molecular Electrochemistry

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Exploration of the active center structure of nitrogen-doped graphene-based catalysts for oxygen reduction reaction

Lai, L., Potts, J. R., Zhan, D., Wang, L., Poh, C. K., Tang, C., Gong, H., Shen, Z., Lin, J., & Ruoff, R. S. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21802j · Cited by 2,277

Hydrogen evolution by a metal-free electrocatalyst

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Graphene/Polyaniline Nanofiber Composites as Supercapacitor Electrodes

Zhang, K., Zhang, L. L., Zhao, X. S., & Wu, J. (2010) · Chemistry of Materials · doi:10.1021/cm902876u · Cited by 2,234

Nitrogen-Doped Graphene and Its Application in Electrochemical Biosensing

Wang, Y., Shao, Y., Matson, D. W., Li, J., & Lin, Y. (2010) · ACS Nano · doi:10.1021/nn100315s · Cited by 2,155

Sulfur-Doped Graphene as an Efficient Metal-free Cathode Catalyst for Oxygen Reduction

Yang, Z., Yao, Z., Li, G., Fang, G., Nie, H., Liu, Z., Zhou, X., Chen, X., & Huang, S. (2012) · ACS Nano · doi:10.1021/nn203393d · Cited by 2,138

Advancing the Electrochemistry of the Hydrogen‐Evolution Reaction through Combining Experiment and Theory

Zheng, Y., Jiao, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201407031 · Cited by 2,046

Ni(OH) 2 Nanoplates Grown on Graphene as Advanced Electrochemical Pseudocapacitor Materials

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Graphane: A two-dimensional hydrocarbon

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Heteroatom-doped graphene materials: syntheses, properties and applications

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Interfacial processes involving electrocatalytic evolution and oxidation of H2, and the role of chemisorbed H

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Measurement of the quantum capacitance of graphene

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Chemical doping of graphene

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Atomic cobalt on nitrogen-doped graphene for hydrogen generation

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Catalyzing the hydrogen evolution reaction (HER) with molybdenum sulfide nanomaterials

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Fabrication of Graphene/Polyaniline Composite Paper via In Situ Anodic Electropolymerization for High-Performance Flexible Electrode

Wang, D.-W., Li, F., Zhao, J., Ren, W., Chen, Z.-G., Tan, J., Wu, Z.-S., Gentle, I., Lu, G. Q., & Cheng, H.-M. (2009) · ACS Nano · doi:10.1021/nn900297m · Cited by 1,517

Exfoliation of Graphite into Graphene in Aqueous Solutions of Inorganic Salts

Parvez, K., Wu, Z.-S., Li, R., Liu, X., Graf, R., Feng, X., & Müllen, K. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5017156 · Cited by 1,440

Fast and reversible surface redox reaction of graphene–MnO2 composites as supercapacitor electrodes

Yan, J., Fan, Z., Wei, T., Qian, W., Zhang, M., & Wei, F. (2010) · Carbon · doi:10.1016/j.carbon.2010.06.047 · Cited by 1,403

Mechanisms of Oxygen Reduction Reaction on Nitrogen-Doped Graphene for Fuel Cells

Zhang, L., & Xia, Z. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp201991j · Cited by 1,362

Fluorographene: A Two‐Dimensional Counterpart of Teflon

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Enhanced Electron Penetration through an Ultrathin Graphene Layer for Highly Efficient Catalysis of the Hydrogen Evolution Reaction

Deng, J., Ren, P., Deng, D., & Bao, X. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201409524 · Cited by 1,314

3D Macroporous Graphene Frameworks for Supercapacitors with High Energy and Power Densities

Choi, B. G., Yang, M., Hong, W. H., Choi, J. W., & Huh, Y. S. (2012) · ACS Nano · doi:10.1021/nn3003345 · Cited by 1,286

High oxygen-reduction activity and durability of nitrogen-doped graphene

Geng, D., Chen, Y., Chen, Y., Li, Y., Li, R., Sun, X., Ye, S., & Knights, S. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00326c · Cited by 1,219

Electrochemistry of Graphene and Related Materials

Ambrosi, A., Chua, C. K., Bonanni, A., & Pumera, M. (2014) · Chemical Reviews · doi:10.1021/cr500023c · Cited by 1,208

Repeated growth and bubbling transfer of graphene with millimetre-size single-crystal grains using platinum

Gao, L., Ren, W., Xu, H., Jin, L., Wang, Z., Ma, T., Ma, L.-P., Zhang, Z., Fu, Q., Peng, L.-M., et al. (2012) · Nature Communications · doi:10.1038/ncomms1702 · Cited by 1,142

Graphene-based nanomaterials and their electrochemistry

Pumera, M. (2010) · Chemical Society Reviews · doi:10.1039/c002690p · Cited by 1,117

Toward Design of Synergistically Active Carbon-Based Catalysts for Electrocatalytic Hydrogen Evolution

Zheng, Y., Jiao, Y., Li, L. H., Xing, T., Chen, Y., Jaroniec, M., & Qiao, S. Z. (2014) · ACS Nano · doi:10.1021/nn501434a · Cited by 1,060

High-Quality Thin Graphene Films from Fast Electrochemical Exfoliation

Su, C.-Y., Lu, A.-Y., Xu, Y., Chen, F.-R., Khlobystov, A. N., & Li, L.-J. (2011) · ACS Nano · doi:10.1021/nn200025p · Cited by 1,030

Liquid Exfoliation of Defect-Free Graphene

Coleman, J. N. (2013) · Accounts of Chemical Research · doi:10.1021/ar300009f · Cited by 971

Heteroatom-Doped Graphene-Based Materials for Energy-Relevant Electrocatalytic Processes

Duan, J., Chen, S., Jaroniec, M., & Qiao, S. Z. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00991 · Cited by 940

Enhanced Electron Penetration through an Ultrathin Graphene Layer for Highly Efficient Catalysis of the Hydrogen Evolution Reaction

Deng, J., Ren, P., Deng, D., & Bao, X. (2015) · Angewandte Chemie · doi:10.1002/ange.201409524 · Cited by 899

High Catalytic Activity of Nitrogen and Sulfur Co‐Doped Nanoporous Graphene in the Hydrogen Evolution Reaction

Ito, Y., Cong, W., Fujita, T., Tang, Z., & Chen, M. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201410050 · Cited by 896

Nitrogen‐Containing Hydrothermal Carbons with Superior Performance in Supercapacitors

Zhao, L., Fan, L., Zhou, M., Guan, H., Qiao, S., Antonietti, M., & Titirici, M. (2010) · Advanced Materials · doi:10.1002/adma.201002647 · Cited by 893

Surface functional groups of carbons and the effects of their chemical character, density and accessibility to ions on electrochemical performance

Seredych, M., Hulicova-Jurcakova, D., Lu, G. Q., & Bandosz, T. J. (2008) · Carbon · doi:10.1016/j.carbon.2008.06.027 · Cited by 879

Controlled Synthesis of Large‐Area and Patterned Electrochemically Reduced Graphene Oxide Films

Zhou, M., Wang, Y., Zhai, Y., Zhai, J., Ren, W., Wang, F., & Dong, S. (2009) · Chemistry – A European Journal · doi:10.1002/chem.200900596 · Cited by 815

From Conception to Realization: An Historial Account of Graphene and Some Perspectives for Its Future

Dreyer, D. R., Ruoff, R. S., & Bielawski, C. W. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201003024 · Cited by 770

Direct electrodeposition of reduced graphene oxide on glassy carbon electrode and its electrochemical application

Chen, L., Tang, Y., Wang, K., Liu, C., & Luo, S. (2011) · Electrochemistry Communications · doi:10.1016/j.elecom.2010.11.033 · Cited by 761

An Advanced Nitrogen‐Doped Graphene/Cobalt‐Embedded Porous Carbon Polyhedron Hybrid for Efficient Catalysis of Oxygen Reduction and Water Splitting

Hou, Y., Wen, Z., Cui, S., Ci, S., Mao, S., & Chen, J. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201403657 · Cited by 741

Gas adsorption on graphene doped with B, N, Al, and S: A theoretical study

Dai, J., Yuan, J., & Giannozzi, P. (2009) · Applied Physics Letters · doi:10.1063/1.3272008 · Cited by 734

Graphene and carbon nanotube composite electrodes for supercapacitors with ultra-high energy density

Cheng, Q., Tang, J., Ma, J., Zhang, H., Shinya, N., & Qin, L.-C. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp21910c · Cited by 733

Porous 3D graphene-based bulk materials with exceptional high surface area and excellent conductivity for supercapacitors

Zhang, L., Zhang, F., Yang, X., Long, G., Wu, Y., Zhang, T., Leng, K., Huang, Y., Ma, Y., Yu, A., et al. (2013) · Scientific Reports · doi:10.1038/srep01408 · Cited by 721

MoS 2 Formed on Mesoporous Graphene as a Highly Active Catalyst for Hydrogen Evolution

Liao, L., Zhu, J., Bian, X., Zhu, L., Scanlon, M. D., Girault, H. H., & Liu, B. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201300318 · Cited by 705

Porous C3N4 Nanolayers@N-Graphene Films as Catalyst Electrodes for Highly Efficient Hydrogen Evolution

Duan, J., Chen, S., Jaroniec, M., & Qiao, S. Z. (2015) · ACS Nano · doi:10.1021/nn506701x · Cited by 701

On the mechanism of enhanced oxygen reduction reaction in nitrogen-doped graphene nanoribbons

Kim, H., Lee, K., Woo, S. I., & Jung, Y. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp21665a · Cited by 694

Folded Structured Graphene Paper for High Performance Electrode Materials

Liu, F., Song, S., Xue, D., & Zhang, H. (2012) · Advanced Materials · doi:10.1002/adma.201104691 · Cited by 657

Electrochemically Exfoliated Graphene as Solution-Processable, Highly Conductive Electrodes for Organic Electronics

Parvez, K., Li, R., Puniredd, S. R., Hernández, Y., Hinkel, F., Wang, S., Feng, X., & Müllen, K. (2013) · ACS Nano · doi:10.1021/nn400576v · Cited by 645

Electrochemical Delamination of CVD-Grown Graphene Film: Toward the Recyclable Use of Copper Catalyst

Wang, Y., Zheng, Y., Xu, X., Dubuisson, E., Bao, Q., Lu, J., & Loh, K. P. (2011) · ACS Nano · doi:10.1021/nn203700w · Cited by 637

Graphene electrochemistry: fundamental concepts through to prominent applications

Brownson, D. A. C., Kampouris, D. K., & Banks, C. E. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35105f · Cited by 619

Highly Stable Performance of Supercapacitors from Phosphorus-Enriched Carbons

Hulicova-Jurcakova, D., Puziy, A. M., Poddubnaya, O. I., Suárez-García, F., Tascón, J. M. D., & Lu, G. Q. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809265m · Cited by 604

Ionic Liquids as Precursors for Nitrogen‐Doped Graphitic Carbon

Paraknowitsch, J. P., Zhang, J., Su, D., Thomas, A., & Antonietti, M. (2010) · Advanced Materials · doi:10.1002/adma.200900965 · Cited by 603

High-Yield Synthesis of Few-Layer Graphene Flakes through Electrochemical Expansion of Graphite in Propylene Carbonate Electrolyte

Wang, J., Manga, K. K., Bao, Q., & Loh, K. P. (2011) · Journal of the American Chemical Society · doi:10.1021/ja203725d · Cited by 596

Generation of B-Doped Graphene Nanoplatelets Using a Solution Process and Their Supercapacitor Applications

Han, J., Zhang, L. L., Lee, S., Oh, J., Lee, K.-S., Potts, J. R., Ji, J., Zhao, X., Ruoff, R. S., & Park, S. (2013) · ACS Nano · doi:10.1021/nn3034309 · Cited by 577

Supercapacitor Electrodes Obtained by Directly Bonding 2D MoS2 on Reduced Graphene Oxide

da Silveira Firmiano, E. G., Rabelo, A. C., Dalmaschio, C. J., Pinheiro, A. N., Pereira, E. C., Schreiner, W. H., & Leite, E. R. (2014) · Advanced Energy Materials · doi:10.1002/aenm.201301380 · Cited by 529

Charge Transport in Chemically Doped 2D Graphene

Lherbier, A., Blase, X., Niquet, Y.-M., Triozon, F., & Roche, S. (2008) · Physical Review Letters · doi:10.1103/physrevlett.101.036808 · Cited by 525

Graphene supported heterogeneous catalysts: An overview

Julkapli, N. M., & Bagheri, S. (2015) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2014.10.129 · Cited by 515

Stabilization of High-Performance Oxygen Reduction Reaction Pt Electrocatalyst Supported on Reduced Graphene Oxide/Carbon Black Composite

Li, Y., Li, Y., Zhu, E., McLouth, T., Chiu, C.-Y., Huang, X., & Huang, Y. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3031449 · Cited by 490

Solution Processable Holey Graphene Oxide and Its Derived Macrostructures for High-Performance Supercapacitors

Xu, Y., Chen, C.-Y., Zhao, Z., Lin, Z., Lee, C., Xu, X., Wang, C., Huang, Y., Shakir, M. I., & Duan, X. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b01212 · Cited by 473

Achieving high specific charge capacitances in Fe3O4/reduced graphene oxide nanocomposites

Shi, W., Zhu, J., Sim, D. H., Tay, Y. Y., Lu, Z., Zhang, X., Sharma, Y., Srinivasan, M., Zhang, H., Hng, H. H., et al. (2011) · Journal of Materials Chemistry · doi:10.1039/c0jm03175e · Cited by 470

Characterization of MoS2–Graphene Composites for High-Performance Coin Cell Supercapacitors

Bissett, M. A., Kinloch, I. A., & Dryfe, R. A. W. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b04672 · Cited by 461

Graphene oxide: the new membrane material

Joshi, R. K., Alwarappan, S., Yoshimura, M., Sahajwalla, V., & Nishina, Y. (2015) · Applied Materials Today · doi:10.1016/j.apmt.2015.06.002 · Cited by 450

B, N- and P, N-doped graphene as highly active catalysts for oxygen reduction reactions in acidic media

Choi, C. H., Chung, M. W., Kwon, H. C., Park, S. H., & Woo, S. I. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta01648j · Cited by 442

Nitrogen doping of graphene and its effect on quantum capacitance, and a new insight on the enhanced capacitance of N-doped carbon

Zhang, L. L., Zhao, X., Ji, H., Stoller, M. D., Lai, L., Murali, S., Mcdonnell, S., Cleveger, B., Wallace, R. M., & Ruoff, R. S. (2012) · Energy & Environmental Science · doi:10.1039/c2ee23442d · Cited by 441

Band gap opening of monolayer and bilayer graphene doped with aluminium, silicon, phosphorus, and sulfur

Denis, P. A. (2010) · Chemical Physics Letters · doi:10.1016/j.cplett.2010.04.038 · Cited by 437

Catalytic Mechanisms of Sulfur-Doped Graphene as Efficient Oxygen Reduction Reaction Catalysts for Fuel Cells

Zhang, L., Niu, J., Li, M., & Xia, Z. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp410501u · Cited by 432

3D WS2 Nanolayers@Heteroatom‐Doped Graphene Films as Hydrogen Evolution Catalyst Electrodes

Duan, J., Chen, S., Chambers, B. A., Andersson, G. G., & Qiao, S. Z. (2015) · Advanced Materials · doi:10.1002/adma.201501692 · Cited by 421

Dispersing Carbon Nanotubes with Graphene Oxide in Water and Synergistic Effects between Graphene Derivatives

Qiu, L., Yang, X., Gou, X., Yang, W., Ma, Z., Wallace, G. G., & Li, D. (2010) · Chemistry – A European Journal · doi:10.1002/chem.201001771 · Cited by 408

Design and tailoring of a hierarchical graphene-carbon nanotube architecture for supercapacitors

Yang, S.-Y., Chang, K.-H., Tien, H.-W., Lee, Y.-F., Li, S.-M., Wang, Y.-S., Wang, J.-Y., Ma, C.-C. M., & Hu, C.-C. (2011) · J. Mater. Chem. · doi:10.1039/c0jm03199b · Cited by 407

Halogenated Graphenes: Rapidly Growing Family of Graphene Derivatives

Karlický, F., Kumara Ramanatha Datta, K., Otyepka, M., & Zbořil, R. (2013) · ACS Nano · doi:10.1021/nn4024027 · Cited by 397

Sulfur-Doped Graphene via Thermal Exfoliation of Graphite Oxide in H2S, SO2, or CS2 Gas

Poh, H. L., Šimek, P., Sofer, Z., & Pumera, M. (2013) · ACS Nano · doi:10.1021/nn401296b · Cited by 372

“Metal‐Free” Catalytic Oxygen Reduction Reaction on Heteroatom‐Doped Graphene is Caused by Trace Metal Impurities

Wang, L., Ambrosi, A., & Pumera, M. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201309171 · Cited by 367

Highly efficient and large-scale synthesis of graphene by electrolytic exfoliation

Wang, G., Wang, B., Park, J., Wang, Y., Sun, B., & Yao, J. (2009) · Carbon · doi:10.1016/j.carbon.2009.07.040 · Cited by 350

Graphane and hydrogenated graphene

Pumera, M., & Wong, C. H. A. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60132c · Cited by 346

Organic Radical-Assisted Electrochemical Exfoliation for the Scalable Production of High-Quality Graphene

Yang, S., Brüller, S., Wu, Z.-S., Liu, Z., Parvez, K., Dong, R., Richard, F., Samorì, P., Feng, X., & Müllen, K. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09000 · Cited by 344

N-Doped Carbon-Wrapped Cobalt Nanoparticles on N-Doped Graphene Nanosheets for High-Efficiency Hydrogen Production

Zhou, W., Zhou, J., Zhou, Y., Lu, J., Zhou, K., Yang, L., Tang, Z., Li, L., & Chen, S. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00331 · Cited by 339

Metal-free B-doped graphene with efficient electrocatalytic activity for hydrogen evolution reaction

Sathe, B. R., Zou, X., & Asefa, T. (2014) · Catal. Sci. Technol. · doi:10.1039/c4cy00075g · Cited by 308

High performance supercapacitors using metal oxide anchored graphene nanosheet electrodes

Rakhi, R. B., Chen, W., Cha, D., & Alshareef, H. N. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm12963e · Cited by 307

Electrochemically Exfoliated Graphene and Graphene Oxide for Energy Storage and Electrochemistry Applications

Ambrosi, A., & Pumera, M. (2016) · Chemistry – A European Journal · doi:10.1002/chem.201503110 · Cited by 305

Highly selective amperometric nitrite sensor based on chemically reduced graphene oxide modified electrode

Mani, V., Periasamy, A. P., & Chen, S. (2012) · Electrochemistry Communications · doi:10.1016/j.elecom.2012.02.009 · Cited by 305

Nanotrench Arrays Reveal Insight into Graphite Electrochemistry

Davies, T. J., Hyde, M. E., & Compton, R. G. (2005) · Angewandte Chemie · doi:10.1002/ange.200462750 · Cited by 302

Nitrogen-Doped Graphene with Pyridinic Dominance as a Highly Active and Stable Electrocatalyst for Oxygen Reduction

Wu, J., Ma, L., Yadav, R. M., Yang, Y., Zhang, X., Vajtai, R., Lou, J., & Ajayan, P. M. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b02902 · Cited by 294

Recent advances in layered transition metal dichalcogenides for hydrogen evolution reaction

Yang, J., & Shin, H. S. (2014) · J. Mater. Chem. A · doi:10.1039/c3ta14151a · Cited by 292

α-Fe2O3 nanotubes-reduced graphene oxide composites as synergistic electrochemical capacitor materials

Lee, K. K., Deng, S., Fan, H. M., Mhaisalkar, S., Tan, H. R., Tok, E. S., Loh, K. P., Chin, W. S., & Sow, C. H. (2012) · Nanoscale · doi:10.1039/c2nr11902a · Cited by 279

Synthesis of Phosphorus‐Doped Graphene and its Wide Potential Window in Aqueous Supercapacitors

Wen, Y., Wang, B., Huang, C., Wang, L., & Hulicova‐Jurcakova, D. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201404779 · Cited by 276

Single stage electrochemical exfoliation method for the production of few-layer graphene via intercalation of tetraalkylammonium cations

Cooper, A. J., Wilson, N. R., Kinloch, I. A., & Dryfe, R. A. W. (2014) · Carbon · doi:10.1016/j.carbon.2013.09.009 · Cited by 269

Assembly of Graphene Oxide–Enzyme Conjugates through Hydrophobic Interaction

Zhang, Y., Zhang, J., Huang, X., Zhou, X., Wu, H., & Guo, S. (2012) · Small · doi:10.1002/smll.201101695 · Cited by 268

Thin films of carbon nanotubes and chemically reduced graphenes for electrochemical micro-capacitors

Byon, H. R., Lee, S. W., Chen, S., Hammond, P. T., & Shao-Horn, Y. (2011) · Carbon · doi:10.1016/j.carbon.2010.09.042 · Cited by 263

Molybdenum sulfide clusters-nitrogen-doped graphene hybrid hydrogel film as an efficient three-dimensional hydrogen evolution electrocatalyst

Chen, S., Duan, J., Tang, Y., Jin, B., & Zhang Qiao, S. (2015) · Nano Energy · doi:10.1016/j.nanoen.2014.09.022 · Cited by 243

N-Doped Graphene Nanoplatelets as Superior Metal-Free Counter Electrodes for Organic Dye-Sensitized Solar Cells

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Is It Possible to Dope Single‐Walled Carbon Nanotubes and Graphene with Sulfur?

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The synthesis of graphene sheets with controlled thickness and order using surfactant-assisted electrochemical processes

Alanyalıoğlu, M., Segura, J. J., Oró-Solè, J., & Casañ-Pastor, N. (2012) · Carbon · doi:10.1016/j.carbon.2011.07.064 · Cited by 231

Improved synthesis of graphene flakes from the multiple electrochemical exfoliation of graphite rod

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INVESTIGATION OF HOMOLOGOUS SERIES AS PRECURSORY HYDROCARBONS FOR ALIGNED CARBON NANOTUBE FORMATION BY THE SPRAY PYROLYSIS METHOD

YANG, Z., NIE, H., ZHOU, X., YAO, Z., HUANG, S., & CHEN, X. (2011) · Nano · doi:10.1142/s1793292011002536 · Cited by 228

Fabrication of Co3O4-reduced graphene oxide scrolls for high-performance supercapacitor electrodes

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A facile preparation route for boron-doped graphene, and its CdTe solar cell application

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Chemically reduced graphene contains inherent metallic impurities present in parent natural and synthetic graphite

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One-step strategy to graphene/Ni(OH)2 composite hydrogels as advanced three-dimensional supercapacitor electrode materials

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Activation of graphene aerogel with phosphoric acid for enhanced electrocapacitive performance

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Role of Peroxide Ions in Formation of Graphene Nanosheets by Electrochemical Exfoliation of Graphite

Rao, K. S., Senthilnathan, J., Liu, Y.-F., & Yoshimura, M. (2014) · Scientific Reports · doi:10.1038/srep04237 · Cited by 197

Cobalt Nanoparticles Embedded in Nitrogen-Doped Carbon for the Hydrogen Evolution Reaction

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Three-dimensional Nitrogen-Doped Graphene Supported Molybdenum Disulfide Nanoparticles as an Advanced Catalyst for Hydrogen Evolution Reaction

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Selective nitrogen doping in graphene for oxygen reduction reactions

Yasuda, S., Yu, L., Kim, J., & Murakoshi, K. (2013) · Chemical Communications · doi:10.1039/c3cc45641b · Cited by 185

First-principles molecular dynamics simulation of O2 reduction on nitrogen-doped carbon

Okamoto, Y. (2009) · Applied Surface Science · doi:10.1016/j.apsusc.2009.08.027 · Cited by 184

Metallic Impurities in Graphenes Prepared from Graphite Can Dramatically Influence Their Properties

Ambrosi, A., Chee, S. Y., Khezri, B., Webster, R. D., Sofer, Z., & Pumera, M. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201106917 · Cited by 174

Electrochemical sensor based on graphene and mesoporous TiO2 for the simultaneous determination of trace colourants in food

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Vanadium oxide nanowire – Graphene binder free nanocomposite paper electrodes for supercapacitors: A facile green approach

Perera, S. D., Liyanage, A. D., Nijem, N., Ferraris, J. P., Chabal, Y. J., & Balkus, K. J. (2013) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.11.118 · Cited by 164

The synthesis of shape-controlled MnO2/graphene composites via a facile one-step hydrothermal method and their application in supercapacitors

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S-doped micro/mesoporous carbon–graphene composites as efficient supercapacitors in alkaline media

Seredych, M., & Bandosz, T. J. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta12252b · Cited by 159

Synthetic routes contaminate graphene materials with a whole spectrum of unanticipated metallic elements

Wong, C. H. A., Sofer, Z., Kubešová, M., Kučera, J., Matějková, S., & Pumera, M. (2014) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1413389111 · Cited by 157

Greener Electrochemical Synthesis of High Quality Graphene Nanosheets Directly from Pencil and its SPR Sensing Application

Singh, V. V., Gupta, G., Batra, A., Nigam, A. K., Boopathi, M., Gutch, P. K., Tripathi, B. K., Srivastava, A., Samuel, M., Agarwal, G. S., et al. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201102525 · Cited by 150

Fabrication of β-cyclodextrin-coated poly (diallyldimethylammonium chloride)-functionalized graphene composite film modified glassy carbon-rotating disk electrode and its application for simultaneous electrochemical determination colorants of sunset yellow and tartrazine

Ye, X., Du, Y., Lu, D., & Wang, C. (2013) · Analytica Chimica Acta · doi:10.1016/j.aca.2013.03.061 · Cited by 146

Impurities in graphenes and carbon nanotubes and their influence on the redox properties

Pumera, M., Ambrosi, A., & Chng, E. (2012) · Chemical Science · doi:10.1039/c2sc21374e · Cited by 140

Self‐Assembled 3D Graphene‐Based Aerogel with Co3O4 Nanoparticles as High‐Performance Asymmetric Supercapacitor Electrode

Xie, L., Su, F., Xie, L., Li, X., Liu, Z., Kong, Q., Guo, X., Zhang, Y., Wan, L., Li, K., et al. (2015) · ChemSusChem · doi:10.1002/cssc.201500355 · Cited by 138

Enhancement of the energy storage properties of supercapacitors using graphene nanosheets dispersed with metal oxide-loaded carbon nanotubes

Rakhi, R. B., & Alshareef, H. N. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2011.06.038 · Cited by 134

High-quality few layer graphene produced by electrochemical intercalation and microwave-assisted expansion of graphite

Morales, G. M., Schifani, P., Ellis, G., et al. (2011) · Carbon · doi:10.1016/j.carbon.2011.03.008 · Cited by 130

Boron-Doped Graphene: Scalable and Tunable p-Type Carrier Concentration Doping

Wang, L., Sofer, Z., Šimek, P., et al. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp405169j · Cited by 129

Electrochemistry of titanium dioxide: some aspects and highlights

Kavan, L. (2011) · The Chemical Record · doi:10.1002/tcr.201100012 · Cited by 127

Precise Tuning of Surface Composition and Electron‐Transfer Properties of Graphene Oxide Films through Electroreduction

Ambrosi, A., & Pumera, M. (2013) · Chemistry - A European Journal · doi:10.1002/chem.201204226 · Cited by 123

Magnesiothermic synthesis of sulfur-doped graphene as an efficient metal-free electrocatalyst for oxygen reduction

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An electrochemical ELISA-like immunosensor for miRNAs detection based on screen-printed gold electrodes modified with reduced graphene oxide and carbon nanotubes

Tran, H. V., Piro, B., Reisberg, S., Nguyen, H. L., Nguyen, T. D., Duc, H. T., & Pham, M. (2014) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2014.06.014 · Cited by 117

Cobalt-nickel bimetallic nanoparticles decorated graphene sensitized imprinted electrochemical sensor for determination of octylphenol

Fang, L., Zhang, Z., Wang, J., Liang, Y., & Biwu, Z. (2015) · Electrochimica Acta · doi:10.1016/j.electacta.2015.04.054 · Cited by 116

Nitrogen‐ and Phosphorus‐Doped Nanoporous Graphene/Graphitic Carbon Nitride Hybrids as Efficient Electrocatalysts for Hydrogen Evolution

Shinde, S. S., Sami, A., & Lee, J. (2015) · ChemCatChem · doi:10.1002/cctc.201500701 · Cited by 114

Graphene materials preparation methods have dramatic influence upon their capacitance

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Micelle-Template Synthesis of Nitrogen-Doped Mesoporous Graphene as an Efficient Metal-Free Electrocatalyst for Hydrogen Production

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‘Bubble-Free’ Electrochemical Delamination of CVD Graphene Films

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Unusual Inherent Electrochemistry of Graphene Oxides Prepared Using Permanganate Oxidants

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Chemical nature of boron and nitrogen dopant atoms in graphene strongly influences its electronic properties

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Multi-nanomaterial electrochemical biosensor based on label-free graphene for detecting cancer biomarkers

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Influence of multi-walled carbon nanotubes on the electrochemical performance of graphene nanocomposites for supercapacitor electrodes

Kim, K.-S., & Park, S. (2010) · Electrochimica Acta · doi:10.1016/j.electacta.2010.10.043 · Cited by 102

Nanostructured SnS-N-doped graphene as an advanced electrocatalyst for the hydrogen evolution reaction

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Sulfur-doped graphene as a catalyst support: Influences of carbon black and ruthenium nanoparticles on the hydrogen evolution reaction performance

Shervedani, R. K., & Amini, A. (2015) · Carbon · doi:10.1016/j.carbon.2015.05.088 · Cited by 91

Lipid–Lipid Interactions in Aminated Reduced Graphene Oxide Interface for Biosensing Application

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Oxidation Debris in Graphene Oxide Is Responsible for Its Inherent Electroactivity

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Highly dual-doped multilayer nanoporous graphene: efficient metal-free electrocatalysts for the hydrogen evolution reaction

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Sensitive bi-enzymatic biosensor based on polyphenoloxidases–gold nanoparticles–chitosan hybrid film–graphene doped carbon paste electrode for carbamates detection

Oliveira, T. M. B. F., Barroso, M. F., Morais, S., Araújo, M. D. S., Freire, C., de Lima‐Neto, P., Correia, A. N., Oliveira, M. B. P. P., & Delerue-Matos, C. M. (2014) · Bioelectrochemistry · doi:10.1016/j.bioelechem.2014.02.003 · Cited by 84

Preparation of nitrogen-doped mesoporous carbon nanopipes for the electrochemical double layer capacitor

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Flexible and porous catalyst electrodes constructed by Co nanoparticles@nitrogen-doped graphene films for highly efficient hydrogen evolution

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Soft Processing of Graphene Nanosheets by Glycine‐Bisulfate Ionic‐Complex‐Assisted Electrochemical Exfoliation of Graphite for Reduction Catalysis

Rao, K. S., Sentilnathan, J., Cho, H., Wu, J., & Yoshimura, M. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201402621 · Cited by 82

Ultrasensitive multi-analyte electrochemical immunoassay based on GNR-modified heated screen-printed carbon electrodes and PS@PDA-metal labels for rapid detection of MMP-9 and IL-6

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Boron and nitrogen doping of graphene via thermal exfoliation of graphite oxide in a BF3 or NH3 atmosphere: contrasting properties

Poh, H. L., Šimek, P., Sofer, Z., TOMANDL, I., & Pumera, M. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta12460f · Cited by 79

Heteroatom modified graphenes: electronic and electrochemical applications

Pumera, M. (2014) · Journal of Materials Chemistry C · doi:10.1039/c4tc00336e · Cited by 78

CO 2 -activated, hierarchical trimodal porous graphene frameworks for ultrahigh and ultrafast capacitive behavior

Yun, S., Kang, S., Park, S., & Park, H. S. (2014) · Nanoscale · doi:10.1039/c4nr00713a · Cited by 72

Boron-doped graphene and boron-doped diamond electrodes: detection of biomarkers and resistance to fouling

Tan, S. M., Poh, H. L., Sofer, Z., & Pumera, M. (2013) · The Analyst · doi:10.1039/c3an00535f · Cited by 67

Impedimetric Detection of microRNA at Graphene Oxide Modified Sensors

Çongur, G., Ekşin, E., & Erdem, A. (2015) · Electrochimica Acta · doi:10.1016/j.electacta.2015.03.210 · Cited by 66

Graphene oxide-based biosensor for detection of platelet-derived microparticles: A potential tool for thrombus risk identification

Kailashiya, J., Singh, N. K., Singh, S. K., Agrawal, V. K., & Dash, D. (2014) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2014.10.056 · Cited by 62

Direct Delamination of Graphene for High‐Performance Plastic Electronics

Wang, X., Tao, L., Hao, Y., Liu, Z., Chou, H., Kholmanov, I. N., Chen, S., Tan, C. C., Jayant, N., Yu, Q., et al. (2013) · Small · doi:10.1002/smll.201301892 · Cited by 60

Improved heterogeneous electron transfer kinetics of fluorinated graphene derivatives

Boopathi, S., Narayanan, T. N., & Kumar, S. S. (2014) · Nanoscale · doi:10.1039/c4nr02563f · Cited by 58

Enhanced Oxygen Reduction Reactions in Fuel Cells on H‐Decorated and B‐Substituted Graphene

Kong, X., Chen, Q., & Sun, Z. (2013) · ChemPhysChem · doi:10.1002/cphc.201200918 · Cited by 57

Thrombin aptasensing with inherently electroactive graphene oxide nanoplatelets as labels

Loo, A. H., Bonanni, A., & Pumera, M. (2013) · Nanoscale · doi:10.1039/c3nr00511a · Cited by 57

Graphene Oxide Nanoribbons from the Oxidative Opening of Carbon Nanotubes Retain Electrochemically Active Metallic Impurities

Wong, C. H. A., Chua, C. K., Khezri, B., Webster, R. D., & Pumera, M. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201303837 · Cited by 56

Single pot electrochemical synthesis of functionalized and phosphorus doped graphene nanosheets for supercapacitor applications

Thirumal, V., Pandurangan, A., Jayavel, R., et al. (2015) · Journal of Materials Science Materials in Electronics · doi:10.1007/s10854-015-3219-5 · Cited by 54

Graphene platforms for the detection of caffeine in real samples

Khoo, W. Y. H., Pumera, M., & Bonanni, A. (2013) · Analytica Chimica Acta · doi:10.1016/j.aca.2013.09.062 · Cited by 53

Facile Synthesis of In–Situ Nitrogenated Graphene Decorated by Few–Layer MoS 2 for Hydrogen Evolution Reaction

Dai, X., Li, Z., Du, K., Sun, H., Yang, Y. K., Zhang, X., Ma, X., & Wang, J. X. (2015) · Electrochimica Acta · doi:10.1016/j.electacta.2015.05.017 · Cited by 49

Capacitance of p‐ and n‐Doped Graphenes is Dominated by Structural Defects Regardless of the Dopant Type

Ambrosi, A., Poh, H. L., Wang, L., Sofer, Z., & Pumera, M. (2014) · ChemSusChem · doi:10.1002/cssc.201400013 · Cited by 48

Microwave-assisted solvothermal synthesis of sulfur-doped graphene for electrochemical sensing

Liu, Y., Ma, Y., Jin, Y., Chen, G., & Zhang, X. (2015) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2014.12.025 · Cited by 47

Wet-chemical nitrogen-doping of graphene nanoplatelets as electrocatalysts for the oxygen reduction reaction

Chang, D. W., Choi, H., & Baek, J. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta07035f · Cited by 44

Clean and efficient transfer of CVD-grown graphene by electrochemical etching of metal substrate

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Chemical Preparation of Graphene Materials Results in Extensive Unintentional Doping with Heteroatoms and Metals

Chua, C. K., Ambrosi, A., Sofer, Z., et al. (2014) · Chemistry - A European Journal · doi:10.1002/chem.201404205 · Cited by 44

Inherent Electrochemistry and Activation of Chemically Modified Graphenes for Electrochemical Applications

Moo, J. G. S., Ambrosi, A., Bonanni, A., & Pumera, M. (2012) · Chemistry - An Asian Journal · doi:10.1002/asia.201100852 · Cited by 43

Simple and label-free detection of DNA hybridization on a modified graphene nanosheets electrode

Benvidi, A., Rajabzadeh, N., Zahedi, H. M., Mazloum‐Ardakani, M., Heidari, M., & Hosseinzadeh, L. (2015) · Talanta · doi:10.1016/j.talanta.2015.01.035 · Cited by 39

Simple and signal-off electrochemical biosensor for mercury(II) based on thymine-mercury-thymine hybridization directly on graphene

Zhang, Y., Xie, J., Liu, Y., Pang, P., Feng, L., Wang, H., Wu, Z., & Yang, W. R. (2015) · Electrochimica Acta · doi:10.1016/j.electacta.2015.04.152 · Cited by 35

Transition Metal‐Depleted Graphenes for Electrochemical Applications via Reduction of CO2 by Lithium

Poh, H. L., Sofer, Z., Luxa, J., & Pumera, M. (2013) · Small · doi:10.1002/smll.201303002 · Cited by 33

Tryptamine functionalized reduced graphene oxide for label-free DNA impedimetric biosensing

Zhang, Z., Luo, L., Chen, G., Ding, Y., Deng, D., & Fan, C. (2014) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2014.03.067 · Cited by 31

Gold Nanospacers Greatly Enhance the Capacitance of Electrochemically Reduced Graphene

Buglione, L., Bonanni, A., Ambrosi, A., & Pumera, M. (2011) · ChemPlusChem · doi:10.1002/cplu.201100016 · Cited by 26

Could Carbonaceous Impurities in Reduced Graphenes be Responsible for Some of Their Extraordinary Electrocatalytic Activities?

Wang, L., Ambrosi, A., & Pumera, M. (2013) · Chemistry - An Asian Journal · doi:10.1002/asia.201300122 · Cited by 20

Partially Reduced Graphene Oxide Paper: A Thin Film Electrode for Electrochemical Capacitors

Hantel, M. M., Kaspar, T., Nesper, R., Wokaun, A. J., & Kötz, R. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.019306jes · Cited by 18

CVD graphene based immunosensor

Loo, A. H., Ambrosi, A., Bonanni, A., et al. (2014) · RSC Advances · doi:10.1039/c4ra03506b · Cited by 16

Metallic impurities availability in reduced graphene is greatly enhanced by its ultrasonication

Toh, R. J., & Pumera, M. (2013) · Faraday Discussions · doi:10.1039/c3fd00005b · Cited by 9

Recent progress in 2D group-VA semiconductors: from theory to experiment

Zhang, S., Guo, S., Chen, Z., Wang, Y., Gao, H., Gómez-Herrero, J., Ares, P., Zamora, F., Zhu, Z., & Zeng, H. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00125h · Cited by 850

Heteroatom doped graphene engineering for energy storage and conversion

Kumar, R., Sahoo, S., Joanni, E., Singh, R. K., Maegawa, K., Tan, W. K., Kawamura, G., Kar, K. K., & Matsuda, A. (2020) · Materials Today · doi:10.1016/j.mattod.2020.04.010 · Cited by 681

Recent progress in the synthesis of graphene and derived materials for next generation electrodes of high performance lithium ion batteries

Kumar, R., Sahoo, S., Joanni, E., Singh, R. K., Tan, W. K., Kar, K. K., & Matsuda, A. (2019) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2019.100786 · Cited by 554

Two‐Dimensional Metal Oxide Nanomaterials for Next‐Generation Rechargeable Batteries

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Two-Dimensional (2D) Nanomaterials towards Electrochemical Nanoarchitectonics in Energy-Related Applications

Khan, A. H., Ghosh, S., Pradhan, B., Dalui, A., Shrestha, L. K., Acharya, S., & Ariga, K. (2017) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20170043 · Cited by 432