Surface chemistry and catalysis confined under two-dimensional materials

The rise of graphene

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Graphene: Status and Prospects

Geim, A. K. (2009) · Science · doi:10.1126/science.1158877 · Cited by 13,942

Two-dimensional atomic crystals

Novoselov, K. S., Jiang, D., Schedin, F., Booth, T. J., Khotkevich, V. V., Morozov, S. V., & Geim, A. K. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0502848102 · Cited by 11,788

The chemistry of graphene oxide

Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010) · Chem. Soc. Rev. · doi:10.1039/b917103g · Cited by 11,653

Van der Waals heterostructures

Geim, A. K., & Grigorieva, I. V. (2013) · Nature · doi:10.1038/nature12385 · Cited by 10,875

The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets

Chhowalla, M., Shin, H. S., Eda, G., Li, L.-J., Loh, K. P., & Zhang, H. (2013) · Nature Chemistry · doi:10.1038/nchem.1589 · Cited by 10,034

2D materials and van der Waals heterostructures

Novoselov, K. S., Mishchenko, A., Carvalho, A., & Castro Neto, A. H. (2016) · Science · doi:10.1126/science.aac9439 · Cited by 7,434

Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials

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Honeycomb Carbon: A Review of Graphene

Allen, M. J., Tung, V. C., & Kaner, R. B. (2010) · Chemical Reviews · doi:10.1021/cr900070d · Cited by 6,998

The structure of suspended graphene sheets

Meyer, J. C., Geim, A. K., Katsnelson, M. I., Novoselov, K. S., Booth, T. J., & Roth, S. (2007) · Nature · doi:10.1038/nature05545 · Cited by 5,032

Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene

Butler, S. Z., Hollen, S. M., Cao, L., Cui, Y., Gupta, J. A., Gutiérrez, H. R., Heinz, T. F., Hong, S. S., Huang, J., Ismach, A. F., et al. (2013) · ACS Nano · doi:10.1021/nn400280c · Cited by 4,878

Graphene-Like Two-Dimensional Materials

Xu, M., Liang, T., Shi, M., & Chen, H. (2013) · Chemical Reviews · doi:10.1021/cr300263a · Cited by 4,531

Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts

Guo, D., Shibuya, R., Akiba, C., Saji, S., Kondo, T., & Nakamura, J. (2016) · Science · doi:10.1126/science.aad0832 · Cited by 4,230

Control of Graphene's Properties by Reversible Hydrogenation: Evidence for Graphane

Elias, D. C., Nair, R. R., Mohiuddin, T. M. G., Morozov, S. V., Blake, P., Halsall, M. P., Ferrari, A. C., Boukhvalov, D. W., Katsnelson, M. I., Geim, A. K., et al. (2009) · Science · doi:10.1126/science.1167130 · Cited by 4,163

Towards the computational design of solid catalysts

Nørskov, J. K., Bligaard, T., Rossmeisl, J., & Christensen, C. H. (2009) · Nature Chemistry · doi:10.1038/nchem.121 · Cited by 4,161

Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells

Qu, L., Liu, Y., Baek, J.-B., & Dai, L. (2010) · ACS Nano · doi:10.1021/nn901850u · Cited by 3,948

Silicene: Compelling Experimental Evidence for Graphenelike Two-Dimensional Silicon

Vogt, P., De Padova, P., Quaresima, C., Avila, J., Frantzeskakis, E., Asensio, M. C., Resta, A., Ealet, B., & Le Lay, G. (2012) · Physical Review Letters · doi:10.1103/physrevlett.108.155501 · Cited by 3,903

Liquid Exfoliation of Layered Materials

Nicolosi, V., Chhowalla, M., Kanatzidis, M. G., Strano, M. S., & Coleman, J. N. (2013) · Science · doi:10.1126/science.1226419 · Cited by 3,796

Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications

Chen, D., Feng, H., & Li, J. (2012) · Chemical Reviews · doi:10.1021/cr300115g · Cited by 3,531

Impermeable Atomic Membranes from Graphene Sheets

Bunch, J. S., Verbridge, S. S., Alden, J. S., van der Zande, A. M., Parpia, J. M., Craighead, H. G., & McEuen, P. L. (2008) · Nano Letters · doi:10.1021/nl801457b · Cited by 2,919

Van der Waals heterostructures and devices

Liu, Y., Weiss, N. O., Duan, X., Cheng, H.-C., Huang, Y., & Duan, X. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.42 · Cited by 2,793

Synthesis of borophenes: Anisotropic, two-dimensional boron polymorphs

Mannix, A. J., Zhou, X.-F., Kiraly, B., Wood, J. D., Alducin, D., Myers, B. D., Liu, X., Fisher, B. L., Santiago, U., Guest, J. R., et al. (2015) · Science · doi:10.1126/science.aad1080 · Cited by 2,744

Large Scale Growth and Characterization of Atomic Hexagonal Boron Nitride Layers

Song, L., Ci, L., Lu, H., Sorokin, P. B., Jin, C., Ni, J., Kvashnin, A. G., Kvashnin, D. G., Lou, J., Yakobson, B. I., et al. (2010) · Nano Letters · doi:10.1021/nl1022139 · Cited by 2,689

Recent Advances in Two-Dimensional Materials beyond Graphene

Bhimanapati, G. R., Lin, Z., Meunier, V., Jung, Y., Cha, J., Das, S., Xiao, D., Son, Y., Strano, M. S., Cooper, V. R., et al. (2015) · ACS Nano · doi:10.1021/acsnano.5b05556 · Cited by 2,659

Metal-Free Catalysts for Oxygen Reduction Reaction

Dai, L., Xue, Y., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,380

Catalysis with two-dimensional materials and their heterostructures

Deng, D., Novoselov, K. S., Fu, Q., Zheng, N., Tian, Z., & Bao, X. (2016) · Nature Nanotechnology · doi:10.1038/nnano.2015.340 · Cited by 2,308

Ultrathin Two-Dimensional Nanomaterials

Zhang, H. (2015) · ACS Nano · doi:10.1021/acsnano.5b05040 · Cited by 2,167

Intercalation compounds of graphite

Dresselhaus, M. S., & Dresselhaus, G. (2002) · Advances in Physics · doi:10.1080/00018730110113644 · Cited by 2,139

Mechanisms for Lithium Insertion in Carbonaceous Materials

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Heteroatom-doped graphene materials: syntheses, properties and applications

Wang, X., Sun, G., Routh, P., Kim, D.-H., Huang, W., & Chen, P. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00141a · Cited by 1,891

The Brønsted–Evans–Polanyi relation and the volcano curve in heterogeneous catalysis

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Chemical doping of graphene

Liu, H., Liu, Y., & Zhu, D. (2011) · J. Mater. Chem. · doi:10.1039/c0jm02922j · Cited by 1,629

New advances in nanographene chemistry

Narita, A., Wang, X.-Y., Feng, X., & Müllen, K. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00183h · Cited by 1,547

An atlas of two-dimensional materials

Miró, P., Audiffred, M., & Heine, T. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00102h · Cited by 1,475

The chemistry of graphene

Loh, K. P., Bao, Q., Ang, P. K., & Yang, J. (2010) · Journal of Materials Chemistry · doi:10.1039/b920539j · Cited by 1,450

Oxidation Resistance of Graphene-Coated Cu and Cu/Ni Alloy

Chen, S., Brown, L., Levendorf, M., Cai, W., Ju, S.-Y., Edgeworth, J., Li, X., Magnuson, C. W., Velamakanni, A., Piner, R. D., et al. (2011) · ACS Nano · doi:10.1021/nn103028d · Cited by 1,374

Triggering the electrocatalytic hydrogen evolution activity of the inert two-dimensional MoS2 surface via single-atom metal doping

Deng, J., Li, H., Xiao, J., Tu, Y., Deng, D., Yang, H., Tian, H., Li, J., Ren, P., & Bao, X. (2015) · Energy & Environmental Science · doi:10.1039/c5ee00751h · Cited by 1,340

Iron Encapsulated within Pod‐like Carbon Nanotubes for Oxygen Reduction Reaction

Deng, D., Yu, L., Chen, X., Wang, G., Jin, L., Pan, X., Deng, J., Sun, G., & Bao, X. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201204958 · Cited by 1,320

Evidence of Silicene in Honeycomb Structures of Silicon on Ag(111)

Feng, B., Ding, Z., Meng, S., Yao, Y., He, X., Cheng, P., Chen, L., & Wu, K. (2012) · Nano Letters · doi:10.1021/nl301047g · Cited by 1,308

Graphene nanosheet: synthesis, molecular engineering, thin film, hybrids, and energy and analytical applications

Guo, S., & Dong, S. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00079e · Cited by 1,293

Graphene: Corrosion-Inhibiting Coating

Prasai, D., Tuberquia, J. C., Harl, R. R., Jennings, G. K., & Bolotin, K. I. (2012) · ACS Nano · doi:10.1021/nn203507y · Cited by 1,291

Functionalized hexagonal boron nitride nanomaterials: emerging properties and applications

Weng, Q., Wang, X., Wang, X., Bando, Y., & Golberg, D. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00869g · Cited by 1,282

Synthesis of Monolayer Hexagonal Boron Nitride on Cu Foil Using Chemical Vapor Deposition

Kim, K. K., Hsu, A., Jia, X., Kim, S. M., Shi, Y., Hofmann, M., Nezich, D., Rodriguez-Nieva, J. F., Dresselhaus, M., Palacios, T., et al. (2012) · Nano Letters · doi:10.1021/nl203249a · Cited by 1,256

Synthesis of Few-Layer Hexagonal Boron Nitride Thin Film by Chemical Vapor Deposition

Shi, Y., Hamsen, C., Jia, X., Kim, K. K., Reina, A., Hofmann, M., Hsu, A., Zhang, K., Li, H., Juang, Z., et al. (2010) · Nano Letters · doi:10.1021/nl1023707 · Cited by 1,231

Buckled Silicene Formation on Ir(111)

Meng, L., Wang, Y., Zhang, L., Du, S., Wu, R., Li, L., Zhang, Y., Li, G., Zhou, H., Hofer, W. A., et al. (2013) · Nano Letters · doi:10.1021/nl304347w · Cited by 1,183

Graphdiyne and graphyne: from theoretical predictions to practical construction

Li, Y., Xu, L., Liu, H., & Li, Y. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60388a · Cited by 1,162

Repeated growth and bubbling transfer of graphene with millimetre-size single-crystal grains using platinum

Gao, L., Ren, W., Xu, H., Jin, L., Wang, Z., Ma, T., Ma, L.-P., Zhang, Z., Fu, Q., Peng, L.-M., et al. (2012) · Nature Communications · doi:10.1038/ncomms1702 · Cited by 1,142

Quasi-Free-Standing Epitaxial Graphene on SiC Obtained by Hydrogen Intercalation

Riedl, C., Coletti, C., Iwasaki, T., Zakharov, A. A., & Starke, U. (2009) · Physical Review Letters · doi:10.1103/physrevlett.103.246804 · Cited by 1,068

Toward N-Doped Graphene via Solvothermal Synthesis

Deng, D., Pan, X., Yu, L., Cui, Y., Jiang, Y., Qi, J., Li, W.-X., Fu, Q., Ma, X., Xue, Q., et al. (2011) · Chemistry of Materials · doi:10.1021/cm102666r · Cited by 1,064

Graphene on metal surfaces

Wintterlin, J., & Bocquet, M.-L. (2009) · Surface Science · doi:10.1016/j.susc.2008.08.037 · Cited by 994

Advances in 2D boron nitride nanostructures: nanosheets, nanoribbons, nanomeshes, and hybrids with graphene

Lin, Y., & Connell, J. W. (2012) · Nanoscale · doi:10.1039/c2nr32201c · Cited by 902

The growth and morphology of epitaxial multilayer graphene

Hass, J., de Heer, W. A., & Conrad, E. H. (2008) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/20/32/323202 · Cited by 874

The surface science of graphene: Metal interfaces, CVD synthesis, nanoribbons, chemical modifications, and defects

Batzill, M. (2012) · Surface Science Reports · doi:10.1016/j.surfrep.2011.12.001 · Cited by 841

Recent development of carbon materials for Li ion batteries

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Nano boron nitride flatland

Pakdel, A., Bando, Y., & Golberg, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60260e · Cited by 809

Two-dimensional gallium nitride realized via graphene encapsulation

Al Balushi, Z. Y., Wang, K., Ghosh, R. K., Vilá, R. A., Eichfeld, S. M., Caldwell, J. D., Qin, X., Lin, Y.-C., DeSario, P. A., Stone, G., et al. (2016) · Nature Materials · doi:10.1038/nmat4742 · Cited by 797

Single layer graphene encapsulating non-precious metals as high-performance electrocatalysts for water oxidation

Cui, X., Ren, P., Deng, D., Deng, J., & Bao, X. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03316k · Cited by 791

Doped graphene for metal-free catalysis

Kong, X.-K., Chen, C.-L., & Chen, Q.-W. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60401b · Cited by 783

Square ice in graphene nanocapillaries

Algara-Siller, G., Lehtinen, O., Wang, F. C., Nair, R. R., Kaiser, U., Wu, H. A., Geim, A. K., & Grigorieva, I. V. (2015) · Nature · doi:10.1038/nature14295 · Cited by 777

Graphene as a Long-Term Metal Oxidation Barrier: Worse Than Nothing

Schriver, M., Regan, W., Gannett, W. J., Zaniewski, A. M., Crommie, M. F., & Zettl, A. (2013) · ACS Nano · doi:10.1021/nn4014356 · Cited by 724

Highly Durable and Active PtFe Nanocatalyst for Electrochemical Oxygen Reduction Reaction

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Electronic and Magnetic Properties of Quasifreestanding Graphene on Ni

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Structural destabilization induced by lithium intercalation in MoS2 and related compounds

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Electrochemical Delamination of CVD-Grown Graphene Film: Toward the Recyclable Use of Copper Catalyst

Wang, Y., Zheng, Y., Xu, X., Dubuisson, E., Bao, Q., Lu, J., & Loh, K. P. (2011) · ACS Nano · doi:10.1021/nn203700w · Cited by 637

Graphene electrochemistry: fundamental concepts through to prominent applications

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Exploring graphene as a corrosion protection barrier

Kirkland, N. T., Schiller, T., Medhekar, N., & Birbilis, N. (2012) · Corrosion Science · doi:10.1016/j.corsci.2011.12.003 · Cited by 601

The structure of interfacial water on gold electrodes studied by x-ray absorption spectroscopy

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Structure and Bonding of Water on Pt(111)

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Carbocatalysts: Graphene Oxide and Its Derivatives

Su, C., & Loh, K. P. (2013) · Accounts of Chemical Research · doi:10.1021/ar300118v · Cited by 570

Heteroepitaxial Growth of Two-Dimensional Hexagonal Boron Nitride Templated by Graphene Edges

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Chemistry and physics of a single atomic layer: strategies and challenges for functionalization of graphene and graphene-based materials

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Graphene Visualizes the First Water Adlayers on Mica at Ambient Conditions

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Monolayer bimetallic surfaces: Experimental and theoretical studies of trends in electronic and chemical properties

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Calling all chemists

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Surface-Energy-Assisted Perfect Transfer of Centimeter-Scale Monolayer and Few-Layer MoS2 Films onto Arbitrary Substrates

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Noble Gas Atoms Inside Fullerenes

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Probing graphene grain boundaries with optical microscopy

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Atomic and electronic structure of few-layer graphene on SiC(0001) studied with scanning tunneling microscopy and spectroscopy

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Growth of High-Crystalline, Single-Layer Hexagonal Boron Nitride on Recyclable Platinum Foil

Kim, G., Jang, A.-R., Jeong, H. Y., Lee, Z., Kang, D. J., & Shin, H. S. (2013) · Nano Letters · doi:10.1021/nl400559s · Cited by 385

Two‐Step Boron and Nitrogen Doping in Graphene for Enhanced Synergistic Catalysis

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Synthesis of large single-crystal hexagonal boron nitride grains on Cu–Ni alloy

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Covalent chemistry on graphene

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Calorimetric heats for CO and oxygen adsorption and for the catalytic CO oxidation reaction on Pt{111}

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Atomically-thick two-dimensional crystals: electronic structure regulation and energy device construction

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Chemistry under Cover: Tuning Metal−Graphene Interaction by Reactive Intercalation

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Toward Fundamentals of Confined Catalysis in Carbon Nanotubes

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Core/Shell Pt/C Nanoparticles Embedded in Mesoporous Carbon as a Methanol‐Tolerant Cathode Catalyst in Direct Methanol Fuel Cells

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Roll‐to‐Roll Green Transfer of CVD Graphene onto Plastic for a Transparent and Flexible Triboelectric Nanogenerator

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Physisorbed, chemisorbed and dissociated O2 on Pt(111) studied by different core level spectroscopy methods

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Tuning the Electronic and Chemical Properties of Monolayer MoS2 Adsorbed on Transition Metal Substrates

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Interface-Confined Oxide Nanostructures for Catalytic Oxidation Reactions

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The quasi-free-standing nature of graphene on H-saturated SiC(0001)

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Complete Corrosion Inhibition through Graphene Defect Passivation

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Observing Graphene Grow: Catalyst–Graphene Interactions during Scalable Graphene Growth on Polycrystalline Copper

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Embedding Pt Nanocrystals in N-Doped Porous Carbon/Carbon Nanotubes toward Highly Stable Electrocatalysts for the Oxygen Reduction Reaction

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Bottom-up Growth of Epitaxial Graphene on 6H-SiC(0001)

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Chemical Vapor Deposition of Graphene Single Crystals

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Repeated and Controlled Growth of Monolayer, Bilayer and Few-Layer Hexagonal Boron Nitride on Pt Foils

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Characterization of oxidized platinum surfaces by X-ray photoelectron spectroscopy

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Graphene coatings: An efficient protection from oxidation

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Non-noble metal catalysts for hydrogenation: A facile method for preparing Co nanoparticles covered with thin layered carbon

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Designed CVD Growth of Graphene via Process Engineering

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Graphene cover-promoted metal-catalyzed reactions

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