Cited by 2,000CO2 Reduction Techniques and CatalystsElectrocatalysts for Energy ConversionCatalysts for Methane Reforming

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CO 2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu 2 O Films

Li, Christina W., Kanan, Matthew W.·2012·Journal of the American Chemical Society

DOI 10.1021/ja3010978

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Abstract

Modified Cu electrodes were prepared by annealing Cu foil in air and electrochemically reducing the resulting Cu(2)O layers. The CO(2) reduction activities of these electrodes exhibited a strong dependence on the initial thickness of the Cu(2)O layer. Thin Cu(2)O layers formed by annealing at 130 °C resulted in electrodes whose activities were indistinguishable from those of polycrystalline Cu. In contrast, Cu(2)O layers formed at 500 °C that were ≥~3 μm thick resulted in electrodes that exhibited large roughness factors and required 0.5 V less overpotential than polycrystalline Cu to reduce CO(2) at a higher rate than H(2)O. The combination of these features resulted in CO(2) reduction geometric current densities >1 mA/cm(2) at overpotentials <0.4 V, a higher level of activity than all previously reported metal electrodes evaluated under comparable conditions. Moreover, the activity of the modified electrodes was stable over the course of several hours, whereas a polycrystalline Cu electrode exhibited deactivation within 1 h under identical conditions. The electrodes described here may be particularly useful for elucidating the structural properties of Cu that determine the distribution between CO(2) and H(2)O reduction and provide a promising lead for the development of practical catalysts for electrolytic fuel synthesis.

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Hori, Y.InModern Aspects of Electrochemistry;Vayenas, C. G.; White, R. E.; Gamboa-Aldeco, M. E., Eds.Springer:New York, 2008; Vol.42, p89.

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Authors: Li, C. W., & Kanan, M. W.
Affiliations: Stanford University (US)
Corresponding author: Kanan, Matthew W.
ORCID: Li, Christina W.
Kanan, Matthew W.
Venue: Journal of the American Chemical Society
Publisher: American Chemical Society (ACS)
Published: 2012-04-20
Volume: 134
Issue: 17
Pages: 7231-7234
ISSN: 0002-7863 (ISSN-L)
1520-5126
DOI: 10.1021/ja3010978
OpenAlex: W2082498048
Cited by: 2,000
References: 29
Citations by year: 2026: 84 · 2025: 109 · 2024: 126 · 2023: 128 · 2022: 168 · 2021: 189 · 2020: 235 · 2019: 194 · 2018: 210 · 2017: 181 · 2016: 155 · 2015: 105 · 2014: 64 · 2013: 44 · 2012: 8
FWCI: 27.14
Type: journal article
Language: en
Open access: closed
Locations: Journal of the American Chemical Society (publishedVersion)
PubMed (publishedVersion)
Funders: National Science Foundation
Stanford Precourt Institute for Energy
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Keywords: CO2 reduction, copper electrode, low overpotential, electrode surface roughness, film thickness dependence, annealing temperature, electrode deactivation, electrocatalysis

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CO 2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu 2 O Films

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