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Carbon-Based Single-Atom Catalysts for Advanced Applications

Gawande, Manoj B., Fornasiero, Paolo, Zbořil, Radek·2020·ACS Catalysis
DOI 10.1021/acscatal.9b04217
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Abstract

Carbon-based materials are widely employed as metal-free catalysts or supports in catalysis, energy, and ecological applications because of their interesting properties. Generally, their high surface areas, size, shape, porosity, and the possibility of incorporating additional moieties through chemical functional designs are believed to be essential for enriching the catalytic activity of carbon-containing materials. Lately, the new field of single-atom catalysts (SACs) has emerged as the finest alternative for not only homogeneous but also heterogeneous catalysts used in various kinds of catalytic applications. Among a variety of SACs, carbon-based SACs are widely investigated catalysts because of their extraordinary features such as tunable morphologies, ordered porosity, and effortless immobilization through various metals (noble and non-noble), making them highly efficient single-atom catalysts for numerous important catalytic applications. Herein, we intend to report on the progress achieved in researching carbon-based single-atom catalysts, including primarily metals such as Co, Cu, Zn, Pd, Ni, Pt, among others, embedded in carbon matrices and applied to applications in organic catalysis, photocatalysis, and electrocatalysis. It is important to point out that the main focus of this Review is directed to the activity and applications of single-atom catalysts, which are discussed in detail; thus, characterization and rationalization are excluded. Finally, we provide a future perspective on the development and progress made on a carbon-based single metal atom for catalysis.

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Metadata

Authors
Gawande, M. B., Fornasiero, P., & Zbořil, R.
Venue
ACS Catalysis
Publisher
American Chemical Society (ACS)
Published
2020-01-10
Volume
10
Issue
3
Pages
2231-2259
ISSN
2155-5435 (ISSN-L)
DOI
10.1021/acscatal.9b04217
OpenAlex
W2999712458
Cited by
750
References
13
FWCI
37.10
Type
journal article
Language
en
Open access
closed
Licence
Funders
  • European Regional Development Fund (CZ.02.1.01/0.0/0.0/15_003/0000416, CZ.02.1.01/0.0/0.0/16_019/0000754)
  • Ministerstvo Školství, Mládeže a Telovýchovy (CZ.02.1.01/0.0/0.0/15_003/0000416, CZ.02.1.01/0.0/0.0/16_019/0000754)

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