The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Electrochemical Reduction of CO at a Copper Electrode
Abstract
CO 2 is electrochemically reduced to CH 4, C 2 H 4, and alcohols in aqueous electrolytes at Cu electrode with high current density. CO 2 is initially reduced to adsorbed CO and further to hydrocarbons and alcohols. This paper describes macroscopic electrolytic reduction of CO at a Cu electrode in various electrolyte solutions in order to reveal the unique properties of Cu electrode in comparison with Fe and Ni electrodes. The reaction products from the Cu electrode are CH 4, C 2 H 4, C 2 H 5 OH, n -C 3 H 7 OH, CH 3 CHO, and C 2 H 5 CHO. Neither C 2 H 6 nor CH 3 OH is produced. CH 4 is favorably produced in aqueous KHCO 3 of high concentrations ( e.g . 0.3 mol dm -3 ), whereas C 2 H 4 and C 2 H 5 OH are produced in dilute KHCO 3 solutions (0.03 mol dm -3 ). Such product selectivity is derived from the electrogenerated OH - in the cathodic reaction, as is the case in the CO 2 reduction. The partial current densities of CH 4, C 2 H 4, and C 2 H 5 OH are correlated with the electrode potential. Tafel relationships hold for C 2 H 4 and C 2 H 5 OH irrespective of pH. The partial current of CH 4 formation is proportional to proton activity and also follows the Tafel relationship. The transfer coefficients are 0.35 for C 2 H 4 formation and 1.33 for CH 4 formation. These facts indicate that the reaction paths of CH 4 and C 2 H 4 formations are separated at an early stage of CO reduction. Ethanol and n -propanol may be reduced from acetaldehyde and propionaldehyde intermediately formed in the reaction. The molecular reaction path is discussed with regard to these experimental results.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Self-citationHori, Y., Kikuchi, K., & Suzuki, S. (1985) · Chemistry Letters · doi:10.1246/cl.1985.1695 · Cited by 1,401
Self-citationMurata, A., & Hori, Y. (1991) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.64.123 · Cited by 544
Self-citationHara, K., Kudo, A., Sakata, T., & Watanabe, M. (1995) · Journal of The Electrochemical Society · doi:10.1149/1.2044182 · Cited by 101
Carbon dioxide reduction at low temperature on various metal electrodes
Azuma, M., Hashimoto, K., Hiramoto, M., Watanabe, M., & Sakata, T. (1989) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/0022-0728(89)87158-x · Cited by 89
Cited by
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649
Designing materials for electrochemical carbon dioxide recycling
Ross, M. B., De Luna, P., Li, Y., Dinh, C.-T., Kim, D., Yang, P., & Sargent, E. H. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0306-7 · Cited by 1,302
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Fundamentals and challenges of electrochemical CO2 reduction using two-dimensional materials
Sun, Z., Ma, T., Tao, H., Fan, Q., & Han, B. (2017) · Chem · doi:10.1016/j.chempr.2017.09.009 · Cited by 1,224
Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes
Calle‐Vallejo, F., & Koper, M. T. M. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201301470 · Cited by 941
Ren, D., Deng, Y., Handoko, A. D., Chen, C. S., Malkhandi, S., & Yeo, B. S. (2015) · ACS Catalysis · doi:10.1021/cs502128q · Cited by 930
Improved CO2 reduction activity towards C2+ alcohols on a tandem gold on copper electrocatalyst
Morales-Guio, C. G., Cave, E. R., Nitopi, S. A., Feaster, J. T., Wang, L., Kuhl, K. P., Jackson, A., Johnson, N. C., Abram, D. N., Hatsukade, T., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0139-9 · Cited by 773
Ren, D., Ang, B. S.-H., & Yeo, B. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02162 · Cited by 721
Theoretical Insights into Heterogeneous (Photo)electrochemical CO2Reduction
Xu, S., & Carter, E. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00481 · Cited by 652
Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
Verdaguer-Casadevall, A., Li, C. W., Johansson, T. P., Scott, S. B., McKeown, J. T., Kumar, M., Stephens, I. E. L., Kanan, M. W., & Chorkendorff, I. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06227 · Cited by 645
Gupta, N., Gattrell, M., & MacDougall, B. (2006) · Journal of Applied Electrochemistry · doi:10.1007/s10800-005-9058-y · Cited by 558
Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
Manthiram, K., Beberwyck, B. J., & Alivisatos, A. P. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5065284 · Cited by 546
Varela, A. S., Kroschel, M., Reier, T., & Strasser, P. (2016) · Catalysis Today · doi:10.1016/j.cattod.2015.06.009 · Cited by 542
Ma, M., Trześniewski, B. J., Xie, J., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604654 · Cited by 530
Electrochemical Reduction of CO2 at Copper Nanofoams
Sen, S., Liu, D., & Palmore, G. T. R. (2014) · ACS Catalysis · doi:10.1021/cs500522g · Cited by 528
One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer
Ma, S., Sadakiyo, M., Luo, R., Heima, M., Yamauchi, M., & Kenis, P. J. A. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.09.124 · Cited by 488
Garg, S., Li, M., Weber, A. Z., Ge, L., Li, L., Rudolph, V., Wang, G., & Rufford, T. E. (2020) · Journal of Materials Chemistry A · doi:10.1039/c9ta13298h · Cited by 478
A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
Feng, X., Jiang, K., Fan, S., & Kanan, M. W. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00022 · Cited by 460
Kas, R., Kortlever, R., Yılmaz, H., Koper, M. T. M., & Mul, G. (2015) · ChemElectroChem · doi:10.1002/celc.201402373 · Cited by 464
Xiao, H., Cheng, T., & Goddard, W. A. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06846 · Cited by 458
Grim, R. G., Huang, Z., Guarnieri, M. T., Ferrell, J. R., Tao, L., & Schaidle, J. A. (2020) · Energy & Environmental Science · doi:10.1039/c9ee02410g · Cited by 454
Cheng, T., Xiao, H., & Goddard, W. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08534 · Cited by 453
Solvents and Supporting Electrolytes in the Electrocatalytic Reduction of CO2
König, M., Vaes, J., Klemm, E., & Pant, D. (2019) · iScience · doi:10.1016/j.isci.2019.07.014 · Cited by 429
Electrochemical CO2 Reduction: Recent Advances and Current Trends
Jones, J., Prakash, G. K. S., & Olah, G. A. (2014) · Israel Journal of Chemistry · doi:10.1002/ijch.201400081 · Cited by 425
Tang, Q., Lee, Y., Li, D.-Y., Choi, W., Liu, C. W., Lee, D., & Jiang, D.-E. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05591 · Cited by 382
Double sulfur vacancies by lithium tuning enhance CO2 electroreduction to n-propanol
Peng, C., Luo, G., Zhang, J., Chen, M., Wang, Z., Sham, T.-K., Zhang, L., Li, Y., & Zheng, G. (2021) · Nature Communications · doi:10.1038/s41467-021-21901-1 · Cited by 359
Tomboc, G. M., Choi, S., Kwon, T., Hwang, Y. J., & Lee, K. (2020) · Advanced Materials · doi:10.1002/adma.201908398 · Cited by 325
Lum, Y., & Ager, J. W. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0201-7 · Cited by 322
Torelli, D. A., Francis, S. A., Crompton, J. C., Javier, A., Thompson, J. R., Brunschwig, B. S., Soriaga, M. P., & Lewis, N. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02888 · Cited by 306
Understanding Surface-Mediated Electrochemical Reactions: CO2 Reduction and Beyond
Dunwell, M., Luc, W., Yan, Y., Jiao, F., & Xu, B. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b02181 · Cited by 298
Ting, L. R. L., Piqué, O., Lim, S. Y., Tanhaei, M., Calle-Vallejo, F., & Yeo, B. S. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05319 · Cited by 268
Electrochemical CO Reduction Builds Solvent Water into Oxygenate Products
Lum, Y., Cheng, T., Goddard, W. A., & Ager, J. W. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b03986 · Cited by 251
Effects of Anion Identity and Concentration on Electrochemical Reduction of CO 2
Resasco, J., Lum, Y., Clark, E., Zeledon, J. Z., & Bell, A. T. (2018) · ChemElectroChem · doi:10.1002/celc.201701316 · Cited by 250
Larrazábal, G. O., Martín, A. J., & Pérez-Ramírez, J. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b01380 · Cited by 176
Low-Overpotential Electroreduction of Carbon Monoxide Using Copper Nanowires
Raciti, D., Cao, L., Livi, K. J. T., Rottmann, P. F., Tang, X., Li, C., Hicks, Z., Bowen, K. H., Hemker, K. J., Mueller, T., et al. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01124 · Cited by 177
Role of oxygen-bound reaction intermediates in selective electrochemical CO 2 reduction
Zhi, X., Vasileff, A., Zheng, Y., Jiao, Y., & Qiao, S.-Z. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00740h · Cited by 149
Role of Subsurface Oxygen on Cu Surfaces for CO2 Electrochemical Reduction
Fields, M., Hong, X., Nørskov, J. K., & Chan, K. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b04983 · Cited by 97
Metadata
- Authors
- Hori, Y., Takahashi, R., Yoshinami, Y., & Murata, A.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-09-01
- Volume
- 101
- Issue
- 36
- Pages
- 7075-7081
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2066753574
- Cited by
- 816
- References
- 5
- FWCI
- 1.41
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
