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Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene
Abstract
Graphene's success has shown that it is possible to create stable, single and few-atom-thick layers of van der Waals materials, and also that these materials can exhibit fascinating and technologically useful properties. Here we review the state-of-the-art of 2D materials beyond graphene. Initially, we will outline the different chemical classes of 2D materials and discuss the various strategies to prepare single-layer, few-layer, and multilayer assembly materials in solution, on substrates, and on the wafer scale. Additionally, we present an experimental guide for identifying and characterizing single-layer-thick materials, as well as outlining emerging techniques that yield both local and global information. We describe the differences that occur in the electronic structure between the bulk and the single layer and discuss various methods of tuning their electronic properties by manipulating the surface. Finally, we highlight the properties and advantages of single-, few-, and many-layer 2D materials in field-effect transistors, spin- and valley-tronics, thermoelectrics, and topological insulators, among many other applications.
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Citations
Cites
Electric Field Effect in Atomically Thin Carbon Films
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., Grigorieva, I. V., & Firsov, A. A. (2004) · Science · doi:10.1126/science.1102896 · Cited by 66,834
Two-dimensional gas of massless Dirac fermions in graphene
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Katsnelson, M. I., Grigorieva, I. V., Dubonos, S. V., & Firsov, A. A. (2005) · Nature · doi:10.1038/nature04233 · Cited by 21,611
Hybrid functionals based on a screened Coulomb potential
Heyd, J., Scuseria, G. E., & Ernzerhof, M. (2003) · The Journal of Chemical Physics · doi:10.1063/1.1564060 · Cited by 19,629
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
Wang, Q. H., Kalantar-Zadeh, K., Kis, A., Coleman, J. N., & Strano, M. S. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.193 · Cited by 16,374
Atomically Thin MoS 2 : A New Direct-Gap Semiconductor
Mak, K. F., Lee, C., Hone, J., Shan, J., & Heinz, T. F. (2010) · Physical Review Letters · doi:10.1103/physrevlett.105.136805 · Cited by 15,586
Self-citationRadisavljevic, B., Radenovic, A., Brivio, J., Giacometti, V., & Kis, A. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2010.279 · Cited by 14,939
Possible highT c superconductivity in the Ba?La?Cu?O system
Bednorz, J. G., & M�ller, K. A. (1986) · Zeitschrift f�r Physik B Condensed Matter · doi:10.1007/bf01303701 · Cited by 14,319
Superior Thermal Conductivity of Single-Layer Graphene
Balandin, A. A., Ghosh, S., Bao, W., Calizo, I., Teweldebrhan, D., Miao, F., & Lau, C. N. (2008) · Nano Letters · doi:10.1021/nl0731872 · Cited by 13,823
Graphene-based composite materials
Stankovich, S., Dikin, D. A., Dommett, G. H. B., Kohlhaas, K. M., Zimney, E. J., Stach, E. A., Piner, R. D., Nguyen, S. T., & Ruoff, R. S. (2006) · Nature · doi:10.1038/nature04969 · Cited by 12,922
Self-citationTwo‐Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
Naguib, M., Kurtoglu, M., Presser, V., Lu, J., Niu, J., Heon, M., Hultman, L., Gogotsi, Y., & Barsoum, M. W. (2011) · Advanced Materials · doi:10.1002/adma.201102306 · Cited by 11,855
Cited by
Photonics and optoelectronics of 2D semiconductor transition metal dichalcogenides
Mak, K. F., & Shan, J. (2016) · Nature Photonics · doi:10.1038/nphoton.2015.282 · Cited by 3,819
Self-citationRecent development of two-dimensional transition metal dichalcogenides and their applications
Choi, W., Choudhary, N., Han, G. H., Park, J., Akinwande, D., & Lee, Y. H. (2017) · Materials Today · doi:10.1016/j.mattod.2016.10.002 · Cited by 2,769
Emerging Device Applications for Semiconducting Two-Dimensional Transition Metal Dichalcogenides
Jariwala, D., Sangwan, V. K., Lauhon, L. J., Marks, T. J., & Hersam, M. C. (2014) · ACS Nano · doi:10.1021/nn500064s · Cited by 2,753
Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes)
Anasori, B., Xie, Y., Beidaghi, M., Lu, J., Hosler, B. C., Hultman, L., Kent, P. R. C., Gogotsi, Y., & Barsoum, M. W. (2015) · ACS Nano · doi:10.1021/acsnano.5b03591 · Cited by 2,110
Emerging challenges and materials for thermal management of electronics
Moore, A. L., & Shi, L. (2014) · Materials Today · doi:10.1016/j.mattod.2014.04.003 · Cited by 2,106
Self-citationTwo-dimensional flexible nanoelectronics
Akinwande, D., Petrone, N., & Hone, J. (2014) · Nature Communications · doi:10.1038/ncomms6678 · Cited by 1,910
Mounet, N., Gibertini, M., Schwaller, P., Campi, D., Merkys, A., Marrazzo, A., Sohier, T., Castelli, I. E., Cepellotti, A., Pizzi, G., et al. (2018) · Nature Nanotechnology · doi:10.1038/s41565-017-0035-5 · Cited by 1,863
Colloquium : Topological band theory
Bansil, A., Lin, H., & Das, T. (2016) · Reviews of Modern Physics · doi:10.1103/revmodphys.88.021004 · Cited by 1,587
Xie, Y., Naguib, M., Mochalin, V. N., Barsoum, M. W., Gogotsi, Y., Yu, X., Nam, K.-W., Yang, X.-Q., Kolesnikov, A. I., & Kent, P. R. C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501520b · Cited by 1,537
Graphene for batteries, supercapacitors and beyond
El-Kady, M. F., Shao, Y., & Kaner, R. B. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.33 · Cited by 1,262
Phosphorene as a Superior Gas Sensor: Selective Adsorption and Distinct I–V Response
Kou, L., Frauenheim, T., & Chen, C. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz501188k · Cited by 1,045
Wang, H., Lu, Z., Xu, S., Kong, D., Cha, J. J., Zheng, G., Hsu, P.-C., Yan, K., Bradshaw, D., Prinz, F. B., et al. (2013) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1316792110 · Cited by 988
Self-citationLaturia, A., Van de Put, M. L., & Vandenberghe, W. G. (2018) · npj 2D Materials and Applications · doi:10.1038/s41699-018-0050-x · Cited by 963
Two‐Dimensional Nanostructured Materials for Gas Sensing
Liu, X., Ma, T., Pinna, N., & Zhang, J. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201702168 · Cited by 851
Controlled Growth of High-Quality Monolayer WS2 Layers on Sapphire and Imaging Its Grain Boundary
Zhang, Y., Zhang, Y., Ji, Q., Ju, J., Yuan, H., Shi, J., Gao, T., Ma, D., Liu, M., Chen, Y., et al. (2013) · ACS Nano · doi:10.1021/nn403454e · Cited by 803
Self-citationHigh yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide
Zheng, J., Zhang, H., Dong, S., Liu, Y., Tai Nai, C., Suk Shin, H., Young Jeong, H., Liu, B., & Ping Loh, K. (2014) · Nature Communications · doi:10.1038/ncomms3995 · Cited by 787
Electrically-Transduced Chemical Sensors Based on Two-Dimensional Nanomaterials
Meng, Z., Stolz, R. M., Mendecki, L., & Mirica, K. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00311 · Cited by 773
Zhou, Y., Zhang, Y., Lin, M., Long, J., Zhang, Z., Lin, H., Wu, J. C.-S., & Wang, X. (2015) · Nature Communications · doi:10.1038/ncomms9340 · Cited by 746
Interface-Assisted Synthesis of 2D Materials: Trend and Challenges
Dong, R., Zhang, T., & Feng, X. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00056 · Cited by 710
Fundamental understanding and applications of plasmon-enhanced Raman spectroscopy
Wang, X., Huang, S.-C., Hu, S., Yan, S., & Ren, B. (2020) · Nature Reviews Physics · doi:10.1038/s42254-020-0171-y · Cited by 689
Recent advance in MXenes: A promising 2D material for catalysis, sensor and chemical adsorption
Zhu, J., Ha, E., Zhao, G., Zhou, Y., Huang, D., Yue, G., Hu, L., Sun, N., Wang, Y., Lee, L. Y. S., et al. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.09.012 · Cited by 659
Ying, Y., Liu, Y., Wang, X., Mao, Y., Cao, W., Hu, P., & Peng, X. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/am5074722 · Cited by 658
Li, D. J., Maiti, U. N., Lim, J., Choi, D. S., Lee, W. J., Oh, Y., Lee, G. Y., & Kim, S. O. (2014) · Nano Letters · doi:10.1021/nl404108a · Cited by 653
Wang, G., Marie, X., Gerber, I., Amand, T., Lagarde, D., Bouet, L., Vidal, M., Balocchi, A., & Urbaszek, B. (2015) · Physical Review Letters · doi:10.1103/physrevlett.114.097403 · Cited by 640
Zeng, M., Xiao, Y., Liu, J., Yang, K., & Fu, L. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00633 · Cited by 574
Wide Band Gap Chalcogenide Semiconductors
Woods-Robinson, R., Han, Y., Zhang, H., Ablekim, T., Khan, I., Persson, K. A., & Zakutayev, A. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00600 · Cited by 513
High Surface Area MoS 2 /Graphene Hybrid Aerogel for Ultrasensitive NO 2 Detection
Long, H., Harley‐Trochimczyk, A., Pham, T., Tang, Z., Shi, T., Zettl, A., Carraro, C., Worsley, M. A., & Maboudian, R. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201601562 · Cited by 479
Optoelectronic crystal of artificial atoms in strain-textured molybdenum disulphide
Li, H., Contryman, A. W., Qian, X., Ardakani, S. M., Gong, Y., Wang, X., Weisse, J. M., Lee, C. H., Zhao, J., Ajayan, P. M., et al. (2015) · Nature Communications · doi:10.1038/ncomms8381 · Cited by 478
Materials Synthesis Insights from Scientific Literature via Text Extraction and Machine Learning
Kim, E., Huang, K., Saunders, A., McCallum, A., Ceder, G., & Olivetti, E. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b03500 · Cited by 473
Jia, J., Xiong, T., Zhao, L., Wang, F., Liu, H., Hu, R., Zhou, J., Zhou, W., & Chen, S. (2017) · ACS Nano · doi:10.1021/acsnano.7b06607 · Cited by 470
Xia, J., Huang, X., Liu, L.-Z., Wang, M., Wang, L., Huang, B., Zhu, D.-D., Li, J.-J., Gu, C.-Z., & Meng, X.-M. (2014) · Nanoscale · doi:10.1039/c4nr02311k · Cited by 468
Schmidt, H., Giustiniano, F., & Eda, G. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00275c · Cited by 466
Halide-assisted atmospheric pressure growth of large WSe2 and WS2 monolayer crystals
Li, S., Wang, S., Tang, D.-M., Zhao, W., Xu, H., Chu, L., Bando, Y., Golberg, D., & Eda, G. (2015) · Applied Materials Today · doi:10.1016/j.apmt.2015.09.001 · Cited by 465
Gold‐Mediated Exfoliation of Ultralarge Optoelectronically‐Perfect Monolayers
Desai, S. B., Madhvapathy, S. R., Amani, M., Kiriya, D., Hettick, M., Tosun, M., Zhou, Y., Dubey, M., Ager, J. W., Chrzan, D., et al. (2016) · Advanced Materials · doi:10.1002/adma.201506171 · Cited by 462
Two‐Dimensional Metal Oxide Nanomaterials for Next‐Generation Rechargeable Batteries
Mei, J., Liao, T., Kou, L., & Sun, Z. (2017) · Advanced Materials · doi:10.1002/adma.201700176 · Cited by 459
Self-surface charge exfoliation and electrostatically coordinated 2D hetero-layered hybrids
Yang, M.-Q., Xu, Y.-J., Lu, W., Zeng, K., Zhu, H., Xu, Q.-H., & Ho, G. W. (2017) · Nature Communications · doi:10.1038/ncomms14224 · Cited by 448
Ultrafast formation of interlayer hot excitons in atomically thin MoS2/WS2 heterostructures
Chen, H., Wen, X., Zhang, J., Wu, T., Gong, Y., Zhang, X., Yuan, J., Yi, C., Lou, J., Ajayan, P. M., et al. (2016) · Nature Communications · doi:10.1038/ncomms12512 · Cited by 432
Analyzing the Carrier Mobility in Transition‐Metal Dichalcogenide MoS2 Field‐Effect Transistors
Yu, Z., Ong, Z., Li, S., Xu, J., Zhang, G., Zhang, Y., Shi, Y., & Wang, X. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201604093 · Cited by 426
Exfoliation of a non-van der Waals material from iron ore hematite
Puthirath Balan, A., Radhakrishnan, S., Woellner, C. F., Sinha, S. K., Deng, L., Reyes, C. D. L., Rao, B. M., Paulose, M., Neupane, R., Apte, A., et al. (2018) · Nature Nanotechnology · doi:10.1038/s41565-018-0134-y · Cited by 423
Wang, S., Ren, C., Tian, H., Yu, J., & Sun, M. (2018) · Physical Chemistry Chemical Physics · doi:10.1039/c8cp00808f · Cited by 423
Tribology of two-dimensional materials: From mechanisms to modulating strategies
Zhang, S., Ma, T., Erdemir, A., & Li, Q. (2019) · Materials Today · doi:10.1016/j.mattod.2018.12.002 · Cited by 407
Excitonic resonances in thin films of WSe2: from monolayer to bulk material
Arora, A., Koperski, M., Nogajewski, K., Marcus, J., Faugeras, C., & Potemski, M. (2015) · Nanoscale · doi:10.1039/c5nr01536g · Cited by 359
Recent Advances in Optoelectronic Devices Based on 2D Materials and Their Heterostructures
Cheng, J., Wang, C., Zou, X., & Liao, L. (2019) · Advanced Optical Materials · doi:10.1002/adom.201800441 · Cited by 359
Biosensors Based on Two-Dimensional MoS2
Kalantar-zadeh, K., & Ou, J. Z. (2016) · ACS Sensors · doi:10.1021/acssensors.5b00142 · Cited by 357
Three-dimensional macro-structures of two-dimensional nanomaterials
Shehzad, K., Xu, Y., Gao, C., & Duan, X. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00218h · Cited by 357
Elemental two-dimensional nanosheets beyond graphene
Kong, X., Liu, Q., Zhang, C., Peng, Z., & Chen, Q. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00937a · Cited by 346
Electronic Transport in Two-Dimensional Materials
Sangwan, V. K., & Hersam, M. C. (2018) · Annual Review of Physical Chemistry · doi:10.1146/annurev-physchem-050317-021353 · Cited by 336
Infrared and Raman chemical imaging and spectroscopy at the nanoscale
Kurouski, D., Dazzi, A., Zenobi, R., & Centrone, A. (2020) · Chemical Society Reviews · doi:10.1039/c8cs00916c · Cited by 324
Exciton valley dynamics probed by Kerr rotation inWSe2monolayers
Zhu, C. R., Zhang, K., Glazov, M., Urbaszek, B., Amand, T., Ji, Z. W., Liu, B. L., & Marie, X. (2014) · Physical Review B · doi:10.1103/physrevb.90.161302 · Cited by 314
Thermoelectric Generation Based on Spin Seebeck Effects
Uchida, K.-I., Adachi, H., Kikkawa, T., Kirihara, A., Ishida, M., Yorozu, S., Maekawa, S., & Saitoh, E. (2016) · Proceedings of the IEEE · doi:10.1109/jproc.2016.2535167 · Cited by 308
Controlled Synthesis of High-Quality Monolayered α-In2Se3 via Physical Vapor Deposition
Zhou, J., Zeng, Q., Lv, D., Sun, L., Niu, L., Fu, W., Liu, F., Shen, Z., Jin, C., & Liu, Z. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b01590 · Cited by 308
Electronic-structure methods for twisted moiré layers
Carr, S., Fang, S., & Kaxiras, E. (2020) · Nature Reviews Materials · doi:10.1038/s41578-020-0214-0 · Cited by 303
Linearly Polarized Excitons in Single- and Few-Layer ReS2 Crystals
Aslan, B., Chenet, D. A., van der Zande, A. M., Hone, J. C., & Heinz, T. F. (2016) · ACS Photonics · doi:10.1021/acsphotonics.5b00486 · Cited by 283
Self-citationRyder, C. R., Wood, J. D., Wells, S. A., & Hersam, M. C. (2016) · ACS Nano · doi:10.1021/acsnano.6b01091 · Cited by 283
Design strategies for two‐dimensional material photodetectors to enhance device performance
Wang, J., Han, J., Chen, X., & Wang, X. (2019) · InfoMat · doi:10.1002/inf2.12004 · Cited by 268
Liu, J., Choi, G.-M., & Cahill, D. G. (2014) · Journal of Applied Physics · doi:10.1063/1.4904513 · Cited by 262
Kuang, Y., Feng, G., Li, P., Bi, Y., Li, Y., & Sun, X. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201509616 · Cited by 259
Mechanical exfoliation of two-dimensional materials
Gao, E., Lin, S.-Z., Qin, Z., Buehler, M. J., Feng, X.-Q., & Xu, Z. (2018) · Journal of the Mechanics and Physics of Solids · doi:10.1016/j.jmps.2018.03.014 · Cited by 258
Patterned arrays of lateral heterojunctions within monolayer two-dimensional semiconductors
Mahjouri-Samani, M., Lin, M.-W., Wang, K., Lupini, A. R., Lee, J., Basile, L., Boulesbaa, A., Rouleau, C. M., Puretzky, A. A., Ivanov, I. N., et al. (2015) · Nature Communications · doi:10.1038/ncomms8749 · Cited by 257
Engineering 2D Architectures toward High‐Performance Micro‐Supercapacitors
Da, Y., Liu, J., Zhou, L., Zhu, X., Chen, X., & Fu, L. (2019) · Advanced Materials · doi:10.1002/adma.201802793 · Cited by 253
Machine Learning in Nanoscience: Big Data at Small Scales
Brown, K. A., Brittman, S., Maccaferri, N., Jariwala, D., & Celano, U. (2020) · Nano Letters · doi:10.1021/acs.nanolett.9b04090 · Cited by 229
Ultralow Density, Monolithic WS2, MoS2, and MoS2/Graphene Aerogels
Worsley, M. A., Shin, S. J., Merrill, M. D., Lenhardt, J., Nelson, A. J., Woo, L. Y., Gash, A. E., Baumann, T. F., & Orme, C. A. (2015) · ACS Nano · doi:10.1021/acsnano.5b00087 · Cited by 182
Orbital Edge States in a Photonic Honeycomb Lattice
Milićević, M., Ozawa, T., Montambaux, G., Carusotto, I., Galopin, E., Lemaître, A., Le Gratiet, L., Sagnes, I., Bloch, J., & Amo, A. (2017) · Physical Review Letters · doi:10.1103/physrevlett.118.107403 · Cited by 117
Thermal Conductance Imaging of Graphene Contacts
Yang, J., Ziade, E., Maragliano, C., Crowder, R., Wang, X., Stefancich, M., Chiesa, M., Swan, A. K., & Schmidt, A. J. (2014) · Journal of Applied Physics · doi:10.1063/1.4889928 · Cited by 85
Functionalization of Nanomaterials: Synthesis and Characterization
Rizvi, M., Gerengi, H., & Gupta, P. (2022) · ACS Symposium Series · doi:10.1021/bk-2022-1418.ch001 · Cited by 55
Observing movement of Dirac cones from single-photon dynamics
Lu, Y.-H., Wang, Y., Chang, Y.-J., Li, Z.-M., Cui, W.-H., Gao, J., Zhou, W.-H., Zheng, H., & Jin, X.-M. (2021) · Physical Review B · doi:10.1103/physrevb.103.064304 · Cited by 7
“The investigations of Dirac cones and graphene have pushed the boundaries of our understanding on emerging physics and materials, for both fundamental and device levels [6–9].”
Background
Metadata
- Authors
- Butler, S. Z., Hollen, S. M., Cao, L., Cui, Y., Gupta, J. A., Gutiérrez, H. R., Heinz, T. F., Hong, S. S., Huang, J., Ismach, A. F., Johnston-Halperin, E., Kuno, M., Plashnitsa, V. V., Robinson, R. D., Ruoff, R. S., Salahuddin, S., Shan, J., Shi, L., Spencer, M. G., Terrones, M., Windl, W., & Goldberger, J. E.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-03-26
- Volume
- 7
- Issue
- 4
- Pages
- 2898-2926
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2024966938
- Cited by
- 4,878
- References
- 249
- FWCI
- 173.76
- Type
- journal article
- Language
- en
- Open access
- closed
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