Metal–organic framework based nanozymes: promising materials for biochemical analysis

Single-atom catalysis of CO oxidation using Pt1/FeOx

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Intrinsic peroxidase-like activity of ferromagnetic nanoparticles

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Nanomaterials with enzyme-like characteristics (nanozymes): next-generation artificial enzymes (II)

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Nanomaterials with enzyme-like characteristics (nanozymes): next-generation artificial enzymes

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Nanozymes: Classification, Catalytic Mechanisms, Activity Regulation, and Applications

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Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts

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Nanozymes: From New Concepts, Mechanisms, and Standards to Applications

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Single‐Atom Electrocatalysts

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Standardized assays for determining the catalytic activity and kinetics of peroxidase-like nanozymes

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Single-atom nanozymes

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Destruction of chemical warfare agents using metal–organic frameworks

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A Single‐Atom Nanozyme for Wound Disinfection Applications

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Molecular Imprinting on Inorganic Nanozymes for Hundred-fold Enzyme Specificity

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Hierarchically Porous M–N–C (M = Co and Fe) Single‐Atom Electrocatalysts with Robust MNx Active Moieties Enable Enhanced ORR Performance

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Surface-Enhanced Raman Scattering Active Gold Nanoparticles with Enzyme-Mimicking Activities for Measuring Glucose and Lactate in Living Tissues

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Metal organic frameworks for sensing applications

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Bioinspired Design of Ultrathin 2D Bimetallic Metal–Organic‐Framework Nanosheets Used as Biomimetic Enzymes

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Multicopper Laccase Mimicking Nanozymes with Nucleotides as Ligands

Liang, H., Lin, F., Zhang, Z., Liu, B., Jiang, S., Yuan, Q., & Liu, J. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b15124 · Cited by 537

Gas sensing using porous materials for automotive applications

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Construction of a bioinspired laccase-mimicking nanozyme for the degradation and detection of phenolic pollutants

Wang, J., Huang, R., Qi, W., Su, R., Binks, B. P., & He, Z. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.05.012 · Cited by 489

Single-Atom Catalysts for Electrochemical Water Splitting

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MIL‐53(Fe): A Metal–Organic Framework with Intrinsic Peroxidase‐Like Catalytic Activity for Colorimetric Biosensing

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Glucose Oxidase-Integrated Metal–Organic Framework Hybrids as Biomimetic Cascade Nanozymes for Ultrasensitive Glucose Biosensing

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Water-stable metal–organic frameworks with intrinsic peroxidase-like catalytic activity as a colorimetric biosensing platform

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Filling in the Gaps between Nanozymes and Enzymes: Challenges and Opportunities

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Fe–N–C Single-Atom Nanozymes for the Intracellular Hydrogen Peroxide Detection

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Synthesis of a mixed valence state Ce-MOF as an oxidase mimetic for the colorimetric detection of biothiols

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Textile/Metal–Organic‐Framework Composites as Self‐Detoxifying Filters for Chemical‐Warfare Agents

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Design and sensing applications of metal–organic framework composites

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Integrated Nanozymes with Nanoscale Proximity for in Vivo Neurochemical Monitoring in Living Brains

Cheng, H., Zhang, L., He, J., Guo, W., Zhou, Z., Zhang, X., Nie, S., & Wei, H. (2016) · Analytical Chemistry · doi:10.1021/acs.analchem.6b00975 · Cited by 324

Copper-Based Metal–Organic Framework Nanoparticles with Peroxidase-Like Activity for Sensitive Colorimetric Detection of Staphylococcus aureus

Wang, S., Deng, W., Yang, L., Tan, Y., Xie, Q., & Yao, S. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b07307 · Cited by 321

A nanosized metal–organic framework of Fe-MIL-88NH2 as a novel peroxidase mimic used for colorimetric detection of glucose

Liu, Y. L., Zhao, X. J., Yang, X. X., & Li, Y. F. (2013) · The Analyst · doi:10.1039/c3an00560g · Cited by 320

Nanozyme Sensor Arrays Based on Heteroatom-Doped Graphene for Detecting Pesticides

Zhu, Y., Wu, J., Han, L., Wang, X., Li, W., Guo, H., & Wei, H. (2020) · Analytical Chemistry · doi:10.1021/acs.analchem.9b05110 · Cited by 308

Cascade Reaction System Integrating Single-Atom Nanozymes with Abundant Cu Sites for Enhanced Biosensing

Wu, Y., Wu, J., Jiao, L., Xu, W., Wang, H., Wei, X., Gu, W., Ren, G., Zhang, N., Zhang, Q., et al. (2020) · Analytical Chemistry · doi:10.1021/acs.analchem.9b05437 · Cited by 307

Single‐Atom Iron Boosts Electrochemiluminescence

Gu, W., Wang, H., Jiao, L., Wu, Y., Chen, Y., Hu, L., Gong, J., Du, D., & Zhu, C. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201914643 · Cited by 296

Self‐Assembled Fe–N‐Doped Carbon Nanotube Aerogels with Single‐Atom Catalyst Feature as High‐Efficiency Oxygen Reduction Electrocatalysts

Zhu, C., Fu, S., Song, J., Shi, Q., Su, D., Engelhard, M. H., Li, X., Xiao, D., Li, D., Estevez, L., et al. (2017) · Small · doi:10.1002/smll.201603407 · Cited by 292

Unprecedented peroxidase-mimicking activity of single-atom nanozyme with atomically dispersed Fe–Nx moieties hosted by MOF derived porous carbon

Niu, X., Shi, Q., Zhu, W., Liu, D., Tian, H., Fu, S., Cheng, N., Li, S., Smith, J. N., Du, D., et al. (2019) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2019.111495 · Cited by 292

A single-atom Fe–N4 catalytic site mimicking bifunctional antioxidative enzymes for oxidative stress cytoprotection

Ma, W., Mao, J., Yang, X., Pan, C., Chen, W., Wang, M., Yu, P., Mao, L., & Li, Y. (2019) · Chemical Communications · doi:10.1039/c8cc08116f · Cited by 283

Single‐Atom Nanozyme Based on Nanoengineered Fe–N–C Catalyst with Superior Peroxidase‐Like Activity for Ultrasensitive Bioassays

Cheng, N., Li, J., Liu, D., Lin, Y., & Du, D. (2019) · Small · doi:10.1002/smll.201901485 · Cited by 277

Unraveling the enzyme-like activity of heterogeneous single atom catalyst

Zhao, C., Xiong, C., Liu, X., Qiao, M., Li, Z., Yuan, T., Wang, J., Qu, Y., Wang, X., Zhou, F., et al. (2019) · Chemical Communications · doi:10.1039/c9cc00199a · Cited by 271

Monitoring of Heparin Activity in Live Rats Using Metal–Organic Framework Nanosheets as Peroxidase Mimics

Cheng, H., Liu, Y., Hu, Y., Ding, Y., Lin, S., Cao, W., Wang, Q., Wu, J., Muhammad, F., Zhao, X., et al. (2017) · Analytical Chemistry · doi:10.1021/acs.analchem.7b02895 · Cited by 267

Facile synthesis of enzyme-embedded magnetic metal–organic frameworks as a reusable mimic multi-enzyme system: mimetic peroxidase properties and colorimetric sensor

Hou, C., Wang, Y., Ding, Q., Jiang, L., Li, M., Zhu, W., Pan, D., Zhu, H., & Liu, M. (2015) · Nanoscale · doi:10.1039/c5nr04994f · Cited by 251

Light-Responsive Metal–Organic Framework as an Oxidase Mimic for Cellular Glutathione Detection

Liu, Y., Zhou, M., Cao, W., Wang, X., Wang, Q., Li, S., & Wei, H. (2019) · Analytical Chemistry · doi:10.1021/acs.analchem.9b00512 · Cited by 244

2D-Metal–Organic-Framework-Nanozyme Sensor Arrays for Probing Phosphates and Their Enzymatic Hydrolysis

Qin, L., Wang, X., Liu, Y., & Wei, H. (2018) · Analytical Chemistry · doi:10.1021/acs.analchem.8b02428 · Cited by 241

Synthesis of nanocrystals of Zr-based metal–organic frameworks with csq-net: significant enhancement in the degradation of a nerve agent simulant

Li, P., Klet, R. C., Moon, S.-Y., Wang, T. C., Deria, P., Peters, A. W., Klahr, B. M., Park, H.-J., Al-Juaid, S. S., Hupp, J. T., et al. (2015) · Chem. Commun. · doi:10.1039/c5cc03398e · Cited by 232

Accelerating peroxidase mimicking nanozymes using DNA

Liu, B., & Liu, J. (2015) · Nanoscale · doi:10.1039/c5nr04176g · Cited by 227

Porphyrin-Encapsulated Metal–Organic Frameworks as Mimetic Catalysts for Electrochemical DNA Sensing via Allosteric Switch of Hairpin DNA

Ling, P., Lei, J., Zhang, L., & Ju, H. (2015) · Analytical Chemistry · doi:10.1021/acs.analchem.5b00001 · Cited by 221

Hemin@metal–organic framework with peroxidase-like activity and its application to glucose detection

Qin, F.-X., Jia, S.-Y., Wang, F.-F., Wu, S.-H., Song, J., & Liu, Y. (2013) · Catalysis Science & Technology · doi:10.1039/c3cy00268c · Cited by 213

Nickel metal-organic framework 2D nanosheets with enhanced peroxidase nanozyme activity for colorimetric detection of H2O2

Chen, J., Shu, Y., Li, H., Xu, Q., & Hu, X. (2018) · Talanta · doi:10.1016/j.talanta.2018.06.075 · Cited by 201

A bimetallic (Co/2Fe) metal-organic framework with oxidase and peroxidase mimicking activity for colorimetric detection of hydrogen peroxide

Yang, H., Yang, R., Zhang, P., Qin, Y., Chen, T., & Ye, F. (2017) · Microchimica Acta · doi:10.1007/s00604-017-2509-4 · Cited by 192

Emerging applications of nanozymes in environmental analysis: Opportunities and trends

Li, X., Wang, L., Du, D., Ni, L., Pan, J., & Niu, X. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2019.115653 · Cited by 186

Peroxidase-like Activity of Metal–Organic Framework [Cu(PDA)(DMF)] and Its Application for Colorimetric Detection of Dopamine

Wang, J., Hu, Y., Zhou, Q., Hu, L., Fu, W., & Wang, Y. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b17488 · Cited by 178

Mixed-Valence Ce-BPyDC Metal–Organic Framework with Dual Enzyme-like Activities for Colorimetric Biosensing

Luo, L., Huang, L., Liu, X., Zhang, W., Yao, X., Dou, L., Zhang, X., Nian, Y., Sun, J., & Wang, J. (2019) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.9b00661 · Cited by 177

2D Graphene Oxide/Fe-MOF Nanozyme Nest with Superior Peroxidase-Like Activity and Its Application for Detection of Woodsmoke Exposure Biomarker

Ruan, X., Liu, D., Niu, X., Wang, Y., Simpson, C. D., Cheng, N., Du, D., & Lin, Y. (2019) · Analytical Chemistry · doi:10.1021/acs.analchem.9b03321 · Cited by 165

Fe3O4 and metal–organic framework MIL-101(Fe) composites catalyze luminol chemiluminescence for sensitively sensing hydrogen peroxide and glucose

Qian Tang, X., Dan Zhang, Y., Wei Jiang, Z., Mei Wang, D., Zhi Huang, C., & Fang Li, Y. (2018) · Talanta · doi:10.1016/j.talanta.2017.10.049 · Cited by 164

Metal-organic framework coated Fe3O4 magnetic nanoparticles with peroxidase-like activity for colorimetric sensing of cholesterol

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When Nanozymes Meet Single‐Atom Catalysis

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Bio-inspired nanozyme: a hydratase mimic in a zeolitic imidazolate framework

Chen, J., Huang, L., Wang, Q., Wu, W., Zhang, H., Fang, Y., & Dong, S. (2019) · Nanoscale · doi:10.1039/c9nr01093a · Cited by 156

2D Single‐Atom Catalyst with Optimized Iron Sites Produced by Thermal Melting of Metal–Organic Frameworks for Oxygen Reduction Reaction

Liu, D., Li, J., Ding, S., Lyu, Z., Feng, S., Tian, H., Huyan, C., Xu, M., Li, T., Du, D., et al. (2020) · Small Methods · doi:10.1002/smtd.201900827 · Cited by 153

Metal–organic framework MIL-53(Fe): facile microwave-assisted synthesis and use as a highly active peroxidase mimetic for glucose biosensing

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A label-free fluorescence assay for hydrogen peroxide and glucose based on the bifunctional MIL-53(Fe) nanozyme

Lin, T., Qin, Y., Huang, Y., Yang, R., Hou, L., Ye, F., & Zhao, S. (2018) · Chemical Communications · doi:10.1039/c7cc09819g · Cited by 147

Colorimetric quantification and discrimination of phenolic pollutants based on peroxidase-like Fe3O4 nanoparticles

Wu, S., Guo, D., Xu, X., Pan, J., & Niu, X. (2019) · Sensors and Actuators B Chemical · doi:10.1016/j.snb.2019.127225 · Cited by 146

A peroxidase-mimicking Zr-based MOF colorimetric sensing array to quantify and discriminate phosphorylated proteins

Wang, L., Hu, Z. L., Wu, S., Pan, J., Xu, X., & Niu, X. (2020) · Analytica Chimica Acta · doi:10.1016/j.aca.2020.04.073 · Cited by 145

Porous Carbon‐Hosted Atomically Dispersed Iron–Nitrogen Moiety as Enhanced Electrocatalysts for Oxygen Reduction Reaction in a Wide Range of pH

Fu, S., Zhu, C., Su, D., Song, J., Yao, S., Feng, S., Engelhard, M., Du, D., & Lin, Y. (2018) · Small · doi:10.1002/smll.201703118 · Cited by 141

Artificial enzymes, “Chemzymes”: current state and perspectives

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Constructing metal–organic framework nanodots as bio-inspired artificial superoxide dismutase for alleviating endotoxemia

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Multifunctional nanozymes: enzyme-like catalytic activity combined with magnetism and surface plasmon resonance

Wu, J., Li, S., & Wei, H. (2018) · Nanoscale Horizons · doi:10.1039/c8nh00070k · Cited by 128

A sensitive fluorescent assay for thiamine based on metal-organic frameworks with intrinsic peroxidase-like activity

Tan, H., Li, Q., Zhou, Z., Ma, C., Song, Y., Xu, F., & Wang, L. (2014) · Analytica Chimica Acta · doi:10.1016/j.aca.2014.11.026 · Cited by 121

Surface charge engineering of nanosized CuS via acidic amino acid modification enables high peroxidase-mimicking activity at neutral pH for one-pot detection of glucose

Niu, X., Xu, X., Li, X., Pan, J., Qiu, F., Zhao, H., & Lan, M. (2018) · Chemical Communications · doi:10.1039/c8cc07800a · Cited by 120

Uncapped nanobranch-based CuS clews used as an efficient peroxidase mimic enable the visual detection of hydrogen peroxide and glucose with fast response

Niu, X., He, Y., Pan, J., Li, X., Qiu, F., Yan, Y., Shi, L., Zhao, H., & Lan, M. (2016) · Analytica Chimica Acta · doi:10.1016/j.aca.2016.10.013 · Cited by 111

Review—Nanozyme-Based Immunosensors and Immunoassays: Recent Developments and Future Trends

Niu, X., Cheng, N., Ruan, X., Du, D., & Lin, Y. (2019) · Journal of The Electrochemical Society · doi:10.1149/2.0082003jes · Cited by 109

Luminescence-Sensing Tb-MOF Nanozyme for the Detection and Degradation of Estrogen Endocrine Disruptors

Wang, L., & Chen, Y. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b22537 · Cited by 105

MOFzyme: Intrinsic protease-like activity of Cu-MOF

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Insights into Catalytic Hydrolysis of Organophosphate Warfare Agents by Metal–Organic Framework NU-1000

Chen, H., Liao, P., Mendonca, M. L., & Snurr, R. Q. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b03641 · Cited by 93

Three hidden talents in one framework: a terephthalic acid-coordinated cupric metal–organic framework with cascade cysteine oxidase- and peroxidase-mimicking activities and stimulus-responsive fluorescence for cysteine sensing

Li, X., Zhou, H., Qi, F., Niu, X., Xu, X., Qiu, F., He, Y., Pan, J., & Ni, L. (2018) · Journal of Materials Chemistry B · doi:10.1039/c8tb02167h · Cited by 90

Light-responsive nanozymes for biosensing

Liu, Y., Wang, X., & Wei, H. (2020) · The Analyst · doi:10.1039/d0an00389a · Cited by 89

Facile synthesis of enzyme functional metal-organic framework for colorimetric detecting H 2 O 2 and ascorbic acid

Gao, C., Zhu, H., Chen, J., & Qiu, H. (2017) · Chinese Chemical Letters · doi:10.1016/j.cclet.2017.02.011 · Cited by 88

Construction of a recyclable oxidase-mimicking Fe3O4@MnOx-based colorimetric sensor array for quantifying and identifying chlorophenols

Xu, X., Wu, S., Guo, D., & Niu, X. (2020) · Analytica Chimica Acta · doi:10.1016/j.aca.2020.02.024 · Cited by 82

Tuning single atom-nanoparticle ratios of Ni-based catalysts for synthesis gas production from CO2

Zhu, W., Fu, J., Liu, J., Chen, Y., Li, X., Huang, K., Cai, Y., He, Y., Zhou, Y., Su, D., et al. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118502 · Cited by 80

Novel and Sensitive Chemiluminescence Sensors Based on 2D-MOF Nanosheets for One-Step Detection of Glucose in Human Urine

Zhu, N., Gu, L., Wang, J., Li, X., Liang, G., Zhou, J., & Zhang, Z. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b00671 · Cited by 78

Polyethylenimine-stabilized silver nanoclusters act as an oxidoreductase mimic for colorimetric determination of chromium(VI)

Xue, Q., Li, X., Peng, Y., Liu, P., Peng, H., & Niu, X. (2020) · Microchimica Acta · doi:10.1007/s00604-020-04232-8 · Cited by 69

Gold alloy-based nanozyme sensor arrays for biothiol detection

Lin, J., Wang, Q., Wang, X., Zhu, Y., Zhou, X., & Wei, H. (2020) · The Analyst · doi:10.1039/d0an00451k · Cited by 66

Carbon nanotube-linked hollow carbon nanospheres doped with iron and nitrogen as single-atom catalysts for the oxygen reduction reaction in acidic solutions

Li, J., Cheng, H., Li, T., Ma, L., Ruan, X., Liu, D., Cheng, H., Liu, C., Du, D., Wei, Z., et al. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta00508k · Cited by 65

Atomically Isolated Iron Atom Anchored on Carbon Nanotubes for Oxygen Reduction Reaction

Liu, D., Li, J., Shi, Q., Feng, S., Lyu, Z., Ding, S., Hao, L., Zhang, Q., Wang, C., Xu, M., et al. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b12054 · Cited by 58

Highly sensitive and selective colorimetric detection of glutathione via enhanced Fenton-like reaction of magnetic metal organic framework

Zhang, Y., Zhang, W., Chen, K., Yang, Q., Hu, N., Suo, Y., & Wang, J. (2018) · Sensors and Actuators B Chemical · doi:10.1016/j.snb.2018.01.221 · Cited by 57

Colorimetric determination of thiol compounds in serum based on Fe-MIL-88NH 2 metal–organic framework as peroxidase mimetics

Jiang, Z., Liu, Y., Hu, X., & Li, Y. (2014) · Analytical Methods · doi:10.1039/c4ay00747f · Cited by 48

Fluorometric determination of the activity of inorganic pyrophosphatase and its inhibitors by exploiting the peroxidase mimicking properties of a two-dimensional metal organic framework

Hu, S., Zhu, L. H., Lam, C. W., Guo, L., Lin, Z., Qiu, B., Wong, K., Chen, G., & Liu, Z. (2019) · Microchimica Acta · doi:10.1007/s00604-019-3250-y · Cited by 38

Applications of Antimicrobial Photodynamic Therapy against Bacterial Biofilms

Songca, S. P., & Adjei, Y. (2022) · International Journal of Molecular Sciences · doi:10.3390/ijms23063209 · Cited by 175