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Controlling H+ vs CO2 Reduction Selectivity on Pb Electrodes
Abstract
Nanocrystalline Pb films prepared by reducing PbO 2 precursors have up to 700-fold lower H + reduction activity than polycrystalline Pb foil electrodes but maintain the ability to reduce CO 2 . As a result, these “oxide-derived” Pb (OD–Pb) electrodes have higher Faradaic efficiency for CO 2 reduction to HCO 2 – in aqueous solutions with almost no competitive H + reduction. Even with very low CO 2 concentrations in N 2 -saturated NaHCO 3 solution, OD–Pb converts CO 2 derived from HCO 3 – decomposition to HCO 2 – with almost quantitative Faradaic efficiency while Pb foil has less than 10% efficiency. Electrokinetic data suggest that the difference in selectivity between the two electrodes is caused by a difference in the coverage of a surface layer—likely a metastable Pb oxide—that is passivating for H + reduction but active for CO 2 reduction.
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Metadata
- Authors
- Lee, C. H., & Kanan, M. W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-12-19
- Volume
- 5
- Issue
- 1
- Pages
- 465-469
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2332828948
- Cited by
- 341
- References
- 4
- FWCI
- 8.30
- Type
- journal article
- Language
- en
- Open access
- closed
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