Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 1,846

The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.

Metal–Organic Framework Derived Hybrid Co3O4-Carbon Porous Nanowire Arrays as Reversible Oxygen Evolution Electrodes

Open access
Ma, Tian Yi, Dai, Sheng, Jaroniec, Mietek, Qiao, Shi Zhang·2014·Journal of the American Chemical Society
DOI 10.1021/ja5082553
Open this paper in CoChat — free account

Abstract

Hybrid porous nanowire arrays composed of strongly interacting Co3O4 and carbon were prepared by a facile carbonization of the metal-organic framework grown on Cu foil. The resulting material, possessing a high surface area of 251 m(2) g(-1) and a large carbon content of 52.1 wt %, can be directly used as the working electrode for oxygen evolution reaction without employing extra substrates or binders. This novel oxygen evolution electrode can smoothly operate in alkaline solutions (e.g., 0.1 and 1.0 M KOH), affording a low onset potential of 1.47 V (vs reversible hydrogen electrode) and a stable current density of 10.0 mA cm(-2) at 1.52 V in 0.1 M KOH solution for at least 30 h, associated with a high Faradaic efficiency of 99.3%. The achieved ultrahigh oxygen evolution activity and strong durability, with superior performance in comparison to the state-of-the-art noble-metal/transition-metal and nonmetal catalysts, originate from the unique nanowire array electrode configuration and in situ carbon incorporation, which lead to the large active surface area, enhanced mass/charge transport capability, easy release of oxygen gas bubbles, and strong structural stability. Furthermore, the hybrid Co3O4-carbon porous nanowire arrays can also efficiently catalyze oxygen reduction reaction, featuring a desirable four-electron pathway for reversible oxygen evolution and reduction, which is potentially useful for rechargeable metal-air batteries, regenerative fuel cells, and other important clean energy devices.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1021/ja5082553

Cites

6 of 6 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Show all 6 references

Research works printed but not linked: 54

  1. Kim T. W., 2014, Science, 343, 990, 10.1126/science.1246913 · DOI · Paper page
  2. Zhang M., 2014, Nat. Chem., 6, 362, 10.1038/nchem.1874 · DOI · Paper page
  3. Yuan C. Z., 2014, Angew. Chem., 126, 1512, 10.1002/ange.201303971 · DOI
  4. Angew. Chem., Int. Ed. 2014, 53, 1488–1504. · DOI · Paper page
  5. Katsounaros I., 2014, Angew. Chem., 126, 104, 10.1002/ange.201306588 · DOI
  6. Angew. Chem., Int. Ed. 2014, 53, 102–121.
  7. Oh S. H., 2012, Nat. Chem., 4, 1004, 10.1038/nchem.1499 · DOI · Paper page
  8. Over H., 2012, Chem. Rev., 112, 3356, 10.1021/cr200247n · DOI · Paper page
  9. Lee Y., 2012, J. Phys. Chem. Lett., 3, 399, 10.1021/jz2016507 · DOI · Paper page
  10. Jin K., 2014, J. Am. Chem. Soc., 136, 7435, 10.1021/ja5026529 · DOI · Paper page
  11. Gong M., 2013, J. Am. Chem. Soc., 135, 8452, 10.1021/ja4027715 · DOI · Paper page
  12. Subbaraman R., 2012, Nat. Mater., 11, 550, 10.1038/nmat3313 · DOI · Paper page
  13. Gao M. R., 2012, J. Am. Chem. Soc., 134, 2930, 10.1021/ja211526y · DOI · Paper page
  14. Liang Y. Y., 2011, Nat. Mater., 10, 780, 10.1038/nmat3087 · DOI · Paper page
  15. Ma T. Y., 2014, Angew. Chem., 126, 7409, 10.1002/ange.201403946 · DOI · Paper page
  16. Angew. Chem., Int. Ed. 2014, 53, 7281–7285. · DOI · Paper page
  17. Tian G. L., 2014, Small, 10, 2251, 10.1002/smll.201303715 · DOI · Paper page
  18. Zhao Y., 2013, Nat. Commun., 4, 2390, 10.1038/ncomms3390 · DOI · Paper page
  19. Park H. W., 2013, J. Electrochem. Soc., 160, A2244, 10.1149/2.097311jes · DOI
  20. Wang J., 2013, Angew. Chem., 125, 5356, 10.1002/ange.201301066 · DOI
  21. Angew. Chem., Int. Ed. 2013, 52, 5248–5253. · DOI · Paper page
  22. Xin S., 2012, Acc. Chem. Res., 45, 1759, 10.1021/ar300094m · DOI · Paper page
  23. Cheng F. Y., 2012, Chem. Soc. Rev., 41, 2172, 10.1039/c1cs15228a · DOI · Paper page
  24. Lang X. Y., 2011, Nat. Nanotechnol., 6, 232, 10.1038/nnano.2011.13 · DOI · Paper page
  25. Wang K., 2014, Small, 10, 14, 10.1002/smll.201301991 · DOI · Paper page
  26. Shen L., 2014, Adv. Funct. Mater., 24, 2630, 10.1002/adfm.201303138 · DOI · Paper page
  27. Jiang Y., 2014, Nano Lett., 14, 365, 10.1021/nl404251p · doi:10.1021/nl404251p
  28. Liao J. Y., 2013, Nano Lett., 13, 5467, 10.1021/nl4030159 · DOI · Paper page
  29. Yuan C., 2012, Energy Environ. Sci., 5, 7883, 10.1039/c2ee21745g · DOI · Paper page
  30. Gong K., 2009, Science, 323, 760, 10.1126/science.1168049 · DOI · Paper page
  31. Liu X. J., 2014, Chem. Mater., 26, 1889, 10.1021/cm4040903 · DOI · Paper page
  32. Li Y., 2010, Adv. Mater., 22, 1926, 10.1002/adma.200903896 · DOI · Paper page
  33. Lee D. U., 2014, Adv. Energy Mater., 4, 1301389, 10.1002/aenm.201301389 · DOI · Paper page
  34. Lu B., 2011, Int. J. Hydrogen Energy, 36, 72, 10.1016/j.ijhydene.2010.09.056 · DOI · Paper page
  35. Artero V., 2011, Angew. Chem., 123, 7376, 10.1002/ange.201007987 · DOI · Paper page
  36. Angew. Chem., Int. Ed. 2011, 50, 7238–7266. · DOI · Paper page
  37. Cui B., 2008, Adv. Funct. Mater., 18, 1440, 10.1002/adfm.200700982 · DOI · Paper page
  38. Sun J. K., 2014, Energy Environ. Sci., 7, 2071, 10.1039/c4ee00517a · DOI · Paper page
  39. Proietti E., 2011, Nat. Commun., 2, 416, 10.1038/ncomms1427 · DOI · Paper page
  40. Furukawa H., 2013, Science, 341, 1230444, 10.1126/science.1230444 · DOI · Paper page
  41. Kaduk J. A., 2001, J. Appl. Crystallogr., 34, 710, 10.1107/S0021889801012857 · DOI
  42. Gu D., 2014, Chem. Soc. Rev., 43, 313, 10.1039/C3CS60155B · DOI · Paper page
  43. Banerjee D., 2014, Angew. Chem., 126, 4448, 10.1002/ange.201310420 · DOI
  44. Angew. Chem., Int. Ed. 2014, 53, 4359–4363. · DOI
  45. Wu J., 2012, Nano Res., 5, 521, 10.1007/s12274-012-0237-y · DOI · Paper page
  46. Li J., 2007, J. Am. Chem. Soc., 129, 9401, 10.1021/ja071122v · DOI · Paper page
  47. Mamaca N., 2012, Appl. Catal. B: Environ., 111, 376, 10.1016/j.apcatb.2011.10.020 · DOI · Paper page
  48. Mao S., 2014, Energy Environ. Sci., 7, 609, 10.1039/C3EE42696C · DOI · Paper page
  49. Zou X., 2013, J. Am. Chem. Soc., 135, 17242, 10.1021/ja407174u · DOI · Paper page
  50. Smith R. D. L., 2013, J. Am. Chem. Soc., 135, 11580, 10.1021/ja403102j · DOI · Paper page
  51. Masa J., 2014, Angew. Chem., 126, 8648, 10.1002/ange.201402710 · doi:10.1002/ange.201402710
  52. Angew. Chem., Int. Ed. 2014, 53, 8508–8512.
  53. Han X. P., 2014, Adv. Mater., 26, 2047, 10.1002/adma.201304867 · DOI · Paper page
  54. Lu Z., 2014, Nat. Commun., 5, 4345, 10.1038/ncomms5345 · DOI · Paper page

Cited by

Metadata

Authors
Ma, T. Y., Dai, S., Jaroniec, M., & Qiao, S. Z.
Venue
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Published
2014-09-22
Volume
136
Issue
39
Pages
13925-13931
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
DOI
10.1021/ja5082553
OpenAlex
W2048407205
Cited by
1,846
References
6
FWCI
66.58
Type
journal article
Language
en
Open access
green
Funders
Australian Research Council (DP130104459, DP140104062)

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.