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Protecting Copper Oxidation State via Intermediate Confinement for Selective CO2 Electroreduction to C2+ Fuels
Abstract
Selective and efficient catalytic conversion of carbon dioxide (CO 2 ) into value-added fuels and feedstocks provides an ideal avenue to high-density renewable energy storage. An impediment to enabling deep CO 2 reduction to oxygenates and hydrocarbons (e.g., C 2+ compounds) is the difficulty of coupling carbon–carbon bonds efficiently. Copper in the +1 oxidation state has been thought to be active for catalyzing C 2+ formation, whereas it is prone to being reduced to Cu 0 at cathodic potentials. Here we report that catalysts with nanocavities can confine carbon intermediates formed in situ, which in turn covers the local catalyst surface and thereby stabilizes Cu + species. Experimental measurements on multihollow cuprous oxide catalyst exhibit a C 2+ Faradaic efficiency of 75.2 ± 2.7% at a C 2+ partial current density of 267 ± 13 mA cm –2 and a large C 2+ -to-C 1 ratio of ∼7.2. Operando Raman spectra, in conjunction with X-ray absorption studies, confirm that Cu + species in the as-designed catalyst are well retained during CO 2 reduction, which leads to the marked C 2+ selectivity at a large conversion rate.
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Cites
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
Atomically dispersed Fe 3+ sites catalyze efficient CO 2 electroreduction to CO
Gu, J., Hsu, C.-S., Bai, L., Chen, H. M., & Hu, X. (2019) · Science · doi:10.1126/science.aaw7515 · Cited by 1,610
Materials for solar fuels and chemicals
Montoya, J. H., Seitz, L. C., Chakthranont, P., Vojvodic, A., Jaramillo, T. F., & Nørskov, J. K. (2017) · Nature Materials · doi:10.1038/nmat4778 · Cited by 1,566
Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products
Gao, D., Arán-Ais, R. M., Jeon, H. S., & Roldan Cuenya, B. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0235-5 · Cited by 1,489
Prospects of CO2 Utilization via Direct Heterogeneous Electrochemical Reduction
Whipple, D. T., & Kenis, P. J. A. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1012627 · Cited by 1,417
Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331
Molecular tuning of CO2-to-ethylene conversion
Li, F., Thevenon, A., Rosas-Hernández, A., Wang, Z., Li, Y., Gabardo, C. M., Ozden, A., Dinh, C. T., Li, J., Wang, Y., et al. (2020) · Nature · doi:10.1038/s41586-019-1782-2 · Cited by 1,275
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
Domino electroreduction of CO2 to methanol on a molecular catalyst
Wu, Y., Jiang, Z., Lu, X., Liang, Y., & Wang, H. (2019) · Nature · doi:10.1038/s41586-019-1760-8 · Cited by 1,194
Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
Zhou, Y., Che, F., Liu, M., Zou, C., Liang, Z., De Luna, P., Yuan, H., Li, J., Wang, Z., Xie, H., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0092-x · Cited by 1,171
Zheng, Y., Vasileff, A., Zhou, X., Jiao, Y., Jaroniec, M., & Qiao, S.-Z. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b02124 · Cited by 1,075
Self-citationDe Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046
Self-citationMolecular electrocatalysts can mediate fast, selective CO 2 reduction in a flow cell
Ren, S., Joulié, D., Salvatore, D., Torbensen, K., Wang, M., Robert, M., & Berlinguette, C. P. (2019) · Science · doi:10.1126/science.aax4608 · Cited by 941
Ren, D., Deng, Y., Handoko, A. D., Chen, C. S., Malkhandi, S., & Yeo, B. S. (2015) · ACS Catalysis · doi:10.1021/cs502128q · Cited by 930
Vasileff, A., Xu, C., Jiao, Y., Zheng, Y., & Qiao, S.-Z. (2018) · Chem · doi:10.1016/j.chempr.2018.05.001 · Cited by 901
Self-citationLarge-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887
Self-citationBio-inspired hydrophobicity promotes CO2 reduction on a Cu surface
Wakerley, D., Lamaison, S., Ozanam, F., Menguy, N., Mercier, D., Marcus, P., Fontecave, M., & Mougel, V. (2019) · Nature Materials · doi:10.1038/s41563-019-0445-x · Cited by 847
Metal ion cycling of Cu foil for selective C–C coupling in electrochemical CO2 reduction
Jiang, K., Sandberg, R. B., Akey, A. J., Liu, X., Bell, D. C., Nørskov, J. K., Chan, K., & Wang, H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0009-x · Cited by 839
Self-citationUnderstanding trends in electrochemical carbon dioxide reduction rates
Liu, X., Xiao, J., Peng, H., Hong, X., Chan, K., & Nørskov, J. K. (2017) · Nature Communications · doi:10.1038/ncomms15438 · Cited by 804
Zhuang, T.-T., Liang, Z.-Q., Seifitokaldani, A., Li, Y., De Luna, P., Burdyny, T., Che, F., Meng, F., Min, Y., Quintero-Bermudez, R., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0084-7 · Cited by 784
Self-citationGILLIAM, R., GRAYDON, J., KIRK, D., & THORPE, S. (2007) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2006.10.062 · Cited by 702
Gong, Q., Ding, P., Xu, M., Zhu, X., Wang, M., Deng, J., Ma, Q., Han, N., Zhu, Y., Lu, J., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-10819-4 · Cited by 678
A Gross‐Margin Model for Defining Technoeconomic Benchmarks in the Electroreduction of CO2
Verma, S., Kim, B., Jhong, H. “., Ma, S., & Kenis, P. J. A. (2016) · ChemSusChem · doi:10.1002/cssc.201600394 · Cited by 655
Xiao, H., Goddard, W. A., Cheng, T., & Liu, Y. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1702405114 · Cited by 621
High-rate electroreduction of carbon monoxide to multi-carbon products
Jouny, M., Luc, W., & Jiao, F. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0133-2 · Cited by 617
Nielsen, D. U., Hu, X.-M., Daasbjerg, K., & Skrydstrup, T. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0051-3 · Cited by 613
Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate
Luc, W., Fu, X., Shi, J., Lv, J.-J., Jouny, M., Ko, B. H., Xu, Y., Tu, Q., Hu, X., Wu, J., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0269-8 · Cited by 600
Binding Site Diversity Promotes CO2 Electroreduction to Ethanol
Li, Y. C., Wang, Z., Yuan, T., Nam, D.-H., Luo, M., Wicks, J., Chen, B., Li, J., Li, F., de Arquer, F. P. G., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b02945 · Cited by 581
Wang, Y., Wang, Z., Dinh, C.-T., Li, J., Ozden, A., Golam Kibria, M., Seifitokaldani, A., Tan, C.-S., Gabardo, C. M., Luo, M., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0397-1 · Cited by 561
Lee, S. Y., Jung, H., Kim, N.-K., Oh, H.-S., Min, B. K., & Hwang, Y. J. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b02173 · Cited by 558
On the origin of the elusive first intermediate of CO 2 electroreduction
Chernyshova, I. V., Somasundaran, P., & Ponnurangam, S. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1802256115 · Cited by 555
Zhuang, T.-T., Pang, Y., Liang, Z.-Q., Wang, Z., Li, Y., Tan, C.-S., Li, J., Dinh, C. T., De Luna, P., Hsieh, P.-L., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0168-4 · Cited by 548
Self-citationJiao, Y., Zheng, Y., Chen, P., Jaroniec, M., & Qiao, S.-Z. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10817 · Cited by 531
Self-citationXiao, H., Cheng, T., Goddard, W. A., & Sundararaman, R. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b11390 · Cited by 527
Verma, S., Hamasaki, Y., Kim, C., Huang, W., Lu, S., Jhong, H.-R. M., Gewirth, A. A., Fujigaya, T., Nakashima, N., & Kenis, P. J. A. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.7b01096 · Cited by 521
A Highly Porous Copper Electrocatalyst for Carbon Dioxide Reduction
Lv, J., Jouny, M., Luc, W., Zhu, W., Zhu, J., & Jiao, F. (2018) · Advanced Materials · doi:10.1002/adma.201803111 · Cited by 497
Self-citationGao, J., Zhang, H., Guo, X., Luo, J., Zakeeruddin, S. M., Ren, D., & Grätzel, M. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07415 · Cited by 495
Zhu, Q., Sun, X., Yang, D., Ma, J., Kang, X., Zheng, L., Zhang, J., Wu, Z., & Han, B. (2019) · Nature Communications · doi:10.1038/s41467-019-11599-7 · Cited by 440
Self-citationGrosse, P., Gao, D., Scholten, F., Sinev, I., Mistry, H., & Roldan Cuenya, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201802083 · Cited by 425
Potential-induced nanoclustering of metallic catalysts during electrochemical CO2 reduction
Huang, J., Hörmann, N., Oveisi, E., Loiudice, A., De Gregorio, G. L., Andreussi, O., Marzari, N., & Buonsanti, R. (2018) · Nature Communications · doi:10.1038/s41467-018-05544-3 · Cited by 420
Vasileff, A., Zheng, Y., & Qiao, S. Z. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700759 · Cited by 405
Self-citationCopper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2
Liang, Z.-Q., Zhuang, T.-T., Seifitokaldani, A., Li, J., Huang, C.-W., Tan, C.-S., Li, Y., De Luna, P., Dinh, C. T., Hu, Y., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-06311-0 · Cited by 393
Recent Advances in CO2 Reduction Electrocatalysis on Copper
Raciti, D., & Wang, C. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00553 · Cited by 383
Lin, L., Li, H., Yan, C., Li, H., Si, R., Li, M., Xiao, J., Wang, G., & Bao, X. (2019) · Advanced Materials · doi:10.1002/adma.201903470 · Cited by 358
Morphology‐Directed Selective Production of Ethylene or Ethane from CO2 on a Cu Mesopore Electrode
Yang, K. D., Ko, W. R., Lee, J. H., Kim, S. J., Lee, H., Lee, M. H., & Nam, K. T. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201610432 · Cited by 354
Gao, D., Scholten, F., & Roldan Cuenya, B. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01416 · Cited by 338
Kibria, M. G., Dinh, C., Seifitokaldani, A., De Luna, P., Burdyny, T., Quintero‐Bermudez, R., Ross, M. B., Bushuyev, O. S., García de Arquer, F. P., Yang, P., et al. (2018) · Advanced Materials · doi:10.1002/adma.201804867 · Cited by 269
Self-citationCu3N Nanocubes for Selective Electrochemical Reduction of CO2 to Ethylene
Yin, Z., Yu, C., Zhao, Z., Guo, X., Shen, M., Li, N., Muzzio, M., Li, J., Liu, H., Lin, H., et al. (2019) · Nano Letters · doi:10.1021/acs.nanolett.9b03324 · Cited by 269
Vasileff, A., Zhi, X., Xu, C., Ge, L., Jiao, Y., Zheng, Y., & Qiao, S.-Z. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02312 · Cited by 262
Self-citationRen, D., Gao, J., Pan, L., Wang, Z., Luo, J., Zakeeruddin, S. M., Hagfeldt, A., & Grätzel, M. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201909610 · Cited by 229
Gao, F., Hu, S., Zhang, X., Zheng, Y., Wang, H., Niu, Z., Yang, P., Bao, R., Ma, T., Dang, Z., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201912348 · Cited by 222
Self-citationDiffusion coefficients of neon, krypton, xenon, carbon monoxide and nitric oxide in water at 10–60°C
Wise, D. L., & Houghton, G. (1968) · Chemical Engineering Science · doi:10.1016/0009-2509(68)89029-3 · Cited by 160
Beyond Copper in CO2 Electrolysis: Effective Hydrocarbon Production on Silver-Nanofoam Catalysts
Dutta, A., Morstein, C. E., Rahaman, M., López, A. C., & Broekmann, P. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01738 · Cited by 151
Nanostructured heterogeneous catalysts for electrochemical reduction of CO2
Gao, D., Cai, F., Wang, G., & Bao, X. (2016) · Current Opinion in Green and Sustainable Chemistry · doi:10.1016/j.cogsc.2016.10.004 · Cited by 62
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Metadata
- Authors
- Yang, P.-P., Zhang, X.-L., Gao, F.-Y., Zheng, Y.-R., Niu, Z.-Z., Yu, X., Liu, R., Wu, Z.-Z., Qin, S., Chi, L.-P., Duan, Y., Ma, T., Zheng, X.-S., Zhu, J.-F., Wang, H.-J., Gao, M.-R., & Yu, S.-H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-03-16
- Volume
- 142
- Issue
- 13
- Pages
- 6400-6408
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3011311522
- Cited by
- 709
- References
- 57
- FWCI
- 17.44
- Type
- journal article
- Language
- en
- Open access
- closed
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