Cited by 361

The DOI matches its Crossref record; 80 of the 80 references it cites were found in a registry or an index.

Orbital Interactions in Bi‐Sn Bimetallic Electrocatalysts for Highly Selective Electrochemical CO2 Reduction toward Formate Production

Wen, Guobin, Lee, Dong Un, Ren, Bohua, Hassan, Fathy M., Jiang, Gaopeng, Cano, Zachary P., Gostick, Jeff, Croiset, Eric, Bai, Zhengyu, Yang, Lin, Chen, Zhongwei·2018·Advanced Energy Materials

DOI 10.1002/aenm.201802427

Open this paper in CoChat — free account

Abstract

A highly selective and durable electrocatalyst for carbon dioxide (CO 2) conversion to formate is developed, consisting of tin (Sn) nanosheets decorated with bismuth (Bi) nanoparticles. Owing to the formation of active sites through favorable orbital interactions at the Sn‐Bi interface, the Bi‐Sn bimetallic catalyst converts CO 2 to formate with a remarkably high Faradaic efficiency (96%) and production rate (0.74 mmol h−1 cm−2) at −1.1 V versus reversible hydrogen electrode. Additionally, the catalyst maintains its initial efficiency over an unprecedented 100 h of operation. Density functional theory reveals that the addition of Bi nanoparticles upshifts the electron states of Sn away from the Fermi level, allowing the HCOO* intermediate to favorably adsorb onto the Bi‐Sn interface compared to a pure Sn surface. This effectively facilitates the flow of electrons to promote selective and durable conversion of CO 2 to formate. This study provides sub‐atomic level insights and a general methodology for bimetallic catalyst developments and surface engineering for highly selective CO 2 electroreduction.

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Integrity signals

Registry

Crossref · 10.1002/aenm.201802427

Cites

80 of 80 references verified0 citation errors · 0 not checkable

Statistics

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Computational Materials Science · doi:10.1016/0927-0256(96)00008-0 · Cited by 75,638
A local exchange-correlation potential for the spin polarized case. i
Barth, U. V., & Hedin, L. (1972) · Journal of Physics C: Solid State Physics · doi:10.1088/0022-3719/5/13/012 · Cited by 5,434
Theoretical surface science and catalysis—calculations and concepts
Hammer, B., & Nørskov, J. K. (2000) · Advances in Catalysis · doi:10.1016/s0360-0564(02)45013-4 · Cited by 3,972
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Aqueous CO2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
Chen, Y., Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309317u · Cited by 1,664
Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes
Álvarez, A., Bansode, A., Urakawa, A., Bavykina, A. V., Wezendonk, T. A., Makkee, M., Gascon, J., & Kapteijn, F. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00816 · Cited by 1,600
CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction
Wang, W.-H., Himeda, Y., Muckerman, J. T., Manbeck, G. F., & Fujita, E. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00197 · Cited by 1,507
A selective and efficient electrocatalyst for carbon dioxide reduction
Lu, Q., Rosen, J., Zhou, Y., Hutchings, G. S., Kimmel, Y. C., Chen, J. G., & Jiao, F. (2014) · Nature Communications · doi:10.1038/ncomms4242 · Cited by 1,478
Catalysis for CO2 conversion: a key technology for rapid introduction of renewable energy in the value chain of chemical industries
Centi, G., Quadrelli, E. A., & Perathoner, S. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00056g · Cited by 1,257
Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen
Alayoglu, S., Nilekar, A. U., Mavrikakis, M., & Eichhorn, B. (2008) · Nature Materials · doi:10.1038/nmat2156 · Cited by 1,245
Design of Single-Atom Co–N5 Catalytic Site: A Robust Electrocatalyst for CO2 Reduction with Nearly 100% CO Selectivity and Remarkable Stability
Pan, Y., Lin, R., Chen, Y., Liu, S., Zhu, W., Cao, X., Chen, W., Wu, K., Cheong, W.-C., Wang, Y., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b00814 · Cited by 1,242
Construction of ZnIn2S4–In2O3 Hierarchical Tubular Heterostructures for Efficient CO2 Photoreduction
Wang, S., Guan, B. Y., & Lou, X. W. D. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b02200 · Cited by 1,218
Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2
Ju, W., Bagger, A., Hao, G.-P., Varela, A. S., Sinev, I., Bon, V., Roldan Cuenya, B., Kaskel, S., Rossmeisl, J., & Strasser, P. (2017) · Nature Communications · doi:10.1038/s41467-017-01035-z · Cited by 1,203
Implementation of gradient-corrected exchange-correlation potentials in Car-Parrinello total-energy calculations
White, J. A., & Bird, D. M. (1994) · Physical Review B · doi:10.1103/physrevb.50.4954 · Cited by 1,198
Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate
Zhang, S., Kang, P., & Meyer, T. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja4113885 · Cited by 1,151
Homogeneous Catalysis for Sustainable Hydrogen Storage in Formic Acid and Alcohols
Sordakis, K., Tang, C., Vogt, L. K., Junge, H., Dyson, P. J., Beller, M., & Laurenczy, G. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00182 · Cited by 1,110
Tin Oxide Dependence of the CO2 Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts
Chen, Y., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2108799 · Cited by 982
Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes
Feaster, J. T., Shi, C., Cave, E. R., Hatsukade, T., Abram, D. N., Kuhl, K. P., Hahn, C., Nørskov, J. K., & Jaramillo, T. F. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00687 · Cited by 950
Ultrathin bismuth nanosheets from in situ topotactic transformation for selective electrocatalytic CO2 reduction to formate
Han, N., Wang, Y., Yang, H., Deng, J., Wu, J., Li, Y., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03712-z · Cited by 914
Coordinatively unsaturated nickel–nitrogen sites towards selective and high-rate CO2electroreduction
Yan, C., Li, H., Ye, Y., Wu, H., Cai, F., Si, R., Xiao, J., Miao, S., Xie, S., Yang, F., et al. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00133b · Cited by 768
Robust carbon dioxide reduction on molybdenum disulphide edges
Asadi, M., Kumar, B., Behranginia, A., Rosen, B. A., Baskin, A., Repnin, N., Pisasale, D., Phillips, P., Zhu, W., Haasch, R., et al. (2014) · Nature Communications · doi:10.1038/ncomms5470 · Cited by 766
Metal‐Free Carbon Materials for CO2 Electrochemical Reduction
Duan, X., Xu, J., Wei, Z., Ma, J., Guo, S., Wang, S., Liu, H., & Dou, S. (2017) · Advanced Materials · doi:10.1002/adma.201701784 · Cited by 754
Tuning Sn-Catalysis for Electrochemical Reduction of CO2 to CO via the Core/Shell Cu/SnO2 Structure
Li, Q., Fu, J., Zhu, W., Chen, Z., Shen, B., Wu, L., Xi, Z., Wang, T., Lu, G., Zhu, J.-J., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00261 · Cited by 676
Self-citation
Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction
Lei, F., Liu, W., Sun, Y., Xu, J., Liu, K., Liang, L., Yao, T., Pan, B., Wei, S., & Xie, Y. (2016) · Nature Communications · doi:10.1038/ncomms12697 · Cited by 675
Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
Verdaguer-Casadevall, A., Li, C. W., Johansson, T. P., Scott, S. B., McKeown, J. T., Kumar, M., Stephens, I. E. L., Kanan, M. W., & Chorkendorff, I. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06227 · Cited by 645
Atomically Dispersed Transition Metals on Carbon Nanotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction
Cheng, Y., Zhao, S., Johannessen, B., Veder, J., Saunders, M., Rowles, M. R., Cheng, M., Liu, C., Chisholm, M. F., De Marco, R., et al. (2018) · Advanced Materials · doi:10.1002/adma.201706287 · Cited by 614
Probing the Reaction Mechanism of CO2 Electroreduction over Ag Films via Operando Infrared Spectroscopy
Firet, N. J., & Smith, W. A. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b02382 · Cited by 577
Ag–Sn Bimetallic Catalyst with a Core–Shell Structure for CO2 Reduction
Luc, W., Collins, C., Wang, S., Xin, H., He, K., Kang, Y., & Jiao, F. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b10435 · Cited by 553
Pd-Catalyzed Electrohydrogenation of Carbon Dioxide to Formate: High Mass Activity at Low Overpotential and Identification of the Deactivation Pathway
Min, X., & Kanan, M. W. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511890h · Cited by 541
Sulfur-Modulated Tin Sites Enable Highly Selective Electrochemical Reduction of CO2 to Formate
Zheng, X., De Luna, P., García de Arquer, F. P., Zhang, B., Becknell, N., Ross, M. B., Li, Y., Banis, M. N., Li, Y., Liu, M., et al. (2017) · Joule · doi:10.1016/j.joule.2017.09.014 · Cited by 515
Mechanistic Insights into the Reduction of CO2 on Tin Electrodes using in Situ ATR-IR Spectroscopy
Baruch, M. F., Pander, J. E., White, J. L., & Bocarsly, A. B. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00402 · Cited by 509
Structure-Sensitive CO2 Electroreduction to Hydrocarbons on Ultrathin 5-fold Twinned Copper Nanowires
Li, Y., Cui, F., Ross, M. B., Kim, D., Sun, Y., & Yang, P. (2017) · Nano Letters · doi:10.1021/acs.nanolett.6b05287 · Cited by 466
Fabrication of Nickel–Cobalt Bimetal Phosphide Nanocages for Enhanced Oxygen Evolution Catalysis
Qiu, B., Cai, L., Wang, Y., Lin, Z., Zuo, Y., Wang, M., & Chai, Y. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201706008 · Cited by 452
Morphology Matters: Tuning the Product Distribution of CO2 Electroreduction on Oxide-Derived Cu Foam Catalysts
Dutta, A., Rahaman, M., Luedi, N. C., Mohos, M., & Broekmann, P. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00770 · Cited by 450
Theoretical Insight into the Trends that Guide the Electrochemical Reduction of Carbon Dioxide to Formic Acid
Yoo, J. S., Christensen, R., Vegge, T., Nørskov, J. K., & Studt, F. (2016) · ChemSusChem · doi:10.1002/cssc.201501197 · Cited by 429
Boosting Formate Production in Electrocatalytic CO 2 Reduction over Wide Potential Window on Pd Surfaces
Jiang, B., Zhang, X.-G., Jiang, K., Wu, D.-Y., & Cai, W.-B. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b12506 · Cited by 402
Rationally designed hierarchical N-doped carbon@NiCo2O4 double-shelled nanoboxes for enhanced visible light CO2 reduction
Wang, S., Guan, B. Y., & Lou, X. W. (. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02934a · Cited by 400
Effect of Chloride Anions on the Synthesis and Enhanced Catalytic Activity of Silver Nanocoral Electrodes for CO 2 Electroreduction
Hsieh, Y.-C., Senanayake, S. D., Zhang, Y., Xu, W., & Polyansky, D. E. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01235 · Cited by 396
Rational Design of Efficient Palladium Catalysts for Electroreduction of Carbon Dioxide to Formate
Klinkova, A., De Luna, P., Dinh, C.-T., Voznyy, O., Larin, E. M., Kumacheva, E., & Sargent, E. H. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b01719 · Cited by 342
Amorphizing of Cu Nanoparticles toward Highly Efficient and Robust Electrocatalyst for CO2 Reduction to Liquid Fuels with High Faradaic Efficiencies
Duan, Y., Meng, F., Liu, K., Yi, S., Li, S., Yan, J., & Jiang, Q. (2018) · Advanced Materials · doi:10.1002/adma.201706194 · Cited by 339
Shape-controlled bismuth nanoflakes as highly selective catalysts for electrochemical carbon dioxide reduction to formate
Kim, S., Dong, W. J., Gim, S., Sohn, W., Park, J. Y., Yoo, C. J., Jang, H. W., & Lee, J.-L. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.05.065 · Cited by 338
Facile CO2 Electro-Reduction to Formate via Oxygen Bidentate Intermediate Stabilized by High-Index Planes of Bi Dendrite Catalyst
Koh, J. H., Won, D. H., Eom, T., Kim, N.-K., Jung, K. D., Kim, H., Hwang, Y. J., & Min, B. K. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00707 · Cited by 325
Tunable Cu Enrichment Enables Designer Syngas Electrosynthesis from CO2
Ross, M. B., Dinh, C. T., Li, Y., Kim, D., De Luna, P., Sargent, E. H., & Yang, P. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b04892 · Cited by 300
Tunable and Efficient Tin Modified Nitrogen‐Doped Carbon Nanofibers for Electrochemical Reduction of Aqueous Carbon Dioxide
Zhao, Y., Liang, J., Wang, C., Ma, J., & Wallace, G. G. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702524 · Cited by 283
Nanostructured Metallic Electrocatalysts for Carbon Dioxide Reduction
Lu, Q., Rosen, J., & Jiao, F. (2015) · ChemCatChem · doi:10.1002/cctc.201402669 · Cited by 271
Rational Design of a Hierarchical Tin Dendrite Electrode for Efficient Electrochemical Reduction of CO2
Won, D. H., Choi, C. H., Chung, J., Chung, M. W., Kim, E., & Woo, S. I. (2015) · ChemSusChem · doi:10.1002/cssc.201500694 · Cited by 267
Electronegativities of elements in valence states and their applications. 1. Electronegativities of elements in valence states
Zhang, Y. (1982) · Inorganic Chemistry · doi:10.1021/ic00141a005 · Cited by 252
Probing the Mechanism of Aqueous CO2 Reduction on Post-Transition-Metal Electrodes using ATR-IR Spectroelectrochemistry
Pander, J. E., Baruch, M. F., & Bocarsly, A. B. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b01879 · Cited by 218
Carbon nanotube containing Ag catalyst layers for efficient and selective reduction of carbon dioxide
Ma, S., Luo, R., Gold, J. I., Yu, A. Z., Kim, B., & Kenis, P. J. A. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta00427j · Cited by 212
Evidence of covalent synergy in silicon–sulfur–graphene yielding highly efficient and long-life lithium-ion batteries
Hassan, F. M., Batmaz, R., Li, J., Wang, X., Xiao, X., Yu, A., & Chen, Z. (2015) · Nature Communications · doi:10.1038/ncomms9597 · Cited by 205
Self-citation
Anchoring and Upgrading Ultrafine NiPd on Room‐Temperature‐Synthesized Bifunctional NH2‐N‐rGO toward Low‐Cost and Highly Efficient Catalysts for Selective Formic Acid Dehydrogenation
Yan, J., Li, S., Yi, S., Wulan, B., Zheng, W., & Jiang, Q. (2018) · Advanced Materials · doi:10.1002/adma.201703038 · Cited by 200
Electrochemical reduction of CO2on defect-rich Bi derived from Bi2S3with enhanced formate selectivity
Zhang, Y., Li, F., Zhang, X., Williams, T., Easton, C. D., Bond, A. M., & Zhang, J. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta00023a · Cited by 199
High-Density Nanosharp Microstructures Enable Efficient CO2 Electroreduction
Saberi Safaei, T., Mepham, A., Zheng, X., Pang, Y., Dinh, C.-T., Liu, M., Sinton, D., Kelley, S. O., & Sargent, E. H. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b03615 · Cited by 196
Electrochemical Reduction of Carbon Dioxide to Syngas and Formate at Dendritic Copper–Indium Electrocatalysts
Hoffman, Z. B., Gray, T. S., Moraveck, K. B., Gunnoe, T. B., & Zangari, G. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01161 · Cited by 187
Recent advances in the nanoengineering of electrocatalysts for CO2reduction
Li, F., MacFarlane, D. R., & Zhang, J. (2018) · Nanoscale · doi:10.1039/c7nr09620h · Cited by 176
Hierarchical Mesoporous SnO2 Nanosheets on Carbon Cloth: A Robust and Flexible Electrocatalyst for CO2 Reduction with High Efficiency and Selectivity
Li, F., Chen, L., Knowles, G. P., MacFarlane, D. R., & Zhang, J. (2016) · Angewandte Chemie · doi:10.1002/ange.201608279 · Cited by 153
Atomic scale enhancement of metal–support interactions between Pt and ZrC for highly stable electrocatalysts
Cheng, N., Banis, M. N., Liu, J., Riese, A., Mu, S. C., Li, R., Sham, T., & Sun, X. A. (2015) · Energy & Environmental Science · doi:10.1039/c4ee04086d · Cited by 140
Dehydrogenation of Formic Acid Catalyzed by a Ruthenium Complex with an N,N′-Diimine Ligand
Guan, C., Zhang, D., Pan, Y., Iguchi, M., Ajitha, M. J., Hu, H., Li, H., Yao, C., Huang, M., Min, S., et al. (2016) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.6b02334 · Cited by 140
Ultrathin Bismuth Nanosheets as a Highly Efficient CO2 Reduction Electrocatalyst
Su, P., Xu, W., Qiu, Y., Zhang, T., Li, X., & Zhang, H. (2018) · ChemSusChem · doi:10.1002/cssc.201702229 · Cited by 140
Hierarchical Tubular Structures Composed of Mn‐Based Mixed Metal Oxide Nanoflakes with Enhanced Electrochemical Properties
Guo, Y. H., Yu, L., Wang, C., Lin, Z., & Lou, X. W. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201501974 · Cited by 137
Bifunctional Interface of Au and Cu for Improved CO2 Electroreduction
Back, S., Kim, J., Kim, Y., & Jung, Y. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b05903 · Cited by 118
Low-energy formate production from CO 2 electroreduction using electrodeposited tin on GDE
Irtem, E., Andreu, T., Parra-Puerto, A., Hernández-Alonso, M. D., García-Rodriguez, S., Riesco-García, J. M., Penelas-Pérez, G., & Morante, J. R. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta04432h · Cited by 111
Exclusive Formation of Formic Acid from CO 2 Electroreduction by a Tunable Pd‐Sn Alloy
Bai, X., Chen, W., Zhao, C., Li, S., Song, Y., Ge, R., Wei, W., & Sun, Y. (2017) · Angewandte Chemie · doi:10.1002/ange.201707098 · Cited by 109
Electrochemical Reduction of Carbon Dioxide
Wu, J., Risalvato, F. G., Sharma, P. P., Pellechia, P. J., Ke, F., & Zhou, X. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.030309jes · Cited by 108
Novel hierarchical SnO2 microsphere catalyst coated on gas diffusion electrode for enhancing energy efficiency of CO2 reduction to formate fuel
Fu, Y., Li, Y., Zhang, X., Liu, Y., Qiao, J., Zhang, J., & Wilkinson, D. P. (2016) · Applied Energy · doi:10.1016/j.apenergy.2016.03.115 · Cited by 98
Stannate derived bimetallic nanoparticles for electrocatalytic CO 2 reduction
Zhang, X., Li, F., Zhang, Y., Bond, A. M., & Zhang, J. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta02429d · Cited by 83
Direct Detection of Electron Transfer Reactions Underpinning the Tin-Catalyzed Electrochemical Reduction of CO2 using Fourier-Transformed ac Voltammetry
Zhang, Y., Chen, L., Li, F., Easton, C. D., Li, J., Bond, A. M., & Zhang, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01305 · Cited by 79
The Oxidation of H2 and CH4 on an Oxygen-Enriched Yttria-Stabilized Zirconia Surface: A Theoretical Study Based on Density Functional Theory
Shishkin, M., & Ziegler, T. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp808049p · Cited by 70
A density functional theory study on the carbon chain growth of ethanol formation on Cu-Co (111) and (211) surfaces
Ren, B., Dong, X., Yu, Y., Wen, G., & Zhang, M. (2017) · Applied Surface Science · doi:10.1016/j.apsusc.2017.03.106 · Cited by 37
Self-citation
Design of ultralong single-crystal nanowire-based bifunctional electrodes for efficient oxygen and hydrogen evolution in a mild alkaline electrolyte
Li, G., Wang, X., Seo, M. H., Hemmati, S., Yu, A., & Chen, Z. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta02745a · Cited by 28
Self-citation
Electrocatalytic Performance of Palladium Dendrites Deposited on Titania Nanotubes for Formic Acid Oxidation
Abraham, B. G., Maniam, K. K., Kuniyil, A., & Chetty, R. (2016) · Fuel Cells · doi:10.1002/fuce.201600023 · Cited by 27
Carbon Dioxide Utilization Coming of Age
Kenis, P. J. A., Dibenedetto, A., & Zhang, T. (2017) · ChemPhysChem · doi:10.1002/cphc.201701204 · Cited by 26
Biomimetic design of monolithic fuel cell electrodes with hierarchical structures
Wang, R., Higgins, D. C., Lee, D. U., Prabhudev, S., Hassan, F. M. B., Chabot, V., Lui, G., Jiang, G., Choi, J., Rasenthiram, L., et al. (2015) · Nano Energy · doi:10.1016/j.nanoen.2015.11.033 · Cited by 20
Self-citation

Single-Atom Fe Catalyst Outperforms Its Homogeneous Counterpart for Activating Peroxymonosulfate to Achieve Effective Degradation of Organic Contaminants
Qian, K., Chen, H., Li, W., Ao, Z., Wu, Y.-N., & Guan, X. (2021) · Environmental Science & Technology · doi:10.1021/acs.est.0c08805 · Cited by 517
Heterostructured Catalysts for Electrocatalytic and Photocatalytic Carbon Dioxide Reduction
Prabhu, P., Jose, V., & Lee, J. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201910768 · Cited by 432
Engineering Bismuth–Tin Interface in Bimetallic Aerogel with a 3D Porous Structure for Highly Selective Electrocatalytic CO2 Reduction to HCOOH
Wu, Z., Wu, H., Cai, W., Wen, Z., Jia, B., Wang, L., Jin, W., & Ma, T. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202102832 · Cited by 354
Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites
Li, L., Ozden, A., Guo, S., Garcı́a de Arquer, F. P., Wang, C., Zhang, M., Zhang, J., Jiang, H., Wang, W., Dong, H., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-25573-9 · Cited by 348
Formation of lattice-dislocated bismuth nanowires on copper foam for enhanced electrocatalytic CO2 reduction at low overpotential
Zhang, X., Sun, X., Guo, S.-X., Bond, A. M., & Zhang, J. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00018f · Cited by 323

See all 361

Authors: Wen, G., Lee, D. U., Ren, B., Hassan, F. M., Jiang, G., Cano, Z. P., Gostick, J., Croiset, E., Bai, Z., Yang, L., & Chen, Z.
Venue: Advanced Energy Materials
Publisher: Wiley
Published: 2018-09-21
Volume: 8
Issue: 31
ISSN: 1614-6832 (ISSN-L)
1614-6840
DOI: 10.1002/aenm.201802427
OpenAlex: W2892092208
Cited by: 361
References: 80
FWCI: 9.50
Type: journal article
Language: en
Open access: closed

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.

Orbital Interactions in Bi‐Sn Bimetallic Electrocatalysts for Highly Selective Electrochemical CO2 Reduction toward Formate Production

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Self-check

Citations

Cites

Cited by

Metadata

Record

About these checks

Data sources