Suboxic deep seawater in the late Paleoproterozoic: evidence from hematitic chert and iron formation related to seafloor-hydrothermal sulfide deposits, central Arizona, USA
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Redox heterogeneities in the oceans indicate that coeval regions of more and less oxygenated waters may have been a common feature during the boring billion.
“Finally, the likelihood of redox heterogeneities in the oceans (Slack et al., 2007; Sperling et al., 2014; Reinhard et al., 2016) tells us that coeval regions of more and less oxygenated waters may also have been a common feature during the boring billion.”
From Oxygenation, Life, and the Planetary System during Earth's Middle History: An Overview (2021) · cites this paper as Slack et al., 2007
Trace and rare-earth element systematics of similar volcanogenic massive sulfide deposits formed at approximately 1.8, 1.7, 1.4, and 1.2 Gya reflect weakly oxygenated (suboxic) conditions in the deep ocean for at least some periods of the mid-Proterozoic.
“The trace and rare-earth element systematics of similar volcanogenic massive sulfide deposits formed at approximately 1.8 Gya, 1.7 Gya, 1.4 Gya, and 1.2 Gya have been interpreted to reflect weakly oxygenated (suboxic) conditions in the deep ocean for at least some periods of the mid-Proterozoic (Little et al. 2021;Slack et al. 2007Slack et al. , 2009)).”
From The History of Ocean Oxygenation (2022) · cites this paper as Slack et al. 2007
The copper-rich composition of volcanogenic massive sulfide deposits requires hydrostatic pressure equivalent to a depth of at least ∼1 km to prevent loss of copper prior to mineralization at the seafloor.
“Importantly, the copper-rich composition of these deposits requires hydrostatic pressure equivalent to a depth of at least ∼1 km to prevent loss of copper prior to mineralization at the seafloor (Slack et al. 2007(Slack et al. , 2009)).”
From The History of Ocean Oxygenation (2022) · cites this paper as Slack et al. 2007
Volcanogenic massive sulfide deposits provide one of the few windows into true deep-ocean chemistry during mid-Proterozoic time.
“Volcanogenic massive sulfide deposits, often containing iron-rich chemical sediments and associated sulfide ores rich in copper, provide one of the few windows into true deep-ocean chemistry during mid-Proterozoic time (Slack et al. 2007).”
From The History of Ocean Oxygenation (2022) · cites this paper as Slack et al. 2007
A weakly oxygenated state is fully consistent with constraints based on stable uranium isotope systematics and the geochemistry of deep-sea volcanogenic massive sulfide deposits.
“and is fully consistent with constraints based on stable uranium isotope systematics (Yang et al. 2017) and the geochemistry of deep-sea volcanogenic massive sulfide deposits (Slack et al. 2007(Slack et al. , 2009)).”
From The History of Ocean Oxygenation (2022) · cites this paper as Slack et al. 2007
The absence of iron-oxide exhalites is unlikely to reflect preservational bias because slightly younger Cu-rich VMS deposits in arc settings contain abundant hematite and magnetite exhalites, jasper, and IF.
“This observation is unlikely to reflect preservational bias because slightly younger 1.84, 1.79, and 1.78 Ga Cu-rich VMS deposits that similarly formed in arc settings contain abundant hematite and magnetite exhalites, jasper, and IF”
From Iron formations: A global record of Neoarchaean to Palaeoproterozoic environmental history (2017) · cites this paper as Slack et al., 2007
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“Finally, the likelihood of redox heterogeneities in the oceans (Slack et al., 2007; Sperling et al., 2014; Reinhard et al., 2016) tells us that coeval regions of more and less oxygenated waters may also have been a common feature during the boring billion.”
BackgroundVolcanogenic Massive Sulfide Deposits
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- Authors
- Slack, J. F., Grenne, T., Bekker, A., Rouxel, O. J., & Lindberg, P. A.
- Affiliations
- United States Geological Survey (US)
- Geological Survey of Norway (NO)
- Carnegie Institution for Science (US)
- Woods Hole Oceanographic Institution (US)
- Laboratoire Interdisciplinaire des Énergies de Demain (FR)
- Corresponding author
- Slack, J.F.
- Venue
- Earth and Planetary Science Letters
- Publisher
- Elsevier BV
- Published
- 2007-03
- Volume
- 255
- Issue
- 1-2
- Pages
- 243-256
- ISSN
- 0012-821X (ISSN-L)
- OpenAlex
- W2166950793
- Cited by
- 277
- References
- 75
- Citations by year
- 2026: 9 · 2025: 13 · 2024: 20 · 2023: 20 · 2022: 17 · 2021: 14 · 2020: 19 · 2019: 7 · 2018: 24 · 2017: 8 · 2016: 21 · 2015: 18 · 2014: 13 · 2013: 18 · 2012: 13
- FWCI
- 5.33
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Earth and Planetary Science Letters (publishedVersion)
- Funders
- Carnegie Institution of Washington
- U.S. Geological Survey
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Keywords
- Late Paleoproterozoic, banded iron formations, jasper, volcanogenic massive sulfide deposits, seafloor hydrothermal deposits, rare earth elements, cerium anomaly, central Arizona
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