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Metal–Organic Framework Based Catalysts for Hydrogen Evolution

Zhu, Bingjun, Zou, Ruqiang, Xu, Qiang·2018·Advanced Energy Materials
DOI 10.1002/aenm.201801193
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Abstract

Highly efficient hydrogen evolution reactions (HERs) will determine the mass distributions of hydrogen‐powered clean technologies in the future. Metal–organic frameworks (MOFs) are emerging as a class of crystalline porous materials. Along with their derivatives, MOFs have recently been under intense study for their applications in various hydrogen production techniques. MOF‐based materials possess unique advantages, such as high specific surface area, crystalline porous structure, diverse and tunable chemical components, which offer attractive functionalities in catalyzing hydrogen evolution processes, by lowering reaction potentials, and speeding up reaction rates. Considering the rapid increase in research interest in hydrogen evolution in the last several years, this review aims to summarize recent advances in MOF‐associated hydrogen evolution research, including electrocatalytic, photocatalytic, and chemocatalytic HER. Particular attention is paid to the design and utilization of postsynthetic modification of MOFs, MOF‐supported catalysts, and MOF derivatives for highly efficient HER. The opportunities and challenges for MOF‐based materials in a hydrogen‐powered clean future are also discussed.

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Metadata

Authors
Zhu, B., Zou, R., & Xu, Q.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2018-06-28
Volume
8
Issue
24
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
DOI
10.1002/aenm.201801193
OpenAlex
W2811287235
Cited by
484
References
14
FWCI
12.39
Type
journal article
Language
en
Open access
closed
Licence
onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Funders
  • National Natural Science Foundation of China (51772008)
  • Changjiang Scholar Program of Chinese Ministry of Education

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Zhu, B., Zou, R., & Xu, Q. (2018). Metal–Organic Framework Based Catalysts for Hydrogen Evolution. Advanced Energy Materials. https://doi.org/10.1002/aenm.201801193

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