Molecular catalysis of CO2 reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes

Semiconductor-based Photocatalytic Hydrogen Generation

Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876

Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels

Benson, E. E., Kubiak, C. P., Sathrum, A. J., & Smieja, J. M. (2009) · Chem. Soc. Rev. · doi:10.1039/b804323j · Cited by 2,059

An Amine‐Functionalized Titanium Metal–Organic Framework Photocatalyst with Visible‐Light‐Induced Activity for CO2 Reduction

Fu, Y., Sun, D., Chen, Y., Huang, R., Ding, Z., Fu, X., & Li, Z. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201108357 · Cited by 1,741

Catalysis of the electrochemical reduction of carbon dioxide

Costentin, C., Robert, M., & Savéant, J.-M. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35360a · Cited by 1,658

Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis

Wang, C., Xie, Z., deKrafft, K. E., & Lin, W. (2011) · Journal of the American Chemical Society · doi:10.1021/ja203564w · Cited by 1,547

A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst

Costentin, C., Drouet, S., Robert, M., & Savéant, J.-M. (2012) · Science · doi:10.1126/science.1224581 · Cited by 1,315

Domino electroreduction of CO2 to methanol on a molecular catalyst

Wu, Y., Jiang, Z., Lu, X., Liang, Y., & Wang, H. (2019) · Nature · doi:10.1038/s41586-019-1760-8 · Cited by 1,194

Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts

Francke, R., Schille, B., & Roemelt, M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00459 · Cited by 1,165

Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide

Kornienko, N., Zhao, Y., Kley, C. S., Zhu, C., Kim, D., Lin, S., Chang, C. J., Yaghi, O. M., & Yang, P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08212 · Cited by 1,158

CO 2 reduction on gas-diffusion electrodes and why catalytic performance must be assessed at commercially-relevant conditions

Burdyny, T., & Smith, W. A. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03134g · Cited by 1,133

Photochemical and Photoelectrochemical Reduction of CO2

Kumar, B., Llorente, M., Froehlich, J., Dang, T., Sathrum, A., & Kubiak, C. P. (2012) · Annual Review of Physical Chemistry · doi:10.1146/annurev-physchem-032511-143759 · Cited by 1,089

Visible-light-driven methane formation from CO2 with a molecular iron catalyst

Rao, H., Schmidt, L. C., Bonin, J., & Robert, M. (2017) · Nature · doi:10.1038/nature23016 · Cited by 1,041

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

Savéant, J.-M. (2008) · Chemical Reviews · doi:10.1021/cr068079z · Cited by 978

A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes

Schouten, K. J. P., Kwon, Y., van der Ham, C. J. M., Qin, Z., & Koper, M. T. M. (2011) · Chemical Science · doi:10.1039/c1sc00277e · Cited by 959

Artificial photosynthesis: opportunities and challenges of molecular catalysts

Zhang, B., & Sun, L. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00897c · Cited by 954

Molecular electrocatalysts can mediate fast, selective CO 2 reduction in a flow cell

Ren, S., Joulié, D., Salvatore, D., Torbensen, K., Wang, M., Robert, M., & Berlinguette, C. P. (2019) · Science · doi:10.1126/science.aax4608 · Cited by 941

Exclusive Ni–N4 Sites Realize Near-Unity CO Selectivity for Electrochemical CO2 Reduction

Li, X., Bi, W., Chen, M., Sun, Y., Ju, H., Yan, W., Zhu, J., Wu, X., Chu, W., Wu, C., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b09074 · Cited by 932

Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes

Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912

Highly selective and active CO2 reduction electrocatalysts based on cobalt phthalocyanine/carbon nanotube hybrid structures

Zhang, X., Wu, Z., Zhang, X., Li, L., Li, Y., Xu, H., Li, X., Yu, X., Zhang, Z., Liang, Y., et al. (2017) · Nature Communications · doi:10.1038/ncomms14675 · Cited by 898

Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways

Wang, D., Huang, R., Liu, W., Sun, D., & Li, Z. (2014) · ACS Catalysis · doi:10.1021/cs501169t · Cited by 869

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

Costentin, C., Drouet, S., Robert, M., & Savéant, J.-M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303560c · Cited by 849

Understanding cation effects in electrochemical CO2 reduction

Ringe, S., Clark, E. L., Resasco, J., Walton, A., Seger, B., Bell, A. T., & Chan, K. (2019) · Energy & Environmental Science · doi:10.1039/c9ee01341e · Cited by 848

Elements of Molecular and Biomolecular Electrochemistry: An Electrochemical Approach to Electron Transfer Chemistry

Savéant, J. (2006) · Wiley eBooks · doi:10.1002/0471758078 · Cited by 743

Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction

Weng, Z., Wu, Y., Wang, M., Jiang, J., Yang, K., Huo, S., Wang, X.-F., Ma, Q., Brudvig, G. W., Batista, V. S., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-02819-7 · Cited by 735

Structure and Valency of a Cobalt−Phosphate Water Oxidation Catalyst Determined by in Situ X-ray Spectroscopy

Kanan, M. W., Yano, J., Surendranath, Y., Dincă, M., Yachandra, V. K., & Nocera, D. G. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1023767 · Cited by 711

Studies on Photocatalytic CO2 Reduction over NH2‐Uio‐66(Zr) and Its Derivatives: Towards a Better Understanding of Photocatalysis on Metal–Organic Frameworks

Sun, D., Fu, Y., Liu, W., Ye, L., Wang, D., Yang, L., Fu, X., & Li, Z. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201301728 · Cited by 667

Cobalt Imidazolate Metal–Organic Frameworks Photosplit CO2 under Mild Reaction Conditions

Wang, S., Yao, W., Lin, J., Ding, Z., & Wang, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201309426 · Cited by 599

Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin

Shen, J., Kortlever, R., Kas, R., Birdja, Y. Y., Diaz-Morales, O., Kwon, Y., Ledezma-Yanez, I., Schouten, K. J. P., Mul, G., & Koper, M. T. M. (2015) · Nature Communications · doi:10.1038/ncomms9177 · Cited by 598

Electrocatalytic CO 2 Conversion to Oxalate by a Copper Complex

Angamuthu, R., Byers, P., Lutz, M., Spek, A. L., & Bouwman, E. (2010) · Science · doi:10.1126/science.1177981 · Cited by 592

Crystal Structure of a Carbon Monoxide Dehydrogenase Reveals a [Ni-4Fe-5S] Cluster

Dobbek, H., Svetlitchnyi, V., Gremer, L., Huber, R., & Meyer, O. (2001) · Science · doi:10.1126/science.1061500 · Cited by 570

Electrochemical CO2 Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution

Weng, Z., Jiang, J., Wu, Y., Wu, Z., Guo, X., Materna, K. L., Liu, W., Batista, V. S., Brudvig, G. W., & Wang, H. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b04746 · Cited by 567

Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt

Fisher, B. J., & Eisenberg, R. (1980) · Journal of the American Chemical Society · doi:10.1021/ja00544a035 · Cited by 559

Supported Cobalt Polyphthalocyanine for High-Performance Electrocatalytic CO2 Reduction

Han, N., Wang, Y., Ma, L., Wen, J., Li, J., Zheng, H., Nie, K., Wang, X., Zhao, F., Li, Y., et al. (2017) · Chem · doi:10.1016/j.chempr.2017.08.002 · Cited by 559

Electrochemical CO2 reduction on Cu2O-derived copper nanoparticles: controlling the catalytic selectivity of hydrocarbons

Kas, R., Kortlever, R., Milbrat, A., Koper, M. T. M., Mul, G., & Baltrusaitis, J. (2014) · Phys. Chem. Chem. Phys. · doi:10.1039/c4cp01520g · Cited by 551

In Situ X-ray Absorption Spectroscopy Investigation of a Bifunctional Manganese Oxide Catalyst with High Activity for Electrochemical Water Oxidation and Oxygen Reduction

Gorlin, Y., Lassalle-Kaiser, B., Benck, J. D., Gul, S., Webb, S. M., Yachandra, V. K., Yano, J., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja3104632 · Cited by 550

Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process

Beley, M., Collin, J. P., Ruppert, R., & Sauvage, J. P. (1986) · Journal of the American Chemical Society · doi:10.1021/ja00284a003 · Cited by 539

Selective Photocatalytic CO2 Reduction in Water through Anchoring of a Molecular Ni Catalyst on CdS Nanocrystals

Kuehnel, M. F., Orchard, K. L., Dalle, K. E., & Reisner, E. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00369 · Cited by 535

Insights into the Low Overpotential Electroreduction of CO2 to CO on a Supported Gold Catalyst in an Alkaline Flow Electrolyzer

Verma, S., Hamasaki, Y., Kim, C., Huang, W., Lu, S., Jhong, H.-R. M., Gewirth, A. A., Fujigaya, T., Nakashima, N., & Kenis, P. J. A. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.7b01096 · Cited by 521

CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine

Wang, M., Torbensen, K., Salvatore, D., Ren, S., Joulié, D., Dumoulin, F., Mendoza, D., Lassalle-Kaiser, B., Işci, U., Berlinguette, C. P., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-11542-w · Cited by 505

Selective CO2 Conversion to Formate Conjugated with H2O Oxidation Utilizing Semiconductor/Complex Hybrid Photocatalysts

Sato, S., Arai, T., Morikawa, T., Uemura, K., Suzuki, T. M., Tanaka, H., & Kajino, T. (2011) · Journal of the American Chemical Society · doi:10.1021/ja204881d · Cited by 500

The concept of Fermi level pinning at semiconductor/liquid junctions. Consequences for energy conversion efficiency and selection of useful solution redox couples in solar devices

Bard, A. J., Bocarsly, A. B., Fan, F. R. F., Walton, E. G., & Wrighton, M. S. (1980) · Journal of the American Chemical Society · doi:10.1021/ja00531a001 · Cited by 498

On the stability of semiconductor electrodes against photodecomposition

Gerischer, H. (1977) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(77)80253-2 · Cited by 491

Carbon dioxide electroreduction on single-atom nickel decorated carbon membranes with industry compatible current densities

Yang, H., Lin, Q., Zhang, C., Yu, X., Cheng, Z., Li, G., Hu, Q., Ren, X., Zhang, Q., Liu, J., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-14402-0 · Cited by 483

Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts

Sun, L., Reddu, V., Fisher, A. C., & Wang, X. (2020) · Energy & Environmental Science · doi:10.1039/c9ee03660a · Cited by 452

Sustainion Imidazolium‐Functionalized Polymers for Carbon Dioxide Electrolysis

Kutz, R. B., Chen, Q., Yang, H., Sajjad, S. D., Liu, Z., & Masel, I. R. (2017) · Energy Technology · doi:10.1002/ente.201600636 · Cited by 427

Electrochemical CO2 Reduction: Recent Advances and Current Trends

Jones, J., Prakash, G. K. S., & Olah, G. A. (2014) · Israel Journal of Chemistry · doi:10.1002/ijch.201400081 · Cited by 425

Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex

Thoi, V. S., Kornienko, N., Margarit, C. G., Yang, P., & Chang, C. J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4074003 · Cited by 376

Differential electrochemical mass spectrometry

Baltruschat, H. (2004) · Journal of the American Society for Mass Spectrometry · doi:10.1016/j.jasms.2004.09.011 · Cited by 368

Nickel(II)-cyclam: an extremely selective electrocatalyst for reduction of CO2 in water

Beley, M., Collin, J.-P., Ruppert, R., & Sauvage, J.-P. (1984) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39840001315 · Cited by 365

Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes

Guo, Z., Cheng, S., Cometto, C., Anxolabéhère-Mallart, E., Ng, S.-M., Ko, C.-C., Liu, G., Chen, L., Robert, M., & Lau, T.-C. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06002 · Cited by 364

Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center

Chen, L., Guo, Z., Wei, X.-G., Gallenkamp, C., Bonin, J., Anxolabéhère-Mallart, E., Lau, K.-C., Lau, T.-C., & Robert, M. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06535 · Cited by 359

Efficient and selective molecular catalyst for the CO 2 -to-CO electrochemical conversion in water

Costentin, C., Robert, M., Savéant, J.-M., & Tatin, A. (2015) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1507063112 · Cited by 355

Electrolysis of Gaseous CO2 to CO in a Flow Cell with a Bipolar Membrane

Salvatore, D. A., Weekes, D. M., He, J., Dettelbach, K. E., Li, Y. C., Mallouk, T. E., & Berlinguette, C. P. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.7b01017 · Cited by 349

High Rate, Selective, and Stable Electroreduction of CO2 to CO in Basic and Neutral Media

Dinh, C.-T., García de Arquer, F. P., Sinton, D., & Sargent, E. H. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01734 · Cited by 348

A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible‐Light Driven CO2 Reduction to CO in CH3CN/H2O Solution

Ouyang, T., Huang, H., Wang, J., Zhong, D., & Lu, T. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201610607 · Cited by 337

Selective and Efficient Photocatalytic CO2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst

Bonin, J., Robert, M., & Routier, M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja510290t · Cited by 328

Photocatalytic CO2 Reduction Using Cu(I) Photosensitizers with a Fe(II) Catalyst

Takeda, H., Ohashi, K., Sekine, A., & Ishitani, O. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01970 · Cited by 321

Covalent Immobilization of a Molecular Catalyst on Cu2O Photocathodes for CO2 Reduction

Schreier, M., Luo, J., Gao, P., Moehl, T., Mayer, M. T., & Grätzel, M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12157 · Cited by 318

Electrocatalytic properties of (tetraazacyclotetradecane)nickel(2+) and Ni2(biscyclam)4+ with respect to carbon dioxide and water reduction

Collin, J. P., Jouaiti, A., & Sauvage, J. P. (1988) · Inorganic Chemistry · doi:10.1021/ic00284a030 · Cited by 316

Homogeneous CO2 Reduction by Ni(cyclam) at a Glassy Carbon Electrode

Froehlich, J. D., & Kubiak, C. P. (2012) · Inorganic Chemistry · doi:10.1021/ic3001619 · Cited by 310

Noncovalent Immobilization of a Molecular Iron-Based Electrocatalyst on Carbon Electrodes for Selective, Efficient CO2-to-CO Conversion in Water

Maurin, A., & Robert, M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12652 · Cited by 307

Electrocatalysis by metal phthalocyanines in the reduction of carbon dioxide

Meshitsuka, S., Ichikawa, M., & Tamaru, K. (1974) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39740000158 · Cited by 306

Photoelectrochemical Reduction of CO2 Coupled to Water Oxidation Using a Photocathode with a Ru(II)–Re(I) Complex Photocatalyst and a CoOx/TaON Photoanode

Sahara, G., Kumagai, H., Maeda, K., Kaeffer, N., Artero, V., Higashi, M., Abe, R., & Ishitani, O. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b09212 · Cited by 303

Nature of the Intermediate Formed in the Reduction of O2 to H2O at the Trinuclear Copper Cluster Active Site in Native Laccase

Lee, S.-K., George, S. D., Antholine, W. E., Hedman, B., Hodgson, K. O., & Solomon, E. I. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0114052 · Cited by 292

Boosting Photocatalytic CO2 Reduction on CsPbBr3 Perovskite Nanocrystals by Immobilizing Metal Complexes

Chen, Z., Hu, Y., Wang, J., Shen, Q., Zhang, Y., Ding, C., Bai, Y., Jiang, G., Li, Z., & Gaponik, N. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.9b04582 · Cited by 289

Electrochemical reduction of carbon dioxide mediated by molecular catalysts

Collin, J. (1989) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(89)80018-9 · Cited by 280

Proton-Coupled Electron Transfer Cleavage of Heavy-Atom Bonds in Electrocatalytic Processes. Cleavage of a C–O Bond in the Catalyzed Electrochemical Reduction of CO2

Costentin, C., Drouet, S., Passard, G., Robert, M., & Savéant, J.-M. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4030148 · Cited by 279

Solar CO2 reduction using H2O by a semiconductor/metal-complex hybrid photocatalyst: enhanced efficiency and demonstration of a wireless system using SrTiO3 photoanodes

Arai, T., Sato, S., Kajino, T., & Morikawa, T. (2013) · Energy & Environmental Science · doi:10.1039/c3ee24317f · Cited by 278

Simultaneous Reduction of CO2 and Splitting of H2O by a Single Immobilized Cobalt Phthalocyanine Electrocatalyst

Morlanés, N., Takanabe, K., & Rodionov, V. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00543 · Cited by 278

Aqueous Electrochemical Reduction of Carbon Dioxide and Carbon Monoxide into Methanol with Cobalt Phthalocyanine

Boutin, E., Wang, M., Lin, J. C., Mesnage, M., Mendoza, D., Lassalle‐Kaiser, B., Hahn, C., Jaramillo, T. F., & Robert, M. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201909257 · Cited by 275

Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO2 to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities

Costentin, C., Passard, G., Robert, M., & Savéant, J.-M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja506193v · Cited by 271

Selectivity control of CO versus HCOO− production in the visible-light-driven catalytic reduction of CO2 with two cooperative metal sites

Guo, Z., Chen, G., Cometto, C., Ma, B., Zhao, H., Groizard, T., Chen, L., Fan, H., Man, W.-L., Yiu, S.-M., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0331-6 · Cited by 269

Covalently Grafting Cobalt Porphyrin onto Carbon Nanotubes for Efficient CO2 Electroreduction

Zhu, M., Chen, J., Huang, L., Ye, R., Xu, J., & Han, Y. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201900499 · Cited by 267

Cobalt Porphyrin Catalyzed Reduction of CO2. Radiation Chemical, Photochemical, and Electrochemical Studies

Behar, D., Dhanasekaran, T., Neta, P., Hosten, C. M., Ejeh, D., Hambright, P., & Fujita, E. (1998) · The Journal of Physical Chemistry A · doi:10.1021/jp9807017 · Cited by 264

Polymer coordination promotes selective CO2reduction by cobalt phthalocyanine

Kramer, W. W., & McCrory, C. C. L. (2016) · Chemical Science · doi:10.1039/c5sc04015a · Cited by 263

Dinuclear Metal Synergistic Catalysis Boosts Photochemical CO2‐to‐CO Conversion

Ouyang, T., Wang, H., Huang, H., Wang, J., Guo, S., Liu, W., Zhong, D., & Lu, T. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201811010 · Cited by 258

Direct Observation of the Local Reaction Environment during the Electrochemical Reduction of CO2

Clark, E. L., & Bell, A. T. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b04058 · Cited by 254

The Homogeneous Reduction of CO2 by [Ni(cyclam)]+: Increased Catalytic Rates with the Addition of a CO Scavenger

Froehlich, J. D., & Kubiak, C. P. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512575v · Cited by 253

Efficient and selective electron mediation of cobalt complexes with cyclam and related macrocycles in the p-terphenyl-catalyzed photoreduction of carbon dioxide

Matsuoka, S., Yamamoto, K., Ogata, T., Kusaba, M., Nakashima, N., Fujita, E., & Yanagida, S. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00055a032 · Cited by 233

Reduction of Cobalt and Iron Corroles and Catalyzed Reduction of CO2

Grodkowski, J., Neta, P., Fujita, E., Mahammed, A., Simkhovich, L., & Gross, Z. (2002) · The Journal of Physical Chemistry A · doi:10.1021/jp013668o · Cited by 230

Highly efficient visible-light driven photocatalytic reduction of CO2 over g-C3N4 nanosheets/tetra(4-carboxyphenyl)porphyrin iron(III) chloride heterogeneous catalysts

Lin, L., Hou, C., Zhang, X., Wang, Y., Chen, Y., & He, T. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.09.033 · Cited by 230

Proton-Assisted Reduction of CO2 by Cobalt Aminopyridine Macrocycles

Chapovetsky, A., Do, T. H., Haiges, R., Takase, M. K., & Marinescu, S. C. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01980 · Cited by 226

Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst

Rao, H., Lim, C.-H., Bonin, J., Miyake, G. M., & Robert, M. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b09740 · Cited by 225

Binary molecular-semiconductor p–n junctions for photoelectrocatalytic CO2 reduction

Shan, B., Vanka, S., Li, T.-T., Troian-Gautier, L., Brennaman, M. K., Mi, Z., & Meyer, T. J. (2019) · Nature Energy · doi:10.1038/s41560-019-0345-y · Cited by 216

Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins. Synergistic Effect of Lewis Acid Cations

Bhugun, I., Lexa, D., & Savéant, J.-M. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9618486 · Cited by 215

A Carbon Nitride/Fe Quaterpyridine Catalytic System for Photostimulated CO2-to-CO Conversion with Visible Light

Cometto, C., Kuriki, R., Chen, L., Maeda, K., Lau, T.-C., Ishitani, O., & Robert, M. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b04007 · Cited by 214

Solar-driven reduction of aqueous CO2 with a cobalt bis(terpyridine)-based photocathode

Leung, J. J., Warnan, J., Ly, K. H., Heidary, N., Nam, D. H., Kuehnel, M. F., & Reisner, E. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0254-2 · Cited by 214

Pendant Hydrogen-Bond Donors in Cobalt Catalysts Independently Enhance CO2 Reduction

Chapovetsky, A., Welborn, M., Luna, J. M., Haiges, R., Miller, T. F., & Marinescu, S. C. (2018) · ACS Central Science · doi:10.1021/acscentsci.7b00607 · Cited by 211

An Iron Electrocatalyst for Selective Reduction of CO2 to Formate in Water: Including Thermochemical Insights

Taheri, A., Thompson, E. J., Fettinger, J. C., & Berben, L. A. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01708 · Cited by 208

Terpyridine complexes of first row transition metals and electrochemical reduction of CO2 to CO

Elgrishi, N., Chambers, M. B., Artero, V., & Fontecave, M. (2014) · Phys. Chem. Chem. Phys. · doi:10.1039/c4cp00451e · Cited by 204

Developing a Mechanistic Understanding of Molecular Electrocatalysts for CO2 Reduction using Infrared Spectroelectrochemistry

Machan, C. W., Sampson, M. D., Chabolla, S. A., Dang, T., & Kubiak, C. P. (2014) · Organometallics · doi:10.1021/om500044a · Cited by 204

Light-induced water oxidation at silicon electrodes functionalized with a cobalt oxygen-evolving catalyst

Pijpers, J. J. H., Winkler, M. T., Surendranath, Y., Buonassisi, T., & Nocera, D. G. (2011) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1106545108 · Cited by 204

Visible‐Light‐Driven CO2 Reduction by Mesoporous Carbon Nitride Modified with Polymeric Cobalt Phthalocyanine

Roy, S., & Reisner, E. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201907082 · Cited by 203

Ultraefficient selective homogeneous catalysis of the electrochemical reduction of carbon dioxide by an iron(0) porphyrin associated with a weak Broensted acid cocatalyst

Bhugun, I., Lexa, D., & Saveant, J.-M. (1994) · Journal of the American Chemical Society · doi:10.1021/ja00090a068 · Cited by 200

Cobalt phthalocyanine coordinated to pyridine-functionalized carbon nanotubes with enhanced CO2 electroreduction

Zhu, M., Chen, J., Guo, R., Xu, J., Fang, X., & Han, Y.-F. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.03.047 · Cited by 198

Molecular cobalt corrole complex for the heterogeneous electrocatalytic reduction of carbon dioxide

Gonglach, S., Paul, S., Haas, M., Pillwein, F., Sreejith, S. S., Barman, S., De, R., Müllegger, S., Gerschel, P., Apfel, U.-P., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-11868-5 · Cited by 198

Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO

Schneider, J., Jia, H., Kobiro, K., Cabelli, D. E., Muckerman, J. T., & Fujita, E. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22528j · Cited by 195

Photoelectrochemical reduction of CO2 in water under visible-light irradiation by a p-type InP photocathode modified with an electropolymerized ruthenium complex

Arai, T., Sato, S., Uemura, K., Morikawa, T., Kajino, T., & Motohiro, T. (2010) · Chemical Communications · doi:10.1039/c0cc02061c · Cited by 193

Turning it off! Disfavouring hydrogen evolution to enhance selectivity for CO production during homogeneous CO2 reduction by cobalt–terpyridine complexes

Elgrishi, N., Chambers, M. B., & Fontecave, M. (2015) · Chemical Science · doi:10.1039/c4sc03766a · Cited by 193

Highly Selective Molecular Catalysts for the CO2-to-CO Electrochemical Conversion at Very Low Overpotential. Contrasting Fe vs Co Quaterpyridine Complexes upon Mechanistic Studies

Cometto, C., Chen, L., Lo, P.-K., Guo, Z., Lau, K.-C., Anxolabéhère-Mallart, E., Fave, C., Lau, T.-C., & Robert, M. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b04412 · Cited by 191

Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO2-to-CO Conversion Catalyzed by Iron Porphyrins

Azcarate, I., Costentin, C., Robert, M., & Savéant, J.-M. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b09947 · Cited by 189

Photoreduction of CO2 on p-type Silicon Using Re(bipy-But)(CO)3Cl: Photovoltages Exceeding 600 mV for the Selective Reduction of CO2 to CO

Kumar, B., Smieja, J. M., & Kubiak, C. P. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp105171b · Cited by 181

Powering a CO2 Reduction Catalyst with Visible Light through Multiple Sub-picosecond Electron Transfers from a Quantum Dot

Lian, S., Kodaimati, M. S., Dolzhnikov, D. S., Calzada, R., & Weiss, E. A. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03134 · Cited by 180

Mechanistic and Kinetic Studies of Cobalt Macrocycles in a Photochemical CO2 Reduction System: Evidence of Co-CO2 Adducts as Intermediates

Ogata, T., Yanagida, S., Brunschwig, B. S., & Fujita, E. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00130a009 · Cited by 173

A monolithic device for CO2 photoreduction to generate liquid organic substances in a single-compartment reactor

Arai, T., Sato, S., & Morikawa, T. (2015) · Energy & Environmental Science · doi:10.1039/c5ee01314c · Cited by 170

Carbon Dioxide Reduction at a Metal Phthalocyanine Catalyzed Carbon Electrode

Kapusta, S., & Hackerman, N. (1984) · Journal of The Electrochemical Society · doi:10.1149/1.2115882 · Cited by 168

Photocatalytically Active Superstructures of Quantum Dots and Iron Porphyrins for Reduction of CO2 to CO in Water

Lian, S., Kodaimati, M. S., & Weiss, E. A. (2018) · ACS Nano · doi:10.1021/acsnano.7b07377 · Cited by 168

Improving the Photocatalytic Reduction of CO2 to CO through Immobilisation of a Molecular Re Catalyst on TiO2

Windle, C. D., Pastor, E., Reynal, A., Whitwood, A. C., Vaynzof, Y., Durrant, J. R., Perutz, R. N., & Reisner, E. (2015) · Chemistry - A European Journal · doi:10.1002/chem.201405041 · Cited by 165

Efficient and selective carbon dioxide reduction on low cost protected Cu2O photocathodes using a molecular catalyst

Schreier, M., Gao, P., Mayer, M. T., Luo, J., Moehl, T., Nazeeruddin, M. K., Tilley, S. D., & Grätzel, M. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03454f · Cited by 163

Electroreduction of carbon dioxide on gas-diffusion electrodes modified by metal phthalocyanines

Furuya, N., & Matsui, K. (1989) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(89)80074-9 · Cited by 162

Electrochemical CO2 reduction to formic acid on a Pd-based formic acid oxidation catalyst

Kortlever, R., Balemans, C., Kwon, Y., & Koper, M. T. M. (2015) · Catalysis Today · doi:10.1016/j.cattod.2014.08.001 · Cited by 160

Homogeneous Photocatalytic Reduction of CO2 to CO Using Iron(0) Porphyrin Catalysts: Mechanism and Intrinsic Limitations

Bonin, J., Chaussemier, M., Robert, M., & Routier, M. (2014) · ChemCatChem · doi:10.1002/cctc.201402515 · Cited by 159

ZnSe quantum dots modified with a Ni(cyclam) catalyst for efficient visible-light driven CO2 reduction in water

Kuehnel, M. F., Sahm, C. D., Neri, G., Lee, J. R., Orchard, K. L., Cowan, A. J., & Reisner, E. (2018) · Chemical Science · doi:10.1039/c7sc04429a · Cited by 158

Reduction of Cobalt and Iron Phthalocyanines and the Role of the Reduced Species in Catalyzed Photoreduction of CO 2

Grodkowski, J., Dhanasekaran, T., Neta, P., Hambright, P., Brunschwig, B. S., Shinozaki, K., & Fujita, E. (2000) · The Journal of Physical Chemistry A · doi:10.1021/jp002709y · Cited by 157

p -Terphenyl-Sensitized Photoreduction of CO 2 with Cobalt and Iron Porphyrins. Interaction between CO and Reduced Metalloporphyrins

Dhanasekaran, T., Grodkowski, J., Neta, P., Hambright, P., & Fujita, E. (1999) · The Journal of Physical Chemistry A · doi:10.1021/jp991423u · Cited by 154

Iron Porphyrin-Catalyzed Reduction of CO 2 . Photochemical and Radiation Chemical Studies

Grodkowski, J., Behar, D., Neta, P., & Hambright, P. (1997) · The Journal of Physical Chemistry A · doi:10.1021/jp9628139 · Cited by 153

Efficient electrocatalytic CO 2 reduction with a molecular cofacial iron porphyrin dimer

Mohamed, E. A., Zahran, Z. N., & Naruta, Y. (2015) · Chemical Communications · doi:10.1039/c5cc04273a · Cited by 149

Intermediates Involved in the 2e – /2H + Reduction of CO 2 to CO by Iron(0) Porphyrin

Mondal, B., Rana, A., Sen, P., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b05992 · Cited by 147

Electrochemical carbon dioxide and bicarbonate reduction on copper in weakly alkaline media

Kortlever, R., Tan, K., Kwon, Y., & Koper, M. T. M. (2013) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-013-2100-9 · Cited by 145

Selective CO2 conversion to formate in water using a CZTS photocathode modified with a ruthenium complex polymer

Arai, T., Tajima, S., Sato, S., Uemura, K., Morikawa, T., & Kajino, T. (2011) · Chemical Communications · doi:10.1039/c1cc16160a · Cited by 144

The Electronic States of Rhenium Bipyridyl Electrocatalysts for CO2 Reduction as Revealed by X‐ray Absorption Spectroscopy and Computational Quantum Chemistry

Benson, E. E., Sampson, M. D., Grice, K. A., Smieja, J. M., Froehlich, J. D., Friebel, D., Keith, J. A., Carter, E. A., Nilsson, A., & Kubiak, C. P. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209911 · Cited by 142

Solar-Driven Photocatalytic CO2 Reduction in Water Utilizing a Ruthenium Complex Catalyst on p-Type Fe2O3 with a Multiheterojunction

Sekizawa, K., Sato, S., Arai, T., & Morikawa, T. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03244 · Cited by 142

Electrocatalysis of CO2 reduction at surface modified metallic and semiconducting electrodes

Cabrera, C. R., & Abruña, H. D. (1986) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(86)80189-9 · Cited by 139

Electronic Structure of a Formal Iron(0) Porphyrin Complex Relevant to CO2 Reduction

Römelt, C., Song, J., Tarrago, M., Rees, J. A., van Gastel, M., Weyhermüller, T., DeBeer, S., Bill, E., Neese, F., & Ye, S. (2017) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b00401 · Cited by 139

Differential Electrochemical Mass Spectrometer Cell Design for Online Quantification of Products Produced during Electrochemical Reduction of CO2

Clark, E. L., Singh, M. R., Kwon, Y., & Bell, A. T. (2015) · Analytical Chemistry · doi:10.1021/acs.analchem.5b02080 · Cited by 136

A Hybrid Co Quaterpyridine Complex/Carbon Nanotube Catalytic Material for CO 2 Reduction in Water

Wang, M., Chen, L., Lau, T., & Robert, M. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201802792 · Cited by 133

Electrochemical membrane reactors for the utilisation of carbon dioxide

Merino‐Garcia, I., Alvarez‐Guerra, E., Albo, J., & Irabien, Á. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.05.032 · Cited by 132

High-Performance Electrochemical CO 2 Reduction Cells Based on Non-noble Metal Catalysts

Xu, L. X., Wu, Y., Yuan, X., Huang, L., Wu, Z., Xuan, J., Wang, Y., & Wang, H. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01681 · Cited by 130

A Unified Electro- and Photocatalytic CO 2 to CO Reduction Mechanism with Aminopyridine Cobalt Complexes

Fernández, S., Franco, F., Casadevall, C., Martin‐Diaconescu, V., Luis, J. M., & Lloret‐Fillol, J. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b06633 · Cited by 130

Electrochemical reduction of CO2 at metal-porphyrin supported gas diffusion electrodes under high pressure CO2

Sonoyama, N., Kirii, M., & Sakata, T. (1999) · Electrochemistry Communications · doi:10.1016/s1388-2481(99)00041-7 · Cited by 127

Studies of electrochemically generated reaction intermediates using modulated specular reflectance spectroscopy

Aylmer-Kelly, A. W. B., Bewick, A., Cantrill, P. R., & Tuxford, A. M. (1973) · Faraday Discussions of the Chemical Society · doi:10.1039/dc9735600096 · Cited by 122

Carbon dioxide activation: thermodynamics of carbon dioxide binding and the involvement of two cobalt centers in the reduction of carbon dioxide by a cobalt(I) macrocycle

Fujita, E., Szalda, D. J., Creutz, C., et al. (1988) · Journal of the American Chemical Society · doi:10.1021/ja00222a079 · Cited by 121

Directing the Reactivity of [HFe 4 N(CO) 12 ] − toward H + or CO 2 Reduction by Understanding the Electrocatalytic Mechanism

Rail, M. D., & Berben, L. A. (2011) · Journal of the American Chemical Society · doi:10.1021/ja208312t · Cited by 121

Electrocatalytic Reduction of CO2 to Formate by an Iron Schiff Base Complex

Nichols, A. W., Chatterjee, S., Sabat, M., & Machan, C. W. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b02955 · Cited by 121

Recent progress in artificial photosynthesis: CO2 photoreduction to valuable chemicals in a heterogeneous system

Handoko, A. D., Li, K., & Tang, J. (2013) · Current Opinion in Chemical Engineering · doi:10.1016/j.coche.2012.12.003 · Cited by 120

In-situ spectroscopic investigation of adsorbed intermediate radicals in electrochemical reactions: CO2− on platinum

Chandrasekaran, K., & Bockris, L. O. (1987) · Surface Science · doi:10.1016/s0039-6028(87)80173-5 · Cited by 116

Efficient electrolyzer for CO 2 splitting in neutral water using earth-abundant materials

Tatin, A., Comminges, C., Kokoh, K. B., Costentin, C., Robert, M., & Savéant, J. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1604628113 · Cited by 116

A copper nickel mixed oxide hole selective layer for Au-free transparent cuprous oxide photocathodes

Son, M., Steier, L., Schreier, M., Mayer, M. T., Luo, J., & Grätzel, M. (2017) · Energy & Environmental Science · doi:10.1039/c6ee03613a · Cited by 115

Tunable, light-assisted co-generation of CO and H 2 from CO 2 and H2O by Re(bipy-tbu)(CO) 3 Cl and p-Si in non-aqueous medium

Kumar, B., Smieja, J. M., Sasayama, A. F., & Kubiak, C. P. (2011) · Chemical Communications · doi:10.1039/c1cc16024a · Cited by 108

Direct XANES Evidence for Charge Transfer in Co−CO2 Complexes

Fujita, E., Furenlid, L. R., & Renner, M. W. (1997) · Journal of the American Chemical Society · doi:10.1021/ja970151a · Cited by 106

Charged ligands for catalyst immobilisation and analysis

Chisholm, D. M., & McIndoe, J. S. (2008) · Dalton Transactions · doi:10.1039/b800371h · Cited by 103

Back-illuminated Si photocathode: a combined experimental and theoretical study for photocatalytic hydrogen evolution

Bae, D., Pedersen, T., Seger, B. J., Malizia, M., Kuznetsov, A. Y., Hansen, O., Chorkendorff, I., & Vesborg, P. C. K. (2014) · Energy & Environmental Science · doi:10.1039/c4ee03723e · Cited by 99

Enhanced Electrochemical Reduction of CO2 Catalyzed by Cobalt and Iron Amino Porphyrin Complexes

Abdinejad, M., Seifitokaldani, A., Dao, C., Sargent, E. H., Zhang, X., & Kraatz, H. (2019) · ACS Applied Energy Materials · doi:10.1021/acsaem.8b01900 · Cited by 99

Carbon dioxide activation by cobalt macrocycles: evidence of hydrogen bonding between bound CO2 and the macrocycle in solution

Fujita, E., Creutz, C., Sutin, N., & Brunschwig, B. S. (1993) · Inorganic Chemistry · doi:10.1021/ic00064a015 · Cited by 98

Electroreduction of carbon dioxide by metal phthalocyanines

Furuya, N., & Koide, S. (1991) · Electrochimica Acta · doi:10.1016/0013-4686(91)80010-6 · Cited by 94

In Situ Electrochemical X-ray Absorption Spectroscopy of Oxygen Reduction Electrocatalysis with High Oxygen Flux

Erickson, E. M., Thorum, M. S., Vasić, R., Marinković, N., Frenkel, A. I., Gewirth, A. A., & Nuzzo, R. G. (2011) · Journal of the American Chemical Society · doi:10.1021/ja210465x · Cited by 89

Electrochemical Reduction of CO[sub 2] with Transition Metal Phthalocyanine and Porphyrin Complexes Supported on Activated Carbon Fibers

Magdesieva, T. V., Yamamoto, T., Tryk, D. A., & Fujishima, A. (2002) · Journal of The Electrochemical Society · doi:10.1149/1.1475690 · Cited by 86

The adsorption of Ni(cyclam)+ at mercury electrodes and its relation to the electrocatalytic reduction of CO2

Balazs, G. B., & Anson, F. C. (1992) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(92)80086-j · Cited by 86

Tertiary Amine-Assisted Electroreduction of Carbon Dioxide to Formate Catalyzed by Iron Tetraphenylporphyrin

Margarit, C. G., Asimow, N. G., Costentin, C., & Nocera, D. G. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b02093 · Cited by 86

Carbon‐Nanotube‐Supported Copper Polyphthalocyanine for Efficient and Selective Electrocatalytic CO2 Reduction to CO

Karapinar, D., Zitolo, A., Huan, T. N., Zanna, S., Taverna, D., Tizei, L. H. G., Giaume, D., Marcus, P., Mougel, V., & Fontecave, M. (2019) · ChemSusChem · doi:10.1002/cssc.201902859 · Cited by 84

Selective Catalytic Electroreduction of CO2 at Silicon Nanowires (SiNWs) Photocathodes Using Non-Noble Metal-Based Manganese Carbonyl Bipyridyl Molecular Catalysts in Solution and Grafted onto SiNWs

Torralba, E., Luo, Y., Compain, J., Chardon‐Noblat, S., & Fabre, B. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01546 · Cited by 83

Visible‐Light‐Driven CO2 Reduction by Mesoporous Carbon Nitride Modified with Polymeric Cobalt Phthalocyanine

Roy, S., & Reisner, E. (2019) · Angewandte Chemie · doi:10.1002/ange.201907082 · Cited by 81

Iron Porphyrin Allows Fast and Selective Electrocatalytic Conversion of CO2 to CO in a Flow Cell

Torbensen, K., Han, C. L., Boudy, B., von Wolff, N., Bertail, C., Braun, W., & Robert, M. (2020) · Chemistry - A European Journal · doi:10.1002/chem.202000160 · Cited by 81

A pendant proton shuttle on [Fe 4 N(CO) 12 ] − alters product selectivity in formate vs. H 2 production via the hydride [H–Fe 4 N(CO) 12 ] −

Loewen, N. D., Thompson, E. J., Kagan, M., Banales, C. L., Myers, T. W., Fettinger, J. C., & Berben, L. A. (2016) · Chemical Science · doi:10.1039/c5sc03169a · Cited by 78

In situ/Operando studies of electrocatalysts using hard X-ray spectroscopy

Lassalle‐Kaiser, B., Gul, S., Kern, J. F., Yachandra, V. K., & Yano, J. (2017) · Journal of Electron Spectroscopy and Related Phenomena · doi:10.1016/j.elspec.2017.05.001 · Cited by 77

A look at periodic trends in d-block molecular electrocatalysts for CO 2 reduction

Jiang, C., Nichols, A. W., & Machan, C. W. (2019) · Dalton Transactions · doi:10.1039/c9dt00491b · Cited by 77

Energy Savings in the Conversion of CO2 to Fuels using an Electrolytic Device

Bevilacqua, M., Filippi, J., Lavacchi, A., Marchionni, A., Miller, H. A., Oberhauser, W., Vesselli, E., & Vizza, F. (2014) · Energy Technology · doi:10.1002/ente.201402014 · Cited by 74

Standard Electrode Potentials for the Reduction of CO2 to CO in Acetonitrile–Water Mixtures Determined Using a Generalized Method for Proton-Coupled Electron-Transfer Reactions

Matsubara, Y. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00548 · Cited by 74

Use of gas-diffusion electrodes for high-rate electrochemical reduction of carbon dioxide. II. Reduction at metal phthalocyanine-impregnated electrodes

Mahmood, M. N., Masheder, D., & Harty, C. J. (1987) · Journal of Applied Electrochemistry · doi:10.1007/bf01023606 · Cited by 72

Molecular Catalysis of Electrochemical Reactions

Savéant, J. (2006) · doi:10.1002/0471758078.ch4 · Cited by 72

Modeling of a microfluidic electrochemical cell for CO2 utilization and fuel production

Wang, H., Leung, D. Y. C., & Xuan, J. (2012) · Applied Energy · doi:10.1016/j.apenergy.2012.06.020 · Cited by 70

Cyclic Voltammetry Analysis of Electrocatalytic Films

Costentin, C., & Savéant, J. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b02376 · Cited by 69

A Multielectrode Electrochemical and Scanning Differential Electrochemical Mass Spectrometry Study of Methanol Oxidation on Electrodeposited PtxRuy

Jambunathan, K., Jayaraman, S., & Hillier, A. C. (2004) · Langmuir · doi:10.1021/la035567i · Cited by 67

Electrocatalytic reduction of CO 2 with CCC-NHC pincer nickel complexes

Cope, J. D., Liyanage, N. P., Kelley, P., Denny, J. A., Valente, E. J., Webster, C. E., Delcamp, J. H., & Hollis, T. K. (2017) · Chemical Communications · doi:10.1039/c6cc06537f · Cited by 67

Stable Molecular Photocathode for Solar-Driven CO2 Reduction in Aqueous Solutions

Li, T., Shan, B., & Meyer, T. J. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.8b02512 · Cited by 66

Highly active and selective photochemical reduction of CO 2 to CO using molecular-defined cyclopentadienone iron complexes

Rosas‐Hernández, A., Alsabeh, P. G., Barsch, E., Junge, H., Ludwig, R., & Beller, M. (2016) · Chemical Communications · doi:10.1039/c6cc01671e · Cited by 62

Electrocatalytic reduction of carbon dioxide at illuminated p-type silicon semiconduccting electrodes

Bradley, M., Tysak, T., Graves, D. J., & Viachiopoulos, N. A. (1983) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39830000349 · Cited by 60

Photocatalytic CO 2 reduction using a molecular cobalt complex deposited on TiO 2 nanoparticles

Jin, T., Liu, C., & Li, G. (2014) · Chemical Communications · doi:10.1039/c4cc00503a · Cited by 59

An ab initio MO/SD-CI study of model complexes of intermediates in electrochemical reduction of carbon dioxide catalyzed by NiCl2(cyclam)

Sakaki, S. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00032a019 · Cited by 59

Oxygen Binding to Cobalt and Iron Phthalocyanines As Determined from in Situ X-ray Absorption Spectroscopy

Miedema, P. S., van Schooneveld, M. M., Bogerd, R., Rocha, T. C. R., Hävecker, M., Knop‐Gericke, A., & de Groot, F. M. F. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp209295f · Cited by 57

Carbon dioxide reduction via light activation of a ruthenium–Ni(cyclam) complex

Herrero, C., Quaranta, A., Ghachtouli, S. E., Vauzeilles, B., Leibl, W., & Aukauloo, A. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp54946a · Cited by 56

On the photoelectrocatalytic reduction of carbon dioxide

Bockris, J. O., & Wass, J. C. (1989) · Materials Chemistry and Physics · doi:10.1016/0254-0584(89)90001-1 · Cited by 55

Toward Visible-Light Photochemical CO2-to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis

Rao, H., Bonin, J., & Robert, M. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b00950 · Cited by 52

Supported molecular catalysts for the heterogeneous CO2 electroreduction

Hu, X., Pedersen, S. U., & Daasbjerg, K. (2019) · Current Opinion in Electrochemistry · doi:10.1016/j.coelec.2019.05.006 · Cited by 51

Influence of adsorption processes on the CO2 electroreduction: An electrochemical mass spectrometry study

Dubé, P., & Brisard, G. M. (2005) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2005.04.016 · Cited by 50

Electrode-Ligand Interactions Dramatically Enhance CO2 Conversion to CO by the [Ni(cyclam)](PF6)2 Catalyst

Wu, Y., Rudshteyn, B., Zhanaidarova, A., Froehlich, J. D., Ding, W., Kubiak, C. P., & Batista, V. S. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01109 · Cited by 49

Molecular catalysts in photoelectrochemical cells

Petit, J., Chartier, P., Beley, M., & Deville, J.-P. (1989) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(89)85137-x · Cited by 46

Solar Fuels: Photoelectrosynthesis of CO from CO2 at p‐Type Si using Fe Porphyrin Electrocatalysts

Alenezi, K. M., Ibrahim, S. K., Li, P., & Pickett, C. J. (2013) · Chemistry - A European Journal · doi:10.1002/chem.201300764 · Cited by 46

Spectroelectrochemical Study of CO 2 Reduction on TiO 2 Electrodes in Acetonitrile

Mendieta-Reyes, N. E., Cheuquepán, W., Rodes, A., & Gómez, R. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02932 · Cited by 45

Electrocatalytic reduction of CO2 to methanol

Ogura, K., & Yoshida, I. (1988) · Journal of Molecular Catalysis · doi:10.1016/0304-5102(88)85072-7 · Cited by 43

Ferrous Ions as Catalysts for Photochemical Reduction of CO2 in Homogeneous Solutions

Grodkowski, J., & Neta, P. (2000) · The Journal of Physical Chemistry A · doi:10.1021/jp993456f · Cited by 42

Electrochemical CO2 Reduction in a Continuous Non-Aqueous Flow Cell with [Ni(cyclam)]2+

Jiang, C., Nichols, A. W., Walzer, J. F., & Machan, C. W. (2020) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.9b03171 · Cited by 42

Photoassisted electro-reduction of CO2 on p-GaAs in the presence of Ni cyclam2+

Beley, M., Collin, J., Sauvage, J., Petit, J., & Chartier, P. (1986) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(86)90281-0 · Cited by 35

Molecular Electrochemistry: Recent Trends and Upcoming Challenges

Savéant, J. (2016) · ChemElectroChem · doi:10.1002/celc.201600430 · Cited by 35

A highly active and robust iron quinquepyridine complex for photocatalytic CO 2 reduction in aqueous acetonitrile solution

Qin, Y., Chen, L., Chen, G., Guo, Z., Wang, L., Fan, H., Robert, M., & Lau, T. (2020) · Chemical Communications · doi:10.1039/d0cc01930e · Cited by 33

Electrocatalytic reduction of carbon dioxide to methanol. Part 2. Effects of metal complex and primary alcohol

Ogura, K., & Takamagari, K. (1986) · Journal of the Chemical Society Dalton Transactions · doi:10.1039/dt9860001519 · Cited by 32

Conversion of carbon monoxide into methanol at room temperature and atmospheric pressure

Ogura, K., & Yamasaki, S. (1985) · Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · doi:10.1039/f19858100267 · Cited by 31

Photoelectrochemical CO2 Reduction by a Molecular Cobalt(II) Catalyst on Planar and Nanostructured Si Surfaces

He, D., Jin, T., Li, W., Pantovich, S. A., Wang, D., & Li, G. (2016) · Chemistry - A European Journal · doi:10.1002/chem.201603068 · Cited by 31

Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction

Behnke, S. L., Manesis, A. C., & Shafaat, H. S. (2018) · Dalton Transactions · doi:10.1039/c8dt02873g · Cited by 31

An Iron Quaterpyridine Complex as Precursor for the Electrocatalytic Reduction of CO2 to Methane

Cometto, C., Chen, L., Mendoza, D., Lassalle‐Kaiser, B., Lau, T., & Robert, M. (2019) · ChemSusChem · doi:10.1002/cssc.201902040 · Cited by 29

Scanning Electrochemical Flow Cell with Online Mass Spectroscopy for Accelerated Screening of Carbon Dioxide Reduction Electrocatalysts

Lai, Y., Jones, R. J. R., Wang, Y., Zhou, L., & Gregoire, J. M. (2019) · ACS Combinatorial Science · doi:10.1021/acscombsci.9b00130 · Cited by 28

Conductive Mesoporous Catalytic Films. Current Distortion and Performance Degradation by Dual-Phase Ohmic Drop Effects. Analysis and Remedies

Andrieux, C. P., Costentin, C., Giovanni, C. D., Savéant, J., & Tard, C. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b07013 · Cited by 22

In situ Analysis of Products in Electrocatalytic Reduction of CO2 with Ni-cyclam by Differential Electrochemical Mass Spectroscopy during Cyclic Voltammetry on an Amalgamated-Gold Mesh Electrode

Hirata, Y., Suga, K., & Fujihira, M. (1990) · Chemistry Letters · doi:10.1246/cl.1990.1155 · Cited by 20

Time-resolved X-ray absorption spectroelectrochemistry of redox active species in solution

Cheaib, K., Maurice, B., Mateo, T., Halime, Z., & Lassalle‐Kaiser, B. (2019) · Journal of Synchrotron Radiation · doi:10.1107/s1600577519013614 · Cited by 16

Electrocatalysis for CO 2 conversion: from fundamentals to value-added products

Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295

Catalytic Reduction of Carbon Monoxide to Liquid Fuels with Recyclable Hydride Donors

Concepcion, J. J., Sampaio, R. N., & Meyer, G. J. (2024) · ACS Catalysis · doi:10.1021/acscatal.4c05083 · Cited by 8