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Occurrence and persistence of perfluorooctanesulfonate and other perfluorinated surfactants in groundwater at a fire-training area at Wurtsmith Air Force Base, Michigan, USAElectronic supplementary information (ESI) available: Map of location of Wurtsmith Air Force Base, Oscoda, MI and surrounding states. See http://www.rsc.org/suppdata/em/b2/b212497a/
Abstract
Various formulations of fire-extinguishing materials, including aqueous film-forming foams (AFFFs), were used as part of fire-training exercises conducted at Wurtsmith Air Force Base (WAFB) in northeastern Michigan from the 1950s until the base was decommissioned in 1993. As a result of past fire-training exercises, AFFF-laden wastewater containing fuels, solvents, and other materials directly entered groundwater without prior treatment. Perfluorinated surfactants are key components in some AFFF formulations. In this study, groundwater was analyzed for perfluoroalkanesulfonates and perfluorocarboxylates. Perfluoroalkanesulfonates were directly detected using negative-ion electrospray ionization mass spectrometry. Derivatized perfluorocarboxylates were detected using electron impact gas chromatography-mass spectrometry. Groundwater from wells around fire-training area FTA-02 at WAFB contained four perfluorinated surfactants ranging in concentration from 3 to 120 microg L(-1): perfluorooctanesulfonate (PFOS); perfluorohexanesulfonate; perfluorooctanoate; and perfluorohexanoate. This is the first report demonstrating that PFOS, recently shown to be toxic to organisms ranging from zooplankton to primates, is still present in groundwater in measurable quantities five or more years after its last known use.
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PFAS likely co-occur with NAPLs at certain types of sites, as has been observed for fire training areas.
“In addition, it is likely that PFAS co-occur with NAPLs at certain types of sites, as has been observed for fire training areas (e.g., Moody et al., 2003, McGuire et al., 2014).”
From Assessing the potential contributions of additional retention processes to PFAS retardation in the subsurface (2018) · cites this paper as Moody et al., 2003
PFAS contamination of soil and groundwater exists at many Department of Defense fire-fighting training sites and other areas.
“For example, it has been demonstrated that PFAS contamination of soil and groundwater exists at many Department of Defense fire-fighting training sites and other areas (Moody and Field, 2000, Moody et al., 2003, Ahrens, 2011, Backe et al., 2013, Anderson et al., 2016).”
From Assessing the potential contributions of additional retention processes to PFAS retardation in the subsurface (2018) · cites this paper as Moody et al., 2003
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Metadata
- Authors
- Moody, C. A., Hebert, G. N., Strauss, S. H., & Field, J. A.
- Venue
- Journal of Environmental Monitoring
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2003-03-10
- Volume
- 5
- Issue
- 2
- Pages
- 341-345
- ISSN
- 1464-0325
- 1464-0333
- Cited by
- 358
- References
- 7
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